CA2209324C - Vdf polymerization process - Google Patents

Vdf polymerization process Download PDF

Info

Publication number
CA2209324C
CA2209324C CA002209324A CA2209324A CA2209324C CA 2209324 C CA2209324 C CA 2209324C CA 002209324 A CA002209324 A CA 002209324A CA 2209324 A CA2209324 A CA 2209324A CA 2209324 C CA2209324 C CA 2209324C
Authority
CA
Canada
Prior art keywords
polymerization process
molecular weight
process according
vdf
end groups
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002209324A
Other languages
English (en)
French (fr)
Other versions
CA2209324A1 (en
Inventor
Giulio Brinati
Paolo Lazzari
Vincenzo Arcella
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Syensqo Specialty Polymers Italy SpA
Original Assignee
Ausimont SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ausimont SpA filed Critical Ausimont SpA
Publication of CA2209324A1 publication Critical patent/CA2209324A1/en
Application granted granted Critical
Publication of CA2209324C publication Critical patent/CA2209324C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F14/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F14/18Monomers containing fluorine
    • C08F14/22Vinylidene fluoride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00Processes of polymerisation
    • C08F2/12Polymerisation in non-solvents
    • C08F2/16Aqueous medium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
CA002209324A 1996-07-01 1997-06-30 Vdf polymerization process Expired - Fee Related CA2209324C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IT96MI001342A IT1295535B1 (it) 1996-07-01 1996-07-01 Processo di polimerizzazione di vinilidenfluoruro (vdf)
ITMI96A001342 1996-07-01

Publications (2)

Publication Number Publication Date
CA2209324A1 CA2209324A1 (en) 1998-01-01
CA2209324C true CA2209324C (en) 2008-09-16

Family

ID=11374511

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002209324A Expired - Fee Related CA2209324C (en) 1996-07-01 1997-06-30 Vdf polymerization process

Country Status (9)

Country Link
US (1) US7122608B1 (https=)
EP (1) EP0816397B1 (https=)
JP (1) JPH1060054A (https=)
KR (1) KR100476078B1 (https=)
CN (1) CN1103785C (https=)
CA (1) CA2209324C (https=)
DE (1) DE69704040T2 (https=)
IT (1) IT1295535B1 (https=)
RU (1) RU2184744C2 (https=)

Families Citing this family (68)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITMI981519A1 (it) 1998-07-02 2000-01-02 Ausimont Spa Processodi polimerizzazione del tfe
IT1307756B1 (it) 1999-02-05 2001-11-19 Ausimont Spa Polimeri elettroliti per batterie ricaricabili al litio.
ITMI991516A1 (it) * 1999-07-09 2001-01-09 Ausimont Spa Sintesi dei copolimeri peralogenati termoprocesabili del clorotrifluoroetilene
US6677414B2 (en) 1999-12-30 2004-01-13 3M Innovative Properties Company Aqueous emulsion polymerization process for the manufacturing of fluoropolymers
US7279522B2 (en) 2001-09-05 2007-10-09 3M Innovative Properties Company Fluoropolymer dispersions containing no or little low molecular weight fluorinated surfactant
EP1364972B1 (en) 2002-05-22 2006-08-30 3M Innovative Properties Company Process for reducing the amount of fluorinated surfactant in aqueous fluoropolymer dispersions
US6812310B2 (en) * 2002-06-21 2004-11-02 3M Innovative Properties Company Process for producing fluoropolymers having a reduced amount of polar end groups
DE60301322T2 (de) 2003-02-28 2006-06-08 3M Innovative Properties Co., St. Paul Fluoropolymerdispersion enthaltend kein oder wenig fluorhaltiges Netzmittel mit niedrigem Molekulargewicht
FR2852016B1 (fr) 2003-03-03 2006-07-07 Atofina Procede de fabrication de pvdf thermiquement stable
FR2852017B1 (fr) 2003-03-03 2005-04-22 Atofina Procede de fabrication de pvdf thermiquement stable
US6841616B2 (en) 2003-03-28 2005-01-11 Arkema Inc. Polymerization of halogen-containing monomers using siloxane surfactant
US6869997B2 (en) 2003-05-06 2005-03-22 Arkema, Inc. Polymerization of fluoromonomers using a 3-allyloxy-2-hydroxy-1-propanesulfonic acid salt as surfactant
ATE502062T1 (de) 2003-10-24 2011-04-15 3M Innovative Properties Co Wässrige dispersionen von polytetrafluorethylenteilchen
EP1533325B1 (en) 2003-11-17 2011-10-19 3M Innovative Properties Company Aqueous dispersions of polytetrafluoroethylene having a low amount of fluorinated surfactant
EP1561742B1 (en) 2004-02-05 2012-11-21 3M Innovative Properties Company Method of recovering fluorinated acid surfactants from adsorbent particles loaded therewith
EP1561729A1 (en) 2004-02-05 2005-08-10 3M Innovative Properties Company Removal of fluorinated surfactants from waste water
US7122610B2 (en) * 2004-04-27 2006-10-17 Arkema Inc. Method of producing thermoplastic fluoropolymers using alkyl sulfonate surfactants
EP1614731B1 (en) 2004-07-05 2008-08-27 3M Innovative Properties Company Primer coating of PTFE for metal substrates
JP2006036986A (ja) * 2004-07-28 2006-02-09 Asahi Glass Co Ltd 含フッ素ポリマーラテックス、その製造方法および含フッ素ポリマー
ITMI20050007A1 (it) * 2005-01-05 2006-07-06 Solvay Solexis Spa Uso di dispersioni acquose di polimeri a base di vdf nella preparazione di vernici per rivestimenti di substrati architettonici
DE602005005317T2 (de) 2005-07-07 2009-03-12 Solvay Solexis S.P.A. Polymerisationsverfahren
EP1743921A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic halopolymer composition
EP1743920A1 (en) 2005-07-13 2007-01-17 Solvay Solexis S.p.A. Thermoplastic fluoropolymer composition
US7671112B2 (en) 2005-07-15 2010-03-02 3M Innovative Properties Company Method of making fluoropolymer dispersion
GB0514398D0 (en) 2005-07-15 2005-08-17 3M Innovative Properties Co Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
GB0525978D0 (en) 2005-12-21 2006-02-01 3M Innovative Properties Co Fluorinated Surfactants For Making Fluoropolymers
GB0523853D0 (en) 2005-11-24 2006-01-04 3M Innovative Properties Co Fluorinated surfactants for use in making a fluoropolymer
US20080015304A1 (en) 2006-07-13 2008-01-17 Klaus Hintzer Aqueous emulsion polymerization process for producing fluoropolymers
US7728087B2 (en) 2005-12-23 2010-06-01 3M Innovative Properties Company Fluoropolymer dispersion and method for making the same
US7754795B2 (en) 2006-05-25 2010-07-13 3M Innovative Properties Company Coating composition
US8119750B2 (en) 2006-07-13 2012-02-21 3M Innovative Properties Company Explosion taming surfactants for the production of perfluoropolymers
ATE510857T1 (de) * 2006-11-09 2011-06-15 Du Pont Wässrige polymerisation eines fluorinierten monomers mithilfe eines polymerisationsmittels mit einer fluorpolyethersäure oder einem salz daraus und einem kurzkettigen fluortensid
EP2084195B1 (en) * 2006-11-09 2011-06-08 E.I. Du Pont De Nemours And Company Aqueous polymerization of fluorinated monomers using polymerization agent comprising fluoropolyether acid or salt and hydrocarbon surfactant
KR20100017848A (ko) 2007-05-23 2010-02-16 쓰리엠 이노베이티브 프로퍼티즈 컴파니 플루오르화 계면활성제의 수성 조성물 및 그의 사용 방법
WO2008154345A1 (en) 2007-06-06 2008-12-18 3M Innovative Properties Company Fluorinated ether compositions and methods of using the same
CN101274969B (zh) * 2007-11-20 2010-12-29 山东东岳神舟新材料有限公司 一种含氟聚合物的微乳液聚合方法
US20090281261A1 (en) * 2008-05-09 2009-11-12 E. I. Du Pont De Nemours And Company Abatement of Fluoroether Carboxylic Acids or Salts Employed in Fluoropolymer Resin Manufacture
EP2133370A1 (en) 2008-06-02 2009-12-16 Solvay Solexis S.p.A. Vinylidene fluoride and trifluoroethylene containing polymers
BRPI0915955A2 (pt) 2008-07-18 2019-02-26 3M Innovative Proferties Company compostos fluorados de éter e métodos para uso dos mesmos
US8629089B2 (en) 2008-12-18 2014-01-14 3M Innovative Properties Company Method of contacting hydrocarbon-bearing formations with fluorinated ether compositions
EP2370527B1 (en) 2008-12-31 2012-10-24 Essilor International (Compagnie Générale D'Optique) Additives for enhancing the antistatic properties of conductive polymer-based coatings
EP2248865A1 (en) 2009-05-07 2010-11-10 Essilor International (Compagnie Générale D'Optique) Antistatic sol/gel compositions and optical articles coated therewith
US8329813B2 (en) 2009-05-08 2012-12-11 E I Du Pont De Nemours And Company Thermal reduction of fluoroether carboxylic acids or salts from fluoropolymer dispersions
CN102822213B (zh) * 2009-12-18 2016-06-15 索尔维特殊聚合物意大利有限公司 制造偏二氟乙烯聚合物分散体的方法
JP5684283B2 (ja) 2009-12-18 2015-03-11 ソルヴェイ・スペシャルティ・ポリマーズ・イタリー・エッセ・ピ・ア フルオロポリマーの製造方法
EP2450193B1 (en) 2010-11-09 2015-05-06 ESSILOR INTERNATIONAL (Compagnie Générale d'Optique) A process for tinting articles, and tintable compositions for use in said process
CN103270060B (zh) 2010-12-22 2016-02-24 索尔维特殊聚合物意大利有限公司 偏二氟乙烯以及三氟乙烯聚合物
US9441054B2 (en) 2010-12-22 2016-09-13 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride copolymers
CN102225980B (zh) * 2011-04-29 2012-11-21 内蒙古三爱富万豪氟化工有限公司 一种含氟醚端基结构的聚偏氟乙烯树脂及其制备方法
MY165000A (en) 2011-07-15 2018-02-28 Solvay Specialty Polymers It Aqueous vinylidene fluoride polymer latex
US10081691B2 (en) 2011-12-16 2018-09-25 Solvay Specialty Polymers Italy S.P.A. Crosslinkable compositions based on vinylidene fluoride-trifluoroethylene polymers
SG11201402891XA (en) 2011-12-16 2014-08-28 Solvay Specialty Polymers It Crosslinkable vinylidene fluoride and trifluoroethylene polymers
CN103987738B (zh) 2011-12-16 2016-06-01 索尔维特殊聚合物意大利有限公司 氟烯丙基磺酰叠氮化物单体以及由此的聚合物
KR102348355B1 (ko) 2013-06-04 2022-01-10 솔베이 스페셜티 폴리머스 이태리 에스.피.에이. 플루오로중합체 복합재의 제조 방법
EP3110858B1 (en) 2014-02-28 2017-12-20 Solvay Specialty Polymers Italy S.p.A. Crosslinkable fluoropolymers
WO2015169836A1 (en) 2014-05-09 2015-11-12 Solvay Specialty Polymers Italy S.P.A. Fluoropolymer compositions
CN103936906B (zh) * 2014-05-09 2016-08-31 成都晨光博达橡塑有限公司 一种不含全氟辛酸或全氟辛磺酸的含氟聚合物
CN103936905B (zh) * 2014-05-09 2016-09-14 成都晨光博达橡塑有限公司 一种含氟聚合物及其制备方法
EP3145993B1 (en) 2014-05-19 2021-09-29 Arkema, Inc. High melt flow fluoropolymer composition
CN104448078A (zh) * 2014-12-08 2015-03-25 浙江孚诺林化工新材料有限公司 一种采用氟醚磺酸盐制备聚偏氟乙烯的方法
FR3043084B1 (fr) 2015-10-29 2017-10-27 Arkema France Copolymeres fluores fonctionnalises
WO2017173258A1 (en) 2016-04-01 2017-10-05 Arkema Inc. 3-d printed fluoropolymer structures
WO2018065306A1 (en) 2016-10-05 2018-04-12 Solvay Specialty Polymers Italy S.P.A. Vinylidene fluoride and trifluoroethylene containing polymers latexes
EP3645587B1 (en) 2017-06-30 2023-06-14 Solvay Specialty Polymers Italy S.p.A. Method for manufacturing partially fluorinated polymers
FR3069544B1 (fr) 2017-07-28 2020-05-15 Arkema France Procede de preparation d'un film de polymere fluore reticule
WO2019057682A1 (en) * 2017-09-20 2019-03-28 Solvay Specialty Polymers Italy S.P.A. POROUS MEMBRANE AND METHOD FOR MANUFACTURING THE SAME
CN109810212B (zh) * 2017-11-20 2020-05-01 中昊晨光化工研究院有限公司 一种高介电常数聚偏氟乙烯及其制备方法和应用
WO2021213868A1 (en) 2020-04-21 2021-10-28 Solvay Specialty Polymers Italy S.P.A. Aqueous dispersion of vinylidene fluoride and trifluoroethylene containing polymers

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IL82308A (en) * 1986-06-26 1990-11-29 Ausimont Spa Microemulsions containing perfluoropolyethers
IT1204903B (it) * 1986-06-26 1989-03-10 Ausimont Spa Processo di polimerizzazione in dispersione acquosa di monomeri florati
IT1265067B1 (it) * 1993-05-18 1996-10-30 Ausimont Spa Processo di (co)polimerizzazione in emulsione acquosa di monomeri olefinici fluorurati
IT1265033B1 (it) * 1993-05-28 1996-10-28 Ausimont Spa Polivinilidenfluoruro ad elevate prestazioni meccaniche ed elevata stabilita' termochimica, e relativo processo di preparazione
IT1271422B (it) * 1993-10-15 1997-05-28 Ausimont Spa Procedimento per la preparazione di copolimeri del tetrafluoroetilene con altri monomeri perfluorurati
IT1265223B1 (it) * 1993-11-25 1996-10-31 Ausimont Spa Processo per la preparazione di polimeri del vinilidenfluoruro

Also Published As

Publication number Publication date
IT1295535B1 (it) 1999-05-12
ITMI961342A0 (https=) 1996-07-01
ITMI961342A1 (it) 1998-01-01
EP0816397A1 (en) 1998-01-07
MX9704991A (es) 1998-06-28
JPH1060054A (ja) 1998-03-03
KR100476078B1 (ko) 2005-06-16
CA2209324A1 (en) 1998-01-01
DE69704040T2 (de) 2001-09-20
DE69704040D1 (de) 2001-03-15
CN1172122A (zh) 1998-02-04
RU2184744C2 (ru) 2002-07-10
EP0816397B1 (en) 2001-02-07
US7122608B1 (en) 2006-10-17
CN1103785C (zh) 2003-03-26
KR980009299A (ko) 1998-04-30

Similar Documents

Publication Publication Date Title
CA2209324C (en) Vdf polymerization process
EP1888655B1 (en) Aqueous emulsion polymerization of fluorinated monomers in the presence of a partially fluorinated oligomer as an emulsifier
JP5439186B2 (ja) フルオロポリエーテル酸または塩および炭化水素系界面活性剤を含む重合剤を用いるフッ素化モノマーの水性重合
EP1904538B1 (en) Aqueous emulsion polymerization of fluorinated monomers using a perfluoropolyether surfactant
EP1904539B1 (en) Aqueous emulsion polymerization of fluorinated monomers using a fluorinated surfactant
CN111040058B (zh) 聚四氟乙烯水性分散液的制造方法
JP7345454B2 (ja) フルオロポリマーを製造する方法
JP7382831B2 (ja) フルオロポリマーの粒子を含む水性ラテックスを製造する方法
EP0752432A2 (en) (Co)polymerization process in aqueous emulsion of fluorinated olefinic monomers
WO2018167189A1 (en) Method for making fluoropolymers
CN106414512B (zh) 含氟聚合物水性分散液的制造方法
WO2022163815A1 (ja) フルオロポリマー組成物の製造方法
EP2513171B1 (en) Method for manufacturing fluoropolymers
EP1833860B1 (en) Fluoroelastomers having low glass transition temperature
CN117362509A (zh) 一种超临界二氧化碳制备全氟醚弹性体的方法
EP1605011B1 (en) Granulated powder of low-molecular polytetrafluoro- ethylene and powder of low-molecular polytetrafluoro- ethylene and processes for producing both
MXPA97004991A (en) Procedure for polymerization of vinilid fluoride
JP2025093884A (ja) フルオロポリマー水性分散液
JP2538267C (https=)

Legal Events

Date Code Title Description
EEER Examination request
MKLA Lapsed