CA1268317A - Production d'alumine a partir de bauxite gibbsite a basse teneur en silice reactive - Google Patents
Production d'alumine a partir de bauxite gibbsite a basse teneur en silice reactiveInfo
- Publication number
- CA1268317A CA1268317A CA000507848A CA507848A CA1268317A CA 1268317 A CA1268317 A CA 1268317A CA 000507848 A CA000507848 A CA 000507848A CA 507848 A CA507848 A CA 507848A CA 1268317 A CA1268317 A CA 1268317A
- Authority
- CA
- Canada
- Prior art keywords
- bauxite
- liquor
- sodium
- attack
- alumina
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 138
- 229910001570 bauxite Inorganic materials 0.000 title claims abstract description 77
- 239000000377 silicon dioxide Substances 0.000 title claims abstract description 69
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 229910001679 gibbsite Inorganic materials 0.000 title claims abstract description 21
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 15
- 239000011734 sodium Substances 0.000 claims abstract description 39
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 38
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 36
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- 239000003518 caustics Substances 0.000 claims abstract description 29
- 238000000034 method Methods 0.000 claims abstract description 28
- 239000000725 suspension Substances 0.000 claims abstract description 27
- 238000005406 washing Methods 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 230000008569 process Effects 0.000 claims abstract description 15
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 13
- JYIMWRSJCRRYNK-UHFFFAOYSA-N dialuminum;disodium;oxygen(2-);silicon(4+);hydrate Chemical compound O.[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Na+].[Na+].[Al+3].[Al+3].[Si+4] JYIMWRSJCRRYNK-UHFFFAOYSA-N 0.000 claims abstract description 12
- MXRIRQGCELJRSN-UHFFFAOYSA-N O.O.O.[Al] Chemical compound O.O.O.[Al] MXRIRQGCELJRSN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 150000004684 trihydrates Chemical class 0.000 claims abstract description 9
- 238000000227 grinding Methods 0.000 claims abstract description 4
- 230000000977 initiatory effect Effects 0.000 claims abstract description 4
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 50
- 229910052681 coesite Inorganic materials 0.000 claims description 21
- 229910052906 cristobalite Inorganic materials 0.000 claims description 21
- 235000012239 silicon dioxide Nutrition 0.000 claims description 21
- 229910052682 stishovite Inorganic materials 0.000 claims description 21
- 229910052905 tridymite Inorganic materials 0.000 claims description 21
- 235000020094 liqueur Nutrition 0.000 claims description 15
- 239000012535 impurity Substances 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- 238000004131 Bayer process Methods 0.000 claims description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 238000000926 separation method Methods 0.000 claims description 4
- 230000009466 transformation Effects 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 238000006243 chemical reaction Methods 0.000 claims description 2
- 238000005304 joining Methods 0.000 claims description 2
- 238000000746 purification Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims description 2
- 239000007858 starting material Substances 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 abstract description 8
- 239000002274 desiccant Substances 0.000 abstract description 2
- 150000003385 sodium Chemical class 0.000 abstract description 2
- 238000000605 extraction Methods 0.000 description 8
- 229910001388 sodium aluminate Inorganic materials 0.000 description 7
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 6
- 238000001556 precipitation Methods 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- 229910052593 corundum Inorganic materials 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 229910052710 silicon Inorganic materials 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 229910001845 yogo sapphire Inorganic materials 0.000 description 4
- 230000030279 gene silencing Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000005063 solubilization Methods 0.000 description 3
- 230000007928 solubilization Effects 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 208000006558 Dental Calculus Diseases 0.000 description 1
- 101000853000 Homo sapiens Interleukin-26 Proteins 0.000 description 1
- 102100036679 Interleukin-26 Human genes 0.000 description 1
- 102220558444 Proteinase-activated receptor 2_N30A_mutation Human genes 0.000 description 1
- 229910018540 Si C Inorganic materials 0.000 description 1
- RKFMOTBTFHXWCM-UHFFFAOYSA-M [AlH2]O Chemical compound [AlH2]O RKFMOTBTFHXWCM-UHFFFAOYSA-M 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- HIGRAKVNKLCVCA-UHFFFAOYSA-N alumine Chemical compound C1=CC=[Al]C=C1 HIGRAKVNKLCVCA-UHFFFAOYSA-N 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000001364 causal effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 229910001648 diaspore Inorganic materials 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000004682 monohydrates Chemical class 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000011403 purification operation Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
- C01F7/0613—Pretreatment of the minerals, e.g. grinding
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
- C01F7/062—Digestion
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
- C01F7/47—Purification of aluminium oxide, aluminium hydroxide or aluminates of aluminates, e.g. removal of compounds of Si, Fe, Ga or of organic compounds from Bayer process liquors
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Inorganic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Nutrition Science (AREA)
- Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR85-06879 | 1985-04-30 | ||
| FR8506879A FR2581053B1 (fr) | 1985-04-30 | 1985-04-30 | Production d'alumine a partir de bauxite a gibbsite a basse teneur en silice reactive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1268317A true CA1268317A (fr) | 1990-05-01 |
Family
ID=9319006
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000507848A Expired - Lifetime CA1268317A (fr) | 1985-04-30 | 1986-04-29 | Production d'alumine a partir de bauxite gibbsite a basse teneur en silice reactive |
Country Status (19)
| Country | Link |
|---|---|
| US (1) | US4650653A (en:Method) |
| EP (1) | EP0203873B1 (en:Method) |
| JP (1) | JPS61251513A (en:Method) |
| CN (1) | CN1009189B (en:Method) |
| AU (1) | AU578359B2 (en:Method) |
| BR (1) | BR8601923A (en:Method) |
| CA (1) | CA1268317A (en:Method) |
| DE (1) | DE3671739D1 (en:Method) |
| ES (1) | ES8704429A1 (en:Method) |
| FR (1) | FR2581053B1 (en:Method) |
| GB (1) | GB2183621B (en:Method) |
| GR (1) | GR861072B (en:Method) |
| HU (1) | HU199351B (en:Method) |
| IE (1) | IE59069B1 (en:Method) |
| IN (1) | IN167247B (en:Method) |
| MY (1) | MY100107A (en:Method) |
| NZ (1) | NZ215963A (en:Method) |
| OA (1) | OA08239A (en:Method) |
| YU (1) | YU44916B (en:Method) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5122349A (en) * | 1988-10-27 | 1992-06-16 | Aluminiumipari Troszt | Process for producing alumina |
| CA2126885A1 (en) * | 1993-06-30 | 1994-12-31 | Gillian Mary Moody | Production of alumina |
| FR2712275B1 (fr) * | 1993-11-09 | 1995-12-15 | Pechiney Aluminium | Procédé de traitement de bauxites contenant un mélange de trihydrate d'alumine et de monohydrate d'alumine. |
| FR2732332B1 (fr) * | 1995-03-31 | 1997-05-09 | Pechiney Aluminium | Procede de traitement de bauxite a trihydrate d'alumine a basse teneur en silice reactive |
| CN1049874C (zh) * | 1996-06-28 | 2000-03-01 | 中国长城铝业公司 | 一种铝土矿浆预脱硅工艺方法 |
| JP2000211919A (ja) * | 1998-11-16 | 2000-08-02 | Sumitomo Chem Co Ltd | アルミナ含有鉱石からの水酸化アルミニウムの製造方法 |
| RU2193009C2 (ru) * | 2000-11-02 | 2002-11-20 | Акционерное общество открытого типа "Всероссийский алюминиево-магниевый институт" | Установка и способ для перколяционного выщелачивания алюминийсодержащего дробленого спека или алюминийсодержащей дробленой руды |
| CN1189398C (zh) * | 2001-07-11 | 2005-02-16 | 住友化学工业株式会社 | 制造氢氧化铝的方法 |
| RU2227787C1 (ru) * | 2002-07-29 | 2004-04-27 | Открытое акционерное общество "Всероссийский алюминиево-магниевый институт" | Установка для перколяционного выщелачивания алюминийсодержащих руд и спеков |
| FR2870535B1 (fr) * | 2004-05-18 | 2007-02-16 | Aluminium Pechiney Soc Par Act | Perfectionnement au procede bayer de production de trihydrate d'alumine par attaque alcaline de bauxite, ledit procede comportant une etape de predessilicatation |
| CN1730393A (zh) * | 2005-07-18 | 2006-02-08 | 贵阳铝镁设计研究院 | 高铁三水铝土矿溶出技术 |
| WO2008067594A1 (en) * | 2006-12-07 | 2008-06-12 | Bhp Billiton Aluminium Australia Pty Ltd | Removal of impurities from bauxite |
| CN101676670B (zh) * | 2008-09-16 | 2011-02-02 | 沈阳铝镁设计研究院 | 一种设备的冷却水供水方法及供水系统 |
| CN113716577B (zh) * | 2021-09-10 | 2023-04-18 | 湖南绿脉环保科技股份有限公司 | 一种含高岭土的含硅铝原料的脱硅方法 |
| CN117163986A (zh) * | 2023-09-07 | 2023-12-05 | 中铝郑州有色金属研究院有限公司 | 一种溶出铝土矿矿浆的方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1171888B (de) * | 1959-04-28 | 1964-06-11 | Chem Fab Heinrichshall Veb | Verfahren zur Abscheidung von Kieselsaeure aus kieselsaeurereichen Bauxiten |
| US3413087A (en) * | 1964-03-13 | 1968-11-26 | Reynolds Metals Co | Method for extracting alumina from its ores |
| FR1506516A (fr) * | 1966-11-08 | 1967-12-22 | Reynolds Metals Co | Perfectionnements aux procédés pour l'extraction d'alumine à partir de minerais alumineux |
| JPS5422198B2 (en:Method) * | 1974-09-28 | 1979-08-04 | ||
| JPS57145029A (en) * | 1981-02-27 | 1982-09-07 | Sumitomo Alum Smelt Co Ltd | Extracting method of alumina from mixed type bauxite |
| JPS585845A (ja) * | 1981-07-02 | 1983-01-13 | Nec Corp | マイクロプロセツサ |
| US4483830A (en) * | 1981-09-10 | 1984-11-20 | Comalco Limited | Production of alumina |
| US4519989A (en) * | 1983-02-22 | 1985-05-28 | Aluminum Company Of America | Removal of organic contaminants from bauxite and other ores |
-
1985
- 1985-04-30 FR FR8506879A patent/FR2581053B1/fr not_active Expired
-
1986
- 1986-04-23 GR GR861072A patent/GR861072B/el unknown
- 1986-04-23 HU HU861697A patent/HU199351B/hu unknown
- 1986-04-24 IN IN314/MAS/86A patent/IN167247B/en unknown
- 1986-04-28 YU YU696/86A patent/YU44916B/xx unknown
- 1986-04-28 NZ NZ215963A patent/NZ215963A/xx unknown
- 1986-04-28 EP EP86420109A patent/EP0203873B1/fr not_active Expired - Lifetime
- 1986-04-28 ES ES554442A patent/ES8704429A1/es not_active Expired
- 1986-04-28 DE DE8686420109T patent/DE3671739D1/de not_active Expired - Lifetime
- 1986-04-29 AU AU56814/86A patent/AU578359B2/en not_active Expired
- 1986-04-29 CN CN86102989A patent/CN1009189B/zh not_active Expired
- 1986-04-29 BR BR8601923A patent/BR8601923A/pt not_active IP Right Cessation
- 1986-04-29 OA OA58849A patent/OA08239A/xx unknown
- 1986-04-29 GB GB8610463A patent/GB2183621B/en not_active Expired
- 1986-04-29 CA CA000507848A patent/CA1268317A/fr not_active Expired - Lifetime
- 1986-04-29 IE IE112686A patent/IE59069B1/en not_active IP Right Cessation
- 1986-04-30 JP JP61100766A patent/JPS61251513A/ja active Granted
- 1986-04-30 US US06/857,316 patent/US4650653A/en not_active Expired - Fee Related
-
1987
- 1987-02-16 MY MYPI87000147A patent/MY100107A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| AU578359B2 (en) | 1988-10-20 |
| GB2183621B (en) | 1989-07-05 |
| YU69686A (en) | 1988-08-31 |
| FR2581053B1 (fr) | 1987-05-29 |
| GB8610463D0 (en) | 1986-06-04 |
| IN167247B (en:Method) | 1990-09-29 |
| DE3671739D1 (de) | 1990-07-12 |
| GB2183621A (en) | 1987-06-10 |
| YU44916B (en) | 1991-04-30 |
| AU5681486A (en) | 1986-11-06 |
| EP0203873B1 (fr) | 1990-06-06 |
| ES554442A0 (es) | 1987-04-01 |
| IE59069B1 (en) | 1993-12-15 |
| ES8704429A1 (es) | 1987-04-01 |
| HU199351B (en) | 1990-02-28 |
| FR2581053A1 (fr) | 1986-10-31 |
| IE861126L (en) | 1986-10-30 |
| CN86102989A (zh) | 1986-12-17 |
| US4650653A (en) | 1987-03-17 |
| GR861072B (en) | 1986-08-19 |
| CN1009189B (zh) | 1990-08-15 |
| BR8601923A (pt) | 1986-12-30 |
| MY100107A (en) | 1989-11-30 |
| NZ215963A (en) | 1988-09-29 |
| EP0203873A1 (fr) | 1986-12-03 |
| OA08239A (fr) | 1987-10-30 |
| JPH0336766B2 (en:Method) | 1991-06-03 |
| JPS61251513A (ja) | 1986-11-08 |
| HUT41326A (en) | 1987-04-28 |
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