CA1106798A - Process for producing tin (ii) sulfate - Google Patents
Process for producing tin (ii) sulfateInfo
- Publication number
- CA1106798A CA1106798A CA270,154A CA270154A CA1106798A CA 1106798 A CA1106798 A CA 1106798A CA 270154 A CA270154 A CA 270154A CA 1106798 A CA1106798 A CA 1106798A
- Authority
- CA
- Canada
- Prior art keywords
- tin
- sulfate
- diaphragm
- solution
- sulfuric acid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910000375 tin(II) sulfate Inorganic materials 0.000 title claims abstract description 42
- OBBXFSIWZVFYJR-UHFFFAOYSA-L tin(2+);sulfate Chemical compound [Sn+2].[O-]S([O-])(=O)=O OBBXFSIWZVFYJR-UHFFFAOYSA-L 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 33
- 230000008569 process Effects 0.000 title claims abstract description 28
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 82
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 66
- 229910010293 ceramic material Inorganic materials 0.000 claims abstract description 3
- 238000005245 sintering Methods 0.000 claims abstract description 3
- 239000011148 porous material Substances 0.000 claims description 13
- 235000011149 sulphuric acid Nutrition 0.000 claims description 6
- 238000005266 casting Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 235000012211 aluminium silicate Nutrition 0.000 claims description 2
- 239000004927 clay Substances 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 238000010304 firing Methods 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims 1
- SYRHIZPPCHMRIT-UHFFFAOYSA-N tin(4+) Chemical class [Sn+4] SYRHIZPPCHMRIT-UHFFFAOYSA-N 0.000 abstract description 7
- FAKFSJNVVCGEEI-UHFFFAOYSA-J tin(4+);disulfate Chemical compound [Sn+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O FAKFSJNVVCGEEI-UHFFFAOYSA-J 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 43
- 229940032330 sulfuric acid Drugs 0.000 description 34
- 238000005868 electrolysis reaction Methods 0.000 description 16
- 239000012528 membrane Substances 0.000 description 14
- 239000007788 liquid Substances 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- QHGNHLZPVBIIPX-UHFFFAOYSA-N tin(ii) oxide Chemical compound [Sn]=O QHGNHLZPVBIIPX-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical compound [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000010802 sludge Substances 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000003011 anion exchange membrane Substances 0.000 description 3
- 150000001450 anions Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 238000001704 evaporation Methods 0.000 description 3
- 238000005192 partition Methods 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000008151 electrolyte solution Substances 0.000 description 2
- 229940021013 electrolyte solution Drugs 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 150000003606 tin compounds Chemical class 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 229910021627 Tin(IV) chloride Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
- GWHRFNPTPGZQIC-UHFFFAOYSA-L [Sn+].[Sn+].[O-]S([O-])(=O)=O Chemical compound [Sn+].[Sn+].[O-]S([O-])(=O)=O GWHRFNPTPGZQIC-UHFFFAOYSA-L 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 229910052793 cadmium Inorganic materials 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000012876 carrier material Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005246 galvanizing Methods 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- -1 hydrogen ions Chemical class 0.000 description 1
- 230000002101 lytic effect Effects 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000010414 supernatant solution Substances 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 238000007704 wet chemistry method Methods 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G19/00—Compounds of tin
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19762602031 DE2602031C2 (de) | 1976-01-21 | 1976-01-21 | Verfahren zur Herstellung von Zinnll-sulfat |
| DEP2602031.5-41 | 1976-01-21 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1106798A true CA1106798A (en) | 1981-08-11 |
Family
ID=5967851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA270,154A Expired CA1106798A (en) | 1976-01-21 | 1977-01-20 | Process for producing tin (ii) sulfate |
Country Status (12)
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4330377A (en) * | 1980-07-10 | 1982-05-18 | Vulcan Materials Company | Electrolytic process for the production of tin and tin products |
| GB2181158B (en) * | 1985-10-08 | 1989-11-15 | Electricity Council | Electrolytic process for the manufacture of salts |
| IT1225210B (it) * | 1988-11-16 | 1990-11-02 | Giuseppe Garuti | Procedimento ed impianto per ottenere solfato di stagno |
| DE4010052A1 (de) * | 1990-03-29 | 1991-10-02 | Goldschmidt Ag Th | Verfahren zur elektrochemischen herstellung von waessrigen zinn-(ii)-chloridloesungen |
| JP2008289387A (ja) * | 2007-05-23 | 2008-12-04 | Daiwa Seiko Inc | 魚釣用スピニングリール |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1901364A (en) * | 1930-11-28 | 1933-03-14 | Cummings Edmund Olin | Process of making basic metal sulphates and recovery of metal from waste metallic compounds |
| US1947006A (en) * | 1931-02-14 | 1934-02-13 | Rufert Chemical Company | Process and apparatus for the preparation of metallic salts |
| US2673837A (en) * | 1949-06-22 | 1954-03-30 | Pennsylvania Salt Mfg Co | Electrolytic production of fluoborates |
| US2943032A (en) * | 1951-06-23 | 1960-06-28 | Nat Res Corp | Electrolytic production of titanium |
| NL120176C (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1958-06-27 | |||
| GB942497A (en) * | 1960-12-05 | 1963-11-20 | Atomic Energy Commission | Inorganic permselective membrane |
| SU141860A1 (ru) * | 1961-01-30 | 1961-11-30 | В.Ф. Грищенко | Способ получени сернокислого олова |
| US3795595A (en) * | 1971-07-29 | 1974-03-05 | Vulcan Materials Co | Electrolytic production of tin and lead salts using anion permselective membranes |
-
1976
- 1976-01-21 DE DE19762602031 patent/DE2602031C2/de not_active Expired
- 1976-12-29 CH CH1642476A patent/CH606491A5/xx not_active IP Right Cessation
-
1977
- 1977-01-13 FR FR7700822A patent/FR2338900A1/fr active Granted
- 1977-01-14 US US05/759,396 patent/US4118293A/en not_active Expired - Lifetime
- 1977-01-17 IT IT47673/77A patent/IT1082663B/it active
- 1977-01-19 BR BR7700370A patent/BR7700370A/pt unknown
- 1977-01-20 CA CA270,154A patent/CA1106798A/en not_active Expired
- 1977-01-20 AT AT33577A patent/AT350036B/de not_active IP Right Cessation
- 1977-01-21 BE BE174293A patent/BE850644A/xx not_active IP Right Cessation
- 1977-01-21 NL NL7700616.A patent/NL166072C/xx not_active IP Right Cessation
- 1977-01-21 JP JP571577A patent/JPS5290493A/ja active Granted
- 1977-01-21 GB GB2585/77A patent/GB1530234A/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| DE2602031C2 (de) | 1977-12-15 |
| ATA33577A (de) | 1978-10-15 |
| CH606491A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1978-10-31 |
| JPS5290493A (en) | 1977-07-29 |
| NL166072B (nl) | 1981-01-15 |
| NL166072C (nl) | 1981-06-15 |
| US4118293A (en) | 1978-10-03 |
| BE850644A (fr) | 1977-05-16 |
| GB1530234A (en) | 1978-10-25 |
| JPS554839B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-02-01 |
| FR2338900B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1980-11-07 |
| DE2602031B1 (de) | 1977-04-21 |
| AT350036B (de) | 1979-05-10 |
| FR2338900A1 (fr) | 1977-08-19 |
| NL7700616A (nl) | 1977-07-25 |
| IT1082663B (it) | 1985-05-21 |
| BR7700370A (pt) | 1977-12-13 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |