CA1334517C - Process for continuous electrodeposition of chromium metal and chromium oxide on metal surfaces - Google Patents
Process for continuous electrodeposition of chromium metal and chromium oxide on metal surfacesInfo
- Publication number
- CA1334517C CA1334517C CA000566584A CA566584A CA1334517C CA 1334517 C CA1334517 C CA 1334517C CA 000566584 A CA000566584 A CA 000566584A CA 566584 A CA566584 A CA 566584A CA 1334517 C CA1334517 C CA 1334517C
- Authority
- CA
- Canada
- Prior art keywords
- chromium
- electrolyte
- process according
- metal
- current
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 title claims abstract description 46
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical group [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims abstract description 41
- 229910000423 chromium oxide Inorganic materials 0.000 title claims abstract description 40
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 28
- 239000002184 metal Substances 0.000 title claims abstract description 28
- 238000004070 electrodeposition Methods 0.000 title claims abstract description 8
- 238000000034 method Methods 0.000 title claims description 28
- 239000003792 electrolyte Substances 0.000 claims abstract description 22
- 238000000576 coating method Methods 0.000 claims description 27
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 21
- 239000011248 coating agent Substances 0.000 claims description 21
- 239000011701 zinc Substances 0.000 claims description 21
- 229910052725 zinc Inorganic materials 0.000 claims description 21
- 238000011282 treatment Methods 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 4
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 4
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 4
- 229910004039 HBF4 Inorganic materials 0.000 claims description 3
- 229910004883 Na2SiF6 Inorganic materials 0.000 claims description 2
- 150000001844 chromium Chemical class 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 1
- 235000011149 sulphuric acid Nutrition 0.000 claims 1
- 239000011651 chromium Substances 0.000 abstract description 31
- 229910052804 chromium Inorganic materials 0.000 abstract description 26
- 230000007797 corrosion Effects 0.000 abstract description 19
- 238000005260 corrosion Methods 0.000 abstract description 19
- 238000000151 deposition Methods 0.000 abstract description 9
- 230000008021 deposition Effects 0.000 abstract description 8
- 229940035427 chromium oxide Drugs 0.000 description 36
- 229940107218 chromium Drugs 0.000 description 25
- 235000012721 chromium Nutrition 0.000 description 25
- 239000005029 tin-free steel Substances 0.000 description 9
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- 239000010410 layer Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 239000003973 paint Substances 0.000 description 6
- 239000000758 substrate Substances 0.000 description 6
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 4
- -1 hydro-gen ions Chemical class 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 241001600451 Chromis Species 0.000 description 3
- 229910001335 Galvanized steel Inorganic materials 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000008397 galvanized steel Substances 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000011780 sodium chloride Substances 0.000 description 3
- 229910001297 Zn alloy Inorganic materials 0.000 description 2
- 229910007567 Zn-Ni Inorganic materials 0.000 description 2
- 229910007614 Zn—Ni Inorganic materials 0.000 description 2
- 230000001464 adherent effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000003487 electrochemical reaction Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000036571 hydration Effects 0.000 description 2
- 238000006703 hydration reaction Methods 0.000 description 2
- 230000021962 pH elevation Effects 0.000 description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 2
- 229910019923 CrOx Inorganic materials 0.000 description 1
- 241001317374 Evides Species 0.000 description 1
- 101100007970 Mus musculus Ctdspl gene Proteins 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- 229910007570 Zn-Al Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920000136 polysorbate Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000004611 spectroscopical analysis Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000005028 tinplate Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/18—Electroplating using modulated, pulsed or reversing current
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/38—Chromatising
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/08—Electrolytic coating other than with metals with inorganic materials by cathodic processes
- C25D9/10—Electrolytic coating other than with metals with inorganic materials by cathodic processes on iron or steel
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/60—Electroplating characterised by the structure or texture of the layers
- C25D5/615—Microstructure of the layers, e.g. mixed structure
- C25D5/617—Crystalline layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S204/00—Chemistry: electrical and wave energy
- Y10S204/08—AC plus DC
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S204/00—Chemistry: electrical and wave energy
- Y10S204/09—Wave forms
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| IT47918A87 | 1987-05-13 | ||
| IT8747918A IT1216808B (it) | 1987-05-13 | 1987-05-13 | Processo di elettrodeposizione in continuo di cromo metallico e di ossido di cromo su superfici metalliche |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1334517C true CA1334517C (en) | 1995-02-21 |
Family
ID=11263343
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000566584A Expired - Fee Related CA1334517C (en) | 1987-05-13 | 1988-05-12 | Process for continuous electrodeposition of chromium metal and chromium oxide on metal surfaces |
Country Status (19)
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0637713B2 (ja) * | 1988-02-27 | 1994-05-18 | 日本鋼管株式会社 | 電解クロメート処理鋼板の製造方法 |
| GB2233347B (en) * | 1989-06-09 | 1994-01-05 | Toyo Kohan Co Ltd | Tin free steel having a chromium bilayer |
| DE3933896C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1989-10-11 | 1990-10-11 | Lpw-Chemie Gmbh, 4040 Neuss, De | |
| US5271823A (en) * | 1992-06-17 | 1993-12-21 | Eaton Corporation | Method of making a trivalent chromium plated engine valve |
| US6099714A (en) * | 1996-08-30 | 2000-08-08 | Sanchem, Inc. | Passification of tin surfaces |
| GB9705149D0 (en) * | 1997-03-13 | 1997-04-30 | Ea Tech Ltd | A method for chromating metals having surface oxide layers |
| US6096183A (en) * | 1997-12-05 | 2000-08-01 | Ak Steel Corporation | Method of reducing defects caused by conductor roll surface anomalies using high volume bottom sprays |
| JP2000282178A (ja) | 1998-10-22 | 2000-10-10 | Nsk Ltd | 転がり軸受 |
| US6331241B1 (en) | 2000-07-24 | 2001-12-18 | Usx Corporation | Method of making chromium-plated steel |
| JP3423702B2 (ja) * | 2000-08-29 | 2003-07-07 | 創輝株式会社 | 金属めっき方法 |
| US20020110700A1 (en) * | 2001-02-12 | 2002-08-15 | Hein Gerald F. | Process for forming decorative films and resulting products |
| US6879239B2 (en) * | 2002-04-08 | 2005-04-12 | Woodlane Environmental Technology, Inc. | Thermostat assembly |
| US7802379B2 (en) * | 2007-03-08 | 2010-09-28 | Nike, Inc. | Article of footwear with indented tip cleats |
| JP2009074168A (ja) * | 2007-08-30 | 2009-04-09 | Nissan Motor Co Ltd | クロムめっき部品およびその製造方法 |
| RU2627076C2 (ru) | 2012-03-30 | 2017-08-03 | Тата Стил Эймейден Б.В. | Подложка с покрытием для упаковочных применений и способ получения упомянутой подложки |
| EP2922984B1 (en) * | 2012-11-21 | 2018-11-14 | Tata Steel IJmuiden BV | Method for producing chromium-chromium oxide coatings applied to steel substrates for packaging applications |
| US10415148B2 (en) * | 2014-03-07 | 2019-09-17 | Macdermid Acumen, Inc. | Passivation of micro-discontinuous chromium deposited from a trivalent electrolyte |
| DE102017206722B4 (de) | 2016-04-26 | 2024-07-11 | Ford Global Technologies, Llc | Verfahren und Vorrichtung zur Herstellung einer beschichteten Oberfläche eines tribologischen Systems |
| US10590514B2 (en) | 2016-07-01 | 2020-03-17 | Xtalic Corporation | Nanostructured aluminum zirconium alloys for improved anodization |
| CN106119726B (zh) * | 2016-08-11 | 2017-12-12 | 宁波市鄞州亚大汽车管件有限公司 | 一种扣压套管接头的制备方法 |
| US10590558B2 (en) | 2016-09-23 | 2020-03-17 | Xtalic Corporation | Nanostructured aluminum alloys for improved hardness |
| CN114080472A (zh) * | 2019-06-26 | 2022-02-22 | 日立安斯泰莫株式会社 | 圆柱装置和金属制滑动部件以及金属制滑动部件的制造方法 |
| KR20230038427A (ko) * | 2020-07-15 | 2023-03-20 | 타타 스틸 네덜란드 테크날러지 베.뷔. | 3가 크롬 전해질로부터 기능성 또는 장식용 크롬층을 전착하는 방법 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3816082A (en) * | 1969-04-21 | 1974-06-11 | Nat Steel Corp | Method of improving the corrosion resistance of zinc coated ferrous metal substrates and the corrosion resistant substrates thus produced |
| US4167460A (en) * | 1978-04-03 | 1979-09-11 | Oxy Metal Industries Corporation | Trivalent chromium plating bath composition and process |
| GB2080827B (en) * | 1980-07-28 | 1984-02-08 | Teksid Spa | Corrosion-proofing metal by electroplating |
| IT1197609B (it) * | 1983-03-21 | 1988-12-06 | Centro Speriment Metallurg | Procedimento perfezionato per la produzione di nastri di acciaio rivestiti |
| IT1212859B (it) * | 1983-03-21 | 1989-11-30 | Centro Speriment Metallurg | Laminati piatti di acciaio rivestiti perfezionati |
| IT1182782B (it) * | 1985-07-18 | 1987-10-05 | Centro Speriment Metallurg | Perfezionamento nei procedimenti di zincatura elettrolitica |
| FR2586711B1 (fr) * | 1985-09-03 | 1989-10-06 | Centre Techn Ind Mecanique | Procede et installation de chromage electrolytique |
-
1987
- 1987-05-13 IT IT8747918A patent/IT1216808B/it active
-
1988
- 1988-04-21 CH CH1475/88A patent/CH679487A5/it not_active IP Right Cessation
- 1988-05-04 MX MX011370A patent/MX167815B/es unknown
- 1988-05-05 AU AU15614/88A patent/AU598928B2/en not_active Ceased
- 1988-05-06 BE BE8800535A patent/BE1001324A3/fr not_active IP Right Cessation
- 1988-05-10 NL NL8801225A patent/NL8801225A/nl not_active Application Discontinuation
- 1988-05-11 IL IL86343A patent/IL86343A/xx unknown
- 1988-05-11 DE DE3816265A patent/DE3816265A1/de active Granted
- 1988-05-11 ES ES8801465A patent/ES2007222A6/es not_active Expired
- 1988-05-11 BR BR8802397A patent/BR8802397A/pt not_active Application Discontinuation
- 1988-05-11 SE SE8801800A patent/SE465517B/sv not_active IP Right Cessation
- 1988-05-11 FR FR888806385A patent/FR2615206B1/fr not_active Expired - Lifetime
- 1988-05-11 AT AT0124088A patent/AT395723B/de not_active IP Right Cessation
- 1988-05-12 GR GR880100309A patent/GR1000166B/el unknown
- 1988-05-12 YU YU919/88A patent/YU45501B/xx unknown
- 1988-05-12 CA CA000566584A patent/CA1334517C/en not_active Expired - Fee Related
- 1988-05-13 JP JP63115034A patent/JPS63303090A/ja active Granted
- 1988-05-13 GB GB8811391A patent/GB2204594B/en not_active Expired - Fee Related
- 1988-05-17 US US07/195,958 patent/US4875983A/en not_active Expired - Fee Related
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |