CA2259574A1 - Method of treating lithium manganese oxide spinel - Google Patents

Method of treating lithium manganese oxide spinel Download PDF

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Publication number
CA2259574A1
CA2259574A1 CA002259574A CA2259574A CA2259574A1 CA 2259574 A1 CA2259574 A1 CA 2259574A1 CA 002259574 A CA002259574 A CA 002259574A CA 2259574 A CA2259574 A CA 2259574A CA 2259574 A1 CA2259574 A1 CA 2259574A1
Authority
CA
Canada
Prior art keywords
spinel
metal salt
carbon dioxide
lithium
manganese oxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
CA002259574A
Other languages
English (en)
French (fr)
Inventor
Enoch I. Wang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duracell Inc USA
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/679,497 external-priority patent/US5733685A/en
Application filed by Individual filed Critical Individual
Publication of CA2259574A1 publication Critical patent/CA2259574A1/en
Abandoned legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G45/00—Compounds of manganese
    • C01G45/12—Complex oxides containing manganese and at least one other metal element
    • C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
    • C01G45/1242—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (Mn2O4)-, e.g. LiMn2O4 or Li(MxMn2-x)O4
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/30—Three-dimensional structures
    • C01P2002/32—Three-dimensional structures spinel-type (AB2O4)
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/50—Solid solutions
    • C01P2002/52—Solid solutions containing elements as dopants
    • C01P2002/54—Solid solutions containing elements as dopants one element only
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/80—Particles consisting of a mixture of two or more inorganic phases
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/40—Electric properties
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Inorganic Compounds Of Heavy Metals (AREA)
  • Secondary Cells (AREA)
CA002259574A 1996-07-12 1997-07-08 Method of treating lithium manganese oxide spinel Abandoned CA2259574A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US08/679,497 US5733685A (en) 1996-07-12 1996-07-12 Method of treating lithium manganese oxide spinel
US679,497 1996-07-12
US08/757,055 US5783328A (en) 1996-07-12 1996-11-26 Method of treating lithium manganese oxide spinel
US757,055 1996-11-26

Publications (1)

Publication Number Publication Date
CA2259574A1 true CA2259574A1 (en) 1998-01-22

Family

ID=27102255

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002259574A Abandoned CA2259574A1 (en) 1996-07-12 1997-07-08 Method of treating lithium manganese oxide spinel

Country Status (11)

Country Link
US (1) US5783328A (https=)
EP (1) EP0910873B1 (https=)
JP (1) JP4197054B2 (https=)
CN (1) CN1195334C (https=)
AR (1) AR007848A1 (https=)
AT (1) ATE371959T1 (https=)
AU (1) AU3596097A (https=)
CA (1) CA2259574A1 (https=)
DE (1) DE69738068T2 (https=)
TW (1) TW360988B (https=)
WO (1) WO1998002930A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220285667A1 (en) * 2021-03-08 2022-09-08 Sk Innovation Co., Ltd. Cathode active material for lithium secondary battery and lithium secondary battery including the same

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JP2001501773A (ja) * 1996-10-10 2001-02-06 メルク パテント ゲゼルシャフト ミット ベシュレンクテル ハフトング 変性電極材料およびその使用
US6869547B2 (en) * 1996-12-09 2005-03-22 Valence Technology, Inc. Stabilized electrochemical cell active material
US6183718B1 (en) 1996-12-09 2001-02-06 Valence Technology, Inc. Method of making stabilized electrochemical cell active material of lithium manganese oxide
CA2279350A1 (en) 1997-01-31 1998-08-06 Volker Hilarius New manganese dioxide electrodes, process for producing the same and their use
JP4185191B2 (ja) * 1998-07-31 2008-11-26 松下電器産業株式会社 スピネル型マンガン酸リチウムの製造方法
US6322744B1 (en) * 1999-02-17 2001-11-27 Valence Technology, Inc. Lithium manganese oxide-based active material
KR100307160B1 (ko) * 1999-03-06 2001-09-26 김순택 리튬 이차 전지용 양극 활물질 및 그 제조 방법
US6506518B1 (en) * 1999-04-27 2003-01-14 Shin-Kobe Electric Machinery Co., Ltd. Lithium secondary battery
US6468695B1 (en) * 1999-08-18 2002-10-22 Valence Technology Inc. Active material having extended cycle life
US6455200B1 (en) 1999-09-02 2002-09-24 Illinois Institute Of Technology Flame-retardant additive for li-ion batteries
US6730435B1 (en) * 1999-10-26 2004-05-04 Sumitomo Chemical Company, Limited Active material for non-aqueous secondary battery, and non-aqueous secondary battery using the same
DE10014884A1 (de) 2000-03-24 2001-09-27 Merck Patent Gmbh Beschichtete Lithium-Mischoxid-Partikel und ein Verfahren zu deren Herstellung
DE10016024A1 (de) 2000-03-31 2001-10-04 Merck Patent Gmbh Aktives Anodenmaterial in elektrochemischen Zellen und Verfahren zu deren Herstellung
JP2002158011A (ja) 2000-09-25 2002-05-31 Samsung Sdi Co Ltd リチウム二次電池用正極活物質及びその製造方法
US6972134B2 (en) * 2000-09-25 2005-12-06 Samsung Sdi Co., Ltd. Method of preparing positive active material for rechargeable lithium batteries
US6984469B2 (en) * 2000-09-25 2006-01-10 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium batteries and method of preparing same
US7138209B2 (en) * 2000-10-09 2006-11-21 Samsung Sdi Co., Ltd. Positive active material for rechargeable lithium battery and method of preparing same
KR100428616B1 (ko) 2001-01-19 2004-04-27 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질 및 그의 제조 방법
US6558844B2 (en) 2001-01-31 2003-05-06 Wilmont F. Howard, Jr. Stabilized spinel battery cathode material and methods
KR100728108B1 (ko) * 2001-04-02 2007-06-13 삼성에스디아이 주식회사 리튬 이차 전지용 양극 및 그의 제조 방법
KR100420034B1 (ko) * 2001-10-17 2004-02-25 삼성에스디아이 주식회사 리튬 이차 전지용 양극 활물질의 제조방법
JP5135664B2 (ja) * 2003-12-05 2013-02-06 日産自動車株式会社 非水電解質リチウムイオン電池用正極材料およびこれを用いた電池
CN1315217C (zh) * 2004-04-22 2007-05-09 天津大学 针管式锂锰电池及其制造方法
US7709149B2 (en) * 2004-09-24 2010-05-04 Lg Chem, Ltd. Composite precursor for aluminum-containing lithium transition metal oxide and process for preparation of the same
CN1855587B (zh) * 2005-04-28 2010-05-05 比亚迪股份有限公司 一种电池正极的制备方法和采用该正极的锂离子电池的制备方法
JP2010177030A (ja) * 2009-01-29 2010-08-12 Nippon Chem Ind Co Ltd リチウム系複合酸化物の表面処理剤、リチウム系複合酸化物の表面処理液、リチウムイオン二次電池用電解液、表面処理リチウムイオン二次電池用正極活物質及びその製造方法、表面処理リチウムイオン二次電池用負極活物質及びその製造方法、並びにリチウムイオン二次電池及びその製造方法
US8999009B2 (en) 2012-03-07 2015-04-07 A123 Systems Llc Surface modification of battery materials and method for making a battery
ES2870712T3 (es) 2013-02-01 2021-10-27 Emd Acquisition Llc Composiciones mejoradas de óxido de litio manganeso
US9905851B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Cathode active material and method of preparing the same
US10236499B2 (en) 2013-07-26 2019-03-19 Lg Chem, Ltd. Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same
US9905850B2 (en) 2013-07-26 2018-02-27 Lg Chem, Ltd. Polycrystalline lithium manganese oxide particles, preparation method thereof, and cathode active material including the same
CN105830260B (zh) * 2013-11-29 2018-10-26 汉阳大学校产学协力团 用于全固态锂二次电池的活性材料，其制造方法和包含其的全固态锂二次电池
CN105838895B (zh) * 2016-05-16 2017-11-17 长沙矿冶研究院有限责任公司 一种从含锂富锰渣中提取锂和锰的方法
CN110148712B (zh) * 2018-02-11 2021-05-25 湖南杉杉能源科技股份有限公司 一种复合包覆改性的富锂锰正极材料及其制备方法
CN113321244B (zh) * 2021-05-19 2022-09-20 上海大学 一种表面改性的层状氧化物正极材料的制备方法及应用

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GB2196785B (en) * 1986-10-29 1990-05-23 Sony Corp Organic electrolyte secondary cell
JP3028582B2 (ja) * 1990-10-09 2000-04-04 ソニー株式会社 非水電解質二次電池
US5266299A (en) * 1991-01-28 1993-11-30 Bell Communications Research, Inc. Method of preparing LI1+XMN204 for use as secondary battery electrode
US5135732A (en) * 1991-04-23 1992-08-04 Bell Communications Research, Inc. Method for preparation of LiMn2 O4 intercalation compounds and use thereof in secondary lithium batteries
JP3238954B2 (ja) * 1992-09-25 2001-12-17 三洋電機株式会社 非水系二次電池
GB9305457D0 (en) * 1993-03-17 1993-05-05 Dowty Electronic Components Lithiated manganese oxide
GB9305440D0 (en) * 1993-03-17 1993-05-05 Dowty Electronic Components Lithiated manganese oxide
US5425932A (en) * 1993-05-19 1995-06-20 Bell Communications Research, Inc. Method for synthesis of high capacity Lix Mn2 O4 secondary battery electrode compounds
CA2114493C (en) * 1994-01-28 1999-01-12 Jeffrey Raymond Dahn Method for increasing the reversible capacity of lithium transition metal oxide cathodes
US5820790A (en) * 1994-11-11 1998-10-13 Japan Storage Battery Co., Ltd. Positive electrode for non-aqueous cell
US5597664A (en) * 1995-09-07 1997-01-28 Kerr-Mcgee Corporation Lithium manganese oxide compound and method of preparation

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20220285667A1 (en) * 2021-03-08 2022-09-08 Sk Innovation Co., Ltd. Cathode active material for lithium secondary battery and lithium secondary battery including the same
US11621412B2 (en) * 2021-03-08 2023-04-04 Sk On Co., Ltd. Cathode active material for lithium secondary battery and lithium secondary battery including the same

Also Published As

Publication number Publication date
AU3596097A (en) 1998-02-09
CN1227672A (zh) 1999-09-01
EP0910873B1 (en) 2007-08-29
EP0910873A1 (en) 1999-04-28
CN1195334C (zh) 2005-03-30
JP4197054B2 (ja) 2008-12-17
ATE371959T1 (de) 2007-09-15
US5783328A (en) 1998-07-21
TW360988B (en) 1999-06-11
AR007848A1 (es) 1999-11-24
JP2001527686A (ja) 2001-12-25
DE69738068D1 (de) 2007-10-11
WO1998002930A1 (en) 1998-01-22
DE69738068T2 (de) 2008-05-21

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Legal Events

Date Code Title Description
EEER Examination request
FZDE Discontinued
FZDE Discontinued

Effective date: 20030708