CA2226366A1 - Novel battery and method for producing the same - Google Patents
Novel battery and method for producing the sameInfo
- Publication number
- CA2226366A1 CA2226366A1 CA002226366A CA2226366A CA2226366A1 CA 2226366 A1 CA2226366 A1 CA 2226366A1 CA 002226366 A CA002226366 A CA 002226366A CA 2226366 A CA2226366 A CA 2226366A CA 2226366 A1 CA2226366 A1 CA 2226366A1
- Authority
- CA
- Canada
- Prior art keywords
- battery
- negative electrode
- positive electrode
- porous separator
- layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title 1
- 239000002245 particle Substances 0.000 abstract 2
- 239000011149 active material Substances 0.000 abstract 1
- 239000006183 anode active material Substances 0.000 abstract 1
- 239000006182 cathode active material Substances 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 150000002500 ions Chemical class 0.000 abstract 1
- 239000011148 porous material Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/411—Organic material
- H01M50/414—Synthetic resins, e.g. thermoplastics or thermosetting resins
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/431—Inorganic material
- H01M50/434—Ceramics
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/443—Particulate material
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/409—Separators, membranes or diaphragms characterised by the material
- H01M50/449—Separators, membranes or diaphragms characterised by the material having a layered structure
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/491—Porosity
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/489—Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M50/497—Ionic conductivity
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
- Y10T29/49115—Electric battery cell making including coating or impregnating
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Cell Separators (AREA)
- Primary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
Disclosed is a battery comprising a positive electrode comprising a cathode active material layer, a negative electrode comprising an anode active material layer, and a porous separator disposed between the positive electrode and the negative electrode, wherein the positive electrode, the negative electrode and the separator are disposed in a casing containing an elec- trolyte, and wherein the porous separator comprises at least one layer of an aggregate form of particles of at least one insulating substance, the layer of the ag- gregate form of particles having a three-dimensional network of voids which function as pores of the porous separator and which are capable of passing ions there- through. The battery of the present invention is advantageous not only in that the battery exhibits excellent discharge characteristics even at a high discharge current density without sacrificing safety, but also in that a large amount of active materials can be accommodated in the battery per unit volume thereof, as compared to the amounts in the case of conventional batteries, so that the battery can exhibit a high performance.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP21903695 | 1995-08-28 | ||
| JP7-219036 | 1995-08-28 | ||
| PCT/JP1996/002414 WO1997008763A1 (en) | 1995-08-28 | 1996-08-28 | Cell and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2226366A1 true CA2226366A1 (en) | 1997-03-06 |
| CA2226366C CA2226366C (en) | 2002-05-21 |
Family
ID=16729257
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002226366A Expired - Lifetime CA2226366C (en) | 1995-08-28 | 1996-08-28 | Novel battery and method for producing the same |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6287720B1 (en) |
| EP (1) | EP0848435B1 (en) |
| JP (1) | JP3253632B2 (en) |
| KR (1) | KR100289973B1 (en) |
| CN (1) | CN1134078C (en) |
| CA (1) | CA2226366C (en) |
| DE (1) | DE69637084T2 (en) |
| TW (1) | TW411636B (en) |
| WO (1) | WO1997008763A1 (en) |
Families Citing this family (134)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5882721A (en) * | 1997-05-01 | 1999-03-16 | Imra America Inc | Process of manufacturing porous separator for electrochemical power supply |
| FR2766969B1 (en) * | 1997-08-04 | 1999-09-24 | Alsthom Cge Alcatel | BINDER FOR NON-AQUEOUS ELECTROCHEMICAL ELECTROCHEMICAL ELECTRODE |
| EP0954042B1 (en) * | 1997-11-19 | 2007-09-05 | Mitsubishi Denki Kabushiki Kaisha | Lithium ion secondary battery and manufacture thereof |
| US6811928B2 (en) * | 1998-01-22 | 2004-11-02 | Mitsubishi Denki Kabushiki Kaisha | Battery with adhesion resin layer including filler |
| JP4031405B2 (en) * | 1998-09-17 | 2008-01-09 | 株式会社東芝 | Non-aqueous electrolyte secondary battery |
| US6451484B1 (en) * | 1999-04-21 | 2002-09-17 | Samsung Sdi Co., Ltd. | Lithium secondary battery and manufacturing method thereof |
| JP4664455B2 (en) * | 1999-05-11 | 2011-04-06 | 株式会社東芝 | Non-aqueous electrolyte secondary battery |
| US20020102456A1 (en) * | 1999-09-20 | 2002-08-01 | Mitsubishi Denki Kabushiki Kaisha | Battery |
| US20030170536A1 (en) * | 1999-09-22 | 2003-09-11 | Mitsubishi Denki Kabushiki Kaisha | Bttery with adhesion resin layer including filler |
| US6432586B1 (en) | 2000-04-10 | 2002-08-13 | Celgard Inc. | Separator for a high energy rechargeable lithium battery |
| EP1291952A1 (en) * | 2000-06-07 | 2003-03-12 | Gs-Melcotec Co.; Ltd. | Battery |
| US6488721B1 (en) | 2000-06-09 | 2002-12-03 | Moltech Corporation | Methods of preparing electrochemical cells |
| JP4754092B2 (en) * | 2000-06-30 | 2011-08-24 | パナソニック株式会社 | Battery electrode plate, method for producing the same, and non-aqueous electrolyte secondary battery using the same |
| KR100362497B1 (en) * | 2000-10-19 | 2002-11-23 | 베스 주식회사 | Porous polymeric electrolyte and method for making the same |
| US7387851B2 (en) * | 2001-07-27 | 2008-06-17 | A123 Systems, Inc. | Self-organizing battery structure with electrode particles that exert a repelling force on the opposite electrode |
| KR101249133B1 (en) * | 2000-10-20 | 2013-04-02 | 매사츄세츠 인스티튜트 오브 테크놀러지 | Bipolar device |
| US6727017B1 (en) * | 2001-04-06 | 2004-04-27 | Changs Ascending Enterprise Co., Ltd. | Methods of fabricating binding layers for a Li-ion polymer battery |
| WO2003012908A2 (en) | 2001-07-27 | 2003-02-13 | Massachusetts Institute Of Technology | Battery structures, self-organizing structures and related methods |
| JP4228177B2 (en) * | 2002-04-24 | 2009-02-25 | 日本電気株式会社 | Secondary battery and battery using the same |
| KR100467455B1 (en) | 2002-07-10 | 2005-01-24 | 삼성에스디아이 주식회사 | Positive active material composition for lithium sulfur battery and lithium sulfur battery fabricated using binder |
| WO2004012286A1 (en) | 2002-07-26 | 2004-02-05 | A123 Systems, Inc. | Bipolar articles and related methods |
| DE10238943B4 (en) * | 2002-08-24 | 2013-01-03 | Evonik Degussa Gmbh | Separator-electrode unit for lithium-ion batteries, method for their production and use in lithium batteries and a battery, comprising the separator-electrode unit |
| CN1732587B (en) * | 2002-12-27 | 2010-10-06 | 松下电器产业株式会社 | Electrochemical element and its manufacturing method |
| JP2004342329A (en) * | 2003-05-12 | 2004-12-02 | Nippon Paint Co Ltd | Coating method of insulated wire having edge portion and insulated wire |
| US7396612B2 (en) * | 2003-07-29 | 2008-07-08 | Matsushita Electric Industrial Co., Ltd. | Lithium ion secondary battery |
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| EP1661195B1 (en) * | 2003-08-18 | 2016-01-13 | PowerGenix Systems, Inc. | Method of manufacturing nickel zinc batteries |
| AU2003264403A1 (en) * | 2003-09-10 | 2005-04-06 | Mitsubishi Plastics, Inc. | Fuel cell separator |
| JP4439226B2 (en) * | 2003-09-11 | 2010-03-24 | 日立マクセル株式会社 | Nonaqueous electrolyte secondary battery |
| KR100611940B1 (en) * | 2003-11-21 | 2006-08-11 | 주식회사 엘지화학 | Improved safety electrochemical cell |
| JP3953026B2 (en) * | 2003-12-12 | 2007-08-01 | 松下電器産業株式会社 | Electrode plate for lithium ion secondary battery, lithium ion secondary battery and method for producing the same |
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| JP4649862B2 (en) * | 2004-04-02 | 2011-03-16 | パナソニック株式会社 | Lithium ion secondary battery and manufacturing method thereof |
| JP4794824B2 (en) * | 2004-04-05 | 2011-10-19 | パナソニック株式会社 | Lithium ion secondary battery and manufacturing method thereof |
| JP4781263B2 (en) * | 2004-06-22 | 2011-09-28 | パナソニック株式会社 | Secondary battery and manufacturing method thereof |
| KR100635761B1 (en) * | 2004-06-25 | 2006-10-17 | 삼성에스디아이 주식회사 | Electrode assembly and secondary battery using same |
| ES3010715T3 (en) | 2004-07-07 | 2025-04-04 | Lg Energy Solution Ltd | New organic/inorganic composite porous film and electrochemical device prepared thereby |
| EP1784876B1 (en) | 2004-09-02 | 2018-01-24 | LG Chem, Ltd. | Organic/inorganic composite porous film and electrochemical device prepared thereby |
| TWI318018B (en) * | 2004-09-02 | 2009-12-01 | Lg Chemical Ltd | Organic/inorganic composite porous film and electrochemical device prepared thereby |
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| US11050095B2 (en) * | 2004-12-08 | 2021-06-29 | Maxell Holdings, Ltd. | Separator for electrochemical device, and electrochemical device |
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- 1996-08-28 CA CA002226366A patent/CA2226366C/en not_active Expired - Lifetime
- 1996-08-28 TW TW085110568A patent/TW411636B/en not_active IP Right Cessation
- 1996-08-28 KR KR1019980700279A patent/KR100289973B1/en not_active Expired - Fee Related
- 1996-08-28 JP JP51012497A patent/JP3253632B2/en not_active Expired - Lifetime
- 1996-08-28 CN CNB961955961A patent/CN1134078C/en not_active Expired - Lifetime
- 1996-08-28 WO PCT/JP1996/002414 patent/WO1997008763A1/en not_active Ceased
- 1996-08-28 US US08/981,092 patent/US6287720B1/en not_active Expired - Lifetime
- 1996-08-28 DE DE69637084T patent/DE69637084T2/en not_active Expired - Lifetime
- 1996-08-28 EP EP96928681A patent/EP0848435B1/en not_active Expired - Lifetime
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| JP3253632B2 (en) | 2002-02-04 |
| EP0848435A1 (en) | 1998-06-17 |
| US6287720B1 (en) | 2001-09-11 |
| KR100289973B1 (en) | 2001-05-15 |
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| EP0848435B1 (en) | 2007-05-16 |
| EP0848435A4 (en) | 2004-08-04 |
| KR19990028977A (en) | 1999-04-15 |
| DE69637084D1 (en) | 2007-06-28 |
| CN1134078C (en) | 2004-01-07 |
| DE69637084T2 (en) | 2008-02-07 |
| CA2226366C (en) | 2002-05-21 |
| TW411636B (en) | 2000-11-11 |
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