CA1196026A - Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition - Google Patents

Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition

Info

Publication number
CA1196026A
CA1196026A CA000450379A CA450379A CA1196026A CA 1196026 A CA1196026 A CA 1196026A CA 000450379 A CA000450379 A CA 000450379A CA 450379 A CA450379 A CA 450379A CA 1196026 A CA1196026 A CA 1196026A
Authority
CA
Canada
Prior art keywords
zeolite
toluene
cesium
methanol
potassium
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA000450379A
Other languages
English (en)
French (fr)
Inventor
Huei-Cheng Liu
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1196026A publication Critical patent/CA1196026A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA000450379A 1983-04-22 1984-03-23 Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition Expired CA1196026A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US06/487,590 US4463204A (en) 1983-04-22 1983-04-22 Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition
US487,590 1983-04-22

Publications (1)

Publication Number Publication Date
CA1196026A true CA1196026A (en) 1985-10-29

Family

ID=23936362

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000450379A Expired CA1196026A (en) 1983-04-22 1984-03-23 Process for alkylating toluene with methanol to form styrene using a low sodium content potassium/cesium modified zeolite catalyst composition

Country Status (4)

Country Link
US (1) US4463204A (enExample)
EP (1) EP0123537A1 (enExample)
JP (1) JPS59205334A (enExample)
CA (1) CA1196026A (enExample)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4499317A (en) * 1983-04-22 1985-02-12 Exxon Research & Engineering Co. Modified zeolite catalyst composition and process for alkylating toluene with methanol to form styrene
US4499318A (en) * 1983-04-22 1985-02-12 Exxon Research & Engineering Co. Modified zeolite catalyst composition and process for alkylating toluene with methanol to form styrene
US4950827A (en) * 1988-03-28 1990-08-21 Institute Of Gas Technology Oxidative coupling of aliphatic and alicyclic hydrocarbons with aliphatic and alicyclic substituted aromatic hydrocarbons
WO2006029398A2 (en) * 2004-09-09 2006-03-16 University Of Washington All-trans-retinol : all-trans-13,14-dihydroretinol saturase and methods of its use
CN100404432C (zh) * 2005-08-02 2008-07-23 中国石油天然气股份有限公司 一种降低沸石改性过程中氨氮污染的方法
ATE509898T1 (de) * 2007-02-23 2011-06-15 Mitsui Chemicals Inc Verfahren zur herstellung einer alkylierten aromatischen verbindung
US20110196182A1 (en) * 2010-02-05 2011-08-11 Fina Technology, Inc. Styrene production processes and catalysts for use therein
US8258359B2 (en) * 2010-04-20 2012-09-04 Fina Technology, Inc. Alkylation of toluene to form styrene and ethylbenzene
US20110257454A1 (en) * 2010-04-20 2011-10-20 Fina Technology, Inc. Use of an Additive in the Coupling of Toluene with a Carbon Source
US20110270006A1 (en) * 2010-04-20 2011-11-03 Fina Technology, Inc. Use of an Additive in the Coupling of Toluene with a Carbon Source
CN101912788B (zh) * 2010-07-31 2012-05-30 太原理工大学 含氨基树脂酚铝双功能催化剂及其合成方法和应用
US20120296138A1 (en) * 2011-05-22 2012-11-22 Fina Technology, Inc. Method for alkylation of toluene to form styrene and ethylbenzene utilizing a moving bed reactor
US8785705B2 (en) * 2011-05-22 2014-07-22 Fina Technology, Inc. Use of a co-feed in the coupling of toluene with a carbon source
US8785706B2 (en) * 2011-05-22 2014-07-22 Fina Technology, Inc. Addition of a base to enhance product yield in alkylation reactions
US8653314B2 (en) * 2011-05-22 2014-02-18 Fina Technology, Inc. Method for providing a co-feed in the coupling of toluene with a carbon source
US8697593B2 (en) * 2012-03-12 2014-04-15 King Fahd University Of Petroleum And Minerals Zeolite catalyst for the alkylation of toluene with methanol
US9802876B2 (en) 2012-07-12 2017-10-31 China Petroleum & Chemical Corporation Alkylating process for alkyl benzenes
CN103539601B (zh) * 2012-07-12 2015-11-18 中国石油化工股份有限公司 用于甲苯与甲醇侧链烷基化制乙苯和苯乙烯的方法
WO2015092812A2 (en) * 2013-11-22 2015-06-25 Reliance Industries Limited A modified faujasite zeolite
RU2544017C1 (ru) 2014-01-28 2015-03-10 Ольга Васильевна Малова Катализатор и способ ароматизации с3-с4 газов, легких углеводородных фракций алифатических спиртов, а также их смесей
RU2550354C1 (ru) 2014-03-28 2015-05-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из легких алифатических углеводородов и установка для его осуществления
RU2558955C1 (ru) 2014-08-12 2015-08-10 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения концентрата ароматических углеводородов из жидких углеводородных фракций и установка для его осуществления
RU2544241C1 (ru) 2014-01-22 2015-03-20 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" Способ получения ароматических углеводородов из природного газа и установка для его осуществления
WO2017155424A1 (en) 2016-03-09 2017-09-14 Limited Liability Company "New Gas Technologies-Synthesis" (Llc "Ngt-Synthesis") Method and plant for producing high-octane gasolines
KR101814076B1 (ko) 2016-05-25 2018-01-02 인하대학교 산학협력단 이산화탄소 및 메탄올을 이용한 톨루엔의 측쇄알킬화 반응 생성물의 제조방법
CN107537546B (zh) * 2016-06-29 2019-09-06 中国石油化工股份有限公司 用于甲苯甲醇侧链烷基化制备乙苯苯乙烯的催化剂及其用途
CN109694305B (zh) * 2017-10-20 2021-12-28 中国石油化工股份有限公司 甲醇转化制二甲苯联产乙苯和异丙苯的方法
RU2747869C1 (ru) 2020-06-29 2021-05-17 Общество С Ограниченной Ответственностью "Новые Газовые Технологии-Синтез" (Ооо "Нгт-Синтез") Способ получения бензинов или концентратов ароматических соединений с различным распределением потоков оксигената и олефинсодержащей фракции
CN114433192B (zh) * 2020-10-20 2024-02-02 中国石油化工股份有限公司 甲醇制芳烃催化剂及其制备方法和应用

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2882244A (en) * 1953-12-24 1959-04-14 Union Carbide Corp Molecular sieve adsorbents
US4115424A (en) * 1976-12-22 1978-09-19 Monsanto Company Zeolite catalyst
JPS5768144A (en) * 1980-10-15 1982-04-26 Ube Ind Ltd Catalyst for synthesizing styrene
JPS5781419A (en) * 1980-11-11 1982-05-21 Ube Ind Ltd Catalyst for synthesizing styrene from toluene and methanol

Also Published As

Publication number Publication date
JPS59205334A (ja) 1984-11-20
US4463204A (en) 1984-07-31
JPH0455176B2 (enExample) 1992-09-02
EP0123537A1 (en) 1984-10-31

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Legal Events

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MKEX Expiry