CA2445599A1 - Metal-supported solid electrolyte electrochemical cell and multi cell reactors incorporating same - Google Patents
Metal-supported solid electrolyte electrochemical cell and multi cell reactors incorporating same Download PDFInfo
- Publication number
- CA2445599A1 CA2445599A1 CA002445599A CA2445599A CA2445599A1 CA 2445599 A1 CA2445599 A1 CA 2445599A1 CA 002445599 A CA002445599 A CA 002445599A CA 2445599 A CA2445599 A CA 2445599A CA 2445599 A1 CA2445599 A1 CA 2445599A1
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- CA
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- Prior art keywords
- electrolyte
- metallic
- layer
- ionically
- conducting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000007784 solid electrolyte Substances 0.000 title claims abstract description 77
- 239000003792 electrolyte Substances 0.000 claims abstract description 403
- 239000012528 membrane Substances 0.000 claims abstract description 160
- 238000000034 method Methods 0.000 claims abstract description 80
- 230000008569 process Effects 0.000 claims abstract description 66
- 239000002184 metal Substances 0.000 claims abstract description 57
- 229910052751 metal Inorganic materials 0.000 claims abstract description 56
- 239000010410 layer Substances 0.000 claims description 508
- 239000007789 gas Substances 0.000 claims description 119
- 238000000576 coating method Methods 0.000 claims description 87
- 239000011248 coating agent Substances 0.000 claims description 67
- 239000000446 fuel Substances 0.000 claims description 58
- 239000007787 solid Substances 0.000 claims description 56
- 239000000463 material Substances 0.000 claims description 49
- 239000011888 foil Substances 0.000 claims description 44
- 229910001220 stainless steel Inorganic materials 0.000 claims description 33
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 32
- 239000000919 ceramic Substances 0.000 claims description 22
- 229910045601 alloy Inorganic materials 0.000 claims description 18
- 239000000956 alloy Substances 0.000 claims description 18
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 18
- 150000002739 metals Chemical class 0.000 claims description 17
- 238000005219 brazing Methods 0.000 claims description 16
- 229910052759 nickel Inorganic materials 0.000 claims description 16
- 239000004020 conductor Substances 0.000 claims description 15
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 13
- 229910052737 gold Inorganic materials 0.000 claims description 13
- 239000010931 gold Substances 0.000 claims description 13
- 238000007254 oxidation reaction Methods 0.000 claims description 13
- 230000003647 oxidation Effects 0.000 claims description 12
- 238000004544 sputter deposition Methods 0.000 claims description 12
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 11
- 239000003054 catalyst Substances 0.000 claims description 11
- 239000002131 composite material Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052709 silver Inorganic materials 0.000 claims description 11
- 239000004332 silver Substances 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 229910021525 ceramic electrolyte Inorganic materials 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 229910000601 superalloy Inorganic materials 0.000 claims description 9
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 8
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 claims description 8
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 claims description 8
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 claims description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 7
- 229910002076 stabilized zirconia Inorganic materials 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 239000000758 substrate Substances 0.000 claims description 6
- 230000000994 depressogenic effect Effects 0.000 claims description 5
- 229910002078 fully stabilized zirconia Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910002077 partially stabilized zirconia Inorganic materials 0.000 claims description 5
- 238000001259 photo etching Methods 0.000 claims description 5
- 238000004891 communication Methods 0.000 claims description 4
- 238000004070 electrodeposition Methods 0.000 claims description 4
- 229910052763 palladium Inorganic materials 0.000 claims description 4
- 229910000416 bismuth oxide Inorganic materials 0.000 claims description 3
- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 claims description 3
- 238000009713 electroplating Methods 0.000 claims description 3
- 238000002407 reforming Methods 0.000 claims description 3
- 239000002356 single layer Substances 0.000 claims description 3
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- 150000002602 lanthanoids Chemical class 0.000 claims description 2
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- 238000001704 evaporation Methods 0.000 claims 5
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- ZJIYREZBRPWMMC-UHFFFAOYSA-N [Sr+2].[La+3].[O-][Cr]([O-])=O Chemical compound [Sr+2].[La+3].[O-][Cr]([O-])=O ZJIYREZBRPWMMC-UHFFFAOYSA-N 0.000 claims 2
- 239000011224 oxide ceramic Substances 0.000 claims 2
- 229910001092 metal group alloy Inorganic materials 0.000 claims 1
- 229910010293 ceramic material Inorganic materials 0.000 abstract description 5
- 230000000712 assembly Effects 0.000 abstract description 3
- 238000000429 assembly Methods 0.000 abstract description 3
- 235000018734 Sambucus australis Nutrition 0.000 abstract 1
- 244000180577 Sambucus australis Species 0.000 abstract 1
- 210000004027 cell Anatomy 0.000 description 295
- 239000001301 oxygen Substances 0.000 description 40
- 229910052760 oxygen Inorganic materials 0.000 description 40
- 239000002001 electrolyte material Substances 0.000 description 24
- 238000004519 manufacturing process Methods 0.000 description 24
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 20
- 238000013461 design Methods 0.000 description 20
- -1 oxygen ions Chemical class 0.000 description 20
- 239000010416 ion conductor Substances 0.000 description 19
- 239000007769 metal material Substances 0.000 description 16
- 238000011112 process operation Methods 0.000 description 13
- 239000010935 stainless steel Substances 0.000 description 13
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 12
- 239000002737 fuel gas Substances 0.000 description 11
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- 239000001257 hydrogen Substances 0.000 description 9
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- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 8
- 239000007788 liquid Substances 0.000 description 8
- 239000011533 mixed conductor Substances 0.000 description 8
- 229910001233 yttria-stabilized zirconia Inorganic materials 0.000 description 8
- 239000013529 heat transfer fluid Substances 0.000 description 7
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 6
- 229910001882 dioxygen Inorganic materials 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000003487 electrochemical reaction Methods 0.000 description 6
- 238000002955 isolation Methods 0.000 description 6
- 238000001755 magnetron sputter deposition Methods 0.000 description 6
- 230000002093 peripheral effect Effects 0.000 description 6
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- 230000032798 delamination Effects 0.000 description 5
- 238000000151 deposition Methods 0.000 description 5
- 239000011532 electronic conductor Substances 0.000 description 5
- 238000005245 sintering Methods 0.000 description 5
- 239000010409 thin film Substances 0.000 description 5
- 238000003466 welding Methods 0.000 description 5
- 239000010965 430 stainless steel Substances 0.000 description 4
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 4
- 239000011195 cermet Substances 0.000 description 4
- 230000008021 deposition Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000010408 film Substances 0.000 description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 4
- 238000003475 lamination Methods 0.000 description 4
- 238000000206 photolithography Methods 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 238000005382 thermal cycling Methods 0.000 description 4
- 238000012546 transfer Methods 0.000 description 4
- RUDFQVOCFDJEEF-UHFFFAOYSA-N yttrium(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Y+3].[Y+3] RUDFQVOCFDJEEF-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 229910001069 Ti alloy Inorganic materials 0.000 description 3
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 238000005524 ceramic coating Methods 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
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- 238000005516 engineering process Methods 0.000 description 3
- 239000012530 fluid Substances 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 229910000423 chromium oxide Inorganic materials 0.000 description 2
- 230000001419 dependent effect Effects 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 238000005566 electron beam evaporation Methods 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 238000000059 patterning Methods 0.000 description 2
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- 238000007747 plating Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000006057 reforming reaction Methods 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 238000003980 solgel method Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- NEAPKZHDYMQZCB-UHFFFAOYSA-N N-[2-[4-[2-(2,3-dihydro-1H-inden-2-ylamino)pyrimidin-5-yl]piperazin-1-yl]ethyl]-2-oxo-3H-1,3-benzoxazole-6-carboxamide Chemical compound C1CN(CCN1CCNC(=O)C2=CC3=C(C=C2)NC(=O)O3)C4=CN=C(N=C4)NC5CC6=CC=CC=C6C5 NEAPKZHDYMQZCB-UHFFFAOYSA-N 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 238000003486 chemical etching Methods 0.000 description 1
- NFYLSJDPENHSBT-UHFFFAOYSA-N chromium(3+);lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+3].[La+3] NFYLSJDPENHSBT-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007907 direct compression Methods 0.000 description 1
- 229910000701 elgiloys (Co-Cr-Ni Alloy) Inorganic materials 0.000 description 1
- 229910021526 gadolinium-doped ceria Inorganic materials 0.000 description 1
- 239000003502 gasoline Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 239000000615 nonconductor Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000001552 radio frequency sputter deposition Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 229910052707 ruthenium Inorganic materials 0.000 description 1
- 238000013341 scale-up Methods 0.000 description 1
- 238000001878 scanning electron micrograph Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
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- 239000002002 slurry Substances 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
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- 239000007921 spray Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052712 strontium Inorganic materials 0.000 description 1
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
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- 238000010345 tape casting Methods 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0202—Collectors; Separators, e.g. bipolar separators; Interconnectors
- H01M8/0247—Collectors; Separators, e.g. bipolar separators; Interconnectors characterised by the form
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0271—Sealing or supporting means around electrodes, matrices or membranes
- H01M8/028—Sealing means characterised by their material
- H01M8/0282—Inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/02—Details
- H01M8/0297—Arrangements for joining electrodes, reservoir layers, heat exchange units or bipolar separators to each other
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/241—Grouping of fuel cells, e.g. stacking of fuel cells with solid or matrix-supported electrolytes
- H01M8/2425—High-temperature cells with solid electrolytes
- H01M8/2432—Grouping of unit cells of planar configuration
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2457—Grouping of fuel cells, e.g. stacking of fuel cells with both reactants being gaseous or vaporised
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/24—Grouping of fuel cells, e.g. stacking of fuel cells
- H01M8/2465—Details of groupings of fuel cells
- H01M8/2483—Details of groupings of fuel cells characterised by internal manifolds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Analytical Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Fuel Cell (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US28685301P | 2001-04-27 | 2001-04-27 | |
| US60/286,853 | 2001-04-27 | ||
| US30302601P | 2001-07-03 | 2001-07-03 | |
| US60/303,026 | 2001-07-03 | ||
| US32656101P | 2001-10-02 | 2001-10-02 | |
| US60/326,561 | 2001-10-02 | ||
| PCT/CA2002/000582 WO2002089243A2 (en) | 2001-04-27 | 2002-04-26 | Metal-supported solid electrolyte electrochemical cell and multi cell reactors incorporating same |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2445599A1 true CA2445599A1 (en) | 2002-11-07 |
Family
ID=27403658
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002445599A Abandoned CA2445599A1 (en) | 2001-04-27 | 2002-04-26 | Metal-supported solid electrolyte electrochemical cell and multi cell reactors incorporating same |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20040219423A1 (enExample) |
| EP (1) | EP1384280A2 (enExample) |
| JP (1) | JP2004522275A (enExample) |
| AU (1) | AU2002252897A1 (enExample) |
| CA (1) | CA2445599A1 (enExample) |
| WO (1) | WO2002089243A2 (enExample) |
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| US6605316B1 (en) | 1999-07-31 | 2003-08-12 | The Regents Of The University Of California | Structures and fabrication techniques for solid state electrochemical devices |
| CA2439586C (en) | 2001-03-02 | 2012-02-28 | Mesosystems Technology, Inc. | Ammonia-based hydrogen generation apparatus and method for using same |
| US7922781B2 (en) | 2001-03-02 | 2011-04-12 | Chellappa Anand S | Hydrogen generation apparatus and method for using same |
| US7867300B2 (en) | 2001-03-02 | 2011-01-11 | Intelligent Energy, Inc. | Ammonia-based hydrogen generation apparatus and method for using same |
| WO2002086987A2 (en) * | 2001-04-23 | 2002-10-31 | Mesosystems Technology, Inc. | Hydrogen generation apparatus and method for using same |
| US8172913B2 (en) | 2002-04-23 | 2012-05-08 | Vencill Thomas R | Array of planar membrane modules for producing hydrogen |
| US7527661B2 (en) * | 2005-04-18 | 2009-05-05 | Intelligent Energy, Inc. | Compact devices for generating pure hydrogen |
| JP4362359B2 (ja) | 2003-12-26 | 2009-11-11 | 本田技研工業株式会社 | 燃料電池及び燃料電池スタック |
| EP1766708B1 (en) * | 2004-07-02 | 2011-12-14 | Battelle Memorial Institute | Solid oxide fuel cell frames and method of manufacture |
| US7427339B2 (en) * | 2004-10-15 | 2008-09-23 | Air Products And Chemicals, Inc. | Heat conducting metal layer for ion conductor stack |
| EP1829112A4 (en) * | 2004-11-30 | 2009-11-18 | Univ California | CONNECTING DIFFERENT MATERIALS |
| KR20070083893A (ko) * | 2004-11-30 | 2007-08-24 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | 전기화학적 장치를 위한 밀봉 접합 구조물 |
| RU2403136C2 (ru) * | 2004-11-30 | 2010-11-10 | Члены Правления Университета Калифорнии | Паяная система с согласованными коэффициентами термического расширения |
| US7767358B2 (en) * | 2005-05-31 | 2010-08-03 | Nextech Materials, Ltd. | Supported ceramic membranes and electrochemical cells and cell stacks including the same |
| US8691467B2 (en) * | 2005-09-30 | 2014-04-08 | Corning Incorporated | Metallic structures for solid oxide fuel cells |
| JP5177474B2 (ja) | 2006-04-24 | 2013-04-03 | 日本碍子株式会社 | セラミックス薄板体 |
| US9243335B2 (en) | 2006-07-07 | 2016-01-26 | Ceres Intellectual Property Company Limited | Metal substrate for fuel cells |
| US8343686B2 (en) | 2006-07-28 | 2013-01-01 | The Regents Of The University Of California | Joined concentric tubes |
| US20080038621A1 (en) * | 2006-08-10 | 2008-02-14 | Ngk Insulators, Ltd. | Electrochemical devices |
| US20090029199A1 (en) * | 2007-05-02 | 2009-01-29 | Celltech Power Llc | Cathode Arrangements for Fuel Cells and Other Applications |
| US20080299436A1 (en) * | 2007-05-30 | 2008-12-04 | General Electric Company | Composite ceramic electrolyte structure and method of forming; and related articles |
| US20090050680A1 (en) * | 2007-08-24 | 2009-02-26 | Protonex Technology Corporation | Method for connecting tubular solid oxide fuel cells and interconnects for same |
| WO2009097110A1 (en) * | 2008-01-30 | 2009-08-06 | Corning Incorporated | Seal structures for solid oxide fuel cell devices |
| KR20110005818A (ko) | 2008-04-18 | 2011-01-19 | 더 리전트 오브 더 유니버시티 오브 캘리포니아 | 고온 전기화학적 장치를 위한 일체형 밀봉재 |
| US8574782B2 (en) * | 2008-10-22 | 2013-11-05 | Utc Power Corporation | Fuel cell repeater unit including frame and separator plate |
| US20110143265A1 (en) * | 2009-12-10 | 2011-06-16 | Jain Kailash C | Low-Resistance Ceramic Electrode for a Solid Oxide Fuel Cell |
| CN102754261B (zh) | 2009-12-22 | 2015-06-17 | 托普索燃料电池股份有限公司 | 用于燃料电池或燃料电池组的互连的制造和校准过程 |
| KR101958429B1 (ko) * | 2017-08-18 | 2019-03-15 | 한국과학기술연구원 | 바이오 가스 개질용 페로브스카이트 촉매 및 이의 제조 방법 |
| US20230021737A1 (en) * | 2017-12-22 | 2023-01-26 | Lyten, Inc. | Carbon-enhanced fuel cells |
| US11761100B2 (en) * | 2018-11-06 | 2023-09-19 | Utility Global, Inc. | Electrochemical device and method of making |
| TWI710161B (zh) * | 2019-02-14 | 2020-11-11 | 國立臺北科技大學 | 適於固態氧化物燃料電池的模組化平板型連接板的製法、包含其製得之連接板的組件及衝壓組件 |
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| US3464861A (en) * | 1964-08-20 | 1969-09-02 | Shell Oil Co | Fuel cells with solid state electrolytes |
| US3525646A (en) * | 1967-08-31 | 1970-08-25 | Raffinage Cie Franc De | Battery of fuel cells of solid electrolyte and the process of making these |
| US4490445A (en) * | 1982-05-24 | 1984-12-25 | Massachusetts Institute Of Technology | Solid oxide electrochemical energy converter |
| JPS6118857A (ja) * | 1984-07-06 | 1986-01-27 | Ngk Insulators Ltd | 電気化学的セルの製造方法 |
| US4877506A (en) * | 1987-04-08 | 1989-10-31 | Fee Darrell C | Monolithic solid electrolyte oxygen pump |
| KR900702589A (ko) * | 1988-05-20 | 1990-12-07 | 어반 하아트 파우비온 | 연료전지 전해질용 고체조성물 |
| DE4002951A1 (de) * | 1990-02-01 | 1991-08-08 | Medicoat Ag Niederrohrdorf | Festelektrolyt - brennstoffzelle und verfahren zu ihrer herstellung |
| US5332483A (en) * | 1990-07-06 | 1994-07-26 | Igr Enterprises, Inc. | Gas separation system |
| US5298342A (en) * | 1992-10-20 | 1994-03-29 | M-C Power Corporation | Fuel cell crossover arrestor and pressure seal |
| JPH07201347A (ja) * | 1993-12-28 | 1995-08-04 | Toshiba Corp | 溶融炭酸塩型燃料電池 |
| US5494700A (en) * | 1994-04-05 | 1996-02-27 | The Curators Of The University Of Missouri | Method of coating a substrate with a metal oxide film from an aqueous solution comprising a metal cation and a polymerizable organic solvent |
| US5681373A (en) * | 1995-03-13 | 1997-10-28 | Air Products And Chemicals, Inc. | Planar solid-state membrane module |
| US5585136A (en) * | 1995-03-22 | 1996-12-17 | Queen's University At Kingston | Method for producing thick ceramic films by a sol gel coating process |
| US5725965A (en) * | 1995-04-25 | 1998-03-10 | Gas Research Institute | Stable high conductivity functionally gradient compositionally layered solid state electrolytes and membranes |
| US5753385A (en) * | 1995-12-12 | 1998-05-19 | Regents Of The University Of California | Hybrid deposition of thin film solid oxide fuel cells and electrolyzers |
| US5741406A (en) * | 1996-04-02 | 1998-04-21 | Northerwestern University | Solid oxide fuel cells having dense yttria-stabilized zirconia electrolyte films and method of depositing electrolyte films |
| US5770326A (en) * | 1996-12-23 | 1998-06-23 | Limaye; Santosh Y. | Monolithic mass and energy transfer cell |
| US6054231A (en) * | 1998-07-24 | 2000-04-25 | Gas Research Institute | Solid oxide fuel cell interconnector |
| US6106967A (en) * | 1999-06-14 | 2000-08-22 | Gas Research Institute | Planar solid oxide fuel cell stack with metallic foil interconnect |
-
2002
- 2002-04-26 JP JP2002586432A patent/JP2004522275A/ja not_active Withdrawn
- 2002-04-26 AU AU2002252897A patent/AU2002252897A1/en not_active Abandoned
- 2002-04-26 US US10/475,938 patent/US20040219423A1/en not_active Abandoned
- 2002-04-26 EP EP02721921A patent/EP1384280A2/en not_active Withdrawn
- 2002-04-26 CA CA002445599A patent/CA2445599A1/en not_active Abandoned
- 2002-04-26 WO PCT/CA2002/000582 patent/WO2002089243A2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| US20040219423A1 (en) | 2004-11-04 |
| EP1384280A2 (en) | 2004-01-28 |
| WO2002089243A2 (en) | 2002-11-07 |
| AU2002252897A1 (en) | 2002-11-11 |
| WO2002089243A3 (en) | 2003-11-20 |
| JP2004522275A (ja) | 2004-07-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |