CA1098507A - Process for producing methacrylic acid and a catalyst - Google Patents

Process for producing methacrylic acid and a catalyst

Info

Publication number
CA1098507A
CA1098507A CA314,344A CA314344A CA1098507A CA 1098507 A CA1098507 A CA 1098507A CA 314344 A CA314344 A CA 314344A CA 1098507 A CA1098507 A CA 1098507A
Authority
CA
Canada
Prior art keywords
catalyst
excluding
less
acid
oxygen
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA314,344A
Other languages
English (en)
French (fr)
Inventor
Mutsumi Matsumoto
Atsushi Sudo
Hideki Sugi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Application granted granted Critical
Publication of CA1098507A publication Critical patent/CA1098507A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8875—Germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8877—Vanadium, tantalum, niobium or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA314,344A 1977-10-31 1978-10-26 Process for producing methacrylic acid and a catalyst Expired CA1098507A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP52129685A JPS5924140B2 (ja) 1977-10-31 1977-10-31 メタクリル酸の製造法及び触媒
JP129685/1977 1977-10-31

Publications (1)

Publication Number Publication Date
CA1098507A true CA1098507A (en) 1981-03-31

Family

ID=15015638

Family Applications (1)

Application Number Title Priority Date Filing Date
CA314,344A Expired CA1098507A (en) 1977-10-31 1978-10-26 Process for producing methacrylic acid and a catalyst

Country Status (11)

Country Link
US (2) US4273676A (US20070244113A1-20071018-C00087.png)
JP (1) JPS5924140B2 (US20070244113A1-20071018-C00087.png)
BE (1) BE871659A (US20070244113A1-20071018-C00087.png)
CA (1) CA1098507A (US20070244113A1-20071018-C00087.png)
DE (1) DE2847288C2 (US20070244113A1-20071018-C00087.png)
ES (1) ES474674A1 (US20070244113A1-20071018-C00087.png)
FR (1) FR2407022A1 (US20070244113A1-20071018-C00087.png)
GB (1) GB2010693B (US20070244113A1-20071018-C00087.png)
IT (1) IT1099821B (US20070244113A1-20071018-C00087.png)
NL (1) NL7810588A (US20070244113A1-20071018-C00087.png)
SU (1) SU873868A3 (US20070244113A1-20071018-C00087.png)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS552619A (en) * 1978-06-21 1980-01-10 Nippon Kayaku Co Ltd Preparation of methacrylic acid and catalyst
DD148728A5 (de) * 1978-12-13 1981-06-10 Nippon Kayaku Kk Verfahren zur herstellung eines katalysators mit heteropolysaeurestruktur
JPS55124734A (en) * 1979-03-22 1980-09-26 Nippon Kayaku Co Ltd Preparation of methacrylic acid
US4419270A (en) * 1980-06-26 1983-12-06 Nippon Shokubai Kagaku Kogyo Co. Ltd. Oxidation catalyst
DE3030243A1 (de) * 1980-08-09 1982-03-18 Basf Ag, 6700 Ludwigshafen Oxidationskatalysator insbesondere fuer die herstellung von methacrylsaeure durch gasphasenoxidation von methacrolein
US4522934A (en) * 1981-04-27 1985-06-11 Atlantic Richfield Company Vanadotungstomolybdophosphoric acid oxidation catalyst
JPS5896041A (ja) * 1981-12-01 1983-06-07 Sumitomo Chem Co Ltd メタクリル酸の製造方法
DE3626256A1 (de) * 1986-08-02 1988-02-11 Roehm Gmbh Heteropolymolybdat-gemische und ihre verwendung als katalysatoren
US4917820A (en) * 1986-08-26 1990-04-17 Nippon Kayaku Kabushiki Kaisha Ethylene removal agent, postharvest preservation agent and deodorant
JPH0753686B2 (ja) * 1986-10-27 1995-06-07 三菱レイヨン株式会社 メタクリル酸の製造法
JP3101821B2 (ja) * 1990-02-15 2000-10-23 三菱レイヨン株式会社 メタクリル酸製造用触媒の調製法
JPH047037A (ja) * 1990-04-23 1992-01-10 Mitsubishi Rayon Co Ltd メタクリル酸製造用触媒の調製法
DE4022212A1 (de) * 1990-07-12 1992-01-16 Basf Ag Massen der allgemeinen formel mo(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)2(pfeil abwaerts)(pfeil hoch)p(pfeil hoch)(pfeil abwaerts)a(pfeil abwaerts)(pfeil hoch)v(pfeil hoch)(pfeil abwaerts)b(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)1(pfeil hoch)(pfeil abwaerts)c(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)2(pfeil hoch)(pfeil abwaerts)d(pfeil abwaerts)(pfeil hoch)x(pfeil hoch)(pfeil hoch)3(pfeil hoch)(pfeil abwaerts)e(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil hoch)b(pfeil hoch)(pfeil abwaerts)f(pfeil abwaerts)(pfeil hoch)r(pfeil hoch)(pfeil hoch)e(pfeil hoch)(pfeil abwaerts)g(pfeil abwaerts)(pfeil hoch)s(pfeil hoch)(pfeil abwaerts)h(pfeil abwaerts)(pfeil hoch)o(pfeil hoch)(pfeil abwaerts)n(pfeil abwaerts)
FR2680702B1 (fr) * 1991-09-03 1994-11-04 Atochem Nouveau systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures et l'oxydation d'aldehydes en acides.
SG126710A1 (en) * 2001-10-31 2006-11-29 Univ Singapore Carbon nanotubes fabrication and hydrogen production
JP3884967B2 (ja) * 2002-02-07 2007-02-21 住友化学株式会社 メタクリル酸の製造方法
US7524792B2 (en) * 2003-06-04 2009-04-28 Basf Aktiengesellschaft Preparation of catalytically active multielement oxide materials which contain at least one of the elements Nb and W and the elements Mo, V and Cu
JP5335490B2 (ja) * 2009-03-09 2013-11-06 住友化学株式会社 メタクリル酸製造用触媒の再生方法及びメタクリル酸の製造方法

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3380931A (en) * 1960-01-12 1968-04-30 Shell Oil Co Oxidation catalysts
NL289375A (US20070244113A1-20071018-C00087.png) * 1962-03-19
US3485877A (en) * 1966-10-21 1969-12-23 Eastman Kodak Co Process for converting ethylenically unsaturated hydrocarbons to carbonylic compounds
US3437690A (en) * 1967-11-21 1969-04-08 Eastman Kodak Co Vapor phase process for preparing unsaturated aliphatic aldehydes and monocarboxylic acids
US3644497A (en) * 1968-11-01 1972-02-22 Celanese Corp Conversion of ethylenically unsaturated compounds using heteropoly-molybdic and heteropolytungstic acids as catalysts
CH569926A5 (US20070244113A1-20071018-C00087.png) * 1973-06-15 1975-11-28 Bartolomeis Spa Forni Ed Impia
US4001316A (en) * 1973-06-15 1977-01-04 Nippon Kayaku Kabushiki Kaisha Method for manufacture of methacrylic acid
US3875220A (en) * 1973-10-11 1975-04-01 Standard Oil Co Ohio Process for the preparation of methacrylic acid from methacrolein
DE2460541C3 (de) * 1973-12-29 1979-10-18 Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan) Phosphor, Molybdän und Vanadium sowie gegebenenfalls Kupfer, Kobalt, Zirkon, Wismut, Antimon und/oder Arsen enthaltender Oxydkatalysator und dessen Verwendung zur Herstellung von Methacrylsäure
GB1430337A (en) * 1974-05-24 1976-03-31 Nippon Kayaku Kk Process for the manufacture of methacrylic acid and oxidation catalyst therefor
JPS5827255B2 (ja) * 1974-05-31 1983-06-08 三菱レイヨン株式会社 不飽和脂肪酸の製造方法
US4000088A (en) * 1974-06-03 1976-12-28 Nippon Kayaku Co., Ltd. Oxidation catalyst for the manufacture of methacrylic acid
US4192951A (en) * 1975-08-11 1980-03-11 Celanese Corporation Hydrocarbon oxidation process
JPS5946934B2 (ja) * 1976-02-09 1984-11-15 東ソー株式会社 メタクリル酸の製法
US4101448A (en) * 1976-05-14 1978-07-18 The Standard Oil Company Catalyst compositions especially useful for preparation of unsaturated acids
JPS53103414A (en) * 1977-02-22 1978-09-08 Sumitomo Chem Co Ltd Preparation of acrylic acid

Also Published As

Publication number Publication date
DE2847288C2 (de) 1987-03-12
JPS5466619A (en) 1979-05-29
SU873868A3 (ru) 1981-10-15
BE871659A (fr) 1979-04-30
US4273676A (en) 1981-06-16
FR2407022B1 (US20070244113A1-20071018-C00087.png) 1983-07-18
ES474674A1 (es) 1979-03-16
IT1099821B (it) 1985-09-28
US4745217A (en) 1988-05-17
NL7810588A (nl) 1979-05-02
JPS5924140B2 (ja) 1984-06-07
FR2407022A1 (fr) 1979-05-25
IT7829107A0 (it) 1978-10-25
GB2010693A (en) 1979-07-04
DE2847288A1 (de) 1979-05-03
GB2010693B (en) 1982-04-07

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Legal Events

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