CA1163589A - Process for production of carbon artifact precursors - Google Patents
Process for production of carbon artifact precursorsInfo
- Publication number
- CA1163589A CA1163589A CA000382591A CA382591A CA1163589A CA 1163589 A CA1163589 A CA 1163589A CA 000382591 A CA000382591 A CA 000382591A CA 382591 A CA382591 A CA 382591A CA 1163589 A CA1163589 A CA 1163589A
- Authority
- CA
- Canada
- Prior art keywords
- pitch
- range
- distillate
- heat
- mercury
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 34
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 27
- 238000000034 method Methods 0.000 title claims description 22
- 239000002243 precursor Substances 0.000 title 1
- 241000282326 Felis catus Species 0.000 claims abstract description 33
- 238000002791 soaking Methods 0.000 claims abstract description 27
- 229920000049 Carbon (fiber) Polymers 0.000 claims abstract description 19
- 239000004917 carbon fiber Substances 0.000 claims abstract description 19
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000009835 boiling Methods 0.000 claims abstract description 13
- 239000002904 solvent Substances 0.000 claims description 20
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 15
- 229910052753 mercury Inorganic materials 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 9
- 238000007380 fibre production Methods 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
- 239000012530 fluid Substances 0.000 claims description 5
- 239000012298 atmosphere Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims 4
- 238000004939 coking Methods 0.000 abstract description 11
- 239000011295 pitch Substances 0.000 description 61
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 48
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 22
- 239000000463 material Substances 0.000 description 21
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 14
- 239000003921 oil Substances 0.000 description 9
- 125000003118 aryl group Chemical group 0.000 description 6
- 239000007789 gas Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 230000001627 detrimental effect Effects 0.000 description 5
- 239000002198 insoluble material Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 238000009987 spinning Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 125000004429 atom Chemical group 0.000 description 3
- 239000000571 coke Substances 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000010998 test method Methods 0.000 description 3
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000012296 anti-solvent Substances 0.000 description 2
- 239000010692 aromatic oil Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 238000003763 carbonization Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000000921 elemental analysis Methods 0.000 description 2
- 238000000605 extraction Methods 0.000 description 2
- 239000012065 filter cake Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 239000003208 petroleum Substances 0.000 description 2
- 238000000425 proton nuclear magnetic resonance spectrum Methods 0.000 description 2
- 230000003014 reinforcing effect Effects 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- SENBJMMSGVHUDH-UHFFFAOYSA-N 2-[4-[[3-[3-benzyl-8-(trifluoromethyl)quinolin-4-yl]phenyl]methylamino]phenyl]acetic acid Chemical compound C1=CC(CC(=O)O)=CC=C1NCC1=CC=CC(C=2C3=CC=CC(=C3N=CC=2CC=2C=CC=CC=2)C(F)(F)F)=C1 SENBJMMSGVHUDH-UHFFFAOYSA-N 0.000 description 1
- CJRJTCMSQLEPFQ-UHFFFAOYSA-N 6-cat Chemical compound ClC1=CC=C2CC(N)CCC2=C1 CJRJTCMSQLEPFQ-UHFFFAOYSA-N 0.000 description 1
- 101150116295 CAT2 gene Proteins 0.000 description 1
- 101100326920 Caenorhabditis elegans ctl-1 gene Proteins 0.000 description 1
- 241001235534 Graphis <ascomycete fungus> Species 0.000 description 1
- 101100126846 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) katG gene Proteins 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 208000036366 Sensation of pressure Diseases 0.000 description 1
- 241000193803 Therea Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- OKTJSMMVPCPJKN-BJUDXGSMSA-N carbon-11 Chemical compound [11C] OKTJSMMVPCPJKN-BJUDXGSMSA-N 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000012120 mounting media Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- GNWXVOQHLPBSSR-UHFFFAOYSA-N oxolane;toluene Chemical compound C1CCOC1.CC1=CC=CC=C1 GNWXVOQHLPBSSR-UHFFFAOYSA-N 0.000 description 1
- 239000011301 petroleum pitch Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000002195 soluble material Substances 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10C—WORKING-UP PITCH, ASPHALT, BITUMEN, TAR; PYROLIGNEOUS ACID
- C10C3/00—Working-up pitch, asphalt, bitumen
- C10C3/002—Working-up pitch, asphalt, bitumen by thermal means
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F9/00—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments
- D01F9/08—Artificial filaments or the like of other substances; Manufacture thereof; Apparatus specially adapted for the manufacture of carbon filaments of inorganic material
- D01F9/12—Carbon filaments; Apparatus specially adapted for the manufacture thereof
- D01F9/14—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments
- D01F9/145—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues
- D01F9/155—Carbon filaments; Apparatus specially adapted for the manufacture thereof by decomposition of organic filaments from pitch or distillation residues from petroleum pitch
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Thermal Sciences (AREA)
- Civil Engineering (AREA)
- Physics & Mathematics (AREA)
- Structural Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Working-Up Tar And Pitch (AREA)
- Inorganic Fibers (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US225,060 | 1981-01-14 | ||
| US06/225,060 US4363715A (en) | 1981-01-14 | 1981-01-14 | Production of carbon artifact precursors |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1163589A true CA1163589A (en) | 1984-03-13 |
Family
ID=22843361
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000382591A Expired CA1163589A (en) | 1981-01-14 | 1981-07-27 | Process for production of carbon artifact precursors |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4363715A (OSRAM) |
| EP (1) | EP0056338B1 (OSRAM) |
| JP (1) | JPS57141488A (OSRAM) |
| AU (1) | AU541898B2 (OSRAM) |
| CA (1) | CA1163589A (OSRAM) |
| DE (1) | DE3265313D1 (OSRAM) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS588786A (ja) * | 1981-07-10 | 1983-01-18 | Mitsubishi Oil Co Ltd | 炭素繊維原料用ピツチの製造方法 |
| JPS58120694A (ja) * | 1982-01-13 | 1983-07-18 | Mitsubishi Oil Co Ltd | 炭素繊維原料ピツチの製造法 |
| US4448670A (en) * | 1982-02-08 | 1984-05-15 | Exxon Research And Engineering Co. | Aromatic pitch production from coal derived distillate |
| US4431512A (en) * | 1982-02-08 | 1984-02-14 | Exxon Research And Engineering Co. | Aromatic pitch from asphaltene-free steam cracker tar fractions |
| US4427530A (en) * | 1982-02-08 | 1984-01-24 | Exxon Research And Engineering Co. | Aromatic pitch derived from a middle fraction of a cat cracker bottom |
| US4522701A (en) * | 1982-02-11 | 1985-06-11 | E. I. Du Pont De Nemours And Company | Process for preparing an anisotropic aromatic pitch |
| DE3363347D1 (en) * | 1982-02-23 | 1986-06-12 | Mitsubishi Oil Co | Pitch as a raw material for making carbon fibers and process for producing the same |
| US4518482A (en) * | 1982-07-19 | 1985-05-21 | E. I. Du Pont De Nemours And Company | Pitch for direct spinning into carbon fibers derived from a coal distillate feedstock |
| CA1199758A (en) * | 1982-07-19 | 1986-01-28 | E. I. Du Pont De Nemours And Company | Pitch for direct spinning into carbon fibers derived from a steam cracker tar feedstock |
| CA1207264A (en) * | 1982-07-19 | 1986-07-08 | Ghazi Dickakian | Pitch for direct spinning into carbon fibers derived from a cat cracker bottoms feedstock |
| US4913889A (en) * | 1983-03-09 | 1990-04-03 | Kashima Oil Company | High strength high modulus carbon fibers |
| US4503026A (en) * | 1983-03-14 | 1985-03-05 | E. I. Du Pont De Nemours And Company | Spinnable precursors from petroleum pitch, fibers spun therefrom and method of preparation thereof |
| JPS59196390A (ja) * | 1983-04-22 | 1984-11-07 | Agency Of Ind Science & Technol | 炭素繊維用ピツチの製造方法 |
| JPS60168787A (ja) * | 1984-02-13 | 1985-09-02 | Fuji Standard Res Kk | ピツチの製造方法 |
| EP0138286B1 (en) * | 1983-05-20 | 1988-01-13 | Fuji Standard Research Inc. | Method of preparing carbonaceous pitch |
| US4600496A (en) * | 1983-05-26 | 1986-07-15 | Phillips Petroleum Company | Pitch conversion |
| JPS61103989A (ja) * | 1984-10-29 | 1986-05-22 | Maruzen Sekiyu Kagaku Kk | 炭素製品製造用ピツチの製造法 |
| JPS62277491A (ja) * | 1986-05-26 | 1987-12-02 | Maruzen Petrochem Co Ltd | メソフエ−ズピツチの製法 |
| US4931162A (en) * | 1987-10-09 | 1990-06-05 | Conoco Inc. | Process for producing clean distillate pitch and/or mesophase pitch for use in the production of carbon filters |
| US4961837A (en) * | 1989-04-28 | 1990-10-09 | Intevep, S.A. | Process for the production of petroleum tar pitch for use as a binder in the production of electrodes |
| DE4200958A1 (de) * | 1992-01-16 | 1993-07-22 | Ruetgerswerke Ag | Sinterfaehiges kohlenstoffpulver und verfahren zu seiner herstellung |
| US8083930B2 (en) * | 2006-08-31 | 2011-12-27 | Exxonmobil Chemical Patents Inc. | VPS tar separation |
| US8709233B2 (en) * | 2006-08-31 | 2014-04-29 | Exxonmobil Chemical Patents Inc. | Disposition of steam cracked tar |
| WO2008027139A1 (en) * | 2006-08-31 | 2008-03-06 | Exxonmobil Chemical Patents Inc. | Method for upgrading steam cracker tar using pox /cocker |
| US7846324B2 (en) | 2007-03-02 | 2010-12-07 | Exxonmobil Chemical Patents Inc. | Use of heat exchanger in a process to deasphalt tar |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2070961A (en) * | 1930-07-18 | 1937-02-16 | Barrett Co | Process of treating tar and pitch |
| US2992181A (en) * | 1957-09-11 | 1961-07-11 | Sinclair Refining Co | Process for producing a petroleum base pitch |
| CH478907A (fr) * | 1966-05-18 | 1969-09-30 | Continental Oil Co | Procédé de fabrication d'un brai à base de pétrole |
| US3537976A (en) * | 1968-09-30 | 1970-11-03 | Monsanto Co | Process for preparing binder pitches |
| US3692663A (en) * | 1971-03-19 | 1972-09-19 | Osaka Gas Co Ltd | Process for treating tars |
| US3919376A (en) * | 1972-12-26 | 1975-11-11 | Union Carbide Corp | Process for producing high mesophase content pitch fibers |
| US4086156A (en) * | 1974-12-13 | 1978-04-25 | Exxon Research & Engineering Co. | Pitch bonded carbon electrode |
| JPS5281321A (en) * | 1975-12-09 | 1977-07-07 | Koa Oil Co Ltd | Method of manufacturing binder pitch from petroleum heavy hydrocarbons |
| FR2392144A1 (fr) * | 1977-05-25 | 1978-12-22 | British Petroleum Co | Procede de fabrication de fibres de carbone et de graphite a partir de brais de petrole |
| US4208267A (en) * | 1977-07-08 | 1980-06-17 | Exxon Research & Engineering Co. | Forming optically anisotropic pitches |
| US4184942A (en) * | 1978-05-05 | 1980-01-22 | Exxon Research & Engineering Co. | Neomesophase formation |
| US4277324A (en) * | 1979-04-13 | 1981-07-07 | Exxon Research & Engineering Co. | Treatment of pitches in carbon artifact manufacture |
| US4219404A (en) * | 1979-06-14 | 1980-08-26 | Exxon Research & Engineering Co. | Vacuum or steam stripping aromatic oils from petroleum pitch |
| JPS56500777A (OSRAM) * | 1979-07-02 | 1981-06-11 | ||
| US4271006A (en) * | 1980-04-23 | 1981-06-02 | Exxon Research And Engineering Company | Process for production of carbon artifact precursor |
-
1981
- 1981-01-14 US US06/225,060 patent/US4363715A/en not_active Expired - Lifetime
- 1981-07-27 CA CA000382591A patent/CA1163589A/en not_active Expired
-
1982
- 1982-01-13 AU AU79485/82A patent/AU541898B2/en not_active Ceased
- 1982-01-14 JP JP57004776A patent/JPS57141488A/ja active Granted
- 1982-01-14 EP EP82300193A patent/EP0056338B1/en not_active Expired
- 1982-01-14 DE DE8282300193T patent/DE3265313D1/de not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0340076B2 (OSRAM) | 1991-06-17 |
| EP0056338A1 (en) | 1982-07-21 |
| US4363715A (en) | 1982-12-14 |
| AU7948582A (en) | 1982-07-22 |
| JPS57141488A (en) | 1982-09-01 |
| DE3265313D1 (en) | 1985-09-19 |
| EP0056338B1 (en) | 1985-08-14 |
| AU541898B2 (en) | 1985-01-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1163589A (en) | Process for production of carbon artifact precursors | |
| EP0038669B1 (en) | Process for preparing a pitch suitable for carbon fiber production | |
| US4219404A (en) | Vacuum or steam stripping aromatic oils from petroleum pitch | |
| CA1131151A (en) | Treatment of pitches in carbon artifact manufacture | |
| US4303631A (en) | Process for producing carbon fibers | |
| EP0066477B1 (en) | Process for producing a mesophase pitch and a carbon fiber by high pressure treatment of a precursor material | |
| US4705618A (en) | Process for the preparation of an intermediate pitch for manufacturing carbon products | |
| EP0086608B1 (en) | Carbon artifact grade pitch and manufacture thereof | |
| US4277325A (en) | Treatment of pitches in carbon artifact manufacture | |
| EP0067581B1 (en) | Process for preparing a pitch material | |
| EP0034410B1 (en) | Process for the preparation of a feedstock for carbon artifact manufacture | |
| US4427531A (en) | Process for deasphaltenating cat cracker bottoms and for production of anisotropic pitch | |
| EP0086607B1 (en) | Carbon artifact grade pitch and manufacture thereof | |
| US4931162A (en) | Process for producing clean distillate pitch and/or mesophase pitch for use in the production of carbon filters | |
| EP0072242B1 (en) | Production of carbon artifact feedstocks | |
| US4414096A (en) | Carbon precursor by hydroheat-soaking of steam cracker tar | |
| EP0120697A2 (en) | Process for preparing a spinnable pitch product |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |