CA1275223C - Detergent compositions - Google Patents
Detergent compositionsInfo
- Publication number
- CA1275223C CA1275223C CA000514216A CA514216A CA1275223C CA 1275223 C CA1275223 C CA 1275223C CA 000514216 A CA000514216 A CA 000514216A CA 514216 A CA514216 A CA 514216A CA 1275223 C CA1275223 C CA 1275223C
- Authority
- CA
- Canada
- Prior art keywords
- soap
- weight
- detergent
- sodium
- composition according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000003599 detergent Substances 0.000 title claims abstract description 77
- 150000001875 compounds Chemical class 0.000 claims abstract description 43
- 239000000344 soap Substances 0.000 claims abstract description 38
- 229920003086 cellulose ether Polymers 0.000 claims abstract description 25
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 15
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims abstract description 13
- -1 C20 primary Chemical class 0.000 claims description 24
- 229910052708 sodium Inorganic materials 0.000 claims description 20
- 239000011734 sodium Substances 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 18
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 10
- 229920001479 Hydroxyethyl methyl cellulose Polymers 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000003333 secondary alcohols Chemical class 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 18
- 238000005406 washing Methods 0.000 abstract description 18
- 239000003795 chemical substances by application Substances 0.000 abstract description 15
- 239000002689 soil Substances 0.000 abstract description 11
- 235000021317 phosphate Nutrition 0.000 description 13
- 125000000217 alkyl group Chemical group 0.000 description 11
- 239000000843 powder Substances 0.000 description 11
- 150000003839 salts Chemical class 0.000 description 11
- 239000000047 product Substances 0.000 description 9
- 229920002678 cellulose Polymers 0.000 description 8
- 239000001913 cellulose Substances 0.000 description 8
- 235000010980 cellulose Nutrition 0.000 description 8
- 239000003760 tallow Substances 0.000 description 8
- 238000009472 formulation Methods 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 125000000129 anionic group Chemical group 0.000 description 6
- 239000003240 coconut oil Substances 0.000 description 6
- 235000019864 coconut oil Nutrition 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- YLGXILFCIXHCMC-JHGZEJCSSA-N methyl cellulose Chemical compound COC1C(OC)C(OC)C(COC)O[C@H]1O[C@H]1C(OC)C(OC)C(OC)OC1COC YLGXILFCIXHCMC-JHGZEJCSSA-N 0.000 description 6
- 229910052700 potassium Inorganic materials 0.000 description 6
- 239000011591 potassium Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- 239000000499 gel Substances 0.000 description 5
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 5
- 229920001983 poloxamer Polymers 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 4
- 229920000812 Crimplene Polymers 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 4
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 4
- 239000002253 acid Substances 0.000 description 4
- 239000007795 chemical reaction product Substances 0.000 description 4
- 229920001577 copolymer Polymers 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- TWNIBLMWSKIRAT-VFUOTHLCSA-N levoglucosan Chemical group O[C@@H]1[C@@H](O)[C@H](O)[C@H]2CO[C@@H]1O2 TWNIBLMWSKIRAT-VFUOTHLCSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 3
- 244000060011 Cocos nucifera Species 0.000 description 3
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 239000007844 bleaching agent Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000008233 hard water Substances 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 150000004760 silicates Chemical class 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FRPJTGXMTIIFIT-UHFFFAOYSA-N tetraacetylethylenediamine Chemical compound CC(=O)C(N)(C(C)=O)C(N)(C(C)=O)C(C)=O FRPJTGXMTIIFIT-UHFFFAOYSA-N 0.000 description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- 229920013683 Celanese Polymers 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 150000001253 acrylic acids Chemical class 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 2
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 description 2
- 150000007942 carboxylates Chemical class 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- SUMDYPCJJOFFON-UHFFFAOYSA-N isethionic acid Chemical compound OCCS(O)(=O)=O SUMDYPCJJOFFON-UHFFFAOYSA-N 0.000 description 2
- 238000010412 laundry washing Methods 0.000 description 2
- 150000004668 long chain fatty acids Chemical class 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000002540 palm oil Substances 0.000 description 2
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 description 2
- 125000003703 phosphorus containing inorganic group Chemical group 0.000 description 2
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 2
- 229920000058 polyacrylate Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 159000000001 potassium salts Chemical class 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 2
- 229960001922 sodium perborate Drugs 0.000 description 2
- 229940045872 sodium percarbonate Drugs 0.000 description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000004711 α-olefin Substances 0.000 description 2
- YRIZYWQGELRKNT-UHFFFAOYSA-N 1,3,5-trichloro-1,3,5-triazinane-2,4,6-trione Chemical compound ClN1C(=O)N(Cl)C(=O)N(Cl)C1=O YRIZYWQGELRKNT-UHFFFAOYSA-N 0.000 description 1
- CFPOJWPDQWJEMO-UHFFFAOYSA-N 2-(1,2-dicarboxyethoxy)butanedioic acid Chemical compound OC(=O)CC(C(O)=O)OC(C(O)=O)CC(O)=O CFPOJWPDQWJEMO-UHFFFAOYSA-N 0.000 description 1
- MIJDSYMOBYNHOT-UHFFFAOYSA-N 2-(ethylamino)ethanol Chemical compound CCNCCO MIJDSYMOBYNHOT-UHFFFAOYSA-N 0.000 description 1
- 102000013142 Amylases Human genes 0.000 description 1
- 108010065511 Amylases Proteins 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- BHPQYMZQTOCNFJ-UHFFFAOYSA-N Calcium cation Chemical compound [Ca+2] BHPQYMZQTOCNFJ-UHFFFAOYSA-N 0.000 description 1
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical class OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 229920003091 Methocel™ Polymers 0.000 description 1
- SUZRRICLUFMAQD-UHFFFAOYSA-N N-Methyltaurine Chemical compound CNCCS(O)(=O)=O SUZRRICLUFMAQD-UHFFFAOYSA-N 0.000 description 1
- OPKOKAMJFNKNAS-UHFFFAOYSA-N N-methylethanolamine Chemical compound CNCCO OPKOKAMJFNKNAS-UHFFFAOYSA-N 0.000 description 1
- JSZVAKSQKFZKNG-UHFFFAOYSA-K P(=O)(O)(O)C(C(C(=O)[O-])(C(=O)[O-])C(=O)[O-])CC.[Na+].[Na+].[Na+] Chemical compound P(=O)(O)(O)C(C(C(=O)[O-])(C(=O)[O-])C(=O)[O-])CC.[Na+].[Na+].[Na+] JSZVAKSQKFZKNG-UHFFFAOYSA-K 0.000 description 1
- BVBIQASDHXEFKW-UHFFFAOYSA-N P1(OCCCCO1)=O.C(CN)N.[Na] Chemical compound P1(OCCCCO1)=O.C(CN)N.[Na] BVBIQASDHXEFKW-UHFFFAOYSA-N 0.000 description 1
- 102000035195 Peptidases Human genes 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 229920000805 Polyaspartic acid Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 239000004365 Protease Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 150000008041 alkali metal carbonates Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004996 alkyl benzenes Chemical class 0.000 description 1
- 229920013820 alkyl cellulose Polymers 0.000 description 1
- 229910000323 aluminium silicate Inorganic materials 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000019418 amylase Nutrition 0.000 description 1
- 229940025131 amylases Drugs 0.000 description 1
- 229920001448 anionic polyelectrolyte Polymers 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical class OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910001424 calcium ion Inorganic materials 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 230000000536 complexating effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 229960002887 deanol Drugs 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 239000012972 dimethylethanolamine Substances 0.000 description 1
- 235000011180 diphosphates Nutrition 0.000 description 1
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 229940012017 ethylenediamine Drugs 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 229920013821 hydroxy alkyl cellulose Polymers 0.000 description 1
- 229910052816 inorganic phosphate Inorganic materials 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 229940045996 isethionic acid Drugs 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- ZBJVLWIYKOAYQH-UHFFFAOYSA-N naphthalen-2-yl 2-hydroxybenzoate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=C(C=CC=C2)C2=C1 ZBJVLWIYKOAYQH-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- MPQXHAGKBWFSNV-UHFFFAOYSA-N oxidophosphanium Chemical group [PH3]=O MPQXHAGKBWFSNV-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- HVAMZGADVCBITI-UHFFFAOYSA-M pent-4-enoate Chemical compound [O-]C(=O)CCC=C HVAMZGADVCBITI-UHFFFAOYSA-M 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 108010064470 polyaspartate Proteins 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 235000015497 potassium bicarbonate Nutrition 0.000 description 1
- TYJJADVDDVDEDZ-UHFFFAOYSA-M potassium hydrogencarbonate Chemical class [K+].OC([O-])=O TYJJADVDDVDEDZ-UHFFFAOYSA-M 0.000 description 1
- 235000013966 potassium salts of fatty acid Nutrition 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003138 primary alcohols Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- ZMRUPTIKESYGQW-UHFFFAOYSA-N propranolol hydrochloride Chemical compound [H+].[Cl-].C1=CC=C2C(OCC(O)CNC(C)C)=CC=CC2=C1 ZMRUPTIKESYGQW-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000017557 sodium bicarbonate Nutrition 0.000 description 1
- WBHQBSYUUJJSRZ-UHFFFAOYSA-M sodium bisulfate Chemical compound [Na+].OS([O-])(=O)=O WBHQBSYUUJJSRZ-UHFFFAOYSA-M 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- MKWYFZFMAMBPQK-UHFFFAOYSA-J sodium feredetate Chemical compound [Na+].[Fe+3].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O MKWYFZFMAMBPQK-UHFFFAOYSA-J 0.000 description 1
- RYYKJJJTJZKILX-UHFFFAOYSA-M sodium octadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCCCC([O-])=O RYYKJJJTJZKILX-UHFFFAOYSA-M 0.000 description 1
- 229940045870 sodium palmitate Drugs 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- 235000013875 sodium salts of fatty acid Nutrition 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- GGXKEBACDBNFAF-UHFFFAOYSA-M sodium;hexadecanoate Chemical compound [Na+].CCCCCCCCCCCCCCCC([O-])=O GGXKEBACDBNFAF-UHFFFAOYSA-M 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 238000001694 spray drying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 229950009390 symclosene Drugs 0.000 description 1
- 239000000271 synthetic detergent Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229960004418 trolamine Drugs 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
- C11D10/045—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap based on non-ionic surface-active compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB858519046A GB8519046D0 (en) | 1985-07-29 | 1985-07-29 | Detergent compositions |
| GB8519046 | 1985-07-29 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1275223C true CA1275223C (en) | 1990-10-16 |
Family
ID=10582999
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000514216A Expired - Fee Related CA1275223C (en) | 1985-07-29 | 1986-07-21 | Detergent compositions |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4732693A (en, 2012) |
| EP (1) | EP0213729B1 (en, 2012) |
| JP (1) | JPS6335700A (en, 2012) |
| AU (1) | AU569195B2 (en, 2012) |
| BR (1) | BR8603565A (en, 2012) |
| CA (1) | CA1275223C (en, 2012) |
| DE (1) | DE3669885D1 (en, 2012) |
| GB (1) | GB8519046D0 (en, 2012) |
| ZA (1) | ZA865613B (en, 2012) |
Families Citing this family (50)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB8519047D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent composition |
| AU605825B2 (en) * | 1987-01-29 | 1991-01-24 | Unilever Plc | Fabric conditioning composition |
| TR23614A (tr) * | 1987-01-29 | 1990-04-30 | Unilever Nv | Camasir oktanli benzin ueretimi |
| US5049302A (en) * | 1988-10-06 | 1991-09-17 | Basf Corporation | Stable liquid detergent compositions with enchanced clay soil detergency and anti-redeposition properties |
| IT1240684B (it) * | 1990-04-26 | 1993-12-17 | Tecnopart Srl | Poliamminoacidi quali builders per formulazioni detergenti |
| US5328690A (en) * | 1991-02-21 | 1994-07-12 | University Of South Alabama | Polyamino acid dispersants |
| WO1992015535A1 (en) * | 1991-03-06 | 1992-09-17 | Donlar Corporation | Polyaspartic acid and its salts for dispersing suspended solids |
| US5284512A (en) * | 1991-03-06 | 1994-02-08 | Donlar Corporation | Polyaspartic acid and its salts for dispersing suspended solids |
| TW239160B (en, 2012) * | 1992-10-27 | 1995-01-21 | Procter & Gamble | |
| FR2708279B1 (fr) * | 1993-07-08 | 1995-09-01 | Rhone Poulenc Chimie | Agent pour formulation détergente à base d'un polyimide et d'un silicate. |
| US6007769A (en) * | 1994-09-06 | 1999-12-28 | S. C. Johnson & Son, Inc. | Single-phase soap compositions |
| GB2297978A (en) † | 1995-02-15 | 1996-08-21 | Procter & Gamble | Detergent compositions containing amylase |
| JP3395488B2 (ja) * | 1995-11-15 | 2003-04-14 | 味の素株式会社 | 毛髪化粧料 |
| EP0900268B1 (en) * | 1996-04-24 | 2001-01-31 | Unilever Plc | Synthetic bar composition comprising alkoxylated surfactants |
| DE19757217A1 (de) * | 1997-12-22 | 1999-06-24 | Henkel Kgaa | Teilchenförmiges Wasch- und Reinigungsmittel |
| GB0127036D0 (en) * | 2001-11-09 | 2002-01-02 | Unilever Plc | Polymers for laundry applications |
| ES2275207T5 (es) † | 2003-02-10 | 2011-12-09 | HENKEL AG & CO. KGAA | Agente de lavado, que contiene agentes de blanqueo, con derivado de la celulosa con capacidad para el desprendimiento de la suciedad, con actividad sobre el algodón. |
| DE502004003835D1 (de) * | 2003-02-10 | 2007-06-28 | Henkel Kgaa | Bleichmittelhaltige wasch- oder reinigungsmittel mit wasserlöslichem buildersystem und schmutzablösevermögendem cellulosederivat |
| EP1592768A2 (de) * | 2003-02-10 | 2005-11-09 | Henkel Kommanditgesellschaft auf Aktien | Verwendung von cellulosederivaten als schaumregulatoren |
| ES2286602T3 (es) * | 2003-02-10 | 2007-12-01 | Henkel Kommanditgesellschaft Auf Aktien | Antecedentes de la invencion. |
| DE10351325A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Wasch- oder Reinigungsmittel mit wasserlöslichem Buildersystem und schmutzablösevermögendem Cellulosederivat |
| DE10351321A1 (de) * | 2003-02-10 | 2004-08-26 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch eine Kombination von Cellulosderivaten |
| ES2279344T3 (es) * | 2003-02-10 | 2007-08-16 | Henkel Kommanditgesellschaft Auf Aktien | Aumento de la capacidad de absorcion de agua de textiles. |
| DE102005026544A1 (de) | 2005-06-08 | 2006-12-14 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
| DE102005026522B4 (de) | 2005-06-08 | 2007-04-05 | Henkel Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch Polymer |
| DE102006039873B4 (de) * | 2006-08-25 | 2013-10-31 | Henkel Ag & Co. Kgaa | Verstärkung der Reinigungsleistung von Waschmitteln durch baumwollaktives schmutzablösevermögendes Cellulosederivat |
| DE102007023827A1 (de) | 2007-05-21 | 2008-11-27 | Henkel Ag & Co. Kgaa | Waschmittel, enthaltend reaktive cyclische Carbonate oder Harnstoffe oder deren Derivate als schmutzablösevermögende Wirkstoffe |
| DE102007038456A1 (de) | 2007-08-14 | 2009-02-19 | Henkel Ag & Co. Kgaa | Polycarbonat-, Polyurethan- und/oder Polyharnstoff-Polyorganosiloxan-Verbindungen als schmutzablösevermögende Wirkstoffe |
| EP2487230B1 (de) | 2007-04-03 | 2014-12-03 | Henkel AG & Co. KGaA | Farbschützendes Wasch- oder Reinigungsmittel |
| WO2008119834A1 (de) | 2007-04-03 | 2008-10-09 | Henkel Ag & Co. Kgaa | Reinigungsmittel |
| EP2487231B1 (de) | 2007-04-03 | 2015-08-05 | Henkel AG & Co. KGaA | Mittel zur Behandlung harter Oberflächen |
| ES2554983T3 (es) | 2007-04-03 | 2015-12-28 | Henkel Ag & Co. Kgaa | Agente de lavado inhibidor del agrisado |
| EP2134824A2 (de) | 2007-04-03 | 2009-12-23 | Henkel AG & Co. KGaA | Waschmittel mit die primärwaschkraft verbessernden wirkstoffen |
| DE102010028378A1 (de) | 2010-04-29 | 2011-11-03 | Henkel Ag & Co. Kgaa | Polyelektrolyt-Komplexe als schmutzablösevermögende Wirkstoffe |
| DE102012206014A1 (de) | 2012-04-12 | 2013-10-17 | Henkel Ag & Co. Kgaa | Mikrofibrilläre Cellulose als schmutzablösevermögender Wirkstoff |
| DE102013219183A1 (de) | 2013-09-24 | 2015-03-26 | Henkel Ag & Co. Kgaa | Cellulosecarbamate als schmutzablösevermögende Wirkstoffe |
| DE102013226005A1 (de) | 2013-12-16 | 2015-06-18 | Henkel Ag & Co. Kgaa | Siloxangruppen-haltige Copolymere als schmutzablösevermögende Wirkstoffe |
| DE102014206987A1 (de) | 2014-04-11 | 2015-10-15 | Henkel Ag & Co. Kgaa | Glycerinesterderivate als schmutzablösevermögende Wirkstoffe |
| DE102015003483A1 (de) | 2015-03-19 | 2016-09-22 | Henkel Ag & Co. Kgaa | Polymere Ester aromatischer Dicarbonsäuren als schmutzablösevermögende Wirkstoffe |
| DE102015224954A1 (de) | 2015-12-11 | 2017-06-14 | Henkel Ag & Co. Kgaa | Reinigungsverstärkende Celluloseether |
| ES2682176T3 (es) | 2016-01-21 | 2018-09-19 | Henkel Ag & Co. Kgaa | Eliminación de suciedades de antitranspirante |
| DE102016202143A1 (de) | 2016-02-12 | 2017-08-17 | Henkel Ag & Co. Kgaa | 6-Desoxy-6-amino-cellulosen als schmutzablösevermögende Wirkstoffe |
| DE102018209990A1 (de) | 2018-06-20 | 2019-12-24 | Henkel Ag & Co. Kgaa | Xylosecarbamate als schmutzablösevermögende Wirkstoffe |
| DE102018210012A1 (de) | 2018-06-20 | 2019-12-24 | Henkel Ag & Co. Kgaa | Chitosanderivate als schmutzablösevermögende Wirkstoffe |
| DE102018209992A1 (de) | 2018-06-20 | 2019-12-24 | Henkel Ag & Co. Kgaa | Pullulanderivate als schmutzablösende Wirkstoffe |
| DE102020200175A1 (de) | 2020-01-09 | 2021-07-15 | Henkel Ag & Co. Kgaa | Carboxymethylierte Poly(2-Vinylpyridine) als schmutzablösevermögende Wirkstoffe |
| DE102020201317A1 (de) | 2020-02-04 | 2021-08-05 | Henkel Ag & Co. Kgaa | Chitosanderivate als schmutzablösevermögende Wirkstoffe |
| CN116018398A (zh) | 2020-08-21 | 2023-04-25 | 陶氏环球技术有限责任公司 | 用于高水结构化和结合的皂条组合物 |
| WO2022182613A1 (en) * | 2021-02-25 | 2022-09-01 | Dow Global Technologies Llc | Cleaning bar |
| DE102022200882A1 (de) | 2022-01-26 | 2023-07-27 | Henkel Ag & Co. Kgaa | Polymere schmutzablösevermögende Wirkstoffe |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB646088A (en) * | 1948-03-15 | 1950-11-15 | Frederick Joseph Pollok | Improvements in or relating to compositions containing soapless detergents |
| NL7110635A (en, 2012) * | 1970-08-04 | 1972-02-08 | ||
| US4020015A (en) * | 1971-10-12 | 1977-04-26 | Lever Brothers Company | Detergent compositions |
| IT972368B (it) * | 1971-10-14 | 1974-05-20 | Gerico Inc | Elemento per la costruzione di strutture di abitazioni e simili per l impiego come giocattolo |
| US3959165A (en) * | 1972-09-15 | 1976-05-25 | Colgate-Palmolive Company | Biodegradable, non-polluting, heavy duty synthetic organic detergent composition |
| DE2256194B2 (de) * | 1972-11-16 | 1979-07-05 | Henkel Kgaa, 4000 Duesseldorf | Waschmittel für Textilien aus Synthesefaser mit einem Gehalt an vergrauungsverhütenden Zusätzen |
| JPS5230962B2 (en, 2012) * | 1972-12-12 | 1977-08-11 | ||
| PH14036A (en) * | 1973-10-15 | 1980-12-12 | Procter & Gamble | Detergent composition and process |
| GB1498520A (en) * | 1974-04-22 | 1978-01-18 | Procter & Gamble | Detergent compositions having soil release properties |
| US4048433A (en) * | 1976-02-02 | 1977-09-13 | The Procter & Gamble Company | Cellulose ethers having a low molecular weight and a high degree of methyl substitution |
| CH619264A5 (en, 2012) * | 1977-02-02 | 1980-09-15 | Savonnerie Union Generale | |
| US4138352A (en) * | 1977-03-07 | 1979-02-06 | The Dow Chemical Company | Detergent compositions with antisoil and antiredeposition properties |
| GB1534641A (en) * | 1977-05-04 | 1978-12-06 | Unilever Ltd | Detergent compositions for fabric washing |
| US4127495A (en) * | 1978-01-19 | 1978-11-28 | Hercules Incorporated | Non-built liquid detergents |
| US4411803A (en) * | 1980-10-27 | 1983-10-25 | Colgate Palmolive Company | Detergent softener compositions |
| EP0100125B1 (en) * | 1982-07-27 | 1988-12-07 | THE PROCTER & GAMBLE COMPANY | Liquid detergent compositions comprising coacervate mixture of alkylcellulose and carboxymethylcellulose and method for preparing them |
| US4441881A (en) * | 1982-09-07 | 1984-04-10 | Lever Brothers Company | Detergent compositions containing ethoxylated fatty alcohols with narrow ethylene oxide distributions |
| US4532067A (en) * | 1984-01-11 | 1985-07-30 | Lever Brothers Company | Liquid detergent compositions containing hydroxypropyl methylcellulose |
| ZA853573B (en) * | 1984-06-01 | 1986-12-30 | Colgate Palmolive Co | Bleaching synthetic detergent composition |
| US4564463A (en) * | 1984-06-15 | 1986-01-14 | Lever Brothers Company | Liquid laundry detergents with improved soil release properties |
| US4566993A (en) * | 1984-06-15 | 1986-01-28 | O'donnell & Associates, Inc. | Liquid detergents containing cellulose ethers stabilized by glycerol |
| GB8519047D0 (en) * | 1985-07-29 | 1985-09-04 | Unilever Plc | Detergent composition |
-
1985
- 1985-07-29 GB GB858519046A patent/GB8519046D0/en active Pending
-
1986
- 1986-07-16 US US06/886,589 patent/US4732693A/en not_active Expired - Fee Related
- 1986-07-21 CA CA000514216A patent/CA1275223C/en not_active Expired - Fee Related
- 1986-07-25 DE DE8686305745T patent/DE3669885D1/de not_active Expired - Fee Related
- 1986-07-25 AU AU60578/86A patent/AU569195B2/en not_active Ceased
- 1986-07-25 EP EP86305745A patent/EP0213729B1/en not_active Expired - Lifetime
- 1986-07-28 JP JP61177479A patent/JPS6335700A/ja active Granted
- 1986-07-28 ZA ZA865613A patent/ZA865613B/xx unknown
- 1986-07-28 BR BR8603565A patent/BR8603565A/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0213729B1 (en) | 1990-03-28 |
| GB8519046D0 (en) | 1985-09-04 |
| ZA865613B (en) | 1988-03-30 |
| EP0213729A1 (en) | 1987-03-11 |
| JPS6335700A (ja) | 1988-02-16 |
| DE3669885D1 (de) | 1990-05-03 |
| JPH0455640B2 (en, 2012) | 1992-09-03 |
| US4732693A (en) | 1988-03-22 |
| AU6057886A (en) | 1987-02-05 |
| BR8603565A (pt) | 1987-03-04 |
| AU569195B2 (en) | 1988-01-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKLA | Lapsed |