CA2332765A1 - Procede de preparation d'acides carboxyliques d'alkyle par carboxylation de methane d'alcanes inferieurs - Google Patents

Procede de preparation d'acides carboxyliques d'alkyle par carboxylation de methane d'alcanes inferieurs Download PDF

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Publication number
CA2332765A1
CA2332765A1 CA002332765A CA2332765A CA2332765A1 CA 2332765 A1 CA2332765 A1 CA 2332765A1 CA 002332765 A CA002332765 A CA 002332765A CA 2332765 A CA2332765 A CA 2332765A CA 2332765 A1 CA2332765 A1 CA 2332765A1
Authority
CA
Canada
Prior art keywords
catalyst
methane
acetic acid
transition metal
carbon dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002332765A
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English (en)
Inventor
James J. Spivey
Makarand R. Gogate
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Research Triangle Institute
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of CA2332765A1 publication Critical patent/CA2332765A1/fr
Abandoned legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/14—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on a carbon-to-carbon unsaturated bond in organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/15—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction of organic compounds with carbon dioxide, e.g. Kolbe-Schmitt synthesis

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

L'invention concerne un procédé permettant de produire des acides carboxyliques d'alkyle, tel de l'acide acétique, directement par une carboxylation d'alcanes, tel du méthane, qui comporte une étape de mise en réaction de dioxyde de carbone et de l'alcane en présence d'un catalyseur hétérogène pour former l'alkyle inférieur.
CA002332765A 1998-05-15 1999-05-14 Procede de preparation d'acides carboxyliques d'alkyle par carboxylation de methane d'alcanes inferieurs Abandoned CA2332765A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US8563298P 1998-05-15 1998-05-15
US60/085,632 1998-05-15
PCT/US1999/010709 WO1999059952A1 (fr) 1998-05-15 1999-05-14 Procede de preparation d'acides carboxyliques d'alkyle par carboxylation de methane d'alcanes inferieurs

Publications (1)

Publication Number Publication Date
CA2332765A1 true CA2332765A1 (fr) 1999-11-25

Family

ID=22192913

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002332765A Abandoned CA2332765A1 (fr) 1998-05-15 1999-05-14 Procede de preparation d'acides carboxyliques d'alkyle par carboxylation de methane d'alcanes inferieurs

Country Status (11)

Country Link
EP (1) EP1080063A1 (fr)
JP (1) JP2002515472A (fr)
KR (1) KR20010071265A (fr)
CN (1) CN1307554A (fr)
AU (1) AU3992999A (fr)
BR (1) BR9911058A (fr)
CA (1) CA2332765A1 (fr)
ID (1) ID28542A (fr)
NO (1) NO20005764L (fr)
WO (1) WO1999059952A1 (fr)
YU (1) YU71100A (fr)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6441222B1 (en) * 2000-05-22 2002-08-27 Eastman Chemical Company Vapor phase carbonylation process using iridium-gold co-catalysts
CN1103330C (zh) * 2000-09-30 2003-03-19 太原理工大学 一种非均相催化体系中合成乙酸的方法
KR101446758B1 (ko) * 2012-11-16 2014-10-01 아주대학교산학협력단 아세틸렌 카르복실화 반응을 이용한 이산화탄소의 처리방법
ES2945873T3 (es) * 2013-07-31 2023-07-10 Res Triangle Inst Oxidos de hierro metal mixtos y usos de los mismos
CN106215957A (zh) * 2016-07-12 2016-12-14 巨化集团技术中心 一种用于制备羧酸乙烯酯的多相催化体系及其使用方法
CN111195514B (zh) * 2018-11-20 2021-03-30 中国科学院大连化学物理研究所 一种单原子分散的铑基催化剂、其制备方法及在甲烷低温氧化反应中的应用
CN111377813B (zh) * 2018-12-31 2023-02-03 中国石油化工股份有限公司 一种合成苯丙炔酸的催化剂、其制备方法及其应用
CN111978170A (zh) * 2019-05-24 2020-11-24 贵州新天鑫化工有限公司 一种苯乙酸的绿色可循环合成方法
CN112892588B (zh) * 2019-12-03 2022-03-29 中国科学院大连化学物理研究所 一种用于低温催化氧化甲烷制备乙酸的原子级单分散的过渡金属催化剂的制备方法与应用
CN113117726B (zh) * 2019-12-31 2023-04-07 中国石油化工股份有限公司 一种合成苯丙炔酸的成型催化剂及其制备和应用
CN113117757B (zh) * 2019-12-31 2023-04-07 中国石油化工股份有限公司 一种合成苯丙炔酸的体相催化剂及其制备和工艺
CA3181051A1 (fr) * 2020-06-09 2021-12-16 Nova Chemicals Corporation Formation d'acide acetique par oxydation selective de methane
EP4001250A1 (fr) * 2020-11-18 2022-05-25 B. Braun Surgical, S.A. Procédé de production de molécules organiques fonctionnalisées et son utilisation
CN115806479A (zh) * 2022-11-18 2023-03-17 南京工业大学 一种转化ch4和co2直接制乙酸的方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5659077A (en) * 1996-03-22 1997-08-19 Natural Resources Canada Production of acetic acid from methane

Also Published As

Publication number Publication date
EP1080063A1 (fr) 2001-03-07
JP2002515472A (ja) 2002-05-28
NO20005764L (no) 2001-01-15
YU71100A (sh) 2002-10-18
BR9911058A (pt) 2001-10-30
NO20005764D0 (no) 2000-11-14
WO1999059952A1 (fr) 1999-11-25
KR20010071265A (ko) 2001-07-28
ID28542A (id) 2001-05-31
AU3992999A (en) 1999-12-06
CN1307554A (zh) 2001-08-08

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