CA2239950C - Syntactic rigid pur/pir foam boardstock - Google Patents
Syntactic rigid pur/pir foam boardstock Download PDFInfo
- Publication number
- CA2239950C CA2239950C CA002239950A CA2239950A CA2239950C CA 2239950 C CA2239950 C CA 2239950C CA 002239950 A CA002239950 A CA 002239950A CA 2239950 A CA2239950 A CA 2239950A CA 2239950 C CA2239950 C CA 2239950C
- Authority
- CA
- Canada
- Prior art keywords
- microspheres
- foam
- bimodal
- hybrid
- syntactic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000006260 foam Substances 0.000 title claims abstract description 64
- 239000004005 microsphere Substances 0.000 claims abstract description 72
- 230000002902 bimodal effect Effects 0.000 claims abstract description 26
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 9
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 8
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 6
- 229920005830 Polyurethane Foam Polymers 0.000 claims abstract description 5
- 239000011496 polyurethane foam Substances 0.000 claims abstract description 5
- 239000004814 polyurethane Substances 0.000 claims description 32
- 239000011495 polyisocyanurate Substances 0.000 claims description 26
- 229920000582 polyisocyanurate Polymers 0.000 claims description 25
- 229920002635 polyurethane Polymers 0.000 claims description 19
- 239000011521 glass Substances 0.000 claims description 5
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 claims description 4
- 239000000919 ceramic Substances 0.000 claims description 4
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 claims description 4
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 claims description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 claims description 2
- 239000001282 iso-butane Substances 0.000 claims description 2
- 239000004604 Blowing Agent Substances 0.000 description 11
- 150000001875 compounds Chemical class 0.000 description 10
- 239000012948 isocyanate Substances 0.000 description 10
- 150000002513 isocyanates Chemical class 0.000 description 9
- 239000000463 material Substances 0.000 description 8
- 229920001228 polyisocyanate Polymers 0.000 description 7
- 239000005056 polyisocyanate Substances 0.000 description 7
- -1 aliphatic hydrocarbon radical Chemical class 0.000 description 6
- 239000000945 filler Substances 0.000 description 6
- 239000011159 matrix material Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 5
- 239000004033 plastic Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- 238000001000 micrograph Methods 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- NSGXIBWMJZWTPY-UHFFFAOYSA-N 1,1,1,3,3,3-hexafluoropropane Chemical class FC(F)(F)CC(F)(F)F NSGXIBWMJZWTPY-UHFFFAOYSA-N 0.000 description 3
- NPNPZTNLOVBDOC-UHFFFAOYSA-N 1,1-difluoroethane Chemical class CC(F)F NPNPZTNLOVBDOC-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 3
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- SUAMPXQALWYDBK-UHFFFAOYSA-N 1,1,1,2,2,3-hexafluoropropane Chemical compound FCC(F)(F)C(F)(F)F SUAMPXQALWYDBK-UHFFFAOYSA-N 0.000 description 2
- FYIRUPZTYPILDH-UHFFFAOYSA-N 1,1,1,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)C(F)(F)F FYIRUPZTYPILDH-UHFFFAOYSA-N 0.000 description 2
- ZDCWZRQSHBQRGN-UHFFFAOYSA-N 1,1,1,2,3-pentafluoropropane Chemical compound FCC(F)C(F)(F)F ZDCWZRQSHBQRGN-UHFFFAOYSA-N 0.000 description 2
- WZLFPVPRZGTCKP-UHFFFAOYSA-N 1,1,1,3,3-pentafluorobutane Chemical compound CC(F)(F)CC(F)(F)F WZLFPVPRZGTCKP-UHFFFAOYSA-N 0.000 description 2
- CXIGIYYQHHRBJC-UHFFFAOYSA-N 1,1,1,4,4,4-hexafluorobutane Chemical compound FC(F)(F)CCC(F)(F)F CXIGIYYQHHRBJC-UHFFFAOYSA-N 0.000 description 2
- AWTOFSDLNREIFS-UHFFFAOYSA-N 1,1,2,2,3-pentafluoropropane Chemical compound FCC(F)(F)C(F)F AWTOFSDLNREIFS-UHFFFAOYSA-N 0.000 description 2
- MWDWMQNTNBHJEI-UHFFFAOYSA-N 1,1,2,3,3-pentafluoropropane Chemical compound FC(F)C(F)C(F)F MWDWMQNTNBHJEI-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 2
- VPKDCDLSJZCGKE-UHFFFAOYSA-N carbodiimide group Chemical group N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 230000001413 cellular effect Effects 0.000 description 2
- 229910000267 dualite Inorganic materials 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003063 flame retardant Substances 0.000 description 2
- 239000004872 foam stabilizing agent Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 238000011068 loading method Methods 0.000 description 2
- MSSNHSVIGIHOJA-UHFFFAOYSA-N pentafluoropropane Chemical compound FC(F)CC(F)(F)F MSSNHSVIGIHOJA-UHFFFAOYSA-N 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 2
- NVSXSBBVEDNGPY-UHFFFAOYSA-N 1,1,1,2,2-pentafluorobutane Chemical class CCC(F)(F)C(F)(F)F NVSXSBBVEDNGPY-UHFFFAOYSA-N 0.000 description 1
- FDOPVENYMZRARC-UHFFFAOYSA-N 1,1,1,2,2-pentafluoropropane Chemical class CC(F)(F)C(F)(F)F FDOPVENYMZRARC-UHFFFAOYSA-N 0.000 description 1
- LVGUZGTVOIAKKC-UHFFFAOYSA-N 1,1,1,2-tetrafluoroethane Chemical compound FCC(F)(F)F LVGUZGTVOIAKKC-UHFFFAOYSA-N 0.000 description 1
- ZXVZGGVDYOBILI-UHFFFAOYSA-N 1,1,2,2,3,3-hexafluoropropane Chemical compound FC(F)C(F)(F)C(F)F ZXVZGGVDYOBILI-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- SKDFWEPBABSFMG-UHFFFAOYSA-N 1,2-dichloro-1,1-difluoroethane Chemical compound FC(F)(Cl)CCl SKDFWEPBABSFMG-UHFFFAOYSA-N 0.000 description 1
- PCHXZXKMYCGVFA-UHFFFAOYSA-N 1,3-diazetidine-2,4-dione Chemical compound O=C1NC(=O)N1 PCHXZXKMYCGVFA-UHFFFAOYSA-N 0.000 description 1
- LFSYUSUFCBOHGU-UHFFFAOYSA-N 1-isocyanato-2-[(4-isocyanatophenyl)methyl]benzene Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=CC=C1N=C=O LFSYUSUFCBOHGU-UHFFFAOYSA-N 0.000 description 1
- OHMHBGPWCHTMQE-UHFFFAOYSA-N 2,2-dichloro-1,1,1-trifluoroethane Chemical compound FC(F)(F)C(Cl)Cl OHMHBGPWCHTMQE-UHFFFAOYSA-N 0.000 description 1
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 1
- HOSGXJWQVBHGLT-UHFFFAOYSA-N 6-hydroxy-3,4-dihydro-1h-quinolin-2-one Chemical group N1C(=O)CCC2=CC(O)=CC=C21 HOSGXJWQVBHGLT-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- VOPWNXZWBYDODV-UHFFFAOYSA-N Chlorodifluoromethane Chemical compound FC(F)Cl VOPWNXZWBYDODV-UHFFFAOYSA-N 0.000 description 1
- 239000004338 Dichlorodifluoromethane Substances 0.000 description 1
- 238000005684 Liebig rearrangement reaction Methods 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- PXBRQCKWGAHEHS-UHFFFAOYSA-N dichlorodifluoromethane Chemical compound FC(F)(Cl)Cl PXBRQCKWGAHEHS-UHFFFAOYSA-N 0.000 description 1
- 235000019404 dichlorodifluoromethane Nutrition 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229940093499 ethyl acetate Drugs 0.000 description 1
- 235000019439 ethyl acetate Nutrition 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- DYDNPESBYVVLBO-UHFFFAOYSA-N formanilide Chemical compound O=CNC1=CC=CC=C1 DYDNPESBYVVLBO-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920006149 polyester-amide block copolymer Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229920001576 syndiotactic polymer Polymers 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/32—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof from compositions containing microballoons, e.g. syntactic foams
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
- C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
- C08J9/143—Halogen containing compounds
- C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
- C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/22—Expanded, porous or hollow particles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US90944797A | 1997-08-11 | 1997-08-11 | |
| US08/909,447 | 1997-08-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2239950A1 CA2239950A1 (en) | 1999-02-11 |
| CA2239950C true CA2239950C (en) | 2007-09-18 |
Family
ID=25427242
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002239950A Expired - Fee Related CA2239950C (en) | 1997-08-11 | 1998-06-09 | Syntactic rigid pur/pir foam boardstock |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US6166109A (enExample) |
| EP (1) | EP0896976B1 (enExample) |
| JP (1) | JPH11140219A (enExample) |
| CN (1) | CN1088005C (enExample) |
| AT (1) | ATE300579T1 (enExample) |
| CA (1) | CA2239950C (enExample) |
| DE (1) | DE69830955T2 (enExample) |
| DK (1) | DK0896976T3 (enExample) |
| ES (1) | ES2245798T3 (enExample) |
| TW (1) | TW408151B (enExample) |
Families Citing this family (64)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PT1233037E (pt) * | 1999-01-26 | 2006-12-29 | Huntsman Int Llc | Poliuretanos termoplásticos |
| US20030060110A1 (en) * | 1999-12-24 | 2003-03-27 | Desai Dilipkumar R. | Expanded extruded polymeric textile |
| CN1321800C (zh) * | 1999-12-24 | 2007-06-20 | 亨茨曼国际有限公司 | 气助注塑 |
| DE50008414D1 (de) * | 2000-04-11 | 2004-12-02 | Siempelkamp Handling Sys Gmbh | Herstellung schaumgefüllter Sandwichelemente mit Schaumauftrag in Kassetten |
| US6682555B2 (en) * | 2000-11-13 | 2004-01-27 | Wit Ip Corporation | Methods for treating the prostate and inhibiting obstruction of the prostatic urethra using biodegradable stents |
| HUP0400742A3 (en) | 2000-12-21 | 2008-03-28 | Dow Global Technologies Inc | Polymer foam and blowing agents compositions containing hydrofluorocarbons and a low-boiling alcohol and/or low-boiling carbonyl compound and process for making them and foamable composition |
| KR20030064859A (ko) | 2000-12-21 | 2003-08-02 | 다우 글로벌 테크놀로지스 인크. | 표준 액상 하이드로플루오로카본과 이산화탄소를 함유하는발포제 조성물 및 중합체성 포움 |
| US7378454B2 (en) * | 2001-04-09 | 2008-05-27 | Toyo Tire & Rubber Co., Ltd. | Polyurethane composition and polishing pad |
| MXPA03010759A (es) * | 2001-05-25 | 2005-09-08 | Univ Lehigh | Microesferas expandibles para aislamiento de espuma y metodos. |
| DE10129232A1 (de) | 2001-06-19 | 2003-01-02 | Basf Ag | Verfahren zur Herstellung von syntaktischen Polyurethan |
| CN100348663C (zh) * | 2001-11-02 | 2007-11-14 | 日本皇冠塞株式会社 | 具有优异的安全性且环保的盖用密封件和金属盖 |
| US7199168B2 (en) * | 2002-02-13 | 2007-04-03 | Bayer Materialscience Llc | Process for making cellular composites using polymeric isocyanates as binders for hollow filler particles |
| JP2003292889A (ja) * | 2002-04-08 | 2003-10-15 | Fujikura Kasei Co Ltd | 発泡性塗料組成物および発泡塗膜を備えた塗装品ならびに発泡塗膜の形成方法 |
| US6913517B2 (en) * | 2002-05-23 | 2005-07-05 | Cabot Microelectronics Corporation | Microporous polishing pads |
| US20040171339A1 (en) * | 2002-10-28 | 2004-09-02 | Cabot Microelectronics Corporation | Microporous polishing pads |
| US6706776B2 (en) | 2002-06-18 | 2004-03-16 | Bayer Corporation | Syntactic foams with improved water resistance, long pot life and short demolding times |
| DE10358371A1 (de) | 2003-12-11 | 2005-07-28 | Basf Ag | Syntaktisches Polyurethan, enthaltend Öl, bevorzugt Ricinusöl |
| DE10358368A1 (de) | 2003-12-11 | 2005-07-07 | Basf Ag | Syntaktische Polyurethane und deren Verwendung zur Off-Shore-Dämmung |
| DE102004010809A1 (de) * | 2004-03-05 | 2005-09-22 | Bayer Materialscience Ag | Flexible Formteile aus geschäumtem Polyurethan und ihre Verwendung |
| KR101009313B1 (ko) * | 2004-05-28 | 2011-01-18 | 알베마를 코포레이션 | 난연제 폴리우레탄 및 그를 위한 첨가제 |
| JP2006022139A (ja) * | 2004-07-06 | 2006-01-26 | Takao Kawai | 微細空洞を有する発泡ポリウレタン及びその製造方法 |
| ITRM20050125A1 (it) * | 2005-03-18 | 2006-09-19 | Aviointeriors S P A | Schiuma poliuretanica con migliorate proprieta' e struttura imbottita realizzata con detta schiuma. |
| ITVA20050025A1 (it) * | 2005-04-15 | 2006-10-16 | Whirlpool Co | Procedimento per la produzione di materiali polimerici espansi e materiale polimerico espanso ottenuto mediante tale procedimento |
| US20070021518A1 (en) * | 2005-07-21 | 2007-01-25 | Lear Corporation | Additives to spray urethane |
| CN100381500C (zh) * | 2006-03-02 | 2008-04-16 | 海洋化工研究院 | 微珠/泡孔复合结构浮力材料 |
| WO2007112104A2 (en) * | 2006-03-24 | 2007-10-04 | Century-Board Usa, Llc | Polyurethane composite materials |
| CN100378166C (zh) * | 2006-04-08 | 2008-04-02 | 海洋化工研究院 | 深海用可加工固体浮力材料及其制备方法 |
| EP1884358B1 (de) * | 2006-08-01 | 2009-03-11 | Epurex Films GmbH & Co. KG | Verfahren zur Herstellung von Mehrschichtfolien aus thermoplastischen Polyurethanen |
| US8445101B2 (en) | 2007-03-21 | 2013-05-21 | Ashtech Industries, Llc | Sound attenuation building material and system |
| US20090239429A1 (en) | 2007-03-21 | 2009-09-24 | Kipp Michael D | Sound Attenuation Building Material And System |
| MX367591B (es) | 2007-03-21 | 2019-08-27 | Ash Tech Ind L L C | Materiales utilitarios que incorporan una matriz de micropartículas. |
| DE102007015660A1 (de) * | 2007-03-31 | 2008-10-02 | Brugg Rohr Ag, Holding | Flexibles wärmeisoliertes Leitungsrohr |
| EP2283089B1 (en) * | 2008-05-27 | 2013-11-20 | Philips Intellectual Property & Standards GmbH | High-voltage generator with a rigid foam material |
| US20100028650A1 (en) * | 2008-07-31 | 2010-02-04 | Nhk Spring Co., Ltd. | Closed-cell urethane sheet, manufacturing method thereof and waterproof sealing materials |
| WO2010022895A1 (de) * | 2008-08-27 | 2010-03-04 | Bayer Materialscience Ag | Viskoelastische polyurethan- und polyisocyanurat-hartschaumstoffe |
| US8591677B2 (en) | 2008-11-04 | 2013-11-26 | Ashtech Industries, Llc | Utility materials incorporating a microparticle matrix formed with a setting agent |
| KR20120117784A (ko) | 2009-11-20 | 2012-10-24 | 바스프 에스이 | 마이크로비드 함유 수지 발포체 |
| KR101231023B1 (ko) * | 2009-11-26 | 2013-02-07 | 제일모직주식회사 | 단열성이 우수한 경질 폴리우레탄 폼 및 그 제조방법 |
| JP5566851B2 (ja) * | 2010-03-04 | 2014-08-06 | 日東電工株式会社 | 熱発泡性樹脂組成物、熱発泡性樹脂シート、熱発泡性積層体、発泡体およびその製造方法 |
| KR101332433B1 (ko) | 2010-08-24 | 2013-11-22 | 제일모직주식회사 | 단열성이 우수한 경질 폴리우레탄 폼 및 그 제조방법 |
| US8937106B2 (en) | 2010-12-07 | 2015-01-20 | Basf Se | Melamine resin foams with nanoporous fillers |
| KR20140040271A (ko) * | 2011-07-19 | 2014-04-02 | 존슨 컨트롤스 테크놀러지 컴퍼니 | 폼 보강된 구조 부재 |
| DE102011083017A1 (de) | 2011-09-20 | 2013-03-21 | Evonik Industries Ag | Verbundwerkstoffe umfassend eine offenzellige Polymermatrix und darin eingebettete Granulate |
| DE102011083011A1 (de) * | 2011-09-20 | 2013-03-21 | Evonik Goldschmidt Gmbh | Verbundwerkstoffe umfassend eine Polymermatrix und darin eingebetteteGranulate |
| AU2012318528A1 (en) | 2011-10-07 | 2014-05-22 | Boral Ip Holdings (Australia) Pty Limited | Inorganic polymer/organic polymer composites and methods of making same |
| EP2657280A1 (de) * | 2012-04-23 | 2013-10-30 | Basf Se | Mineralstoffpartikel enthaltender Polyurethan-Verbundwerkstoff |
| US8883869B2 (en) * | 2012-08-08 | 2014-11-11 | Provee Technologies, Llc | Impact absorbing foam |
| CN103240884B (zh) * | 2013-05-07 | 2015-07-15 | 西北工业大学 | 具有双峰分布的聚碳酸酯微孔材料的制备方法 |
| US9752015B2 (en) | 2014-08-05 | 2017-09-05 | Boral Ip Holdings (Australia) Pty Limited | Filled polymeric composites including short length fibers |
| GB201420055D0 (en) * | 2014-11-11 | 2014-12-24 | Technion Res & Dev Foundation | Low density micropsheres |
| JP5828950B1 (ja) * | 2014-11-21 | 2015-12-09 | サンユレック株式会社 | ポリウレタン樹脂組成物、封止材及び電気電子部品 |
| US9988512B2 (en) | 2015-01-22 | 2018-06-05 | Boral Ip Holdings (Australia) Pty Limited | Highly filled polyurethane composites |
| US10030126B2 (en) | 2015-06-05 | 2018-07-24 | Boral Ip Holdings (Australia) Pty Limited | Filled polyurethane composites with lightweight fillers |
| WO2016201285A1 (en) * | 2015-06-12 | 2016-12-15 | 3M Innovative Properties Company | Buoyancy module |
| US20170267585A1 (en) | 2015-11-12 | 2017-09-21 | Amitabha Kumar | Filled polyurethane composites with size-graded fillers |
| US11283186B2 (en) | 2016-03-25 | 2022-03-22 | Commscope Technologies Llc | Antennas having lenses formed of lightweight dielectric materials and related dielectric materials |
| US11431100B2 (en) * | 2016-03-25 | 2022-08-30 | Commscope Technologies Llc | Antennas having lenses formed of lightweight dielectric materials and related dielectric materials |
| AT518807B1 (de) * | 2016-06-21 | 2018-07-15 | Rainer Kurbos Dr | Diskoschaum |
| DE102017206542A1 (de) * | 2017-04-19 | 2018-10-25 | Bayerische Motoren Werke Aktiengesellschaft | Herstellungsverfahren für ein Faserverbundbauteil |
| CN111095674B (zh) | 2017-09-15 | 2022-02-18 | 康普技术有限责任公司 | 制备复合介电材料的方法 |
| DE102017216409B4 (de) * | 2017-09-15 | 2022-01-05 | Weberit Werke Dräbing Gmbh | Kunststoffbauteil, druckfederführungselement und zweimassenschwungrad |
| EP3587465A1 (en) * | 2018-06-27 | 2020-01-01 | Solvay Sa | Process for the preparation of a polyurethane foam |
| CN113061284B (zh) * | 2021-03-24 | 2023-03-14 | 中国科学院深圳先进技术研究院 | 一种轻质有机复合材料及其制备方法 |
| US20240317960A1 (en) * | 2023-03-23 | 2024-09-26 | Natural Polymers, LLC | Polyisocyanurate/polyurethane foam compositions and related methods |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1200063A (en) * | 1966-12-01 | 1970-07-29 | Minnesota Mining & Mfg | Nailable polyurethane resins |
| US3510392A (en) * | 1968-09-16 | 1970-05-05 | Pittsburgh Corning Corp | Glass nodules in cellular polyurethane |
| US4038238A (en) * | 1973-08-29 | 1977-07-26 | The Dow Chemical Company | Low density rapid-setting polyurethanes |
| US4082702A (en) * | 1975-09-18 | 1978-04-04 | Dow Corning Corporation | Flame retardant rigid polyurethane syntactic foam |
| US4303736A (en) * | 1979-07-20 | 1981-12-01 | Leonard Torobin | Hollow plastic microspheres |
| US4303729A (en) * | 1979-07-20 | 1981-12-01 | Torobin Leonard B | Hollow plastic microspheres |
| US4843104A (en) * | 1987-03-19 | 1989-06-27 | Pierce & Stevens | Syntactic polymer foam compositions containing microsphere fillers |
| US4722943A (en) * | 1987-03-19 | 1988-02-02 | Pierce & Stevens Corporation | Composition and process for drying and expanding microspheres |
| US4902722A (en) * | 1987-11-19 | 1990-02-20 | Pierce & Stevens Corp. | Expandable graphic art printing media using a syntactic foam based on mixture of unexpanded and expanded hollow polymeric microspheres |
| US4916173A (en) * | 1988-05-06 | 1990-04-10 | Ciba-Geigy Corporation | Polyurethane syntactic foam modeling stock |
| US4959395A (en) * | 1988-06-28 | 1990-09-25 | The B. F. Goodrich Company | Bulk polymerized molded products containing cycloolefin monoments with microencapsulated blowing agents |
| JPH04257429A (ja) * | 1991-02-08 | 1992-09-11 | Oji Paper Co Ltd | シート状発泡体の製造方法 |
-
1998
- 1998-06-09 CA CA002239950A patent/CA2239950C/en not_active Expired - Fee Related
- 1998-07-20 TW TW087111759A patent/TW408151B/zh not_active IP Right Cessation
- 1998-07-29 ES ES98114186T patent/ES2245798T3/es not_active Expired - Lifetime
- 1998-07-29 EP EP98114186A patent/EP0896976B1/en not_active Expired - Lifetime
- 1998-07-29 AT AT98114186T patent/ATE300579T1/de not_active IP Right Cessation
- 1998-07-29 DE DE69830955T patent/DE69830955T2/de not_active Expired - Fee Related
- 1998-07-29 DK DK98114186T patent/DK0896976T3/da active
- 1998-08-07 CN CN98116227A patent/CN1088005C/zh not_active Expired - Fee Related
- 1998-08-10 JP JP10236604A patent/JPH11140219A/ja active Pending
- 1998-09-23 US US09/159,014 patent/US6166109A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2245798T3 (es) | 2006-01-16 |
| JPH11140219A (ja) | 1999-05-25 |
| DK0896976T3 (da) | 2005-10-10 |
| US6166109A (en) | 2000-12-26 |
| DE69830955D1 (de) | 2005-09-01 |
| CA2239950A1 (en) | 1999-02-11 |
| CN1088005C (zh) | 2002-07-24 |
| ATE300579T1 (de) | 2005-08-15 |
| HK1021519A1 (en) | 2000-06-16 |
| CN1223927A (zh) | 1999-07-28 |
| DE69830955T2 (de) | 2006-04-20 |
| EP0896976A1 (en) | 1999-02-17 |
| EP0896976B1 (en) | 2005-07-27 |
| TW408151B (en) | 2000-10-11 |
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