KR100617891B1 - 회전 성형법용 안정화제 혼합물 - Google Patents
회전 성형법용 안정화제 혼합물 Download PDFInfo
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- KR100617891B1 KR100617891B1 KR1020000009799A KR20000009799A KR100617891B1 KR 100617891 B1 KR100617891 B1 KR 100617891B1 KR 1020000009799 A KR1020000009799 A KR 1020000009799A KR 20000009799 A KR20000009799 A KR 20000009799A KR 100617891 B1 KR100617891 B1 KR 100617891B1
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- 125000003229 2-methylhexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
- C08K5/34926—Triazines also containing heterocyclic groups other than triazine groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/04—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould
- B29C41/06—Rotational or centrifugal casting, i.e. coating the inside of a mould by rotating the mould about two or more axes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
- B29C41/42—Removing articles from moulds, cores or other substrates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/34—Component parts, details or accessories; Auxiliary operations
- B29C41/46—Heating or cooling
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/32—Compounds containing nitrogen bound to oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
- C08K5/3435—Piperidines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2022/00—Hollow articles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Moulding By Coating Moulds (AREA)
Abstract
Description
G1과 G2가 독립적으로 탄소수 6 내지 22의 직쇄 또는 측쇄 알킬 그룹이고 G3이 탄소수 1 내지 22의 직쇄 또는 측쇄 알킬인 화학식 III의 화합물이 또한 바람직하다. G1과 G2가 각각 독립적으로 탄소수 12 내지 22의 직쇄 또는 측쇄 알킬이고 G3이 메틸인 화학식 III의 화합물이 특히 바람직하다. G1, G2 및 G3이 각각 독립적으로 탄소수 12 내지 22의 직쇄 또는 측쇄 알킬인 화학식 III의 화합물이 매우 특히 바람직하다. 특히 바람직한 성분(ii)은 디데실 메틸 아민 옥사이드, 트리데실 아민 옥사이드, 트리도데실 아민 옥사이드 및 트리헥사데실 아민 옥사이드로 이루어진 그룹으로부터 선택된다.
288℃에서의 체류 시간(분) | 제형의 황색도 지수 | |||
A | B | C | D | |
6 | -2.13 | -3.80 | -3.49 | -3.00 |
8 | -1.72 | -4.08 | -3.86 | -3.30 |
10 | -0.10 | -1.86 | -2.63 | -2.70 |
12 | 9.58 | 0.96 | -0.15 | -0.46 |
14 | 8.00 | 3.14 | 5.28 | 1.40 |
288℃에서의 체류 시간(분) | 충격 강도[취성(%)] | |
제형 A | 제형 B | |
6 | 0 | 0 |
8 | 20 | 0 |
10 | 20 | 0 |
12 | 100 | 100 |
Claims (21)
- 폴리올레핀을 유기 포스파이트 및 포스포나이트로 이루어진 그룹으로부터 선택된 하나 이상의 화합물(a), 하이드록실아민 유도체(i)와 아민 옥사이드 유도체(ii)로 이루어진 그룹으로부터 선택된 하나 이상의 화합물(b) 및 장애 아민 안정화제들로 이루어진 그룹으로부터 선택된 하나 이상의 화합물(c)을 포함하는 안정화제 혼합물로 충전시키고, 당해 혼합물을 금형에 충전시킨 다음, 금형을 오븐 속에서 280℃ 이상으로 가열하여, 안정화된 폴리올레핀을 용융시키고, 금형을 두 개 이상의 축 둘레로 회전시켜 플라스틱 재료를 벽에 분산시킨 다음, 금형을 계속 회전시키면서 냉각시키고, 이어서 금형을 개방하여, 생성된 중공 제품을 취출(取出)함을 포함하는, 폴리올레핀 중공 제품의 제조방법.
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Applications Claiming Priority (6)
Application Number | Priority Date | Filing Date | Title |
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US25972499A | 1999-03-01 | 1999-03-01 | |
US9/259,724 | 1999-03-01 | ||
US09/259,724 | 1999-03-01 | ||
US09/455,143 | 1999-12-06 | ||
US09/455,143 US6444733B1 (en) | 1999-03-01 | 1999-12-06 | Stabilizer combination for the rotomolding process |
US9/455,143 | 1999-12-06 |
Publications (2)
Publication Number | Publication Date |
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KR20000062662A KR20000062662A (ko) | 2000-10-25 |
KR100617891B1 true KR100617891B1 (ko) | 2006-09-08 |
Family
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Application Number | Title | Priority Date | Filing Date |
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KR1020000009799A KR100617891B1 (ko) | 1999-03-01 | 2000-02-28 | 회전 성형법용 안정화제 혼합물 |
Country Status (5)
Country | Link |
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US (1) | US6444733B1 (ko) |
JP (1) | JP5554666B2 (ko) |
KR (1) | KR100617891B1 (ko) |
AR (1) | AR022780A1 (ko) |
RU (1) | RU2242364C2 (ko) |
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US20040007798A1 (en) * | 2002-04-30 | 2004-01-15 | Kreager Andrew S. | Polymer blends for tip molding process and method of forming a plastic part |
US20040147650A1 (en) * | 2003-01-24 | 2004-07-29 | General Electric Company | Process for stabilization of polymer compositions |
US20040183053A1 (en) * | 2003-03-20 | 2004-09-23 | Pearson Jason Clay | Process for the preparation of a hindered amine light stabilizer salt |
CA2435986C (en) * | 2003-07-24 | 2011-08-30 | Nova Chemicals Corporation | Rotomolding process with reduced cycle times |
KR20070004649A (ko) * | 2004-01-27 | 2007-01-09 | 시바 스페셜티 케미칼스 홀딩 인크. | 열적으로 안정한 양이온성 광경화성 조성물 |
US7291669B2 (en) * | 2004-03-16 | 2007-11-06 | Ciba Specialty Chemicals Corporation | Stabilized polyolefin compositions |
EP1600477A1 (en) * | 2004-05-28 | 2005-11-30 | Total Petrochemicals Research Feluy | Use of thermoplastic composition comprising polyethylene glycol as additive |
EP1600474A1 (en) * | 2004-05-28 | 2005-11-30 | Total Petrochemicals Research Feluy | Use of fluoropolymers for rotomolding |
EP1721931A1 (en) * | 2005-05-09 | 2006-11-15 | Total Petrochemicals Research Feluy | mono-layer rotomoulded articles prepared from blends comprising polyethylene |
SA07280006B1 (ar) * | 2006-02-01 | 2011-05-14 | سيبا سبشيالتي كيميكالز هولدينج انك | استخدام امينات ثنائية معاقة فراغياً كإضافات معالجة في عمليات التشكيل الدوراني |
WO2007118794A1 (en) | 2006-04-13 | 2007-10-25 | Ciba Holding Inc. | Sulphonium salt initiators |
US20080105995A1 (en) * | 2006-11-08 | 2008-05-08 | Outokumpu Technology Oyj a public limited company of Finland | Method and apparatus for making spiral separators |
EP2197840B1 (en) | 2007-10-10 | 2013-11-06 | Basf Se | Sulphonium salt initiators |
US7976729B2 (en) * | 2008-01-02 | 2011-07-12 | Chemtura Corporation | Stabilized polymer compositions |
DE102008001475A1 (de) * | 2008-04-30 | 2009-11-05 | Evonik Degussa Gmbh | Phenolharz-aufweisende Polymerzusammensetzung |
CA2651514C (en) * | 2009-01-29 | 2016-05-03 | Nova Chemicals Corporation | Stabilized rotomolded parts |
CA2759289C (en) | 2009-04-21 | 2019-01-15 | Basf Corporation | Rotomolding process for polyethylene articles |
AU2011344159B2 (en) * | 2010-12-13 | 2016-01-07 | Cytec Technology Corp. | Processing additives and uses of same in rotational molding |
US11267951B2 (en) | 2010-12-13 | 2022-03-08 | Cytec Technology Corp. | Stabilizer compositions containing substituted chroman compounds and methods of use |
EP2511332B1 (en) * | 2011-04-15 | 2014-09-17 | Borealis AG | Polyolefin pipe with improved migration behaviour |
RU2662823C2 (ru) * | 2012-06-13 | 2018-07-31 | Сайтек Текнолоджи Корп. | Стабилизирующие композиции, содержащие замещенные хромановые соединения, и способы применения |
PT2912075T (pt) | 2012-10-02 | 2017-03-23 | Bluestar Silicones France | Composição reticulável/polimerizável por via catiónica compreendendo um borato de iodónio e libertando um odor aceitável |
EP2909213A4 (en) | 2012-10-18 | 2016-06-08 | Reliance Ind Ltd | TETRAOXA-DIPHOSPHASPIRO COMPOUNDS |
RU2650965C2 (ru) * | 2015-12-18 | 2018-04-18 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Кабардино-Балкарский государственный университет им. Х.М. Бербекова" (КБГУ) | Способ получения полимерной композиции |
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US5834541A (en) * | 1997-05-02 | 1998-11-10 | Montell North America Inc. | Olefin polymer composition having low smoke generation and fiber and film prepared therefrom |
-
1999
- 1999-12-06 US US09/455,143 patent/US6444733B1/en not_active Expired - Lifetime
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2000
- 2000-02-28 KR KR1020000009799A patent/KR100617891B1/ko active IP Right Grant
- 2000-02-28 AR ARP000100864A patent/AR022780A1/es active IP Right Grant
- 2000-03-01 RU RU2000104948/04A patent/RU2242364C2/ru active
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AR022780A1 (es) | 2002-09-04 |
US6444733B1 (en) | 2002-09-03 |
JP5554666B2 (ja) | 2014-07-23 |
KR20000062662A (ko) | 2000-10-25 |
JP2010270343A (ja) | 2010-12-02 |
RU2242364C2 (ru) | 2004-12-20 |
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