CA2263662A1 - Oxy-fluorures de lithium manganese pour electrodes de batteries aux ions de lithium rechargeables - Google Patents

Oxy-fluorures de lithium manganese pour electrodes de batteries aux ions de lithium rechargeables Download PDF

Info

Publication number
CA2263662A1
CA2263662A1 CA002263662A CA2263662A CA2263662A1 CA 2263662 A1 CA2263662 A1 CA 2263662A1 CA 002263662 A CA002263662 A CA 002263662A CA 2263662 A CA2263662 A CA 2263662A CA 2263662 A1 CA2263662 A1 CA 2263662A1
Authority
CA
Canada
Prior art keywords
rechargeable battery
capacity
compounds
lithium manganese
cells
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002263662A
Other languages
English (en)
Inventor
Glenn G. Amatucci
Jean-Marie Tarascon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Iconectiv LLC
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/706,546 external-priority patent/US5674645A/en
Application filed by Individual filed Critical Individual
Publication of CA2263662A1 publication Critical patent/CA2263662A1/fr
Abandoned legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Manganates manganites or permanganates
    • C01G45/1221—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof
    • C01G45/1242—Manganates or manganites with a manganese oxidation state of Mn(III), Mn(IV) or mixtures thereof of the type [Mn2O4]-, e.g. LiMn2O4, Li[MxMn2-x]O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/0018—Mixed oxides or hydroxides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/0018—Mixed oxides or hydroxides
    • C01G49/0072—Mixed oxides or hydroxides containing manganese
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G49/00—Compounds of iron
    • C01G49/009—Compounds containing, besides iron, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G51/00—Compounds of cobalt
    • C01G51/40—Cobaltates
    • C01G51/42—Cobaltates containing alkali metals, e.g. LiCoO2
    • C01G51/44—Cobaltates containing alkali metals, e.g. LiCoO2 containing manganese
    • C01G51/54—Cobaltates containing alkali metals, e.g. LiCoO2 containing manganese of the type [Mn2O4]-, e.g. Li(CoxMn2-x)04, Li(MyCoxMn2-x-y)O4
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/582—Halogenides
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H01M4/1315—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx containing halogen atoms, e.g. LiCoOxFy
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Secondary Cells (AREA)

Abstract

La stabilité et la capacité de mise en cycle des batteries aux ions de lithium rechargeables peuvent être améliorées par l'utilisation de matières qui permettent d'insérer des composantes d'électrodes d'oxy-fluorures de lithium-manganèse dont la formule générale est Li¿1+x?M¿y?Mn¿2-x-y?O¿4-z?F¿z?, dans laquelle M représente un métal, tel que Co, Cr, ou Fe, et x?0,4, y?0,3 et 0,05?z?1,0.
CA002263662A 1996-09-06 1997-09-04 Oxy-fluorures de lithium manganese pour electrodes de batteries aux ions de lithium rechargeables Abandoned CA2263662A1 (fr)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/706,546 US5674645A (en) 1996-09-06 1996-09-06 Lithium manganese oxy-fluorides for li-ion rechargeable battery electrodes
US08/706,546 1996-09-06
PCT/US1997/015588 WO1998010476A1 (fr) 1996-09-06 1997-09-04 Oxy-fluorures de lithium manganese pour electrodes de batteries aux ions de lithium rechargeables

Publications (1)

Publication Number Publication Date
CA2263662A1 true CA2263662A1 (fr) 1998-03-12

Family

ID=56289789

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002263662A Abandoned CA2263662A1 (fr) 1996-09-06 1997-09-04 Oxy-fluorures de lithium manganese pour electrodes de batteries aux ions de lithium rechargeables

Country Status (5)

Country Link
EP (1) EP0947012A4 (fr)
JP (1) JP2000514773A (fr)
AU (1) AU711516B2 (fr)
CA (1) CA2263662A1 (fr)
WO (1) WO1998010476A1 (fr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100296877B1 (ko) * 1999-05-27 2001-07-12 김순택 리튬 이차 전지용 양극 활물질 및 그를 이용한 리튬 이차 전지
EP1119062A3 (fr) * 2000-01-21 2003-07-09 New Billion Investments Limited Batterie électrique rechargeable à l' état solide du type Chrome-Fluor-Lithium
JP2001319653A (ja) * 2000-05-12 2001-11-16 Hitachi Maxell Ltd 非水二次電池
JP2002151080A (ja) * 2000-11-15 2002-05-24 Sony Corp 正極活物質および非水電解質電池、並びにそれらの製造方法
US7556655B2 (en) 2003-03-14 2009-07-07 3M Innovative Properties Company Method of producing lithium ion cathode materials
JP5017010B2 (ja) * 2007-08-08 2012-09-05 株式会社日立製作所 リチウム二次電池
JP7065341B2 (ja) * 2017-01-19 2022-05-12 パナソニックＩｐマネジメント株式会社 正極活物質、および、電池

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2098953A5 (fr) * 1970-07-31 1972-03-10 Anvar
JPH06243871A (ja) * 1993-02-16 1994-09-02 Sanyo Electric Co Ltd 非水系二次電池
US5296318A (en) * 1993-03-05 1994-03-22 Bell Communications Research, Inc. Rechargeable lithium intercalation battery with hybrid polymeric electrolyte
US5460904A (en) * 1993-08-23 1995-10-24 Bell Communications Research, Inc. Electrolyte activatable lithium-ion rechargeable battery cell
US5425932A (en) * 1993-05-19 1995-06-20 Bell Communications Research, Inc. Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
US5370949A (en) * 1993-07-09 1994-12-06 National Research Council Of Canada Materials for use as cathodes in lithium electrochemical cells
JPH07240200A (ja) * 1994-02-28 1995-09-12 Fuji Photo Film Co Ltd 非水二次電池

Also Published As

Publication number Publication date
WO1998010476A1 (fr) 1998-03-12
EP0947012A4 (fr) 2000-02-09
EP0947012A1 (fr) 1999-10-06
JP2000514773A (ja) 2000-11-07
AU711516B2 (en) 1999-10-14
AU4799697A (en) 1998-03-06

Similar Documents

Publication Publication Date Title
US5674645A (en) Lithium manganese oxy-fluorides for li-ion rechargeable battery electrodes
US5759720A (en) Lithium aluminum manganese oxy-fluorides for Li-ion rechargeable battery electrodes
US6878490B2 (en) Positive electrode active materials for secondary batteries and methods of preparing same
KR101056463B1 (ko) 리튬금속산화물 재료, 및 합성방법과 용도
JP3571671B2 (ja) リチオ化酸化物材料およびその製造方法
Xia et al. Studies on an Li Mn O spinel system (obtained by melt-impregnation) as a cathode for 4 V lithium batteries part 1. Synthesis and electrochemical behaviour of LixMn2O4
EP2907180B1 (fr) Composés de nickelate dopé
US5425932A (en) Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
US8052955B2 (en) Lithium-based materials and methods of forming the same
JP5236878B2 (ja) リチウムセルおよびバッテリー用の酸化リチウム電極
KR100424646B1 (ko) 전지용 활물질 및 그 제조방법
JP5199522B2 (ja) スピネル型リチウム・マンガン複合酸化物、その製造方法および用途
KR20190008120A (ko) 충전식 리튬 이온 배터리용 Ni계 캐소드 재료
EP2415105B1 (fr) Matériau actif négatif haute tension pour une batterie au lithium rechargeable
KR20180011049A (ko) 정극재료, 이를 정극에 사용한 리튬 이차 전지
AU711516B2 (en) Lithium manganese oxy-fluorides for li-ion rechargeable battery electrodes
JP4830136B2 (ja) リチウム二次電池用スピネル系マンガン酸化物およびこれを用いたリチウム二次電池
JPH11312522A (ja) リチウム二次電池用正極材料及びリチウム二次電池
US5932374A (en) Lithium magnesium manganese oxy-fluorides for Li-ion rechargeable battery electrodes
KR100424638B1 (ko) 리튬 이차전지용 양극 활물질 및 그의 제조방법
JPH10241685A (ja) 非水電解質二次電池
Butz et al. Structural and electrochemical effects of cobalt doping on lithium manganese oxide spinel
MXPA99011065A (en) Lithium aluminum manganese oxy-flourides for li-ion rechargeable battery electrodes

Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued
FZDE Discontinued

Effective date: 20030904