CA1101053A - Rechargeable galvanic cell - Google Patents
Rechargeable galvanic cellInfo
- Publication number
- CA1101053A CA1101053A CA308,929A CA308929A CA1101053A CA 1101053 A CA1101053 A CA 1101053A CA 308929 A CA308929 A CA 308929A CA 1101053 A CA1101053 A CA 1101053A
- Authority
- CA
- Canada
- Prior art keywords
- zinc
- galvanic cell
- cell
- anode
- oxide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 58
- 239000011701 zinc Substances 0.000 claims abstract description 56
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 55
- 239000003792 electrolyte Substances 0.000 claims abstract description 30
- 229910052751 metal Inorganic materials 0.000 claims abstract description 17
- 239000002184 metal Substances 0.000 claims abstract description 17
- 230000001427 coherent effect Effects 0.000 claims abstract description 14
- 238000011065 in-situ storage Methods 0.000 claims abstract description 10
- 239000011148 porous material Substances 0.000 claims abstract description 7
- 229910044991 metal oxide Inorganic materials 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 15
- 239000011248 coating agent Substances 0.000 claims description 12
- 238000000576 coating method Methods 0.000 claims description 12
- 150000004706 metal oxides Chemical class 0.000 claims description 12
- 229910000464 lead oxide Inorganic materials 0.000 claims description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 235000015110 jellies Nutrition 0.000 claims description 6
- 239000008274 jelly Substances 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 6
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 3
- 239000005751 Copper oxide Substances 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 229910000431 copper oxide Inorganic materials 0.000 claims description 3
- 150000004676 glycans Chemical class 0.000 claims description 3
- 229920001282 polysaccharide Polymers 0.000 claims description 3
- 239000005017 polysaccharide Substances 0.000 claims description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 3
- 230000006872 improvement Effects 0.000 claims description 2
- 229920002401 polyacrylamide Polymers 0.000 claims description 2
- 230000008569 process Effects 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 1
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 18
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 10
- 239000000843 powder Substances 0.000 description 9
- 239000011787 zinc oxide Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 7
- 229910052802 copper Inorganic materials 0.000 description 7
- 239000010949 copper Substances 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000007858 starting material Substances 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- -1 i.e. Substances 0.000 description 4
- UKWHYYKOEPRTIC-UHFFFAOYSA-N mercury(ii) oxide Chemical compound [Hg]=O UKWHYYKOEPRTIC-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 229920001778 nylon Polymers 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000010405 anode material Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 3
- 229910000480 nickel oxide Inorganic materials 0.000 description 3
- QELJHCBNGDEXLD-UHFFFAOYSA-N nickel zinc Chemical compound [Ni].[Zn] QELJHCBNGDEXLD-UHFFFAOYSA-N 0.000 description 3
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 229920002821 Modacrylic Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 235000010980 cellulose Nutrition 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000013528 metallic particle Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 238000011536 re-plating Methods 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 229920001410 Microfiber Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 238000005576 amination reaction Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 229940106135 cellulose Drugs 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000007596 consolidation process Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 229940101209 mercuric oxide Drugs 0.000 description 1
- 239000003658 microfiber Substances 0.000 description 1
- 238000001000 micrograph Methods 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 239000012255 powdered metal Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000004627 regenerated cellulose Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 235000013580 sausages Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000004347 surface barrier Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/244—Zinc electrodes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Cell Electrode Carriers And Collectors (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/829,924 US4091181A (en) | 1977-09-01 | 1977-09-01 | Rechargeable galvanic cell |
| US829,924 | 1977-09-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1101053A true CA1101053A (en) | 1981-05-12 |
Family
ID=25255915
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA308,929A Expired CA1101053A (en) | 1977-09-01 | 1978-08-08 | Rechargeable galvanic cell |
Country Status (7)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4368244A (en) * | 1980-06-11 | 1983-01-11 | General Electric Company | Zinc electrode for use in rechargeable electrochemical cells |
| US4281047A (en) * | 1980-06-11 | 1981-07-28 | General Electric Company | Zinc electrode made from a modified zinc oxide for use in rechargeable electrochemical cells |
| US4333994A (en) * | 1981-03-27 | 1982-06-08 | Union Carbide Corporation | Cell employing a coiled electrode assembly |
| JPS6289749A (ja) * | 1985-10-15 | 1987-04-24 | Mitsubishi Petrochem Co Ltd | 電極材料 |
| JPS6348979A (ja) * | 1986-08-19 | 1988-03-01 | Fuji Photo Film Co Ltd | Ｃｒｔのコントラスト調整装置 |
| DE3902648A1 (de) * | 1989-01-30 | 1990-08-09 | Varta Batterie | Galvanisches element |
| EP0578501B1 (en) * | 1992-07-10 | 1998-05-27 | Nippon Oil Co. Ltd. | Zinc electrode for alkaline storage battery |
| DE4233412C1 (de) * | 1992-10-05 | 1994-02-17 | Freudenberg Carl Fa | Hydrophiliertes Separatorenmaterial aus Faservliesstoff für elektrochemische Energiespeicher und Verfahren zu seiner Herstellung |
| WO1996001505A1 (en) * | 1994-07-06 | 1996-01-18 | Elmer Hughett | Electric vehicle cell |
| US5532075A (en) * | 1994-07-06 | 1996-07-02 | Alexander Manufacturing Corporation | Small battery cell |
| US5521021A (en) * | 1994-07-06 | 1996-05-28 | Alexander Manufacturing Corporation | Electric vehicle cell |
| CA2194490A1 (en) * | 1994-07-06 | 1996-01-18 | Elmer Hughett | Small battery cell |
| WO2000059062A1 (fr) | 1999-03-29 | 2000-10-05 | Kawasaki Jukogyo Kabushiki Kaisha | Accumulateur et equipement ou dispositif integrant cet accumulateur dans sa structure, et procede de generation d'energie repartie localement et procede de generation d'energie utilise |
| US6426867B1 (en) * | 2000-05-05 | 2002-07-30 | Wilson Greatbatch, Ltd. | Protection device having tapered ribs and method of assembling a battery with a protection device and an electrical component |
| AR045347A1 (es) | 2003-08-08 | 2005-10-26 | Rovcal Inc | Celda alcalina de alta capacidad |
| JP5144931B2 (ja) | 2003-08-18 | 2013-02-13 | パワージェニックス システムズ， インコーポレーテッド | ニッケル亜鉛電池の製造方法 |
| US20060207084A1 (en) * | 2004-08-17 | 2006-09-21 | Powergenix, Inc. | Method of manufacturing nickel zinc batteries |
| AR047875A1 (es) | 2004-06-04 | 2006-03-01 | Rovcal Inc | Celdas alcalinas que presentan alta capacidad |
| US8703330B2 (en) * | 2005-04-26 | 2014-04-22 | Powergenix Systems, Inc. | Nickel zinc battery design |
| WO2009123888A1 (en) * | 2008-04-02 | 2009-10-08 | Powergenix Systems, Inc. | Cylindrical nickel-zinc cell with negative can |
| EP2394324B1 (de) | 2009-02-09 | 2015-06-10 | VARTA Microbattery GmbH | Knopfzellen und verfahren zu ihrer herstellung |
| DE102009060800A1 (de) | 2009-06-18 | 2011-06-09 | Varta Microbattery Gmbh | Knopfzelle mit Wickelelektrode und Verfahren zu ihrer Herstellung |
| DE102015212226A1 (de) * | 2015-06-30 | 2017-01-05 | Robert Bosch Gmbh | Komponente für eine Batteriezelle und Batteriezelle |
| US11450847B2 (en) | 2019-01-23 | 2022-09-20 | Energizer Brands, Llc | Alkaline electrochemical cells comprising increased zinc oxide levels |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3042732A (en) * | 1959-10-14 | 1962-07-03 | Union Carbide Corp | Anodes for alkaline cells |
| DE1771604C3 (de) * | 1968-06-14 | 1973-10-31 | Varta Batterie Ag, 3000 Hannover | Wiederaufladbares Braunstein/Zink Element mit alkalischem Elektrolyten, bei dem die Kapazität der Zinkelektrode weniger als 40% der tatsachlichen Kapa zitat der Braunsteinelektrode betragt |
| US3785868A (en) * | 1970-11-20 | 1974-01-15 | Gates Rubber Co | Zinc electrode |
| DE2101734A1 (de) * | 1971-01-15 | 1972-07-27 | Deutsche Automobilgesellsch | Elektrode für galvanische Elemente und Verfahren zu ihrer Herstellung |
| JPS5461B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-11-21 | 1979-01-05 | ||
| FR2319211A1 (fr) * | 1975-07-24 | 1977-02-18 | Wonder | Perfectionnements aux accumulateurs, notamment aux accumulateurs argent-zinc |
-
1977
- 1977-09-01 US US05/829,924 patent/US4091181A/en not_active Expired - Lifetime
-
1978
- 1978-08-08 CA CA308,929A patent/CA1101053A/en not_active Expired
- 1978-08-30 DE DE2837729A patent/DE2837729C3/de not_active Expired
- 1978-08-31 FR FR7825138A patent/FR2402308A1/fr active Granted
- 1978-08-31 JP JP10698278A patent/JPS5448049A/ja active Granted
- 1978-08-31 GB GB7835121A patent/GB2003652B/en not_active Expired
-
1983
- 1983-03-16 SG SG112/83A patent/SG11283G/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| DE2837729C3 (de) | 1982-02-25 |
| FR2402308A1 (fr) | 1979-03-30 |
| JPS5448049A (en) | 1979-04-16 |
| JPS6157661B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1986-12-08 |
| SG11283G (en) | 1984-07-20 |
| DE2837729A1 (de) | 1979-03-08 |
| US4091181A (en) | 1978-05-23 |
| GB2003652B (en) | 1982-08-04 |
| GB2003652A (en) | 1979-03-14 |
| FR2402308B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1983-02-25 |
| DE2837729B2 (de) | 1981-02-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |