CA2109840A1 - Fuel mixture, method of producing it, and its use - Google Patents
Fuel mixture, method of producing it, and its useInfo
- Publication number
- CA2109840A1 CA2109840A1 CA002109840A CA2109840A CA2109840A1 CA 2109840 A1 CA2109840 A1 CA 2109840A1 CA 002109840 A CA002109840 A CA 002109840A CA 2109840 A CA2109840 A CA 2109840A CA 2109840 A1 CA2109840 A1 CA 2109840A1
- Authority
- CA
- Canada
- Prior art keywords
- oil
- fuel mixture
- mixture according
- volume
- gasoline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Abandoned
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Fats And Perfumes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Preparation Of Compounds By Using Micro-Organisms (AREA)
Abstract
Abstract The invention relates to a fuel mixture which contains at least one vegetable and/or animal oil, at least one aliphatic alcohol having 1 to 5 C-atoms and gasoline and which can be produced by mixing these components. This fuel mixture is suitable for all types of diesel engines without modification measures and can also be used as heating oil.
Description
-1- 210~8~0 5p-clf ~c~ .ion U~ ' ~he ~n~r~tlor~ r~1ste~ t~ a ~el s~lYtUXC~ a ~rocc6~s for i~ pr~t6l~ an~ v u~: o~ th~ S~el ~1xtur~ for dle~el ~ 5 a~d ~ ~Ra~ oi1.
Cor~Y~ntiorfaï 1~ ~Uid fURl~ ~o~ i~tr al c~uCtion in ~ nc~nt o~ turo- o~ hydrocaL~ ons and ar~
~Ln1y ob~ined ~rom ~lner~l oiJ.. In vie~ ~:R' t~e ed c~dQ il r¢~ourco~ and t~ pria~ ùe~lopmont ~n erudc oi,1, the~e i~ n~d ror ~uels in wrlicn ~c~e ~a~ e ~y~ccarbons at_lees~ p~:rtly rQplao~d b~ r~
~1:i~ z~ ngain, ~uc~ ;a~',y o;l;, 0;
an~al or v~et~le origin, Due to a drastie rnduction of t3~ por~ion o~ thG ~ ologic~lly not d~c~mpori~ble . ~:
hy~-oc~r~on~ s15X ~r enYlran~ental p~l lution cona~o~l~d ~ith a po~ei~le ~ klng out of ~ ls ~d~r~bly redu~ed. -~ .
~S ~ ~k~m ~Y O~-PS 116 4sa atte3ptS havs ~lrt~y b~en D~d~ ~lnc~ the b~inning ~f t~i~ century 'Ca r~place ~ ~
nydroc:al~ i.n Sual~ lc~holo ~ free f~tty ~cids ~:
o~ in~ ~ got~bl~f oils ser~r ~ ng as Dtlxinc~ int-r-~ ~1 ~c, ~ue7 ~c~ 6 ~or inte~ co~bu~tion eng~srles ~,rith -- :.
uret~t~r ii~e del;cr~ a in DIE-OS 24 ~ 737, which ~ore~t o~ ~ hyd~s~.Q~ mlxtu~e tres~ular qasolin- or pr~miu~ ~r4de ga~oiiAe~ and ~ ~nixture of~ an ~lcoh~
with ~ ~.n 4 C-atom~ ar.d uatcr ~ po~ bly o.1 tc~ z~ ~y ~o~ght o~ a ~ ta~ nich al~o serve9 a~; a ~lxiny iAte~di~
: '..~ "'': . ~ .
,-' ~'.:' 210984~
DJ;-PS 11 49 170 an~ 31 S0 g88 descs~e di~o~l ~uels, in w~ich up 'co ~0~ o~ h~d~ocarbon~ ara r~pl~c~d ~y allcyl ~tty .acid er-~;e~ e~tablc 2ilc and ~rhleh alsc~ o~n'c3in ~laohol~ i~ up to ~iVe c,3rbon ~l.omsl. `, ~lo~o~ er, i~ ~Y ~a~r~ l here to ~ot.ple~oiy cov~r~ tne o$1s obta~ned rrom p3.ant~ to alkyl fatty ~cia elstOEs, in ptl-~clcul~r ae~hyl ~tty ~cid ~t~r.~, wr~i~h D~ans, on t~4 On~ hasl~, a hl~ exPendlture~ on th~
oth~r han~ lu~ o~ s~lyc~ine ~l~iah is -~
~icul'c to util~ze. ~he ~Iyd~cA~o~ ~nixtur-3 o~ Dl~-PS ::
31 ~9 170 i~ ~ cl~ical ga~ oil, i.. e. a ~e~roleum -f~aetlcn. ~he diesel ruel ~xtu~e5 o-t DE-P8 ~ ~ So ~8~
- m~y po~ly eont~lr 0.1 to ;% Sy wei~h~ of an i~nition aac~le~a~;or :iaid dl~ uels whlo~ ~o u~:4d in asri.^~lt~ra ~
tractor~ YQ ~-.loud Dolnts ~C~ e no~ ~elo r ~ C, due to wh~c~ 'chey ~n snly ~e used to a very l~tc:d flegr~ ~n ~nnter.
: : : ,: : ~ . ~:-:
A.tte81~s h~e hls2 alrea~y b~n ~o te ~a~e non-re~
~i~ d ~gP~t~bLe oils ~uerl a~ ~ps oi~ S'uels ln in~rnal ~olsl5u~ti.s*~ c~l~-6, .
~6-P5 4359324 d~elo-~ a ~.iesel ~uel con~lgting of ~o ~S~ Or ~ ~utyl ~lcohol ~n~l 75 to 25~ o~ a v~g~t;~bl~
o~l. US-P-~ ~557734 di~clos~s ~ d~,e~el fu~l con~i~t~ng o~
~ 1e oil, ~c~b~nol or oet~2.nol an~ ~ sCra~gnt Cl-ain oc~o~, US~PS 4509953 ~ w~.o~ieo 2~ di~c~l f~
oondctinq of 70 to 90 Vo;L~, sras oil or h-~vy oil r~spec,iiwly~ 10 to 30 ~Vol~ rthanol and up to 3D t~01~ .- :
gatoline- ~
Xa~re~ , erle use o~ these ~uo~ ay~: r-qulr-d n~iv- mc~llticatlon me~U~es ~rith rospect to ~he : .:
en9~ne~ opcr;~tcd wL'ch th i. DI~R, to thc~e ~c4ts ~he en~ral ps~udla~ w~ co~bor~ccd 'c~t it is l~npo~ib~
'co op~rate engines irlt~nded ~o~ operation ~i~ch mine~31 ~ue~S ~ h ~uels ha~lng a high ~harR of f att.y olls ; ~ ,~
u~t~out mD~ fi~ti~n ~e~ure~
,. ,.. . ~ ,.
.., .
- -- -- :. . ~ -.
~ 2109840 ~t ~g th~ ob~ o~ p~e~ inY~ n to p~c~v~de fu~l mlxture ln ~rhleh ratty o~l~ can bQ U9e~ ac ra~
~a~riall6, ttlSiah ~ro~ again~ ch ha6 an l~pro~rcd cloud Floin'C, ~ la~g~ly blolz~lca~y ce~o~po~Lable and c~l be SI A ~ ~es o f dl~sQl ~ ,ne~
w~tnou~ arly ;llo~rlcat~on mêasures, ~oreov~, lt shoul~
'b~ at lca~t c~u$vala~t ~o m~nc~l d~ uol~i as ~eg~e ~nln~ pe~So~ance and t~ aYoid ~ecr pheno-,~,n~ .
A~cDrd~ o the present ln~en~ion th~s ob~ecc is a~ne~ by 4 ~uol ~ctt~r~, wh~* eon~a~ns . .
- 8; ~t l~a¢t on~ V~t~bl~ andJor ani~nal o~
.
~) At. I P~t ~ne aliphatlc alCohol havin~J 1 to ~ c-a~oms and : .
c~ gaaoline.
Yor~over~ a proc~s for produci~ thls f~el mlxture is p~:o~ , ~hlch 1~ e'cari~ed ~n that ;~t lea3t n~ v~get~bl~ ~ndlos~ .~n~ l oil, At least one al ipha~ic ~locohol h~-~ing 1 to 5 C~ a lln~ ga~olin~ A~ mixed. - : :
S~id f~cl m~u~o ~s pr~ rably uoe~ ;!15 f~lel fo~ die~el es or a~ heatln~ oll.
rx~ple~ a2 the ~'egctable ndJor anl~l o$1~ uo-d 3a ~ :
a~mponan~ ~) in ~ne ruel ~lx~ accordlng ~o t~c inYen~ n are rape oil ~ ~oybc~n oil, cotton oil, ~nt~o~er oll, c~sto~ oil, olive oil, pe~nUt oil, ~ n oll, a~ond oil. F~ln ~c~el oll, cnconuS oll, ~ust2l.r ~Ll ~n~ SisJ olls. R~p~ oil ~?hlc2~ is a ~l~c~e c~f, f ~.tty ~:~cidfi partly esteri~$~d with ~lycerins ls used wl~n pre~e~cncQ a~ oo~ponent ~), eir~co a large ~uasltlty lL i~ vr~,il~J ~ an~l lt can 1~ o~tain~d. in ~ilmp~,y -~
~açhlon frtsm rspe 6~ds ~y mQan6 oS ~r~!~cin~. T;tle used rap6 c~. ca~ bo ~ix~d lnto t~e ~uel 211ix~ aaaordi~g the ~wenti~n bot~l c~udely p~essed and deguDmed ~nd -~
21098~0 ~4~ -:
a~ a ~fi~ A ~onverslon ~o al~cyl Qsto~ a i~ ~4 ~ ;
requ~d isl DE-PS 31 ~9 1~o ~nd ~ o ~ not necea~ary, D~e tD ~le ~i6s~n of this3 proc~ 5tGp i.
bQCo~06 pce611~ c~ Xet d~e~el fuels whicha~
b$ol~ ~ally dec~posal~le eo ~L çrreat ox~ent dir~ctly fram ~ ltural produe~lor~ wlthou~'c t~Q~e bc~ l~g - .
fu~ er ~gy casts an~ ~ras~e ma~er~ als suc:h as glyoox~!. ~e wcigh~ eh31ro of the oo~ponent .~ .in the fuel mi;xt~e /~cco~d~ ng t~ tlle lnventlon l~i ~ultably to 8-8% by voluD~e, ii 19 ere~e~a~ly bQ~wQ~n 65 and a5 ~ YO~ nd p~rtlcul~rly prcf~r~ed l;,.3tw~:n 70 ~nci 80 by vo~e. :
' lio~h t~ ht-ch~in ~nd b~an~d alcohDls w~ D
~-ato~ c~n b~ u~ed ae eO~ponent ~) ~n t~ '81 ~ixtur~
3000rd~n5 to th6 inYention. Mon~al~oh~ CiU~
t~an~1, e~al~o~, ~ropanol, bl2tAnol, p~nt~nol, iso~o~ru~ obutanol, t~r~f~7utor,01, ~ -me~r~ylbut~nol, 2-n~ct~ylbl~d~lol, 3-me~hylbu~anDl, 1, 1-dl~3et~ylpropanol ,?-~lim~h~lpropanol arQ us~ wi~}~ pr~ .eo, :
i~ollr4~ 01 b~ln~ osp~cl~l~y pr~rr6,~
~ulQrlol c~n al~o be. W~d, vh~ch, l~k- t-h~ u~d oil~
c-n be produl-ed i~ icul.~ l production . ~he weiqht 6~a~ of ~e cbnpon~nt b) ln the ~!u~l ~ixture a~!cord~ng to th~ irv~ntion 1~ pze~~ly G to 20~ ~y volu~ei it i~ ~n ga;cticular betwQen 10 arl~ 15~ ~y vt~lUme.
A~y optlon~l g~oL~ne C~n be ~sed ~6 ~a~so1int: ~:wuy~nent el ls~ U~e ruel ~u~e ~ceordi7~g to th~ in~ ion, r~ r o~-oI~ne or pr~iu~ad~ qc~coll~e; however, ::~ `
tc~ qaw1ine 13 used ~ tn pre~ere~ce. ~est gasolins ifi i. ~i~
th~ dcssig~ted ~o~ rcf~ncd g~col~o~ oil~ng point c~ 130 to 22~'C and a . na~h Po~nt asce~xalned aceor~ to ~bel-PHr~cy of ~ 21C ~cf. n~ 51 632, n Novo7nSer 19~1, dra~t ~Q~uarr ~ 6~. 'rhe te~t g~solir~
u~ed acGort.~ o t~e i~er~ion C~n ~ . q . have ar~ octane ~at~n~ os 120 to 1~ 0. qhe ~lght shar~ of th~ ~a.~rlin.~
c~o~ c) 1~ prc~cr3~1~f 6 to 20~ ~y ~o~e; ie 1~ ln p~t~c~læ b~twecn ~0 and 15~ by ~rolu~Q.
' ~: ': ;'"' - - ~,;-,- :
21~984~
~ . --5--.
C~0~3rs~ a~ tiyes o~n al~ bs added to t~e fuel D~e ~eeurdlno ~ the ~n~ention. t~ to 1~6 bv vol~lm,~
diQthyl l~thor ~s ~ ~ably added AS l~;ta~t~9- 21it ~or ~c ~per~tion of ~1~1 e~lnaG in ~inter.
uol ~it~re dCO~ to the ~ c~ntlon wl~ich is ~rod~ced ~ aixin~ the CO~pRnen~:~ a), b) an~ c) ~an bQ
used 1.n ~ll dies~l nginH~ ~rl~ou'c a ~peoial ~ets~oSit-~ins to the new ruel beln~ n-c~o~y. Accor~lingly, th~
~uel mix~-~re ~cco~ to the invent~on can e.g. 3~2~Ye for opero.t~ng ai~el ~n~lnqs 1~ ca2s, t~ucke, ff.gr~cu~
t~al and ro~R~ ao~n~o, 3tand-by uni~s, p~mps ln~l .hip6. ~eec cnglnes oar~ ~e oper?~tR(~ alt~rna~Lngly with the r..e~ re ac~ordis~g ~o t2~e i~vention an custo~-ary ~i.7-~ral diccel ~uel~, a h~ mobility ~ci~çl ~n p~tsc~la~ ~d~_ov~C ~'or -zr~ ~d ~
:: -~O ~ b.;Dl~ ~od a~ oo~,ponent b~ ~n *~e fuel mixtu.reac~;~rd~ ~o ttle ln~,rontion/ -ln pa~t~cular the i~;opro~
panol, cerve ~ ontl-colc~ng ,gent tar pi~ton ring~ ~nd D . ~b.e ~gol i nQ ~dde~ i!l3 ~dditi~re leads t~
~e c~ 'ica~l~n o~ ix~re and l~de to ar~
~pra~d igmition pe~l~Or~llaJlCQ 0~ ~c2~e 2~el r~.xtu~o, te9t ~ s21irle su~lyi ng tl~ bec~ v~ es A good i~nitio~
per~!o~nc- of tlle f~els me~ arl ad-~antageou~ start1~g o~ ~n~ a ~o~th r4nn~ o~ ~e ~ cl engine du~
t~ a short mixture prq?~ n cl~e or a ~hort i~ni~ion del~y; in the c~se o~ a lonc l~nltion d~lay, 'che kno~n ~d1es~1 ~no~ 8 ~Ludi~le.
: ~. ~ .:. -:
u~t qas te~ts arQ aa~1e~ ol,t S;lr t~e f~
~x~ure accDid~ng ~o ~he inYent~on used il~ d~e601 engin~-:, thc ~lues o~t~ d b~th for hy~lso~:~40n~i ~nd l ~ -ni~ogen oxlde~ an~ for c~bo~ ~on~xide are ~ar b~
~e Yalues r~quix~d by th~ ~e~ 1y ~alid Europ~n ,i: : . . ~ ::
21~8~ ~
~rd for ~i~se~, 6xb.4ustei gace~. ~h~ 6~ h~r dloxide ~e cf t~.e ~ sU~ 6~ S ;logll~ 3~11 25 co~p~re~ e uf~Ya~ cl; o~ o.15~ ln t~Q ~a~c; ol!
custo~lW, ~ne~2. dles~l ~uel~, ~inc~ tSc u~ed co~- :
pone~t~ prac~.oally ro~ ulp~l~r.
, ~rhe ~uel miX~llre accordlng ~o tne invemlon can also bQ
Y~ c lou 'ce~pcratllrc6 ~rithout any probl~ a~ t~zy occur ln lYlnter a~ta ln el~vatee~ re$~1c~s, buo~ it~
cl~u~ point resche Yaluos l~p to -2~C, 2n~ th~ ~xtus~
doe5 a~co not rlocculate Bt l~we~ t:emper~t~res. ~his lo~ sl~h~t~ti~lly ~rc~.der ~ppl~cability as -compare-l ~lth the kno~n di~4el fuel~ on mhc ba::;is o~
le and an~al ~ats.
~ne ~o~owi~ ~xa~pl~s d~d to~t~ ~xplain th~ in~ ~n~ion P~o~ct;ion examPl~ 1 tw S~
uel mi~urQ~ ~cs~r~ing to the in~remt~ on wer~
~r~uc~ by ~imp~e mix~ng ~` ;` :!.. , 1 ) ~ by olum~
ll 80 ~-E~han~l 10 ~ :
gular ~a~oline 10 -R~p- o~l 7S .
Ioop~op~r~ol 12 . 5 :~
~t ~a6011~e 1~.5 ,- : ,,~ ., ,.-: .
-: .;: ,. ~: ~
~"' ' ' ~ ~ : ' :
. ~, .
: ~
. 21 098~ 0 ~
; . . .
sr voiu~e Sun~ oi~ 73 ~aline l~.fi , ~p~ oil76 :~
P~p- oil74 pr~p~nol 12 ~e~nanol7 ~ -l onqine~ , .,, "~ "
q?he ~uel ~Xt~*a3 acco~dinSI to t.he ~nvent~on wer~ -t~ted ln d~ esel ~ncrlnes of ~ f~r~nt con~t~ction dt~n~ no2~el op~ration. ~ uetion vehicles wor~
o~nae~n a rhlch wer~ no~ led ln their eonstrue~
t~on. q~e ~ls~on d}spl~co~nt of t~a tcG'w:d nglnes w~O
~ve~ ~ . 6 1 ond 3, 0 1. All fuels msntione~ the 6 ~i~ to 5) wor¢ u~ed in th- v hicl~
!rhece t~ did not ro8ult ~ any ~unct1s~na~ t.urb~
~nce. ~inat.i ons c~ th ~ Y.6t ~ V21~ f a crlr JOO ~-turbo ~fter dri~rlng cycl~ r;c~ . 04 s~owed that the e~in~ion values ~ elo~ t~- ha~nda~y ~alu~s of ; :~
~nQ h~rc~p~n n~andard ~ icl~fl o~ thi~ const~uc~ ; - ~ -, ~
~-' ." , . ' ~ "~' ' ' . :' ; :
: ,:
2 1 5~0U9 thc ~ t g~a6 VtllU~S ~a~ ained ~or t~4 ~ Dlx~e aCco~iing ~io th~ ln~ --nt~on ac~tording tO o~le 2 It~t re~ult~ in she d~ a; cycle ) .
e~tl ~ou~y v~,lu~ ~gf~ EC~ ~ 04 ~or ~e~ ~L~u~ ~ .ccor~ylns~ fi~C~
t~ Lnvent1 CO 7.~,Z 3C,OO~C.OO .
8C ~ttl L~ Cl - -~C ~ 8.UO~Ø00 ~. . ` .~`
Jl Offli C~l~ S ~ . 2 5 6 _ 1 . 10 1 . 3 0 . ::.,.,. `:.,,-'~;:
':' '' ' .- ' '~
: . ., '.~:. ,~
',~
. . ,, ~ .. , ,. ,.~
:. ", ,"' ~;
:
:
: ; . ' ' . . :
- '.'- ' : . ' ' ' ~ . .. , ' ', ': .' ., , : ' ' ' " ' " . ` : :
Cor~Y~ntiorfaï 1~ ~Uid fURl~ ~o~ i~tr al c~uCtion in ~ nc~nt o~ turo- o~ hydrocaL~ ons and ar~
~Ln1y ob~ined ~rom ~lner~l oiJ.. In vie~ ~:R' t~e ed c~dQ il r¢~ourco~ and t~ pria~ ùe~lopmont ~n erudc oi,1, the~e i~ n~d ror ~uels in wrlicn ~c~e ~a~ e ~y~ccarbons at_lees~ p~:rtly rQplao~d b~ r~
~1:i~ z~ ngain, ~uc~ ;a~',y o;l;, 0;
an~al or v~et~le origin, Due to a drastie rnduction of t3~ por~ion o~ thG ~ ologic~lly not d~c~mpori~ble . ~:
hy~-oc~r~on~ s15X ~r enYlran~ental p~l lution cona~o~l~d ~ith a po~ei~le ~ klng out of ~ ls ~d~r~bly redu~ed. -~ .
~S ~ ~k~m ~Y O~-PS 116 4sa atte3ptS havs ~lrt~y b~en D~d~ ~lnc~ the b~inning ~f t~i~ century 'Ca r~place ~ ~
nydroc:al~ i.n Sual~ lc~holo ~ free f~tty ~cids ~:
o~ in~ ~ got~bl~f oils ser~r ~ ng as Dtlxinc~ int-r-~ ~1 ~c, ~ue7 ~c~ 6 ~or inte~ co~bu~tion eng~srles ~,rith -- :.
uret~t~r ii~e del;cr~ a in DIE-OS 24 ~ 737, which ~ore~t o~ ~ hyd~s~.Q~ mlxtu~e tres~ular qasolin- or pr~miu~ ~r4de ga~oiiAe~ and ~ ~nixture of~ an ~lcoh~
with ~ ~.n 4 C-atom~ ar.d uatcr ~ po~ bly o.1 tc~ z~ ~y ~o~ght o~ a ~ ta~ nich al~o serve9 a~; a ~lxiny iAte~di~
: '..~ "'': . ~ .
,-' ~'.:' 210984~
DJ;-PS 11 49 170 an~ 31 S0 g88 descs~e di~o~l ~uels, in w~ich up 'co ~0~ o~ h~d~ocarbon~ ara r~pl~c~d ~y allcyl ~tty .acid er-~;e~ e~tablc 2ilc and ~rhleh alsc~ o~n'c3in ~laohol~ i~ up to ~iVe c,3rbon ~l.omsl. `, ~lo~o~ er, i~ ~Y ~a~r~ l here to ~ot.ple~oiy cov~r~ tne o$1s obta~ned rrom p3.ant~ to alkyl fatty ~cia elstOEs, in ptl-~clcul~r ae~hyl ~tty ~cid ~t~r.~, wr~i~h D~ans, on t~4 On~ hasl~, a hl~ exPendlture~ on th~
oth~r han~ lu~ o~ s~lyc~ine ~l~iah is -~
~icul'c to util~ze. ~he ~Iyd~cA~o~ ~nixtur-3 o~ Dl~-PS ::
31 ~9 170 i~ ~ cl~ical ga~ oil, i.. e. a ~e~roleum -f~aetlcn. ~he diesel ruel ~xtu~e5 o-t DE-P8 ~ ~ So ~8~
- m~y po~ly eont~lr 0.1 to ;% Sy wei~h~ of an i~nition aac~le~a~;or :iaid dl~ uels whlo~ ~o u~:4d in asri.^~lt~ra ~
tractor~ YQ ~-.loud Dolnts ~C~ e no~ ~elo r ~ C, due to wh~c~ 'chey ~n snly ~e used to a very l~tc:d flegr~ ~n ~nnter.
: : : ,: : ~ . ~:-:
A.tte81~s h~e hls2 alrea~y b~n ~o te ~a~e non-re~
~i~ d ~gP~t~bLe oils ~uerl a~ ~ps oi~ S'uels ln in~rnal ~olsl5u~ti.s*~ c~l~-6, .
~6-P5 4359324 d~elo-~ a ~.iesel ~uel con~lgting of ~o ~S~ Or ~ ~utyl ~lcohol ~n~l 75 to 25~ o~ a v~g~t;~bl~
o~l. US-P-~ ~557734 di~clos~s ~ d~,e~el fu~l con~i~t~ng o~
~ 1e oil, ~c~b~nol or oet~2.nol an~ ~ sCra~gnt Cl-ain oc~o~, US~PS 4509953 ~ w~.o~ieo 2~ di~c~l f~
oondctinq of 70 to 90 Vo;L~, sras oil or h-~vy oil r~spec,iiwly~ 10 to 30 ~Vol~ rthanol and up to 3D t~01~ .- :
gatoline- ~
Xa~re~ , erle use o~ these ~uo~ ay~: r-qulr-d n~iv- mc~llticatlon me~U~es ~rith rospect to ~he : .:
en9~ne~ opcr;~tcd wL'ch th i. DI~R, to thc~e ~c4ts ~he en~ral ps~udla~ w~ co~bor~ccd 'c~t it is l~npo~ib~
'co op~rate engines irlt~nded ~o~ operation ~i~ch mine~31 ~ue~S ~ h ~uels ha~lng a high ~harR of f att.y olls ; ~ ,~
u~t~out mD~ fi~ti~n ~e~ure~
,. ,.. . ~ ,.
.., .
- -- -- :. . ~ -.
~ 2109840 ~t ~g th~ ob~ o~ p~e~ inY~ n to p~c~v~de fu~l mlxture ln ~rhleh ratty o~l~ can bQ U9e~ ac ra~
~a~riall6, ttlSiah ~ro~ again~ ch ha6 an l~pro~rcd cloud Floin'C, ~ la~g~ly blolz~lca~y ce~o~po~Lable and c~l be SI A ~ ~es o f dl~sQl ~ ,ne~
w~tnou~ arly ;llo~rlcat~on mêasures, ~oreov~, lt shoul~
'b~ at lca~t c~u$vala~t ~o m~nc~l d~ uol~i as ~eg~e ~nln~ pe~So~ance and t~ aYoid ~ecr pheno-,~,n~ .
A~cDrd~ o the present ln~en~ion th~s ob~ecc is a~ne~ by 4 ~uol ~ctt~r~, wh~* eon~a~ns . .
- 8; ~t l~a¢t on~ V~t~bl~ andJor ani~nal o~
.
~) At. I P~t ~ne aliphatlc alCohol havin~J 1 to ~ c-a~oms and : .
c~ gaaoline.
Yor~over~ a proc~s for produci~ thls f~el mlxture is p~:o~ , ~hlch 1~ e'cari~ed ~n that ;~t lea3t n~ v~get~bl~ ~ndlos~ .~n~ l oil, At least one al ipha~ic ~locohol h~-~ing 1 to 5 C~ a lln~ ga~olin~ A~ mixed. - : :
S~id f~cl m~u~o ~s pr~ rably uoe~ ;!15 f~lel fo~ die~el es or a~ heatln~ oll.
rx~ple~ a2 the ~'egctable ndJor anl~l o$1~ uo-d 3a ~ :
a~mponan~ ~) in ~ne ruel ~lx~ accordlng ~o t~c inYen~ n are rape oil ~ ~oybc~n oil, cotton oil, ~nt~o~er oll, c~sto~ oil, olive oil, pe~nUt oil, ~ n oll, a~ond oil. F~ln ~c~el oll, cnconuS oll, ~ust2l.r ~Ll ~n~ SisJ olls. R~p~ oil ~?hlc2~ is a ~l~c~e c~f, f ~.tty ~:~cidfi partly esteri~$~d with ~lycerins ls used wl~n pre~e~cncQ a~ oo~ponent ~), eir~co a large ~uasltlty lL i~ vr~,il~J ~ an~l lt can 1~ o~tain~d. in ~ilmp~,y -~
~açhlon frtsm rspe 6~ds ~y mQan6 oS ~r~!~cin~. T;tle used rap6 c~. ca~ bo ~ix~d lnto t~e ~uel 211ix~ aaaordi~g the ~wenti~n bot~l c~udely p~essed and deguDmed ~nd -~
21098~0 ~4~ -:
a~ a ~fi~ A ~onverslon ~o al~cyl Qsto~ a i~ ~4 ~ ;
requ~d isl DE-PS 31 ~9 1~o ~nd ~ o ~ not necea~ary, D~e tD ~le ~i6s~n of this3 proc~ 5tGp i.
bQCo~06 pce611~ c~ Xet d~e~el fuels whicha~
b$ol~ ~ally dec~posal~le eo ~L çrreat ox~ent dir~ctly fram ~ ltural produe~lor~ wlthou~'c t~Q~e bc~ l~g - .
fu~ er ~gy casts an~ ~ras~e ma~er~ als suc:h as glyoox~!. ~e wcigh~ eh31ro of the oo~ponent .~ .in the fuel mi;xt~e /~cco~d~ ng t~ tlle lnventlon l~i ~ultably to 8-8% by voluD~e, ii 19 ere~e~a~ly bQ~wQ~n 65 and a5 ~ YO~ nd p~rtlcul~rly prcf~r~ed l;,.3tw~:n 70 ~nci 80 by vo~e. :
' lio~h t~ ht-ch~in ~nd b~an~d alcohDls w~ D
~-ato~ c~n b~ u~ed ae eO~ponent ~) ~n t~ '81 ~ixtur~
3000rd~n5 to th6 inYention. Mon~al~oh~ CiU~
t~an~1, e~al~o~, ~ropanol, bl2tAnol, p~nt~nol, iso~o~ru~ obutanol, t~r~f~7utor,01, ~ -me~r~ylbut~nol, 2-n~ct~ylbl~d~lol, 3-me~hylbu~anDl, 1, 1-dl~3et~ylpropanol ,?-~lim~h~lpropanol arQ us~ wi~}~ pr~ .eo, :
i~ollr4~ 01 b~ln~ osp~cl~l~y pr~rr6,~
~ulQrlol c~n al~o be. W~d, vh~ch, l~k- t-h~ u~d oil~
c-n be produl-ed i~ icul.~ l production . ~he weiqht 6~a~ of ~e cbnpon~nt b) ln the ~!u~l ~ixture a~!cord~ng to th~ irv~ntion 1~ pze~~ly G to 20~ ~y volu~ei it i~ ~n ga;cticular betwQen 10 arl~ 15~ ~y vt~lUme.
A~y optlon~l g~oL~ne C~n be ~sed ~6 ~a~so1int: ~:wuy~nent el ls~ U~e ruel ~u~e ~ceordi7~g to th~ in~ ion, r~ r o~-oI~ne or pr~iu~ad~ qc~coll~e; however, ::~ `
tc~ qaw1ine 13 used ~ tn pre~ere~ce. ~est gasolins ifi i. ~i~
th~ dcssig~ted ~o~ rcf~ncd g~col~o~ oil~ng point c~ 130 to 22~'C and a . na~h Po~nt asce~xalned aceor~ to ~bel-PHr~cy of ~ 21C ~cf. n~ 51 632, n Novo7nSer 19~1, dra~t ~Q~uarr ~ 6~. 'rhe te~t g~solir~
u~ed acGort.~ o t~e i~er~ion C~n ~ . q . have ar~ octane ~at~n~ os 120 to 1~ 0. qhe ~lght shar~ of th~ ~a.~rlin.~
c~o~ c) 1~ prc~cr3~1~f 6 to 20~ ~y ~o~e; ie 1~ ln p~t~c~læ b~twecn ~0 and 15~ by ~rolu~Q.
' ~: ': ;'"' - - ~,;-,- :
21~984~
~ . --5--.
C~0~3rs~ a~ tiyes o~n al~ bs added to t~e fuel D~e ~eeurdlno ~ the ~n~ention. t~ to 1~6 bv vol~lm,~
diQthyl l~thor ~s ~ ~ably added AS l~;ta~t~9- 21it ~or ~c ~per~tion of ~1~1 e~lnaG in ~inter.
uol ~it~re dCO~ to the ~ c~ntlon wl~ich is ~rod~ced ~ aixin~ the CO~pRnen~:~ a), b) an~ c) ~an bQ
used 1.n ~ll dies~l nginH~ ~rl~ou'c a ~peoial ~ets~oSit-~ins to the new ruel beln~ n-c~o~y. Accor~lingly, th~
~uel mix~-~re ~cco~ to the invent~on can e.g. 3~2~Ye for opero.t~ng ai~el ~n~lnqs 1~ ca2s, t~ucke, ff.gr~cu~
t~al and ro~R~ ao~n~o, 3tand-by uni~s, p~mps ln~l .hip6. ~eec cnglnes oar~ ~e oper?~tR(~ alt~rna~Lngly with the r..e~ re ac~ordis~g ~o t2~e i~vention an custo~-ary ~i.7-~ral diccel ~uel~, a h~ mobility ~ci~çl ~n p~tsc~la~ ~d~_ov~C ~'or -zr~ ~d ~
:: -~O ~ b.;Dl~ ~od a~ oo~,ponent b~ ~n *~e fuel mixtu.reac~;~rd~ ~o ttle ln~,rontion/ -ln pa~t~cular the i~;opro~
panol, cerve ~ ontl-colc~ng ,gent tar pi~ton ring~ ~nd D . ~b.e ~gol i nQ ~dde~ i!l3 ~dditi~re leads t~
~e c~ 'ica~l~n o~ ix~re and l~de to ar~
~pra~d igmition pe~l~Or~llaJlCQ 0~ ~c2~e 2~el r~.xtu~o, te9t ~ s21irle su~lyi ng tl~ bec~ v~ es A good i~nitio~
per~!o~nc- of tlle f~els me~ arl ad-~antageou~ start1~g o~ ~n~ a ~o~th r4nn~ o~ ~e ~ cl engine du~
t~ a short mixture prq?~ n cl~e or a ~hort i~ni~ion del~y; in the c~se o~ a lonc l~nltion d~lay, 'che kno~n ~d1es~1 ~no~ 8 ~Ludi~le.
: ~. ~ .:. -:
u~t qas te~ts arQ aa~1e~ ol,t S;lr t~e f~
~x~ure accDid~ng ~o ~he inYent~on used il~ d~e601 engin~-:, thc ~lues o~t~ d b~th for hy~lso~:~40n~i ~nd l ~ -ni~ogen oxlde~ an~ for c~bo~ ~on~xide are ~ar b~
~e Yalues r~quix~d by th~ ~e~ 1y ~alid Europ~n ,i: : . . ~ ::
21~8~ ~
~rd for ~i~se~, 6xb.4ustei gace~. ~h~ 6~ h~r dloxide ~e cf t~.e ~ sU~ 6~ S ;logll~ 3~11 25 co~p~re~ e uf~Ya~ cl; o~ o.15~ ln t~Q ~a~c; ol!
custo~lW, ~ne~2. dles~l ~uel~, ~inc~ tSc u~ed co~- :
pone~t~ prac~.oally ro~ ulp~l~r.
, ~rhe ~uel miX~llre accordlng ~o tne invemlon can also bQ
Y~ c lou 'ce~pcratllrc6 ~rithout any probl~ a~ t~zy occur ln lYlnter a~ta ln el~vatee~ re$~1c~s, buo~ it~
cl~u~ point resche Yaluos l~p to -2~C, 2n~ th~ ~xtus~
doe5 a~co not rlocculate Bt l~we~ t:emper~t~res. ~his lo~ sl~h~t~ti~lly ~rc~.der ~ppl~cability as -compare-l ~lth the kno~n di~4el fuel~ on mhc ba::;is o~
le and an~al ~ats.
~ne ~o~owi~ ~xa~pl~s d~d to~t~ ~xplain th~ in~ ~n~ion P~o~ct;ion examPl~ 1 tw S~
uel mi~urQ~ ~cs~r~ing to the in~remt~ on wer~
~r~uc~ by ~imp~e mix~ng ~` ;` :!.. , 1 ) ~ by olum~
ll 80 ~-E~han~l 10 ~ :
gular ~a~oline 10 -R~p- o~l 7S .
Ioop~op~r~ol 12 . 5 :~
~t ~a6011~e 1~.5 ,- : ,,~ ., ,.-: .
-: .;: ,. ~: ~
~"' ' ' ~ ~ : ' :
. ~, .
: ~
. 21 098~ 0 ~
; . . .
sr voiu~e Sun~ oi~ 73 ~aline l~.fi , ~p~ oil76 :~
P~p- oil74 pr~p~nol 12 ~e~nanol7 ~ -l onqine~ , .,, "~ "
q?he ~uel ~Xt~*a3 acco~dinSI to t.he ~nvent~on wer~ -t~ted ln d~ esel ~ncrlnes of ~ f~r~nt con~t~ction dt~n~ no2~el op~ration. ~ uetion vehicles wor~
o~nae~n a rhlch wer~ no~ led ln their eonstrue~
t~on. q~e ~ls~on d}spl~co~nt of t~a tcG'w:d nglnes w~O
~ve~ ~ . 6 1 ond 3, 0 1. All fuels msntione~ the 6 ~i~ to 5) wor¢ u~ed in th- v hicl~
!rhece t~ did not ro8ult ~ any ~unct1s~na~ t.urb~
~nce. ~inat.i ons c~ th ~ Y.6t ~ V21~ f a crlr JOO ~-turbo ~fter dri~rlng cycl~ r;c~ . 04 s~owed that the e~in~ion values ~ elo~ t~- ha~nda~y ~alu~s of ; :~
~nQ h~rc~p~n n~andard ~ icl~fl o~ thi~ const~uc~ ; - ~ -, ~
~-' ." , . ' ~ "~' ' ' . :' ; :
: ,:
2 1 5~0U9 thc ~ t g~a6 VtllU~S ~a~ ained ~or t~4 ~ Dlx~e aCco~iing ~io th~ ln~ --nt~on ac~tording tO o~le 2 It~t re~ult~ in she d~ a; cycle ) .
e~tl ~ou~y v~,lu~ ~gf~ EC~ ~ 04 ~or ~e~ ~L~u~ ~ .ccor~ylns~ fi~C~
t~ Lnvent1 CO 7.~,Z 3C,OO~C.OO .
8C ~ttl L~ Cl - -~C ~ 8.UO~Ø00 ~. . ` .~`
Jl Offli C~l~ S ~ . 2 5 6 _ 1 . 10 1 . 3 0 . ::.,.,. `:.,,-'~;:
':' '' ' .- ' '~
: . ., '.~:. ,~
',~
. . ,, ~ .. , ,. ,.~
:. ", ,"' ~;
:
:
: ; . ' ' . . :
- '.'- ' : . ' ' ' ~ . .. , ' ', ': .' ., , : ' ' ' " ' " . ` : :
Claims (10)
1. A fuel mixture containing a) 60 to 88% by volume of at least one vegetable and/or animal fatty oil, b) 6 to 20% by volume of an aliphatic alcohol with 1 to 5 c atoms, and c) 6 to 20% by volume gasoline.
2. A fuel mixture according to claim 1, characterized in that the component a) is selected from rape oil, soy bean oil, cotton oil, sunflower oil, castor oil, olive oil, corn oil, almond oil, palm kernel oil, coconut oil, mustard oil or peanut oil.
3. A fuel mixture according to claim 1 or 2, characterized in that the component a) is rape oil.
4. A fuel mixture according to claim 3, characterized in that the rape oil is crudely pressed and degummed.
5. A fuel mixture according to claim 3, characterized in that the rape oil is a raffinate.
6. A fuel mixture according to any of claims 1 to 5, characterized in that the component b) is a straight chain or branched monoalcohol.
7. A fuel mixture according to claim 6, characterized in that the component b) is isopropanol.
8. A fuel mixture according to any of claims 1 to 7, characterized in that the gasoline is a test gasoline.
9. A process for production of a fuel mixture according to any of claims 1 to 8, characterized in that a) 60 to 88% by volume of at least one vegetable and/or animal oil, b) 6 to 20% by volume of at least one straight chain or branched chain monoalcohol with 1 to 5 c atoms, and c) 6 to 20% by volume gasoline are mixed.
10. Use of a fuel mixture according to any of claims 1 to 8 as fuel for diesel engines or as heating oil.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEP4116905.0 | 1991-05-23 | ||
| DE4116905A DE4116905C1 (en) | 1991-05-23 | 1991-05-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA2109840A1 true CA2109840A1 (en) | 1992-11-26 |
Family
ID=6432292
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA002109840A Abandoned CA2109840A1 (en) | 1991-05-23 | 1992-05-19 | Fuel mixture, method of producing it, and its use |
Country Status (24)
| Country | Link |
|---|---|
| EP (1) | EP0587654B1 (en) |
| JP (1) | JPH06510804A (en) |
| CN (1) | CN1066871A (en) |
| AT (1) | ATE126262T1 (en) |
| AU (1) | AU1923392A (en) |
| BR (1) | BR9206047A (en) |
| CA (1) | CA2109840A1 (en) |
| CZ (1) | CZ250693A3 (en) |
| DE (2) | DE4116905C1 (en) |
| EC (1) | ECSP920833A (en) |
| HU (1) | HUT66425A (en) |
| IE (1) | IE66401B1 (en) |
| IL (1) | IL101919A0 (en) |
| MX (1) | MX9202451A (en) |
| MY (1) | MY108334A (en) |
| NZ (1) | NZ242871A (en) |
| PL (1) | PL168837B1 (en) |
| PT (1) | PT100510B (en) |
| SI (1) | SI9200086A (en) |
| UY (1) | UY23416A1 (en) |
| WO (1) | WO1992020761A1 (en) |
| YU (1) | YU53092A (en) |
| ZA (1) | ZA923754B (en) |
| ZW (1) | ZW7592A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7867296B2 (en) * | 2007-11-30 | 2011-01-11 | IFP Energies Nouvelles | High ethanol-content fuel compositions |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4333418C1 (en) * | 1993-09-30 | 1994-10-13 | Tessol Kraftstoffe Mineraloele | Fuel mixture |
| FR2728267B1 (en) * | 1994-12-14 | 1997-03-14 | Total Raffinage Distribution | NEW FUEL BASED ON VEGETABLE OIL AND AN OIL CUT RICH IN AROMATIC COMPOUNDS |
| IT1268891B1 (en) * | 1994-12-15 | 1997-03-13 | Alpha Trading Spa | LOW ENVIRONMENTAL IMPACT FUELS. |
| US6716258B2 (en) | 1999-12-21 | 2004-04-06 | Exxonmobil Research And Engineering Company | Fuel composition |
| US6447558B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
| US6447557B1 (en) | 1999-12-21 | 2002-09-10 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
| US6458176B2 (en) | 1999-12-21 | 2002-10-01 | Exxonmobil Research And Engineering Company | Diesel fuel composition |
| US7279018B2 (en) | 2002-09-06 | 2007-10-09 | Fortum Oyj | Fuel composition for a diesel engine |
| US8022258B2 (en) | 2005-07-05 | 2011-09-20 | Neste Oil Oyj | Process for the manufacture of diesel range hydrocarbons |
| JP5189981B2 (en) | 2006-08-18 | 2013-04-24 | Ｊｘ日鉱日石エネルギー株式会社 | Biomass processing method, fuel for fuel cell, gasoline, diesel fuel, liquefied petroleum gas and synthetic resin |
| KR101025406B1 (en) | 2007-01-11 | 2011-03-28 | 네모토 프로젝트 인더스트리 캄파니 리미티드 | Method for treating fuel oil |
| US8575409B2 (en) | 2007-12-20 | 2013-11-05 | Syntroleum Corporation | Method for the removal of phosphorus |
| US20090300971A1 (en) | 2008-06-04 | 2009-12-10 | Ramin Abhari | Biorenewable naphtha |
| US8581013B2 (en) | 2008-06-04 | 2013-11-12 | Syntroleum Corporation | Biorenewable naphtha composition and methods of making same |
| US8231804B2 (en) | 2008-12-10 | 2012-07-31 | Syntroleum Corporation | Even carbon number paraffin composition and method of manufacturing same |
| US8394900B2 (en) | 2010-03-18 | 2013-03-12 | Syntroleum Corporation | Profitable method for carbon capture and storage |
| US9328303B2 (en) | 2013-03-13 | 2016-05-03 | Reg Synthetic Fuels, Llc | Reducing pressure drop buildup in bio-oil hydroprocessing reactors |
| US8969259B2 (en) | 2013-04-05 | 2015-03-03 | Reg Synthetic Fuels, Llc | Bio-based synthetic fluids |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2010005A (en) * | 1932-04-06 | 1935-08-06 | Du Pont | Motor fuel |
| DE2441737A1 (en) * | 1974-08-30 | 1976-03-11 | Gerhard Goldmann | Liquid hydrocarbon motor fuels - contg alcohol-water mixts., to reduce combustion residues and save fuel |
| JPS5939000B2 (en) * | 1979-07-04 | 1984-09-20 | 積水化成品工業株式会社 | fuel composition |
| NZ194219A (en) * | 1980-04-10 | 1982-03-16 | Yanmar Diesel Engine Co | Diesel fuel containing an alcohol gas oil and castor oil |
| US4359324A (en) * | 1981-03-27 | 1982-11-16 | Elsea Jr Hugh R | Diesel engine fuel composition and use of same for operating diesel engines |
| JPS58208391A (en) * | 1982-05-31 | 1983-12-05 | Komatsu Ltd | Alcohol blend fuel for diesel engine |
| US4557734A (en) * | 1984-08-08 | 1985-12-10 | The United States Of America As Represented By The Secretary Of Agriculture | Microemulsions from vegetable oil and lower alcohol with octanol surfactant as alternative fuel for diesel engines |
-
1991
- 1991-05-23 DE DE4116905A patent/DE4116905C1/de not_active Expired - Fee Related
-
1992
- 1992-05-13 MY MYPI92000809A patent/MY108334A/en unknown
- 1992-05-15 EC EC1992000833A patent/ECSP920833A/en unknown
- 1992-05-15 ZW ZW75/92A patent/ZW7592A1/en unknown
- 1992-05-19 DE DE59203242T patent/DE59203242D1/en not_active Expired - Fee Related
- 1992-05-19 CN CN92102922A patent/CN1066871A/en active Pending
- 1992-05-19 CZ CS932506A patent/CZ250693A3/en unknown
- 1992-05-19 EP EP92911317A patent/EP0587654B1/en not_active Expired - Lifetime
- 1992-05-19 IL IL101919A patent/IL101919A0/en unknown
- 1992-05-19 AT AT92911317T patent/ATE126262T1/en not_active IP Right Cessation
- 1992-05-19 PL PL92301375A patent/PL168837B1/en unknown
- 1992-05-19 JP JP4510409A patent/JPH06510804A/en active Pending
- 1992-05-19 BR BR9206047A patent/BR9206047A/en not_active Application Discontinuation
- 1992-05-19 WO PCT/EP1992/001102 patent/WO1992020761A1/en active IP Right Grant
- 1992-05-19 AU AU19233/92A patent/AU1923392A/en not_active Abandoned
- 1992-05-19 CA CA002109840A patent/CA2109840A1/en not_active Abandoned
- 1992-05-19 HU HU9303305A patent/HUT66425A/en unknown
- 1992-05-20 YU YU53092A patent/YU53092A/en unknown
- 1992-05-20 UY UY23416A patent/UY23416A1/en unknown
- 1992-05-21 PT PT100510A patent/PT100510B/en not_active IP Right Cessation
- 1992-05-22 MX MX9202451A patent/MX9202451A/en unknown
- 1992-05-22 ZA ZA923754A patent/ZA923754B/en unknown
- 1992-05-22 SI SI19929200086A patent/SI9200086A/en unknown
- 1992-05-22 NZ NZ242871A patent/NZ242871A/en unknown
- 1992-07-01 IE IE921671A patent/IE66401B1/en not_active IP Right Cessation
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7867296B2 (en) * | 2007-11-30 | 2011-01-11 | IFP Energies Nouvelles | High ethanol-content fuel compositions |
Also Published As
| Publication number | Publication date |
|---|---|
| PT100510B (en) | 1999-07-30 |
| YU53092A (en) | 1994-06-24 |
| ATE126262T1 (en) | 1995-08-15 |
| ECSP920833A (en) | 1993-07-29 |
| IE66401B1 (en) | 1995-12-27 |
| UY23416A1 (en) | 1992-05-26 |
| CN1066871A (en) | 1992-12-09 |
| PT100510A (en) | 1993-10-29 |
| MX9202451A (en) | 1994-06-30 |
| AU1923392A (en) | 1992-12-30 |
| CZ250693A3 (en) | 1994-04-13 |
| DE4116905C1 (en) | 1992-08-13 |
| IL101919A0 (en) | 1992-12-30 |
| IE921671A1 (en) | 1992-12-02 |
| HU9303305D0 (en) | 1994-03-28 |
| EP0587654A1 (en) | 1994-03-23 |
| NZ242871A (en) | 1993-09-27 |
| EP0587654B1 (en) | 1995-08-09 |
| ZA923754B (en) | 1992-12-30 |
| ZW7592A1 (en) | 1992-09-23 |
| WO1992020761A1 (en) | 1992-11-26 |
| JPH06510804A (en) | 1994-12-01 |
| DE59203242D1 (en) | 1995-09-14 |
| MY108334A (en) | 1996-09-30 |
| PL168837B1 (en) | 1996-04-30 |
| BR9206047A (en) | 1995-05-30 |
| HUT66425A (en) | 1994-11-28 |
| SI9200086A (en) | 1992-11-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FZDE | Discontinued |