CA2254663C - Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation - Google Patents

Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation Download PDF

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Publication number
CA2254663C
CA2254663C CA002254663A CA2254663A CA2254663C CA 2254663 C CA2254663 C CA 2254663C CA 002254663 A CA002254663 A CA 002254663A CA 2254663 A CA2254663 A CA 2254663A CA 2254663 C CA2254663 C CA 2254663C
Authority
CA
Canada
Prior art keywords
radiation
tert
composition
butyl
bis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002254663A
Other languages
English (en)
French (fr)
Other versions
CA2254663A1 (en
Inventor
Edmund Kwok-Leung Lau
Satchit Srinivasan
Peter James Perron
Peter Shelsey Solera
Anthony David Debellis
Chia-Hu Chang
Gerald Anthony Capocci
Joseph Steven Puglisi
Douglas Wayne Horsey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF Schweiz AG
LyondellBasell Advanced Polyolefins USA Inc
Original Assignee
Ciba Spezialitaetenchemie Holding AG
Solvay Engineered Polymers Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ciba Spezialitaetenchemie Holding AG, Solvay Engineered Polymers Inc filed Critical Ciba Spezialitaetenchemie Holding AG
Publication of CA2254663A1 publication Critical patent/CA2254663A1/en
Application granted granted Critical
Publication of CA2254663C publication Critical patent/CA2254663C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/28—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16—Ethylene-propylene or ethylene-propylene-diene copolymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00—Compositions of unspecified rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking
    • C08L2312/06—Crosslinking by radiation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
    • C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
    • C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Polymerisation Methods In General (AREA)
CA002254663A 1997-12-02 1998-11-30 Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation Expired - Fee Related CA2254663C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US98250897A 1997-12-02 1997-12-02
US08/982,508 1997-12-02

Publications (2)

Publication Number Publication Date
CA2254663A1 CA2254663A1 (en) 1999-06-02
CA2254663C true CA2254663C (en) 2009-01-27

Family

ID=25529236

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002254663A Expired - Fee Related CA2254663C (en) 1997-12-02 1998-11-30 Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation

Country Status (7)

Country Link
US (2) US6488882B2 (https=)
EP (1) EP0921152B1 (https=)
JP (1) JP4340987B2 (https=)
KR (1) KR100545752B1 (https=)
CA (1) CA2254663C (https=)
DE (1) DE69834092T2 (https=)
ES (1) ES2260825T3 (https=)

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* Cited by examiner, † Cited by third party
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EP0921152B1 (en) 1997-12-02 2006-04-05 Ciba SC Holding AG Polyolefin materials having enhanced surface durability and methods of making the same by exposure to radiation
US6541568B1 (en) 2000-06-01 2003-04-01 Solvay Engineered Polymers Polyolefin materials having enhanced surface durability
JP2003080583A (ja) * 2000-08-31 2003-03-19 Tokai Rubber Ind Ltd 燃料ホースの製法およびそれに用いる紫外線架橋組成物
EP1340788A3 (de) * 2002-02-22 2004-03-17 Nexans Verfahren zur Herstellung eines Compounds auf Basis eines thermoplastischen Kunststoffs
US7198576B2 (en) * 2003-06-17 2007-04-03 Acushnet Company Golf ball comprising UV-cured non-surface layer
US7323256B2 (en) * 2003-11-13 2008-01-29 Cree, Inc. Large area, uniformly low dislocation density GaN substrate and process for making the same
US7082050B2 (en) 2003-11-30 2006-07-25 Union Semiconductor Technology Corporation Method to equalize word current circuitry
EP1888686B1 (en) * 2005-06-07 2013-01-23 Basf Se Scratch resistant polyolefins
US20070056845A1 (en) * 2005-09-13 2007-03-15 Applied Materials, Inc. Multiple zone sputtering target created through conductive and insulation bonding
US7744803B2 (en) * 2006-08-02 2010-06-29 Shawcor Ltd. Photo-crosslinkable polyolefin compositions
KR101274622B1 (ko) * 2006-09-26 2013-06-14 삼성디스플레이 주식회사 밀봉제 및 이를 이용한 액정 표시 장치
US20080114091A1 (en) * 2006-11-15 2008-05-15 Sealed Air Corporation (Us) Apparatus and Method for Preparing a UV-Induced Crosslinked Foam
WO2008063590A1 (en) * 2006-11-24 2008-05-29 North Carolina State University Electroactive nanostructured polymers as tunable organic actuators
EP1944327B2 (en) † 2007-01-09 2018-11-28 Borealis Technology Oy A cross-linking agent
US20080289575A1 (en) * 2007-05-24 2008-11-27 Burrows Brian H Methods and apparatus for depositing a group iii-v film using a hydride vapor phase epitaxy process
ATE476252T1 (de) * 2007-05-30 2010-08-15 Iie Ges Fuer Innovative Indust Vorrichtung zur polymerisation
DE602007008925D1 (de) 2007-12-21 2010-10-14 Borealis Tech Oy Polyolefinzusammensetzung für Mitte-/Hoch-/Höchstspannungskabel mit verbesserter elektrischer Durchbruchfestigkeit
CN101932623A (zh) * 2008-01-17 2010-12-29 巴斯夫欧洲公司 改性的烯烃聚合物
US7867433B2 (en) * 2008-05-30 2011-01-11 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked articles
US8765832B2 (en) 2011-10-14 2014-07-01 Exxonmobil Chemical Patents Inc. Polyolefin-based crosslinked compositions and methods of making them
PL2163576T3 (pl) * 2008-09-09 2012-04-30 Borealis Ag Kompozycja poliolefinowa do średnio-/wysoko-/ekstra- wysokonapięciowych kabli zawierająca benzofenonowy stabilizator napięcia
US20100264566A1 (en) * 2009-03-17 2010-10-21 Suss Microtec Inc Rapid fabrication of a microelectronic temporary support for inorganic substrates
US8742019B2 (en) * 2009-10-02 2014-06-03 Exxonmobil Chemical Patents Inc. Crosslinked polyolefin polymer blends
RU2436814C2 (ru) * 2009-10-29 2011-12-20 Руслан Гиглович Дзадзамия Способ изготовления термоусаживающихся материалов
US9303138B2 (en) * 2011-09-21 2016-04-05 Exxonmobil Chemical Patents Inc. Elastomeric composition for pharmaceutical articles
WO2013122227A1 (ja) * 2012-02-16 2013-08-22 日東電工株式会社 赤外線反射基板の製造方法
CN107513196B (zh) * 2016-06-17 2020-04-14 常州百思通复合材料有限公司 一种使用微波高效加热高分子聚合物的方法
GB2565587A (en) * 2017-08-18 2019-02-20 Addivant Switzerland Gmbh Insulation composition
CN110563975A (zh) * 2019-09-16 2019-12-13 深圳市刚塑科技有限公司 一种聚合物材料表面用硬化防划伤处理方法

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US4000216A (en) 1970-09-22 1976-12-28 Rohm And Haas Company Surface altering agent for thermoplastic polymers
US4039720A (en) 1976-05-03 1977-08-02 Ppg Industries, Inc. Laminated windshield with improved innerlayer
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US4255303A (en) 1979-04-25 1981-03-10 Union Carbide Corporation Polyethylene composition containing talc filler for electrical applications
US4303697A (en) 1979-05-17 1981-12-01 E. I. Du Pont De Nemours And Company Process for improving the adhesion of paint to polyolefin surfaces
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US4478876A (en) 1980-12-18 1984-10-23 General Electric Company Process of coating a substrate with an abrasion resistant ultraviolet curable composition
JPS5898704A (ja) 1981-12-08 1983-06-11 Nippon Telegr & Teleph Corp <Ntt> 光フアイバ心線
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Also Published As

Publication number Publication date
JPH11236467A (ja) 1999-08-31
EP0921152A2 (en) 1999-06-09
EP0921152B1 (en) 2006-04-05
US20030013780A1 (en) 2003-01-16
KR100545752B1 (ko) 2006-06-29
JP4340987B2 (ja) 2009-10-07
ES2260825T3 (es) 2006-11-01
US6790874B2 (en) 2004-09-14
EP0921152A3 (en) 1999-08-25
US6488882B2 (en) 2002-12-03
US20010020047A1 (en) 2001-09-06
DE69834092T2 (de) 2006-09-21
DE69834092D1 (de) 2006-05-18
CA2254663A1 (en) 1999-06-02
KR19990062664A (ko) 1999-07-26

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Effective date: 20121130