CA2312372A1 - Flame retardant compositions - Google Patents
Flame retardant compositions Download PDFInfo
- Publication number
- CA2312372A1 CA2312372A1 CA002312372A CA2312372A CA2312372A1 CA 2312372 A1 CA2312372 A1 CA 2312372A1 CA 002312372 A CA002312372 A CA 002312372A CA 2312372 A CA2312372 A CA 2312372A CA 2312372 A1 CA2312372 A1 CA 2312372A1
- Authority
- CA
- Canada
- Prior art keywords
- flame retardant
- irganox
- dripping
- compositions
- flame
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000003063 flame retardant Substances 0.000 title claims abstract description 22
- 239000000203 mixture Substances 0.000 title abstract description 44
- 229920006126 semicrystalline polymer Polymers 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 6
- 230000000996 additive effect Effects 0.000 claims abstract description 4
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 claims description 13
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 claims 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 6
- 229920001684 low density polyethylene Polymers 0.000 abstract description 6
- 239000004702 low-density polyethylene Substances 0.000 abstract description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 abstract description 6
- DQXBYHZEEUGOBF-UHFFFAOYSA-N but-3-enoic acid;ethene Chemical compound C=C.OC(=O)CC=C DQXBYHZEEUGOBF-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005038 ethylene vinyl acetate Substances 0.000 abstract description 5
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 abstract description 4
- 229910000287 alkaline earth metal oxide Inorganic materials 0.000 abstract description 4
- 229910000410 antimony oxide Inorganic materials 0.000 abstract description 4
- DERLTVRRWCJVCP-UHFFFAOYSA-N ethene;ethyl acetate Chemical compound C=C.CCOC(C)=O DERLTVRRWCJVCP-UHFFFAOYSA-N 0.000 abstract description 4
- 150000004679 hydroxides Chemical class 0.000 abstract description 4
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- JODIJOMWCAXJJX-UHFFFAOYSA-N [O-2].[Al+3].[O-2].[Zn+2] Chemical compound [O-2].[Al+3].[O-2].[Zn+2] JODIJOMWCAXJJX-UHFFFAOYSA-N 0.000 abstract description 3
- UOCIZHQMWNPGEN-UHFFFAOYSA-N dialuminum;oxygen(2-);trihydrate Chemical compound O.O.O.[O-2].[O-2].[O-2].[Al+3].[Al+3] UOCIZHQMWNPGEN-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004408 titanium dioxide Substances 0.000 abstract description 3
- XPPKVPWEQAFLFU-UHFFFAOYSA-J diphosphate(4-) Chemical compound [O-]P([O-])(=O)OP([O-])([O-])=O XPPKVPWEQAFLFU-UHFFFAOYSA-J 0.000 abstract 1
- 235000011180 diphosphates Nutrition 0.000 abstract 1
- 238000007706 flame test Methods 0.000 description 17
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 15
- HCILJBJJZALOAL-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)-n'-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyl]propanehydrazide Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)NNC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 HCILJBJJZALOAL-UHFFFAOYSA-N 0.000 description 13
- 229920003345 Elvax® Polymers 0.000 description 12
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 description 12
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 11
- 239000000347 magnesium hydroxide Substances 0.000 description 11
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 11
- 235000012254 magnesium hydroxide Nutrition 0.000 description 11
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 description 8
- 239000002245 particle Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- -1 organohalide compounds Chemical class 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- AQPHBYQUCKHJLT-UHFFFAOYSA-N 1,2,3,4,5-pentabromo-6-(2,3,4,5,6-pentabromophenyl)benzene Chemical group BrC1=C(Br)C(Br)=C(Br)C(Br)=C1C1=C(Br)C(Br)=C(Br)C(Br)=C1Br AQPHBYQUCKHJLT-UHFFFAOYSA-N 0.000 description 3
- 229920000742 Cotton Polymers 0.000 description 3
- 239000003431 cross linking reagent Substances 0.000 description 3
- 239000002671 adjuvant Substances 0.000 description 2
- 239000003963 antioxidant agent Substances 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- YEAUATLBSVJFOY-UHFFFAOYSA-N tetraantimony hexaoxide Chemical compound O1[Sb](O2)O[Sb]3O[Sb]1O[Sb]2O3 YEAUATLBSVJFOY-UHFFFAOYSA-N 0.000 description 2
- 150000003918 triazines Chemical class 0.000 description 2
- WURBVZBTWMNKQT-UHFFFAOYSA-N 1-(4-chlorophenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)butan-2-one Chemical compound C1=NC=NN1C(C(=O)C(C)(C)C)OC1=CC=C(Cl)C=C1 WURBVZBTWMNKQT-UHFFFAOYSA-N 0.000 description 1
- LMYSNFBROWBKMB-UHFFFAOYSA-N 4-[2-(dipropylamino)ethyl]benzene-1,2-diol Chemical compound CCCN(CCC)CCC1=CC=C(O)C(O)=C1 LMYSNFBROWBKMB-UHFFFAOYSA-N 0.000 description 1
- XQTJQXCPQYOAIJ-UHFFFAOYSA-N 4-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OC(CC)CCCOC(=O)C=C XQTJQXCPQYOAIJ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- OKKRPWIIYQTPQF-UHFFFAOYSA-N Trimethylolpropane trimethacrylate Chemical compound CC(=C)C(=O)OCC(CC)(COC(=O)C(C)=C)COC(=O)C(C)=C OKKRPWIIYQTPQF-UHFFFAOYSA-N 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000009795 derivation Methods 0.000 description 1
- 210000000416 exudates and transudate Anatomy 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 230000000979 retarding effect Effects 0.000 description 1
- 229920002397 thermoplastic olefin Polymers 0.000 description 1
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K21/00—Fireproofing materials
- C09K21/14—Macromolecular materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34928—Salts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Fireproofing Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US98593697A | 1997-12-05 | 1997-12-05 | |
| US08/985936 | 1997-12-05 | ||
| PCT/US1998/006763 WO1999029776A1 (en) | 1997-12-05 | 1998-04-03 | Flame retardant compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2312372A1 true CA2312372A1 (en) | 1999-06-17 |
Family
ID=25531924
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002312372A Abandoned CA2312372A1 (en) | 1997-12-05 | 1998-04-03 | Flame retardant compositions |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1036111B1 (enExample) |
| JP (1) | JP4179750B2 (enExample) |
| CA (1) | CA2312372A1 (enExample) |
| DE (1) | DE69825074T2 (enExample) |
| ES (1) | ES2224374T3 (enExample) |
| WO (1) | WO1999029776A1 (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183881A (zh) * | 2011-12-29 | 2013-07-03 | 深圳市宏商材料科技股份有限公司 | 一种环保型热收缩应力套管及其制备方法 |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205309B (zh) * | 2007-11-30 | 2010-10-27 | 上海锦湖日丽塑料有限公司 | 三氧化二锑增效剂 |
| CN105461960A (zh) * | 2016-02-17 | 2016-04-06 | 黄秀茹 | 一种用于聚合物的添加剂及其制备方法以及由其组成的聚合物组合物 |
| WO2018085366A1 (en) * | 2016-11-02 | 2018-05-11 | Dow Global Technologies Llc | Flame-retardant, moisture-cured wire and cable constructions with improved glancing impact performance |
| MX2019009938A (es) * | 2017-03-03 | 2019-10-09 | Dow Global Technologies Llc | Retardante de flama, construcciones de alambres y cables pirorretardantes curados por humedad con rendimiento al impacto tangencial mejorado. |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3819575A (en) * | 1971-04-30 | 1974-06-25 | Cities Service Co | Flame retardant compositions |
| DE2506831A1 (de) * | 1975-02-18 | 1976-08-26 | Basf Ag | Schwerbrennbare formmassen auf der basis von polymerisaten des propylens |
| JPS58101128A (ja) * | 1981-12-11 | 1983-06-16 | Toshiba Corp | 難燃性樹脂組成物 |
| JP2630700B2 (ja) * | 1991-11-19 | 1997-07-16 | 株式会社フジクラ | 難燃性ポリオレフィン系チューブおよび熱収縮チューブ |
| IT1271414B (it) * | 1993-10-05 | 1997-05-28 | Enichem Spa | Composizione polimeriche a base di polietileni a bassissima densita' e loro uso per il rivestimento di gallerie |
| US5578666A (en) * | 1994-07-29 | 1996-11-26 | Polytechnic University | Flame retardant composition |
-
1998
- 1998-04-03 JP JP2000524358A patent/JP4179750B2/ja not_active Expired - Fee Related
- 1998-04-03 DE DE69825074T patent/DE69825074T2/de not_active Expired - Lifetime
- 1998-04-03 WO PCT/US1998/006763 patent/WO1999029776A1/en not_active Ceased
- 1998-04-03 ES ES98915299T patent/ES2224374T3/es not_active Expired - Lifetime
- 1998-04-03 EP EP98915299A patent/EP1036111B1/en not_active Expired - Lifetime
- 1998-04-03 CA CA002312372A patent/CA2312372A1/en not_active Abandoned
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103183881A (zh) * | 2011-12-29 | 2013-07-03 | 深圳市宏商材料科技股份有限公司 | 一种环保型热收缩应力套管及其制备方法 |
| CN103183881B (zh) * | 2011-12-29 | 2016-06-01 | 深圳市宏商材料科技股份有限公司 | 一种环保型热收缩应力套管及其制备方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| DE69825074T2 (de) | 2005-08-11 |
| EP1036111B1 (en) | 2004-07-14 |
| DE69825074D1 (de) | 2004-08-19 |
| JP4179750B2 (ja) | 2008-11-12 |
| ES2224374T3 (es) | 2005-03-01 |
| EP1036111A1 (en) | 2000-09-20 |
| JP2001525476A (ja) | 2001-12-11 |
| WO1999029776A1 (en) | 1999-06-17 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |