CA2433663C - Acidic hard-surface antimicrobial cleaner - Google Patents
Acidic hard-surface antimicrobial cleaner Download PDFInfo
- Publication number
- CA2433663C CA2433663C CA002433663A CA2433663A CA2433663C CA 2433663 C CA2433663 C CA 2433663C CA 002433663 A CA002433663 A CA 002433663A CA 2433663 A CA2433663 A CA 2433663A CA 2433663 C CA2433663 C CA 2433663C
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- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 30
- 230000002378 acidificating effect Effects 0.000 title description 6
- 239000000203 mixture Substances 0.000 claims abstract description 101
- 239000002253 acid Substances 0.000 claims abstract description 49
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000002904 solvent Substances 0.000 claims abstract description 28
- -1 aliphatic alcohols Chemical class 0.000 claims abstract description 27
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 17
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000004094 surface-active agent Substances 0.000 claims abstract description 14
- 239000006184 cosolvent Substances 0.000 claims abstract description 13
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 11
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 claims abstract description 8
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims abstract description 7
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 claims abstract description 4
- 238000004140 cleaning Methods 0.000 claims description 43
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 22
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 22
- 235000019441 ethanol Nutrition 0.000 claims description 20
- 239000003945 anionic surfactant Substances 0.000 claims description 17
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 15
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 15
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 15
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 14
- 239000004310 lactic acid Substances 0.000 claims description 11
- 235000014655 lactic acid Nutrition 0.000 claims description 11
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 11
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 claims description 10
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 10
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 9
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 8
- 238000011012 sanitization Methods 0.000 claims description 8
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 8
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 claims description 7
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 7
- WBIQQQGBSDOWNP-UHFFFAOYSA-N 2-dodecylbenzenesulfonic acid Chemical compound CCCCCCCCCCCCC1=CC=CC=C1S(O)(=O)=O WBIQQQGBSDOWNP-UHFFFAOYSA-N 0.000 claims description 6
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- 229940060296 dodecylbenzenesulfonic acid Drugs 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 6
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 claims description 5
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- 150000008051 alkyl sulfates Chemical class 0.000 claims description 5
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- 150000004996 alkyl benzenes Chemical class 0.000 claims description 3
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 claims description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 claims description 3
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- 238000001035 drying Methods 0.000 claims description 2
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- QCAHUFWKIQLBNB-UHFFFAOYSA-N 3-(3-methoxypropoxy)propan-1-ol Chemical compound COCCCOCCCO QCAHUFWKIQLBNB-UHFFFAOYSA-N 0.000 claims 2
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- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims 2
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- 239000004210 ether based solvent Substances 0.000 abstract description 4
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- 238000012360 testing method Methods 0.000 description 16
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- 239000000645 desinfectant Substances 0.000 description 11
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- 235000015165 citric acid Nutrition 0.000 description 7
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- 230000000249 desinfective effect Effects 0.000 description 4
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- AEIJTFQOBWATKX-UHFFFAOYSA-N octane-1,2-diol Chemical compound CCCCCCC(O)CO AEIJTFQOBWATKX-UHFFFAOYSA-N 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
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- 229920000728 polyester Polymers 0.000 description 1
- WSHYKIAQCMIPTB-UHFFFAOYSA-M potassium;2-oxo-3-(3-oxo-1-phenylbutyl)chromen-4-olate Chemical compound [K+].[O-]C=1C2=CC=CC=C2OC(=O)C=1C(CC(=O)C)C1=CC=CC=C1 WSHYKIAQCMIPTB-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
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- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
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- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/049—Cleaning or scouring pads; Wipes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/43—Solvents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2034—Monohydric alcohols aromatic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Detergent Compositions (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/760,035 | 2001-01-12 | ||
| US09/760,035 US6699825B2 (en) | 2001-01-12 | 2001-01-12 | Acidic hard-surface antimicrobial cleaner |
| PCT/US2002/000928 WO2002059244A2 (en) | 2001-01-12 | 2002-01-11 | Acidic hard-surface antimicrobial cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2433663A1 CA2433663A1 (en) | 2002-08-01 |
| CA2433663C true CA2433663C (en) | 2007-12-11 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002433663A Expired - Lifetime CA2433663C (en) | 2001-01-12 | 2002-01-11 | Acidic hard-surface antimicrobial cleaner |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6699825B2 (enExample) |
| JP (1) | JP4180376B2 (enExample) |
| AR (1) | AR032497A1 (enExample) |
| AU (1) | AU2002246993B2 (enExample) |
| CA (1) | CA2433663C (enExample) |
| GB (1) | GB2385859B (enExample) |
| MX (1) | MXPA03006234A (enExample) |
| TW (1) | TWI246533B (enExample) |
| WO (1) | WO2002059244A2 (enExample) |
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| JP4375991B2 (ja) * | 2003-04-09 | 2009-12-02 | 関東化学株式会社 | 半導体基板洗浄液組成物 |
| US20050019421A1 (en) * | 2003-07-23 | 2005-01-27 | 3M Innovative Properties Company | Disinfecting compositions and methods of making and using same |
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| US20050227898A1 (en) * | 2004-04-09 | 2005-10-13 | Leskowicz James J | Zero to low VOC glass and general purpose cleaner |
| US6969698B2 (en) * | 2004-04-13 | 2005-11-29 | S. C. Johnson & Son, Inc. | Aerosol cleaner |
| US7094742B2 (en) * | 2004-04-23 | 2006-08-22 | Jelmar, Llc | Hard surface cleaning compositions containing a sultaine and a mixture of organic acids |
| US7610647B2 (en) * | 2004-09-03 | 2009-11-03 | S.C. Johnson & Son, Inc. | Cleaning system |
| JP4988560B2 (ja) * | 2005-03-31 | 2012-08-01 | カルピス株式会社 | 酸性飲料の製造方法 |
| WO2006109242A1 (en) * | 2005-04-14 | 2006-10-19 | Koninklijke Philips Electronics N.V. | Cleaning fluid for electrical personal care apparatus |
| EP1721960A1 (en) * | 2005-05-12 | 2006-11-15 | The Procter & Gamble Company | Liquid acidic hard surface cleaning composition |
| US20060285995A1 (en) * | 2005-06-15 | 2006-12-21 | 3M Innovative Properties Company | Compositions and methods of use |
| US20060293214A1 (en) * | 2005-06-28 | 2006-12-28 | Lily Cheng | Synergistic acidic ternary biocidal compositions |
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| US12247185B2 (en) | 2020-11-25 | 2025-03-11 | Ecolab Usa Inc. | Multipurpose alkaline compositions and methods of use |
| CA3207112A1 (en) * | 2021-01-04 | 2022-07-07 | Harcros Chemicals, Inc. | Antimicrobial compounds based on glucoheptonic acids and their salts |
| US20230111060A1 (en) * | 2021-10-07 | 2023-04-13 | The Clorox Company | Quat-Based Compostable and Biodegradable Premoistened Cleaning and Disinfecting Wipes System |
| CN114360657A (zh) * | 2021-12-23 | 2022-04-15 | 张家口卷烟厂有限责任公司 | 转化糖用酸转化剂用量的确定方法、装置、设备和存储介质 |
| EP4253066A2 (en) * | 2022-03-31 | 2023-10-04 | Brother Kogyo Kabushiki Kaisha | Liquid discharging device |
| US20230340373A1 (en) * | 2022-04-20 | 2023-10-26 | Tygrus Llc | Cleaning wipes |
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| US3915633A (en) | 1972-09-21 | 1975-10-28 | Colgate Palmolive Co | Complexing acid pre-wash composition and method |
| US3969258A (en) | 1974-10-10 | 1976-07-13 | Pennwalt Corporation | Low foaming acid-anionic surfactant sanitizer compositions |
| US4975217A (en) | 1981-07-20 | 1990-12-04 | Kimberly-Clark Corporation | Virucidal composition, the method of use and the product therefor |
| US4690779A (en) | 1983-06-16 | 1987-09-01 | The Clorox Company | Hard surface cleaning composition |
| DE3713998A1 (de) | 1987-04-27 | 1988-11-10 | Henkel Kgaa | Reinigungsmittel fuer harte oberflaechen |
| DE3905063A1 (de) | 1989-02-18 | 1990-08-23 | Schuelke & Mayr Gmbh | Verspruehbares flaechendesinfektionsmittel |
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-
2001
- 2001-01-12 US US09/760,035 patent/US6699825B2/en not_active Expired - Lifetime
-
2002
- 2002-01-11 GB GB0315108A patent/GB2385859B/en not_active Expired - Lifetime
- 2002-01-11 CA CA002433663A patent/CA2433663C/en not_active Expired - Lifetime
- 2002-01-11 WO PCT/US2002/000928 patent/WO2002059244A2/en not_active Ceased
- 2002-01-11 JP JP2002559532A patent/JP4180376B2/ja not_active Expired - Lifetime
- 2002-01-11 AU AU2002246993A patent/AU2002246993B2/en not_active Expired
- 2002-01-11 TW TW091100323A patent/TWI246533B/zh not_active IP Right Cessation
- 2002-01-11 MX MXPA03006234A patent/MXPA03006234A/es active IP Right Grant
- 2002-01-11 AR ARP020100091A patent/AR032497A1/es active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| GB0315108D0 (en) | 2003-07-30 |
| JP2004523616A (ja) | 2004-08-05 |
| CA2433663A1 (en) | 2002-08-01 |
| WO2002059244A3 (en) | 2003-03-13 |
| AR032497A1 (es) | 2003-11-12 |
| TWI246533B (en) | 2006-01-01 |
| US6699825B2 (en) | 2004-03-02 |
| JP4180376B2 (ja) | 2008-11-12 |
| AU2002246993B2 (en) | 2006-02-23 |
| MXPA03006234A (es) | 2003-09-22 |
| GB2385859A (en) | 2003-09-03 |
| US20020155969A1 (en) | 2002-10-24 |
| WO2002059244A2 (en) | 2002-08-01 |
| GB2385859B (en) | 2005-01-19 |
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| Date | Code | Title | Description |
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| EEER | Examination request | ||
| MKEX | Expiry |
Effective date: 20220111 |