CA2141611A1 - Peroxy bleaching composition stabilized with ethylenediamine-n, n'-disuccinic acid - Google Patents
Peroxy bleaching composition stabilized with ethylenediamine-n, n'-disuccinic acidInfo
- Publication number
- CA2141611A1 CA2141611A1 CA002141611A CA2141611A CA2141611A1 CA 2141611 A1 CA2141611 A1 CA 2141611A1 CA 002141611 A CA002141611 A CA 002141611A CA 2141611 A CA2141611 A CA 2141611A CA 2141611 A1 CA2141611 A1 CA 2141611A1
- Authority
- CA
- Canada
- Prior art keywords
- composition according
- weight
- bleaching
- detergent composition
- compositions
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 264
- 238000004061 bleaching Methods 0.000 title claims abstract description 79
- VKZRWSNIWNFCIQ-UHFFFAOYSA-N 2-[2-(1,2-dicarboxyethylamino)ethylamino]butanedioic acid Chemical compound OC(=O)CC(C(O)=O)NCCNC(C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-UHFFFAOYSA-N 0.000 title claims abstract description 7
- 125000000864 peroxy group Chemical group O(O*)* 0.000 title description 25
- 239000003599 detergent Substances 0.000 claims abstract description 97
- -1 peroxy compound Chemical class 0.000 claims abstract description 93
- 150000003839 salts Chemical class 0.000 claims abstract description 54
- 239000007844 bleaching agent Substances 0.000 claims abstract description 48
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 7
- 239000004758 synthetic textile Substances 0.000 claims abstract description 7
- 239000000463 material Substances 0.000 claims description 68
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 40
- 150000001875 compounds Chemical class 0.000 claims description 37
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 35
- 239000002253 acid Substances 0.000 claims description 29
- 239000004094 surface-active agent Substances 0.000 claims description 25
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 22
- 239000007787 solid Substances 0.000 claims description 20
- 239000011734 sodium Substances 0.000 claims description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 16
- 150000004965 peroxy acids Chemical class 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 16
- 229910052708 sodium Inorganic materials 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000004115 Sodium Silicate Substances 0.000 claims description 14
- 229920005646 polycarboxylate Polymers 0.000 claims description 13
- 102000004190 Enzymes Human genes 0.000 claims description 12
- 108090000790 Enzymes Proteins 0.000 claims description 12
- 229910052783 alkali metal Inorganic materials 0.000 claims description 11
- 239000010457 zeolite Substances 0.000 claims description 11
- 150000004967 organic peroxy acids Chemical class 0.000 claims description 10
- 150000001340 alkali metals Chemical class 0.000 claims description 9
- 239000003945 anionic surfactant Substances 0.000 claims description 9
- 150000007942 carboxylates Chemical class 0.000 claims description 9
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 9
- 239000000194 fatty acid Substances 0.000 claims description 9
- 229930195729 fatty acid Natural products 0.000 claims description 9
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- 150000003138 primary alcohols Chemical class 0.000 claims description 9
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 9
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 230000003287 optical effect Effects 0.000 claims description 8
- BGRWYDHXPHLNKA-UHFFFAOYSA-N Tetraacetylethylenediamine Chemical group CC(=O)N(C(C)=O)CCN(C(C)=O)C(C)=O BGRWYDHXPHLNKA-UHFFFAOYSA-N 0.000 claims description 7
- 125000000129 anionic group Chemical group 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 125000002091 cationic group Chemical group 0.000 claims description 6
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 6
- 239000002689 soil Substances 0.000 claims description 6
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 5
- 229910019142 PO4 Inorganic materials 0.000 claims description 5
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 claims description 5
- 150000004665 fatty acids Chemical class 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 239000000429 sodium aluminium silicate Substances 0.000 claims description 5
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 5
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 5
- 235000019351 sodium silicates Nutrition 0.000 claims description 5
- 239000000654 additive Substances 0.000 claims description 4
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 4
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 4
- 239000002304 perfume Substances 0.000 claims description 4
- 239000000725 suspension Substances 0.000 claims description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
- 150000003863 ammonium salts Chemical class 0.000 claims description 3
- 230000003625 amylolytic effect Effects 0.000 claims description 3
- 238000004851 dishwashing Methods 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 239000000835 fiber Substances 0.000 claims description 3
- 239000001257 hydrogen Chemical group 0.000 claims description 3
- 229910052739 hydrogen Chemical group 0.000 claims description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 claims description 2
- 229920002126 Acrylic acid copolymer Polymers 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 2
- 239000003093 cationic surfactant Substances 0.000 claims description 2
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical group [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 claims description 2
- 238000005187 foaming Methods 0.000 claims description 2
- 239000002563 ionic surfactant Substances 0.000 claims description 2
- 159000000003 magnesium salts Chemical class 0.000 claims description 2
- 230000002797 proteolythic effect Effects 0.000 claims description 2
- 229940045872 sodium percarbonate Drugs 0.000 claims description 2
- 239000002888 zwitterionic surfactant Substances 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 230000002366 lipolytic effect Effects 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 50
- 230000008569 process Effects 0.000 abstract description 36
- 238000003860 storage Methods 0.000 abstract description 9
- 239000007864 aqueous solution Substances 0.000 abstract description 7
- 239000002657 fibrous material Substances 0.000 abstract description 3
- VKZRWSNIWNFCIQ-WDSKDSINSA-N (2s)-2-[2-[[(1s)-1,2-dicarboxyethyl]amino]ethylamino]butanedioic acid Chemical compound OC(=O)C[C@@H](C(O)=O)NCCN[C@H](C(O)=O)CC(O)=O VKZRWSNIWNFCIQ-WDSKDSINSA-N 0.000 description 43
- 239000000243 solution Substances 0.000 description 36
- 239000000047 product Substances 0.000 description 32
- 239000004615 ingredient Substances 0.000 description 28
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 24
- 125000000217 alkyl group Chemical group 0.000 description 24
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 21
- 239000007921 spray Substances 0.000 description 18
- 229910000323 aluminium silicate Inorganic materials 0.000 description 16
- 125000004432 carbon atom Chemical group C* 0.000 description 16
- 239000000843 powder Substances 0.000 description 16
- 150000002500 ions Chemical class 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 229920001577 copolymer Polymers 0.000 description 13
- 239000004744 fabric Substances 0.000 description 13
- 229910021653 sulphate ion Inorganic materials 0.000 description 13
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 12
- 229910001385 heavy metal Inorganic materials 0.000 description 12
- 238000005342 ion exchange Methods 0.000 description 12
- 229920001296 polysiloxane Polymers 0.000 description 12
- 239000000377 silicon dioxide Substances 0.000 description 12
- 239000003381 stabilizer Substances 0.000 description 12
- 239000005977 Ethylene Substances 0.000 description 11
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 11
- 239000008187 granular material Substances 0.000 description 11
- 239000011230 binding agent Substances 0.000 description 10
- 239000004902 Softening Agent Substances 0.000 description 9
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 9
- 229910021536 Zeolite Inorganic materials 0.000 description 9
- 229940088598 enzyme Drugs 0.000 description 9
- 150000004760 silicates Chemical class 0.000 description 9
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 8
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 8
- 238000000576 coating method Methods 0.000 description 8
- 150000002191 fatty alcohols Chemical class 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Substances [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 8
- 125000003342 alkenyl group Chemical group 0.000 description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 description 7
- 239000013522 chelant Substances 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000354 decomposition reaction Methods 0.000 description 7
- 238000009472 formulation Methods 0.000 description 7
- 230000002209 hydrophobic effect Effects 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 6
- QXNVGIXVLWOKEQ-UHFFFAOYSA-N Disodium Chemical compound [Na][Na] QXNVGIXVLWOKEQ-UHFFFAOYSA-N 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 6
- 239000012190 activator Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 229910052681 coesite Inorganic materials 0.000 description 6
- 229910052906 cristobalite Inorganic materials 0.000 description 6
- 229920001519 homopolymer Polymers 0.000 description 6
- 238000010348 incorporation Methods 0.000 description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 6
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 6
- 235000012239 silicon dioxide Nutrition 0.000 description 6
- 230000006641 stabilisation Effects 0.000 description 6
- 238000011105 stabilization Methods 0.000 description 6
- 229910052682 stishovite Inorganic materials 0.000 description 6
- 229910052905 tridymite Inorganic materials 0.000 description 6
- 108010065511 Amylases Proteins 0.000 description 5
- 102000013142 Amylases Human genes 0.000 description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 5
- KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
- 229920001131 Pulp (paper) Polymers 0.000 description 5
- 238000005054 agglomeration Methods 0.000 description 5
- 230000002776 aggregation Effects 0.000 description 5
- 150000001298 alcohols Chemical class 0.000 description 5
- 150000001408 amides Chemical group 0.000 description 5
- 235000019418 amylase Nutrition 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 5
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 5
- 239000004927 clay Substances 0.000 description 5
- 238000007046 ethoxylation reaction Methods 0.000 description 5
- 238000001694 spray drying Methods 0.000 description 5
- 239000003760 tallow Substances 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical group [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 108091005804 Peptidases Proteins 0.000 description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 4
- 229940025131 amylases Drugs 0.000 description 4
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- 229920002678 cellulose Polymers 0.000 description 4
- 239000001913 cellulose Substances 0.000 description 4
- 238000007580 dry-mixing Methods 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 235000019197 fats Nutrition 0.000 description 4
- JPZROSNLRWHSQQ-UHFFFAOYSA-N furan-2,5-dione;prop-2-enoic acid Chemical compound OC(=O)C=C.O=C1OC(=O)C=C1 JPZROSNLRWHSQQ-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910021647 smectite Inorganic materials 0.000 description 4
- 229910052938 sodium sulfate Inorganic materials 0.000 description 4
- 235000011152 sodium sulphate Nutrition 0.000 description 4
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 4
- 235000000346 sugar Nutrition 0.000 description 4
- CKLJMWTZIZZHCS-UHFFFAOYSA-N D-OH-Asp Natural products OC(=O)C(N)CC(O)=O CKLJMWTZIZZHCS-UHFFFAOYSA-N 0.000 description 3
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- 102000004882 Lipase Human genes 0.000 description 3
- 108090001060 Lipase Proteins 0.000 description 3
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- 240000008042 Zea mays Species 0.000 description 3
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 3
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 3
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- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 229960005261 aspartic acid Drugs 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 3
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- 235000005822 corn Nutrition 0.000 description 3
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 3
- 229910017053 inorganic salt Inorganic materials 0.000 description 3
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- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
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- WYGJTQGGQYPSQV-UHFFFAOYSA-N 3,4-diacetylhex-3-ene-2,5-dione Chemical group CC(=O)C(C(C)=O)=C(C(C)=O)C(C)=O WYGJTQGGQYPSQV-UHFFFAOYSA-N 0.000 description 2
- 239000004382 Amylase Substances 0.000 description 2
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical class OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 239000004705 High-molecular-weight polyethylene Substances 0.000 description 2
- CKLJMWTZIZZHCS-UWTATZPHSA-N L-Aspartic acid Natural products OC(=O)[C@H](N)CC(O)=O CKLJMWTZIZZHCS-UWTATZPHSA-N 0.000 description 2
- 239000004367 Lipase Substances 0.000 description 2
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
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- 230000002688 persistence Effects 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 238000003918 potentiometric titration Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- NJKRDXUWFBJCDI-UHFFFAOYSA-N propane-1,1,2,3-tetracarboxylic acid Chemical class OC(=O)CC(C(O)=O)C(C(O)=O)C(O)=O NJKRDXUWFBJCDI-UHFFFAOYSA-N 0.000 description 1
- NJEVMKZODGWUQT-UHFFFAOYSA-N propane-1,1,3,3-tetracarboxylic acid Chemical class OC(=O)C(C(O)=O)CC(C(O)=O)C(O)=O NJEVMKZODGWUQT-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 239000010865 sewage Substances 0.000 description 1
- 238000005549 size reduction Methods 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 description 1
- QSKQNALVHFTOQX-UHFFFAOYSA-M sodium nonanoyloxybenzenesulfonate Chemical compound [Na+].CCCCCCCCC(=O)OC1=CC=CC=C1S([O-])(=O)=O QSKQNALVHFTOQX-UHFFFAOYSA-M 0.000 description 1
- XWPCPDYPKRDGNE-UHFFFAOYSA-N sodium;(2,3,4-trimethylphenyl) hexanoate Chemical compound [Na].CCCCCC(=O)OC1=CC=C(C)C(C)=C1C XWPCPDYPKRDGNE-UHFFFAOYSA-N 0.000 description 1
- NKAAEMMYHLFEFN-ZVGUSBNCSA-M sodium;(2r,3r)-2,3,4-trihydroxy-4-oxobutanoate Chemical compound [Na+].OC(=O)[C@H](O)[C@@H](O)C([O-])=O NKAAEMMYHLFEFN-ZVGUSBNCSA-M 0.000 description 1
- MIKSWWHQLZYKGU-UHFFFAOYSA-M sodium;2-benzoyloxybenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1OC(=O)C1=CC=CC=C1 MIKSWWHQLZYKGU-UHFFFAOYSA-M 0.000 description 1
- UJRAXLUXHBUNDO-UHFFFAOYSA-M sodium;hydron;oxalate Chemical compound [Na+].OC(=O)C([O-])=O UJRAXLUXHBUNDO-UHFFFAOYSA-M 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 229940037312 stearamide Drugs 0.000 description 1
- 230000000707 stereoselective effect Effects 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000003107 substituted aryl group Chemical group 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 235000011044 succinic acid Nutrition 0.000 description 1
- 125000000020 sulfo group Chemical group O=S(=O)([*])O[H] 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 235000011149 sulphuric acid Nutrition 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 108010075550 termamyl Proteins 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 150000004685 tetrahydrates Chemical class 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
- C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
- C09K15/20—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing nitrogen and oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
- C11D3/394—Organic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB929216408A GB9216408D0 (en) | 1992-08-01 | 1992-08-01 | Stabilized bleaching compositions |
| GB9216408.6 | 1992-08-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2141611A1 true CA2141611A1 (en) | 1994-02-17 |
Family
ID=10719699
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002141611A Abandoned CA2141611A1 (en) | 1992-08-01 | 1993-07-21 | Peroxy bleaching composition stabilized with ethylenediamine-n, n'-disuccinic acid |
Country Status (12)
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9216410D0 (en) * | 1992-08-01 | 1992-09-16 | Procter & Gamble | Detergent compositions |
| WO1995025159A1 (en) * | 1994-03-17 | 1995-09-21 | The Procter & Gamble Company | Bleach improvement with manganese ethylenediamine-n,n'-disuccinate |
| NZ290516A (en) † | 1994-07-27 | 1998-07-28 | Dow Chemical Co | An analytical process using computer software for determining the biodegradability of aspartic acid derivatives; chelating a metal ion then biodegrading the chelate |
| CA2213633C (en) * | 1995-02-28 | 2002-01-22 | The Procter & Gamble Company | Laundry pretreatment with peroxide bleaches containing chelators for iron, copper or manganese for reduced fabric damage |
| GB9507659D0 (en) | 1995-04-13 | 1995-05-31 | Ass Octel | Alkylation process |
| DE19518150A1 (de) * | 1995-05-17 | 1996-11-21 | Ciba Geigy Ag | Mikrobiologisches Verfahren zur Herstellung von (S,S)-N,N'-Ethylendiamindibernsteinsäure |
| US5905065A (en) * | 1995-06-27 | 1999-05-18 | The Procter & Gamble Company | Carpet cleaning compositions and method for cleaning carpets |
| US5759439A (en) * | 1996-06-14 | 1998-06-02 | The Procter & Gamble Company | Peroxygen bleaching compositions comprising peroxygen bleach and a fabric protection agent suitable for use as a pretreater for fabrics |
| ATE321574T1 (de) | 1995-08-31 | 2006-04-15 | Procter & Gamble | Verwendung von allylalkohol als ein mittel zur verminderung von schlechten gerüchen |
| DE19600018A1 (de) | 1996-01-03 | 1997-07-10 | Henkel Kgaa | Waschmittel mit bestimmten oxidierten Oligosacchariden |
| FI115469B (fi) * | 1996-02-19 | 2005-05-13 | Kemira Oyj | Menetelmä kemiallisen selluloosamateriaalin käsittelemiseksi |
| FI115470B (fi) * | 1996-02-19 | 2005-05-13 | Kemira Oyj | Menetelmä kemiallisen selluloosamateriaalin käsittelemiseksi |
| FI115642B (fi) * | 1996-02-19 | 2005-06-15 | Kemira Oyj | Korkeasaantomassojen valkaisumenetelmä |
| FI115641B (fi) * | 1996-02-19 | 2005-06-15 | Kemira Oyj | Korkeasaantomassojen valkaisumenetelmä |
| DE19630278A1 (de) * | 1996-07-26 | 1998-01-29 | Basf Ag | Komplexbildner für die Zellstoff- und Holzstoffbleiche, die Papierherstellung sowie das Deinking von Altpapier |
| US7044985B2 (en) * | 1999-12-21 | 2006-05-16 | Clariant Finance (Bvi) Limited | Process for pre-treating cellulosic fibers and cellulosic fiber blends |
| DE10339164A1 (de) * | 2003-08-26 | 2005-03-31 | Henkel Kgaa | Stabilisierung von Wasserstoffperoxid während der Auflösung alkalisierend wirkender Feststoffe in wasserstoffperoxidhaltigen Systemen |
| JP4248466B2 (ja) * | 2004-09-03 | 2009-04-02 | 株式会社島精機製作所 | 繊維製品の染色方法 |
| EP1811080A1 (en) * | 2006-01-24 | 2007-07-25 | Solvay SA | Process for the bleaching of mechanical paper pulp |
| GB0714575D0 (en) | 2007-07-26 | 2007-09-05 | Innospec Ltd | Composition |
| GB0721587D0 (en) * | 2007-11-02 | 2007-12-12 | Innospec Ltd | Process for bleaching pulp |
| EP2103676A1 (en) * | 2008-03-18 | 2009-09-23 | The Procter and Gamble Company | A laundry detergent composition comprising the magnesium salt of ethylene diamine-n'n' -disuccinic acid |
| WO2010118206A2 (en) * | 2009-04-08 | 2010-10-14 | Sunsonix | Process and apparatus for removal of contaminating material from substrates |
| US20130209575A1 (en) * | 2011-08-29 | 2013-08-15 | E I Du Pont De Nemours And Company | Multi-part kit system for the preparation of a disinfectant |
| CN102363929A (zh) * | 2011-11-30 | 2012-02-29 | 中冶纸业银河有限公司 | 一种提高纸浆过氧化氢漂白效率的方法 |
| CN103666834B (zh) * | 2012-09-07 | 2015-06-17 | 杨平 | 医用织物洗涤剂及其使用方法 |
| EA201691672A1 (ru) * | 2014-02-20 | 2017-02-28 | Юнилевер Н.В. | Композиция для посудомоечной машины |
| CN105907483B (zh) * | 2016-05-08 | 2019-01-15 | 浙江艾卡医学科技有限公司 | 一种含氧的多功能洗涤剂组合物 |
| CZ309643B6 (cs) * | 2021-07-21 | 2023-06-07 | Univerzita Pardubice | Hořečnaté sole derivátů asparagové kyseliny a jejich použití jako stabilizátorů peroxidu vodíku |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE590477A (enrdf_load_stackoverflow) * | 1959-07-01 | |||
| GB1304521A (enrdf_load_stackoverflow) * | 1969-06-17 | 1973-01-24 | ||
| FR2323631A1 (fr) * | 1975-09-15 | 1977-04-08 | Ugine Kuhlmann | Persels mixtes stables en melange lixiviel |
| US4378300A (en) * | 1981-12-10 | 1983-03-29 | Colgate-Palmolive Company | Peroxygen bleaching composition |
| DE3526405A1 (de) * | 1985-07-24 | 1987-02-05 | Henkel Kgaa | Schichtsilikate mit beschraenktem quellvermoegen, verfahren zu ihrer herstellung und ihre verwendung in wasch- und reinigungsmitteln |
| US4704233A (en) * | 1986-11-10 | 1987-11-03 | The Procter & Gamble Company | Detergent compositions containing ethylenediamine-N,N'-disuccinic acid |
| HUT64391A (en) * | 1990-11-14 | 1993-12-28 | Procter & Gamble | Nonphosphated dishwashing compositions with oxygen belach systems and method for producing them |
-
1992
- 1992-08-01 GB GB929216408A patent/GB9216408D0/en active Pending
-
1993
- 1993-07-21 JP JP6505354A patent/JPH07509523A/ja active Pending
- 1993-07-21 AU AU47785/93A patent/AU666403B2/en not_active Ceased
- 1993-07-21 WO PCT/US1993/006837 patent/WO1994003553A1/en not_active Application Discontinuation
- 1993-07-21 KR KR1019950700419A patent/KR950703038A/ko not_active Withdrawn
- 1993-07-21 EP EP93918280A patent/EP0652924A4/en not_active Withdrawn
- 1993-07-21 CA CA002141611A patent/CA2141611A1/en not_active Abandoned
- 1993-07-30 MA MA23250A patent/MA22947A1/fr unknown
- 1993-07-30 TR TR00688/93A patent/TR28150A/xx unknown
- 1993-07-31 CN CN93117440A patent/CN1084560A/zh active Pending
- 1993-08-02 MX MX9304665A patent/MX9304665A/es unknown
- 1993-10-13 TW TW082108467A patent/TW255911B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| WO1994003553A1 (en) | 1994-02-17 |
| MA22947A1 (fr) | 1994-04-01 |
| TR28150A (tr) | 1996-02-29 |
| CN1084560A (zh) | 1994-03-30 |
| EP0652924A1 (en) | 1995-05-17 |
| AU666403B2 (en) | 1996-02-08 |
| AU4778593A (en) | 1994-03-03 |
| GB9216408D0 (en) | 1992-09-16 |
| KR950703038A (ko) | 1995-08-23 |
| MX9304665A (es) | 1994-03-31 |
| JPH07509523A (ja) | 1995-10-19 |
| TW255911B (enrdf_load_stackoverflow) | 1995-09-01 |
| EP0652924A4 (en) | 1995-06-14 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| FZDE | Dead |