CA1186511A - Process for the preparation of hydrogencontaining gases - Google Patents
Process for the preparation of hydrogencontaining gasesInfo
- Publication number
- CA1186511A CA1186511A CA000390112A CA390112A CA1186511A CA 1186511 A CA1186511 A CA 1186511A CA 000390112 A CA000390112 A CA 000390112A CA 390112 A CA390112 A CA 390112A CA 1186511 A CA1186511 A CA 1186511A
- Authority
- CA
- Canada
- Prior art keywords
- atoms
- shift
- catalyst
- oxide
- shift process
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 70
- 230000008569 process Effects 0.000 title claims abstract description 68
- 239000007789 gas Substances 0.000 title claims abstract description 48
- 238000002360 preparation method Methods 0.000 title claims abstract description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 51
- 238000006243 chemical reaction Methods 0.000 claims abstract description 30
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000010949 copper Substances 0.000 claims abstract description 19
- 239000011787 zinc oxide Substances 0.000 claims abstract description 13
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000005751 Copper oxide Substances 0.000 claims abstract description 12
- 229910000431 copper oxide Inorganic materials 0.000 claims abstract description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 7
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 7
- 239000001257 hydrogen Substances 0.000 claims abstract description 7
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229910000423 chromium oxide Inorganic materials 0.000 claims abstract description 6
- 238000002407 reforming Methods 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims description 22
- 239000011701 zinc Substances 0.000 claims description 15
- 229910052751 metal Inorganic materials 0.000 claims description 12
- 239000002184 metal Substances 0.000 claims description 12
- 239000011651 chromium Substances 0.000 claims description 11
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 4
- 239000007858 starting material Substances 0.000 claims description 4
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 3
- 230000003009 desulfurizing effect Effects 0.000 claims description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract description 16
- 230000015572 biosynthetic process Effects 0.000 abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 13
- 229910021529 ammonia Inorganic materials 0.000 abstract description 8
- 229910052742 iron Inorganic materials 0.000 abstract description 7
- 238000003786 synthesis reaction Methods 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 5
- 229910052802 copper Inorganic materials 0.000 abstract description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 abstract description 2
- 238000006477 desulfuration reaction Methods 0.000 abstract description 2
- 230000023556 desulfurization Effects 0.000 abstract description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 3
- 238000004519 manufacturing process Methods 0.000 abstract 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 31
- 229910002092 carbon dioxide Inorganic materials 0.000 description 16
- 238000002474 experimental method Methods 0.000 description 12
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 9
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 8
- 229910001868 water Inorganic materials 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- -1 iron carbides Chemical class 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000004075 alteration Effects 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- ONIOAEVPMYCHKX-UHFFFAOYSA-N carbonic acid;zinc Chemical compound [Zn].OC(O)=O ONIOAEVPMYCHKX-UHFFFAOYSA-N 0.000 description 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 2
- 238000009533 lab test Methods 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 101150114464 ATRN gene Proteins 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- 101100256149 Salmonella typhimurium (strain 14028s / SGSC 2262) sarA gene Proteins 0.000 description 1
- WVYYHSKIGBEZCQ-UHFFFAOYSA-N [O-2].[O-2].[Cr+3].[Fe+2] Chemical compound [O-2].[O-2].[Cr+3].[Fe+2] WVYYHSKIGBEZCQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009172 bursting Effects 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/86—Chromium
- B01J23/868—Chromium copper and chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/80—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Catalysts (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DK4908/80 | 1980-11-18 | ||
DK490880A DK147937C (da) | 1980-11-18 | 1980-11-18 | Fremgangsmaade til fremstilling af hydrogenholdige gasser, specielt ammoniaksyntesegas, ud fra carbonhydrider |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1186511A true CA1186511A (en) | 1985-05-07 |
Family
ID=8137741
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA000390112A Expired CA1186511A (en) | 1980-11-18 | 1981-11-16 | Process for the preparation of hydrogencontaining gases |
Country Status (12)
Country | Link |
---|---|
JP (1) | JPS57123803A (de) |
AU (1) | AU545285B2 (de) |
CA (1) | CA1186511A (de) |
DE (1) | DE3145651C2 (de) |
DK (1) | DK147937C (de) |
FR (1) | FR2494252B1 (de) |
GB (1) | GB2087855B (de) |
IN (1) | IN156530B (de) |
IT (1) | IT1144938B (de) |
MX (1) | MX158726A (de) |
NL (1) | NL188794C (de) |
SE (1) | SE448084B (de) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111498804A (zh) * | 2020-03-20 | 2020-08-07 | 中海石油化学股份有限公司 | 一种烃类蒸汽转化法制合成氨低温变换结构 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3837308A1 (de) * | 1988-11-03 | 1990-05-10 | Basf Ag | Kupferhaltiger katalysator zur tieftemperaturkonvertierung |
GB9820608D0 (en) * | 1998-09-23 | 1998-11-11 | Ici Plc | Hydrogen |
US20080128655A1 (en) * | 2006-12-05 | 2008-06-05 | Diwakar Garg | Process and apparatus for production of hydrogen using the water gas shift reaction |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1010871A (en) * | 1962-08-24 | 1965-11-24 | Ici Ltd | Water-gas conversion and catalysts therefor |
FR1386570A (fr) * | 1963-01-02 | 1965-01-22 | Chemetron Corp | Procédé de préparation d'hydrogène, catalyseurs destinés à cet effet et procédé de préparation de ces catalyseurs |
AT247285B (de) * | 1963-01-02 | 1966-05-25 | Chemetron Corp | Verfahren zur Konvertierung von Kohlenmonoxyd und zur Herstellung eines für diese Konvertierung geeigneten Katalysators |
DE1542632B2 (de) * | 1963-07-30 | 1976-12-16 | Basf Ag, 6700 Ludwigshafen | Verfahren zur herstellung von wasserstoff |
FR1412053A (fr) * | 1963-10-02 | 1965-09-24 | Pullman Inc | Procédé perfectionné de production d'hydrogène à partir de vapeur d'eau et d'oxyde de carbone |
GB1082298A (en) * | 1963-12-16 | 1967-09-06 | Catalysts & Chem Inc | Improvements in the production of copper-zinc catalysts |
GB1084863A (en) * | 1965-01-06 | 1967-09-27 | Grafton Magna Ltd | Improvements in or relating to adjustable supports |
DE1542044C3 (de) * | 1965-10-19 | 1980-03-27 | Catalysts And Chemicals Inc., Louisville, Ky. (V.St.A.) | Katalysator, der nach Reduktion als aktive Bestandteile Zinkoxid und Kupfer enthält |
US3567655A (en) * | 1967-08-01 | 1971-03-02 | Himichiski Kom | Method of producing a low-temperature catalyst for the conversion of carbon monoxide with steam |
DE2043417A1 (de) * | 1969-09-05 | 1971-04-29 | Alco Standard Corp , Cleveland, Ohio (V St A ) | Verfahren und Vorrichtung zum Her stellen von Wasserstoff und Wasserstoff enthaltende Gasgemische |
US3922337A (en) * | 1970-07-22 | 1975-11-25 | Ici Ltd | Hydrogen |
JPS508038A (de) * | 1973-05-29 | 1975-01-28 |
-
1980
- 1980-11-18 DK DK490880A patent/DK147937C/da not_active IP Right Cessation
-
1981
- 1981-11-09 SE SE8106627A patent/SE448084B/sv not_active IP Right Cessation
- 1981-11-10 GB GB8133838A patent/GB2087855B/en not_active Expired
- 1981-11-16 CA CA000390112A patent/CA1186511A/en not_active Expired
- 1981-11-17 AU AU77558/81A patent/AU545285B2/en not_active Ceased
- 1981-11-17 FR FR8121460A patent/FR2494252B1/fr not_active Expired
- 1981-11-17 DE DE3145651A patent/DE3145651C2/de not_active Expired - Fee Related
- 1981-11-17 IT IT25145/81A patent/IT1144938B/it active
- 1981-11-17 MX MX190149A patent/MX158726A/es unknown
- 1981-11-17 NL NLAANVRAGE8105202,A patent/NL188794C/xx not_active IP Right Cessation
- 1981-11-18 IN IN1283/CAL/81A patent/IN156530B/en unknown
- 1981-11-18 JP JP56183928A patent/JPS57123803A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111498804A (zh) * | 2020-03-20 | 2020-08-07 | 中海石油化学股份有限公司 | 一种烃类蒸汽转化法制合成氨低温变换结构 |
Also Published As
Publication number | Publication date |
---|---|
IN156530B (de) | 1985-08-24 |
FR2494252A1 (fr) | 1982-05-21 |
MX158726A (es) | 1989-03-07 |
AU7755881A (en) | 1982-05-27 |
IT1144938B (it) | 1986-10-29 |
NL188794C (nl) | 1992-10-01 |
FR2494252B1 (fr) | 1986-04-04 |
DK147937B (da) | 1985-01-14 |
JPS57123803A (en) | 1982-08-02 |
DK147937C (da) | 1985-07-01 |
NL188794B (nl) | 1992-05-06 |
DE3145651A1 (de) | 1982-08-19 |
AU545285B2 (en) | 1985-07-11 |
DK490880A (da) | 1982-05-19 |
GB2087855A (en) | 1982-06-03 |
GB2087855B (en) | 1984-06-27 |
DE3145651C2 (de) | 1996-07-11 |
NL8105202A (nl) | 1982-06-16 |
IT8125145A0 (it) | 1981-11-17 |
JPH0317761B2 (de) | 1991-03-08 |
SE448084B (sv) | 1987-01-19 |
SE8106627L (sv) | 1982-05-19 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
MKEX | Expiry |