CA2158971A1 - High efficiency, hydrogen-driven cooling device - Google Patents
High efficiency, hydrogen-driven cooling deviceInfo
- Publication number
- CA2158971A1 CA2158971A1 CA002158971A CA2158971A CA2158971A1 CA 2158971 A1 CA2158971 A1 CA 2158971A1 CA 002158971 A CA002158971 A CA 002158971A CA 2158971 A CA2158971 A CA 2158971A CA 2158971 A1 CA2158971 A1 CA 2158971A1
- Authority
- CA
- Canada
- Prior art keywords
- heat
- working fluid
- reaction zone
- catalyst
- organic hydride
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 238000001816 cooling Methods 0.000 title claims abstract description 35
- 229910052739 hydrogen Inorganic materials 0.000 title description 3
- 239000001257 hydrogen Substances 0.000 title description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title description 2
- 239000012530 fluid Substances 0.000 claims abstract description 69
- 238000006243 chemical reaction Methods 0.000 claims abstract description 60
- 238000006356 dehydrogenation reaction Methods 0.000 claims abstract description 50
- 150000004678 hydrides Chemical class 0.000 claims abstract description 48
- 239000003054 catalyst Substances 0.000 claims abstract description 45
- 230000001143 conditioned effect Effects 0.000 claims abstract description 17
- 238000002485 combustion reaction Methods 0.000 claims abstract description 11
- 239000007789 gas Substances 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 29
- 238000000034 method Methods 0.000 claims description 21
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 16
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 15
- 229910052707 ruthenium Inorganic materials 0.000 claims description 11
- 229910052703 rhodium Inorganic materials 0.000 claims description 10
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052702 rhenium Inorganic materials 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 229910052741 iridium Inorganic materials 0.000 claims description 5
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 239000012528 membrane Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 claims description 2
- 238000000576 coating method Methods 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims 4
- 229910052760 oxygen Inorganic materials 0.000 claims 4
- 239000001301 oxygen Substances 0.000 claims 4
- 125000004429 atom Chemical group 0.000 claims 1
- 239000000047 product Substances 0.000 description 33
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Substances [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 9
- 239000002184 metal Substances 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 150000002739 metals Chemical class 0.000 description 6
- 239000007791 liquid phase Substances 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical group CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 4
- 239000012071 phase Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000002131 composite material Substances 0.000 description 3
- 229910001510 metal chloride Inorganic materials 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- 241000282320 Panthera leo Species 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 239000010419 fine particle Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- -1 methylcycloh.oY~nP Chemical compound 0.000 description 2
- 239000012279 sodium borohydride Substances 0.000 description 2
- 229910000033 sodium borohydride Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- 101100240353 Mus musculus Nectin4 gene Proteins 0.000 description 1
- YFONKFDEZLYQDH-OPQQBVKSSA-N N-[(1R,2S)-2,6-dimethyindan-1-yl]-6-[(1R)-1-fluoroethyl]-1,3,5-triazine-2,4-diamine Chemical compound C[C@@H](F)C1=NC(N)=NC(N[C@H]2C3=CC(C)=CC=C3C[C@@H]2C)=N1 YFONKFDEZLYQDH-OPQQBVKSSA-N 0.000 description 1
- 229910021604 Rhodium(III) chloride Inorganic materials 0.000 description 1
- 229910019891 RuCl3 Inorganic materials 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 150000001924 cycloalkanes Chemical class 0.000 description 1
- DIOQZVSQGTUSAI-NJFSPNSNSA-N decane Chemical compound CCCCCCCCC[14CH3] DIOQZVSQGTUSAI-NJFSPNSNSA-N 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 101150109949 endou gene Proteins 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000013529 heat transfer fluid Substances 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- DIOQZVSQGTUSAI-UHFFFAOYSA-N n-butylhexane Natural products CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- SONJTKJMTWTJCT-UHFFFAOYSA-K rhodium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Rh+3] SONJTKJMTWTJCT-UHFFFAOYSA-K 0.000 description 1
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- PXXNTAGJWPJAGM-UHFFFAOYSA-N vertaline Natural products C1C2C=3C=C(OC)C(OC)=CC=3OC(C=C3)=CC=C3CCC(=O)OC1CC1N2CCCC1 PXXNTAGJWPJAGM-UHFFFAOYSA-N 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B27/00—Machines, plants or systems, using particular sources of energy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
- C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
- C01B3/0015—Organic compounds; Solutions thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US035,812 | 1993-03-23 | ||
| US08/035,812 US5291735A (en) | 1993-03-23 | 1993-03-23 | High efficiency, hydrogen-driven cooling device |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2158971A1 true CA2158971A1 (en) | 1994-09-29 |
Family
ID=21884921
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002158971A Abandoned CA2158971A1 (en) | 1993-03-23 | 1993-11-15 | High efficiency, hydrogen-driven cooling device |
Country Status (10)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4410914C2 (de) * | 1994-03-29 | 1996-03-28 | Daimler Benz Aerospace Ag | Vorrichtung zum Abführen von Wärme |
| RU2159396C1 (ru) * | 1999-12-03 | 2000-11-20 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная система с регенерацией топлива |
| RU2168680C1 (ru) * | 2000-02-28 | 2001-06-10 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная установка |
| RU2166706C1 (ru) * | 2000-05-25 | 2001-05-10 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергохолодильная система |
| RU2169319C1 (ru) * | 2000-05-25 | 2001-06-20 | Военный инженерно-космический университет им. А.Ф. Можайского | Анаэробная энергоустановка с двигателем стирлинга и водородосодержащим топливом |
| US7186396B2 (en) * | 2003-11-26 | 2007-03-06 | Asemblon, Inc. | Method for hydrogen storage and delivery |
| US7181919B2 (en) * | 2004-03-31 | 2007-02-27 | Denso Corporation | System utilizing waste heat of internal combustion engine |
| US7574870B2 (en) * | 2006-07-20 | 2009-08-18 | Claudio Filippone | Air-conditioning systems and related methods |
| KR20110014590A (ko) * | 2008-04-17 | 2011-02-11 | 신크로니, 아이엔씨. | 저-손실 금속 회전자를 구비한 고속 영구자석 모터 및 발전기 |
| BRPI0907304A2 (pt) | 2008-04-18 | 2016-06-14 | Synchrony Inc | "máquina" |
| US9583991B2 (en) * | 2009-06-24 | 2017-02-28 | Synchrony, Inc. | Systems, devices, and/or methods for managing magnetic bearings |
| EP2586121B1 (en) | 2010-06-23 | 2019-12-11 | Synchrony, Inc. | Split magnetic thrust bearing |
| JP5602698B2 (ja) * | 2011-09-22 | 2014-10-08 | 株式会社日立製作所 | 動力変換システム |
| KR101360003B1 (ko) * | 2012-04-25 | 2014-02-24 | 한국수력원자력 주식회사 | 발열 및 흡열을 동시에 제어할 수 있는 수소저장용기 |
| KR101569677B1 (ko) | 2015-02-04 | 2015-11-17 | 한국기계연구원 | 고희박연소를 이용한 트라이젠 시스템 및 그 제어방법 |
| IT201700098472A1 (it) * | 2017-09-01 | 2019-03-01 | Angelantoni Test Tech S R L In Breve Att S R L | Dispositivo di refrigerazione. |
| US11697780B1 (en) * | 2018-01-18 | 2023-07-11 | Reaction Systems, Inc. | Decahydronaphthalene as an endothermic fuel for hypersonic vehicles |
| US11111448B1 (en) | 2018-01-18 | 2021-09-07 | Reaction Systems Inc. | Decahydronaphthalene as an endothermic fuel for hypersonic vehicles |
| FR3097218B1 (fr) * | 2019-06-14 | 2022-05-06 | Alagy Serge Zareh | Procede et systeme de recuperation d’energie pour dispositif consommateur de dihydrogene |
| WO2025016560A1 (en) * | 2023-07-19 | 2025-01-23 | Nuovo Pignone Tecnologie - S.R.L. | A process and a system of carbon oxides-free hydrogen production |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2034412B (en) * | 1978-09-20 | 1982-11-10 | Chatwin F | Combined gas and steam turbine engine |
| US4347711A (en) * | 1980-07-25 | 1982-09-07 | The Garrett Corporation | Heat-actuated space conditioning unit with bottoming cycle |
| US4346752A (en) * | 1981-01-19 | 1982-08-31 | United Technologies Corporation | Self-driven chemical heat pipe |
| US4476918A (en) * | 1982-06-28 | 1984-10-16 | United Technologies Corporation | Method and apparatus for a temperature-shifted chemical heat pipe |
| US4478814A (en) * | 1982-09-30 | 1984-10-23 | United Technologies Corporation | Gas transporting system |
| US4567033A (en) * | 1984-10-25 | 1986-01-28 | United Technologies Corporation | Low-energy method for freeing chemically bound hydrogen |
| US4614176A (en) * | 1985-10-23 | 1986-09-30 | United Technologies Corporation | Catalytic metal hydride space heater |
| EP0239680B1 (en) * | 1986-03-25 | 1990-12-12 | Mitsui Engineering and Shipbuilding Co, Ltd. | Heat pump |
| WO1987007360A1 (en) * | 1986-05-19 | 1987-12-03 | Yamato Kosan Co., Ltd. | Heat exchanging system |
| US4712610A (en) * | 1986-11-28 | 1987-12-15 | United Technologies Corporation | Chemical heat pipe employing self-driven chemical pump based on a molar increase |
| US4754607A (en) * | 1986-12-12 | 1988-07-05 | Allied-Signal Inc. | Power generating system |
| US4942733A (en) * | 1987-03-26 | 1990-07-24 | Sundstrand Corporation | Hot gas generator system |
| US4999993A (en) * | 1987-11-25 | 1991-03-19 | Fluor Corporation | Reactor expander topping cycle |
| US4850859A (en) * | 1988-09-30 | 1989-07-25 | United Technologies Corporation | Liquid fueled hydrogen heater |
| SE468910B (sv) * | 1989-04-18 | 1993-04-05 | Gen Electric | Kraftaggregat, vid vilket halten av skadliga foeroreningar i avgaserna minskas |
| US5129236A (en) * | 1990-09-06 | 1992-07-14 | Solomon Fred D | Heat pump system |
| US5136854A (en) * | 1991-01-25 | 1992-08-11 | Abdelmalek Fawzy T | Centrifugal gas compressor - expander for refrigeration |
-
1993
- 1993-03-23 US US08/035,812 patent/US5291735A/en not_active Expired - Fee Related
- 1993-11-15 WO PCT/US1993/011037 patent/WO1994021974A1/en active IP Right Grant
- 1993-11-15 BR BR9307828A patent/BR9307828A/pt not_active Application Discontinuation
- 1993-11-15 DE DE69314058T patent/DE69314058T2/de not_active Expired - Fee Related
- 1993-11-15 CA CA002158971A patent/CA2158971A1/en not_active Abandoned
- 1993-11-15 KR KR1019950704046A patent/KR960701345A/ko not_active Withdrawn
- 1993-11-15 ES ES94901495T patent/ES2108414T3/es not_active Expired - Lifetime
- 1993-11-15 JP JP6514575A patent/JPH08507360A/ja active Pending
- 1993-11-15 EP EP94901495A patent/EP0688418B1/en not_active Expired - Lifetime
- 1993-11-19 TW TW082109759A patent/TW241329B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| DE69314058D1 (de) | 1997-10-23 |
| EP0688418A1 (en) | 1995-12-27 |
| BR9307828A (pt) | 1995-11-14 |
| EP0688418B1 (en) | 1997-09-17 |
| DE69314058T2 (de) | 1998-04-09 |
| US5291735A (en) | 1994-03-08 |
| WO1994021974A1 (en) | 1994-09-29 |
| ES2108414T3 (es) | 1997-12-16 |
| KR960701345A (ko) | 1996-02-24 |
| JPH08507360A (ja) | 1996-08-06 |
| TW241329B (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1995-02-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |