CA1283273C - Process and apparatus for carrying out oxidation in the anthraquinone process for the preparation of hydrogen peroxide - Google Patents
Process and apparatus for carrying out oxidation in the anthraquinone process for the preparation of hydrogen peroxideInfo
- Publication number
- CA1283273C CA1283273C CA000508543A CA508543A CA1283273C CA 1283273 C CA1283273 C CA 1283273C CA 000508543 A CA000508543 A CA 000508543A CA 508543 A CA508543 A CA 508543A CA 1283273 C CA1283273 C CA 1283273C
- Authority
- CA
- Canada
- Prior art keywords
- working solution
- gas
- reactor
- process according
- hydrogenated working
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000000034 method Methods 0.000 title claims abstract description 31
- 238000007254 oxidation reaction Methods 0.000 title claims abstract description 27
- 230000003647 oxidation Effects 0.000 title claims abstract description 26
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 title claims abstract description 12
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 title claims abstract description 9
- 150000004056 anthraquinones Chemical class 0.000 title claims abstract description 9
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000007789 gas Substances 0.000 claims abstract description 46
- 239000012224 working solution Substances 0.000 claims abstract description 38
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims abstract description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000001301 oxygen Substances 0.000 claims abstract description 5
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 5
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 4
- 125000004122 cyclic group Chemical group 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 14
- 239000007788 liquid Substances 0.000 claims description 7
- 238000002309 gasification Methods 0.000 claims 1
- 239000000463 material Substances 0.000 description 5
- 238000012856 packing Methods 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- -1 hydroquinone compound Chemical class 0.000 description 3
- FYGHSUNMUKGBRK-UHFFFAOYSA-N 1,2,3-trimethylbenzene Chemical compound CC1=CC=CC(C)=C1C FYGHSUNMUKGBRK-UHFFFAOYSA-N 0.000 description 2
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- QNLZIZAQLLYXTC-UHFFFAOYSA-N 1,2-dimethylnaphthalene Chemical compound C1=CC=CC2=C(C)C(C)=CC=C21 QNLZIZAQLLYXTC-UHFFFAOYSA-N 0.000 description 2
- AZQWKYJCGOJGHM-UHFFFAOYSA-N 1,4-benzoquinone Chemical compound O=C1C=CC(=O)C=C1 AZQWKYJCGOJGHM-UHFFFAOYSA-N 0.000 description 2
- QPUYECUOLPXSFR-UHFFFAOYSA-N 1-methylnaphthalene Chemical compound C1=CC=C2C(C)=CC=CC2=C1 QPUYECUOLPXSFR-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OLBVUFHMDRJKTK-UHFFFAOYSA-N [N].[O] Chemical compound [N].[O] OLBVUFHMDRJKTK-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229930195733 hydrocarbon Natural products 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000001228 spectrum Methods 0.000 description 2
- YTZKOQUCBOVLHL-UHFFFAOYSA-N tert-butylbenzene Chemical compound CC(C)(C)C1=CC=CC=C1 YTZKOQUCBOVLHL-UHFFFAOYSA-N 0.000 description 2
- 238000009827 uniform distribution Methods 0.000 description 2
- HSKPJQYAHCKJQC-UHFFFAOYSA-N 1-ethylanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2CC HSKPJQYAHCKJQC-UHFFFAOYSA-N 0.000 description 1
- JORLUGVBYJSSAW-UHFFFAOYSA-N 2-ethyl-1,2,3,4-tetrahydroanthracene-9,10-dione Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1CC(CC)CC2 JORLUGVBYJSSAW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- GTVWRXDRKAHEAD-UHFFFAOYSA-N Tris(2-ethylhexyl) phosphate Chemical compound CCCCC(CC)COP(=O)(OCC(CC)CCCC)OCC(CC)CCCC GTVWRXDRKAHEAD-UHFFFAOYSA-N 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000006267 biphenyl group Chemical group 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229940110728 nitrogen / oxygen Drugs 0.000 description 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/022—Preparation from organic compounds
- C01B15/023—Preparation from organic compounds by the alkyl-anthraquinone process
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00168—Controlling or regulating processes controlling the viscosity
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT136185 | 1985-05-07 | ||
| ATA1361/85 | 1985-05-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1283273C true CA1283273C (en) | 1991-04-23 |
Family
ID=3512223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000508543A Expired - Fee Related CA1283273C (en) | 1985-05-07 | 1986-05-06 | Process and apparatus for carrying out oxidation in the anthraquinone process for the preparation of hydrogen peroxide |
Country Status (10)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE541158C2 (en) * | 2017-04-19 | 2019-04-16 | Eb Nuberg Ab | Oxidation column for hydrogen peroxide production |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FI82920C (fi) * | 1989-09-22 | 1995-04-04 | Kemira Oy | Foerfarande foer framstaellning av vaeteperoxid |
| FR2730987B1 (fr) * | 1995-02-28 | 1997-05-23 | Chemoxal Sa | Installation de production d'eau oxygenee sur le site d'une papeterie |
| DE19843573A1 (de) | 1998-09-23 | 2000-03-30 | Degussa | Blasensäule und deren Verwendung |
| DE10052323A1 (de) | 2000-10-21 | 2002-05-02 | Degussa | Kontinierliches Verfahren zur Hydrierung |
| EP1209122A1 (de) * | 2000-11-24 | 2002-05-29 | Degussa AG | Verfahren zur kontinuierlichen Oxidation |
| DE10207407A1 (de) | 2002-02-21 | 2003-09-04 | Degussa | Verfahren zur Herstellung von Wasserstoffperoxid |
| EP1919825B1 (en) * | 2005-08-31 | 2012-01-04 | Fmc Corporation | Auto-oxidation production of hydrogen peroxide via oxidation in a microreactor |
| JP2015020940A (ja) * | 2013-07-22 | 2015-02-02 | 国立大学法人静岡大学 | 過酸化水素合成方法 |
| CN105800565A (zh) * | 2014-12-31 | 2016-07-27 | 湖南长岭石化科技开发有限公司 | 蒽醌法制过氧化氢的氢化方法和生产过氧化氢的方法 |
| CN105800562A (zh) * | 2014-12-31 | 2016-07-27 | 湖南长岭石化科技开发有限公司 | 蒽醌法制过氧化氢的萃取方法和过氧化氢的制备方法 |
| CN105800563A (zh) * | 2014-12-31 | 2016-07-27 | 湖南长岭石化科技开发有限公司 | 蒽醌法制过氧化氢的氧化萃取方法和生产过氧化氢的方法 |
| CN105800564A (zh) * | 2014-12-31 | 2016-07-27 | 湖南长岭石化科技开发有限公司 | 蒽醌法制过氧化氢的氧化方法和生产过氧化氢的方法 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE740674C (de) * | 1939-07-05 | 1943-10-26 | Ig Farbenindustrie Ag | Durchfuehrung von Reaktionen zwischen Gasen und Fluessigkeiten |
| GB740051A (en) * | 1953-04-01 | 1955-11-09 | Pintsch Bamag Ag | Method of continuously performing reactions between gases and liquid |
| DE1212970C2 (de) * | 1960-10-18 | 1966-09-29 | Bombrini Parodi Delfino Societ | Vorrichtung zur katalytischen Oxydation von organischen Verbindungen im fluessigen Zustand mit Sauerstoff |
| DE2003268C3 (de) * | 1970-01-26 | 1974-01-31 | Deutsche Gold- Und Silber-Scheideanstalt Vormals Roessler, 6000 Frankfurt | Vorrichtung zur Durchführung der Oxydation im Anthrachinonverfahren zur Herstellung von Wasserstoffperoxid |
| SE377455B (enrdf_load_stackoverflow) * | 1973-05-11 | 1975-07-07 | Elektrokemiska Ab | |
| US4428923A (en) * | 1982-11-09 | 1984-01-31 | Degussa Aktiengesellschaft | Continuous process for the production of hydrogen peroxide according to the anthraquinone process |
-
1986
- 1986-04-29 IN IN382/DEL/86A patent/IN168293B/en unknown
- 1986-04-30 ZA ZA863259A patent/ZA863259B/xx unknown
- 1986-05-06 CA CA000508543A patent/CA1283273C/en not_active Expired - Fee Related
- 1986-05-06 EP EP86902766A patent/EP0221931B1/de not_active Expired
- 1986-05-06 DE DE8686902766T patent/DE3666797D1/de not_active Expired
- 1986-05-06 WO PCT/AT1986/000039 patent/WO1986006710A1/de active IP Right Grant
- 1986-05-06 AU AU58681/86A patent/AU587257B2/en not_active Ceased
- 1986-05-06 AT AT86902766T patent/ATE47819T1/de not_active IP Right Cessation
- 1986-05-06 JP JP61502651A patent/JPS62502821A/ja active Pending
- 1986-05-06 AR AR30386686A patent/AR240549A1/es active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE541158C2 (en) * | 2017-04-19 | 2019-04-16 | Eb Nuberg Ab | Oxidation column for hydrogen peroxide production |
Also Published As
| Publication number | Publication date |
|---|---|
| AU5868186A (en) | 1986-12-04 |
| WO1986006710A1 (en) | 1986-11-20 |
| AU587257B2 (en) | 1989-08-10 |
| ATE47819T1 (de) | 1989-11-15 |
| AR240549A1 (es) | 1990-05-31 |
| DE3666797D1 (en) | 1989-12-14 |
| EP0221931A1 (de) | 1987-05-20 |
| IN168293B (enrdf_load_stackoverflow) | 1991-03-09 |
| ZA863259B (en) | 1986-12-30 |
| EP0221931B1 (de) | 1989-11-08 |
| JPS62502821A (ja) | 1987-11-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |