CA1268016A - Particules retroreflechissantes, et leur fabrication - Google Patents
Particules retroreflechissantes, et leur fabricationInfo
- Publication number
- CA1268016A CA1268016A CA000483245A CA483245A CA1268016A CA 1268016 A CA1268016 A CA 1268016A CA 000483245 A CA000483245 A CA 000483245A CA 483245 A CA483245 A CA 483245A CA 1268016 A CA1268016 A CA 1268016A
- Authority
- CA
- Canada
- Prior art keywords
- spheres
- granule
- granules
- sheet
- glass spheres
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000002245 particle Substances 0.000 title claims description 34
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- 239000008187 granular material Substances 0.000 claims abstract description 152
- QXJJQWWVWRCVQT-UHFFFAOYSA-K calcium;sodium;phosphate Chemical compound [Na+].[Ca+2].[O-]P([O-])([O-])=O QXJJQWWVWRCVQT-UHFFFAOYSA-K 0.000 claims abstract description 56
- 239000000463 material Substances 0.000 claims abstract description 47
- 238000007373 indentation Methods 0.000 claims abstract description 42
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 20
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 11
- 238000000034 method Methods 0.000 claims description 8
- 229920003023 plastic Polymers 0.000 claims description 6
- 239000004033 plastic Substances 0.000 claims description 6
- 238000005507 spraying Methods 0.000 claims description 6
- 229920000426 Microplastic Polymers 0.000 claims description 5
- 238000005299 abrasion Methods 0.000 claims description 3
- 239000002985 plastic film Substances 0.000 claims description 3
- 238000007790 scraping Methods 0.000 claims description 2
- 239000012815 thermoplastic material Substances 0.000 claims 9
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 238000004140 cleaning Methods 0.000 claims 1
- 239000003973 paint Substances 0.000 abstract description 32
- 239000003550 marker Substances 0.000 abstract description 21
- 239000000203 mixture Substances 0.000 abstract description 7
- 229920001187 thermosetting polymer Polymers 0.000 abstract description 6
- 238000002310 reflectometry Methods 0.000 description 15
- 229920005989 resin Polymers 0.000 description 15
- 239000011347 resin Substances 0.000 description 15
- 239000007788 liquid Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- -1 polyethylene Polymers 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical group C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000002950 deficient Effects 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 150000002118 epoxides Chemical group 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001225 polyester resin Polymers 0.000 description 2
- 239000004645 polyester resin Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- 239000005368 silicate glass Substances 0.000 description 2
- HUAUNKAZQWMVFY-UHFFFAOYSA-M sodium;oxocalcium;hydroxide Chemical compound [OH-].[Na+].[Ca]=O HUAUNKAZQWMVFY-UHFFFAOYSA-M 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 239000002023 wood Substances 0.000 description 2
- BKVALJGAKNDDJJ-UHFFFAOYSA-N 3,4-dimethylhexa-1,5-diene Chemical group C=CC(C)C(C)C=C BKVALJGAKNDDJJ-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 241000517645 Abra Species 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 240000004543 Vicia ervilia Species 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001464 adherent effect Effects 0.000 description 1
- 150000001279 adipic acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 150000001536 azelaic acids Chemical class 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000001030 cadmium pigment Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 235000021384 green leafy vegetables Nutrition 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 229910000464 lead oxide Inorganic materials 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical class [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000000088 plastic resin Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001228 polyisocyanate Polymers 0.000 description 1
- 239000005056 polyisocyanate Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 239000012463 white pigment Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical class [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01C—CONSTRUCTION OF, OR SURFACES FOR, ROADS, SPORTS GROUNDS, OR THE LIKE; MACHINES OR AUXILIARY TOOLS FOR CONSTRUCTION OR REPAIR
- E01C7/00—Coherent pavings made in situ
- E01C7/08—Coherent pavings made in situ made of road-metal and binders
- E01C7/35—Toppings or surface dressings; Methods of mixing, impregnating, or spreading them
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
- B29C43/02—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
- B29C43/04—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
- B29C43/06—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds continuously movable in one direction, e.g. mounted on chains, belts
- B29C43/08—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds continuously movable in one direction, e.g. mounted on chains, belts with circular movement, e.g. mounted on rolls, turntables
- B29C43/085—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds continuously movable in one direction, e.g. mounted on chains, belts with circular movement, e.g. mounted on rolls, turntables and material fed in a continuous form, e.g. as a band
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D11/00—Producing optical elements, e.g. lenses or prisms
- B29D11/00605—Production of reflex reflectors
- B29D11/00615—Production of reflex reflectors moulded by partially embedding reflective elements, e.g. glass beads, into the surface of a support, e.g. to make prefabricated road markings
-
- E—FIXED CONSTRUCTIONS
- E01—CONSTRUCTION OF ROADS, RAILWAYS, OR BRIDGES
- E01F—ADDITIONAL WORK, SUCH AS EQUIPPING ROADS OR THE CONSTRUCTION OF PLATFORMS, HELICOPTER LANDING STAGES, SIGNS, SNOW FENCES, OR THE LIKE
- E01F9/00—Arrangement of road signs or traffic signals; Arrangements for enforcing caution
- E01F9/50—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users
- E01F9/506—Road surface markings; Kerbs or road edgings, specially adapted for alerting road users characterised by the road surface marking material, e.g. comprising additives for improving friction or reflectivity; Methods of forming, installing or applying markings in, on or to road surfaces
- E01F9/524—Reflecting elements specially adapted for incorporation in or application to road surface markings
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B5/00—Optical elements other than lenses
- G02B5/12—Reflex reflectors
- G02B5/126—Reflex reflectors including curved refracting surface
- G02B5/128—Reflex reflectors including curved refracting surface transparent spheres being embedded in matrix
Landscapes
- Engineering & Computer Science (AREA)
- Civil Engineering (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Structural Engineering (AREA)
- Architecture (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Ophthalmology & Optometry (AREA)
- Road Signs Or Road Markings (AREA)
- Illuminated Signs And Luminous Advertising (AREA)
- Optical Elements Other Than Lenses (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US65394384A | 1984-09-21 | 1984-09-21 | |
| US653,943 | 1984-09-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA1268016C CA1268016C (fr) | 1990-04-24 |
| CA1268016A true CA1268016A (fr) | 1990-04-24 |
Family
ID=24622896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000483245A Expired CA1268016A (fr) | 1984-09-21 | 1985-06-05 | Particules retroreflechissantes, et leur fabrication |
Country Status (8)
| Country | Link |
|---|---|
| JP (1) | JPS6177803A (fr) |
| AU (1) | AU573898B2 (fr) |
| BR (1) | BR8503932A (fr) |
| CA (1) | CA1268016A (fr) |
| DE (1) | DE3524661A1 (fr) |
| FR (1) | FR2570726B1 (fr) |
| GB (1) | GB2164762B (fr) |
| MX (1) | MX170384B (fr) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1307971C (fr) * | 1988-06-09 | 1992-09-29 | Thomas Peter Hedblom | Materiau de marquage de chaussees |
| NL8802472A (nl) * | 1988-10-10 | 1990-05-01 | Homer Hollandse Meet En Regels | Document met daarop aangebrachte randominformatie, drager van deze randominformatie alsmede werkwijze en inrichting voor het aflezen van deze randominformatie. |
| DE4238168A1 (de) * | 1992-10-15 | 1994-04-21 | Gerhard Cammann | Verfahren und Einrichtung zur Herstellung von lichtreflektierenden Flächen, insbesondere Straßenmarkierungen wie Randstreifen, Mittelstreifen oder dergleichen |
| DE9205350U1 (fr) * | 1992-04-17 | 1992-06-17 | Swarco Vestglas Vestische Strahl- Und Reflexglas Gmbh, 4350 Recklinghausen, De | |
| DE19521847A1 (de) * | 1995-06-16 | 1996-12-19 | Gerhard Cammann | Verfahren und Einrichtung zur Herstellung von lichtreflektierenden Bausteinen, von lichtreflektierenden Flächen wie Straßenmarkierungen, Randstreifen, Mittelstreifen oder dergleichen |
| US5835271A (en) * | 1995-06-29 | 1998-11-10 | Minnesota Mining And Manufacturing Company | Encased retroreflective elements and method for making |
| AUPO430296A0 (en) * | 1996-12-20 | 1997-01-23 | Rogers, Barry Heith | Marking composition |
| SE9700064L (sv) * | 1997-01-10 | 1998-07-11 | Qualisys Ab | Metod och anordning för tillverkning av en med en beläggning försedd kropp |
| CA2265773A1 (fr) * | 1997-07-16 | 1999-01-28 | Minnesota Mining And Manufacturing Company | Marque sur chaussee pourvue de protuberances et procede de production |
| DE19962953B4 (de) * | 1999-12-24 | 2006-01-26 | Bundesdruckerei Gmbh | Verfahren zur Codierung von thermoplastischen Kunststoffprodukten |
| GB0213727D0 (en) * | 2002-06-14 | 2002-07-24 | Prismo Ltd | Retroreflective device and method of manufacture thereof |
| GB2402694B (en) | 2003-06-11 | 2006-03-15 | Prismo Ltd | Method and apparatus for manufacturing a retroflective device |
| KR100586406B1 (ko) * | 2004-06-11 | 2006-06-08 | 김현대 | 큐브코너형 재귀반사 소자 제조방법 및 그 재귀반사 소자 |
| FR2885363B1 (fr) * | 2005-05-04 | 2007-09-28 | Appia | Materiau reflechissant pour revetement de voie de circulation |
| PL1967554T3 (pl) | 2007-02-23 | 2013-01-31 | Triflex Gmbh& Co Kg | Zestaw podkładowy i zestaw do znakowania |
| US9207373B2 (en) | 2007-04-10 | 2015-12-08 | Stoncor Group, Inc. | Methods for fabrication and highway marking usage of agglomerated retroreflective beads |
| US10308816B2 (en) | 2014-05-05 | 2019-06-04 | Potters Industries, Llc | Coatings for pelletized thermoplastic pavement marking compositions |
| PL3172380T3 (pl) * | 2014-07-25 | 2019-04-30 | Schmidt Juergen | Elementy teksturowe do powierzchni komunikacyjnych, ich zastosowanie i sposób wytwarzania powierzchni komunikacyjnych |
| CN108025958B (zh) | 2015-09-11 | 2021-04-09 | 3M创新有限公司 | 具有小珠共混物的耐用回射元件 |
| AU2018225296A1 (en) * | 2017-02-23 | 2019-09-19 | Lam Nguyen | Improved coatings for pelletized thermoplastic pavement marking compositions |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB688310A (en) * | 1950-09-02 | 1953-03-04 | R S Clare & Company Ltd | Improvements in or relating to road marking means and compositions |
| FR1211669A (fr) * | 1957-09-18 | 1960-03-17 | Minnesota Mining & Mfg | Matériau granulaire réfléchissant la lumière notamment pour le jalonnement des routes |
| US3036928A (en) * | 1959-12-18 | 1962-05-29 | Cataphote Corp | Retroreflective composition and method of applying same |
| US3171827A (en) * | 1960-10-31 | 1965-03-02 | Prismo Safety Corp | Reflective granules |
| US3247158A (en) * | 1962-02-07 | 1966-04-19 | Standard Oil Co | Filled plastisol compositions |
| US3252376A (en) * | 1962-02-16 | 1966-05-24 | Prismo Safety Corp | Reflex reflective granule and marking material made thereof |
| US3254563A (en) * | 1963-11-12 | 1966-06-07 | Prismo Safety Corp | Retro-reflective particles and reflective markers and compositions containing such particles |
| US3518221A (en) * | 1967-10-30 | 1970-06-30 | Monsanto Co | Reinforcing fillers in a matrix of two thermosetting resins |
| FR1604009A (en) * | 1968-08-05 | 1971-06-28 | Reflective element, eg a road marker - stud | |
| FR2082537A5 (en) * | 1970-03-19 | 1971-12-10 | Tech Tuiles Briques Centre | Tetrahedral ceramic granules - for use in road surfacing concrete etc |
| FR2101024A1 (fr) * | 1970-08-07 | 1972-03-31 | France Etat | Revetement de chaussee,son procede de fabrication et de mise en place |
| IT1001490B (it) * | 1972-05-24 | 1976-04-20 | Eigenmann Ludwig | Perfezionamento ai materiali per segnaletica stradale orizzontale e relativi materiali perfezionati ad alta visibilita aderenza e resi stenza all usura |
| US3859407A (en) * | 1972-05-15 | 1975-01-07 | Corning Glass Works | Method of manufacturing particles of uniform size and shape |
| FR2194192A5 (fr) * | 1972-07-27 | 1974-02-22 | Loing Verreries | |
| US3867178A (en) * | 1972-09-05 | 1975-02-18 | Potters Industries Inc | Method for coating discrete particles |
| JPS5131735A (fr) * | 1974-09-13 | 1976-03-18 | Ookee Kasei Kk | |
| GB1531480A (en) * | 1974-12-20 | 1978-11-08 | Bagshaw R | Retroreflective elements |
| US4072403A (en) * | 1975-07-16 | 1978-02-07 | Ludwig Eigenmann | Retro-reflecting assembly |
| US4388359A (en) * | 1982-04-23 | 1983-06-14 | Minnesota Mining And Manufacturing Company | Embossed pavement-marking sheet material |
-
1985
- 1985-06-05 CA CA000483245A patent/CA1268016A/fr not_active Expired
- 1985-06-19 GB GB08515548A patent/GB2164762B/en not_active Expired
- 1985-06-26 JP JP60138045A patent/JPS6177803A/ja active Pending
- 1985-07-04 MX MX205892A patent/MX170384B/es unknown
- 1985-07-10 DE DE19853524661 patent/DE3524661A1/de active Granted
- 1985-08-19 BR BR8503932A patent/BR8503932A/pt not_active IP Right Cessation
- 1985-09-18 AU AU47565/85A patent/AU573898B2/en not_active Expired
- 1985-09-19 FR FR8514159A patent/FR2570726B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| AU4756585A (en) | 1986-03-27 |
| DE3524661A1 (de) | 1986-04-03 |
| GB2164762B (en) | 1988-05-18 |
| CA1268016C (fr) | 1990-04-24 |
| FR2570726B1 (fr) | 1987-08-21 |
| BR8503932A (pt) | 1986-05-27 |
| DE3524661C2 (fr) | 1989-07-20 |
| GB8515548D0 (en) | 1985-07-24 |
| MX170384B (es) | 1993-08-18 |
| FR2570726A1 (fr) | 1986-03-28 |
| GB2164762A (en) | 1986-03-26 |
| JPS6177803A (ja) | 1986-04-21 |
| AU573898B2 (en) | 1988-06-23 |
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