CA1089613A - Manufacture of flame-retardant regenerated cellulose fibres - Google Patents
Manufacture of flame-retardant regenerated cellulose fibresInfo
- Publication number
- CA1089613A CA1089613A CA232,448A CA232448A CA1089613A CA 1089613 A CA1089613 A CA 1089613A CA 232448 A CA232448 A CA 232448A CA 1089613 A CA1089613 A CA 1089613A
- Authority
- CA
- Canada
- Prior art keywords
- component
- flame
- compound
- fibres
- viscose
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 23
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 22
- 229920003043 Cellulose fiber Polymers 0.000 title claims abstract description 10
- 239000004627 regenerated cellulose Substances 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title abstract description 3
- 150000001875 compounds Chemical class 0.000 claims abstract description 36
- 229920000297 Rayon Polymers 0.000 claims abstract description 33
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 19
- 238000009987 spinning Methods 0.000 claims abstract description 17
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 12
- 239000012757 flame retardant agent Substances 0.000 claims abstract description 11
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- -1 flame-retardant phosphorus compounds Chemical class 0.000 claims abstract description 10
- 229910052736 halogen Inorganic materials 0.000 claims abstract description 10
- 150000002367 halogens Chemical class 0.000 claims abstract description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 10
- 239000011574 phosphorus Substances 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims abstract description 7
- YTVQIZRDLKWECQ-UHFFFAOYSA-N 2-benzoylcyclohexan-1-one Chemical compound C=1C=CC=CC=1C(=O)C1CCCCC1=O YTVQIZRDLKWECQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- WRWYTKCTJKBQST-UHFFFAOYSA-N [3-(hydroxymethylamino)-3-oxopropyl]phosphonic acid Chemical compound OCNC(=O)CCP(O)(O)=O WRWYTKCTJKBQST-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 5
- 239000007859 condensation product Substances 0.000 claims abstract description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 150000001408 amides Chemical class 0.000 claims abstract description 4
- 150000001412 amines Chemical class 0.000 claims abstract description 4
- 239000004202 carbamide Substances 0.000 claims abstract description 4
- 229920002627 poly(phosphazenes) Polymers 0.000 claims abstract description 4
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 238000009833 condensation Methods 0.000 claims abstract description 3
- 230000005494 condensation Effects 0.000 claims abstract description 3
- 239000011347 resin Substances 0.000 claims abstract description 3
- 229920005989 resin Polymers 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 18
- 239000001913 cellulose Substances 0.000 claims description 15
- 229920002678 cellulose Polymers 0.000 claims description 14
- 239000004753 textile Substances 0.000 claims description 12
- IUPSCXDOKZWYRB-UHFFFAOYSA-N 1,2,3$l^{2}-triphosphirene Chemical compound [P]1P=P1 IUPSCXDOKZWYRB-UHFFFAOYSA-N 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 5
- 125000002947 alkylene group Chemical group 0.000 claims description 4
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 4
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 claims description 2
- WBLIXGSTEMXDSM-UHFFFAOYSA-N chloromethane Chemical compound Cl[CH2] WBLIXGSTEMXDSM-UHFFFAOYSA-N 0.000 claims description 2
- 238000010559 graft polymerization reaction Methods 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 claims description 2
- 150000003018 phosphorus compounds Chemical class 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- OBSZRRSYVTXPNB-UHFFFAOYSA-N tetraphosphorus Chemical compound P12P3P1P32 OBSZRRSYVTXPNB-UHFFFAOYSA-N 0.000 claims description 2
- 235000010980 cellulose Nutrition 0.000 claims 2
- 239000007983 Tris buffer Substances 0.000 claims 1
- ZUWHQXKNRYNJDL-UHFFFAOYSA-N [hydroxy-tris(hydroxymethyl)-lambda5-phosphanyl]methanol Chemical compound OCP(O)(CO)(CO)CO ZUWHQXKNRYNJDL-UHFFFAOYSA-N 0.000 claims 1
- 125000000217 alkyl group Chemical group 0.000 claims 1
- 229940106135 cellulose Drugs 0.000 claims 1
- 239000000243 solution Substances 0.000 claims 1
- 229920002554 vinyl polymer Polymers 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 3
- FYAMXEPQQLNQDM-UHFFFAOYSA-N Tris(1-aziridinyl)phosphine oxide Chemical compound C1CN1P(N1CC1)(=O)N1CC1 FYAMXEPQQLNQDM-UHFFFAOYSA-N 0.000 abstract description 2
- CAHAMHDKTHDHBX-UHFFFAOYSA-N [N]P(=O)=O Chemical compound [N]P(=O)=O CAHAMHDKTHDHBX-UHFFFAOYSA-N 0.000 abstract description 2
- 208000012886 Vertigo Diseases 0.000 description 12
- 239000004744 fabric Substances 0.000 description 12
- 230000000694 effects Effects 0.000 description 10
- 239000000835 fiber Substances 0.000 description 6
- 235000014786 phosphorus Nutrition 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 230000001771 impaired effect Effects 0.000 description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 3
- 230000001143 conditioned effect Effects 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 230000001112 coagulating effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- CPQCSJYYDADLCZ-UHFFFAOYSA-N n-methylhydroxylamine Chemical compound CNO CPQCSJYYDADLCZ-UHFFFAOYSA-N 0.000 description 2
- CHEANNSDVJOIBS-MHZLTWQESA-N (3s)-3-cyclopropyl-3-[3-[[3-(5,5-dimethylcyclopenten-1-yl)-4-(2-fluoro-5-methoxyphenyl)phenyl]methoxy]phenyl]propanoic acid Chemical compound COC1=CC=C(F)C(C=2C(=CC(COC=3C=C(C=CC=3)[C@@H](CC(O)=O)C3CC3)=CC=2)C=2C(CCC=2)(C)C)=C1 CHEANNSDVJOIBS-MHZLTWQESA-N 0.000 description 1
- QIVUCLWGARAQIO-OLIXTKCUSA-N (3s)-n-[(3s,5s,6r)-6-methyl-2-oxo-1-(2,2,2-trifluoroethyl)-5-(2,3,6-trifluorophenyl)piperidin-3-yl]-2-oxospiro[1h-pyrrolo[2,3-b]pyridine-3,6'-5,7-dihydrocyclopenta[b]pyridine]-3'-carboxamide Chemical compound C1([C@H]2[C@H](N(C(=O)[C@@H](NC(=O)C=3C=C4C[C@]5(CC4=NC=3)C3=CC=CN=C3NC5=O)C2)CC(F)(F)F)C)=C(F)C=CC(F)=C1F QIVUCLWGARAQIO-OLIXTKCUSA-N 0.000 description 1
- XWZVMQUGLNNOSG-UHFFFAOYSA-N 3-diethoxyphosphoryl-n-(hydroxymethyl)propanamide Chemical compound CCOP(=O)(OCC)CCC(=O)NCO XWZVMQUGLNNOSG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- UXJHQBVRZUANLK-UHFFFAOYSA-N azanylidyne(dichloro)-$l^{5}-phosphane Chemical class ClP(Cl)#N UXJHQBVRZUANLK-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- CBOIHMRHGLHBPB-UHFFFAOYSA-N hydroxymethyl Chemical compound O[CH2] CBOIHMRHGLHBPB-UHFFFAOYSA-N 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- APVPOHHVBBYQAV-UHFFFAOYSA-N n-(4-aminophenyl)sulfonyloctadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NS(=O)(=O)C1=CC=C(N)C=C1 APVPOHHVBBYQAV-UHFFFAOYSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/667—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain
- D06M15/673—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing phosphorus in the main chain containing phosphorus and nitrogen in the main chain
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/06—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from viscose
- D01F2/08—Composition of the spinning solution or the bath
- D01F2/10—Addition to the spinning solution or spinning bath of substances which exert their effect equally well in either
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/68—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof
- D06M11/70—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with phosphorus or compounds thereof, e.g. with chlorophosphonic acid or salts thereof with oxides of phosphorus; with hypophosphorous, phosphorous or phosphoric acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/285—Phosphines; Phosphine oxides; Phosphine sulfides; Phosphinic or phosphinous acids or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
- D06M15/431—Amino-aldehyde resins modified by phosphorus compounds by phosphines or phosphine oxides; by oxides or salts of the phosphonium radical
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
- D06M15/43—Amino-aldehyde resins modified by phosphorus compounds
- D06M15/432—Amino-aldehyde resins modified by phosphorus compounds by phosphonic acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Artificial Filaments (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ATA6759/74 | 1974-08-20 | ||
AT675974A AT333932B (de) | 1974-08-20 | 1974-08-20 | Verfahren zur herstellung flammfester celluloseregeneratfasern |
Publications (1)
Publication Number | Publication Date |
---|---|
CA1089613A true CA1089613A (en) | 1980-11-18 |
Family
ID=3589469
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CA232,448A Expired CA1089613A (en) | 1974-08-20 | 1975-07-29 | Manufacture of flame-retardant regenerated cellulose fibres |
Country Status (14)
Country | Link |
---|---|
US (1) | US4063883A (forum.php) |
AT (1) | AT333932B (forum.php) |
BE (1) | BE832514A (forum.php) |
BR (1) | BR7505286A (forum.php) |
CA (1) | CA1089613A (forum.php) |
CH (1) | CH582251A5 (forum.php) |
DD (1) | DD119622A5 (forum.php) |
DK (1) | DK145187C (forum.php) |
FR (1) | FR2282489A1 (forum.php) |
GB (1) | GB1485533A (forum.php) |
IT (1) | IT1041259B (forum.php) |
NL (1) | NL7509847A (forum.php) |
SE (1) | SE410202B (forum.php) |
SU (1) | SU635886A3 (forum.php) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012094723A1 (en) * | 2011-01-13 | 2012-07-19 | Blmh Technologies Inc. | Method for forming a fire resistant cellulose product, and associated apparatus |
Families Citing this family (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2909600A1 (de) * | 1979-03-12 | 1980-09-18 | Hoechst Ag | Aktive hydroxyl- und halogenhaltige phosphornitride und verfahren zur herstellung |
JPS6211792A (ja) * | 1985-02-27 | 1987-01-20 | Dainippon Ink & Chem Inc | 難燃剤及び難燃木質物 |
GB9309617D0 (en) * | 1993-05-11 | 1993-06-23 | Courtaulds Fibres Ltd | Fibre production process |
WO1996010443A1 (en) * | 1994-09-30 | 1996-04-11 | The University Of New Mexico | Phosphorus nitride agents to protect against fires and explosions |
US5766746A (en) * | 1994-11-07 | 1998-06-16 | Lenzing Aktiengesellschaft | Flame retardant non-woven textile article |
AT401656B (de) * | 1994-11-07 | 1996-11-25 | Chemiefaser Lenzing Ag | Flammfestes nicht gewebtes textiles gebilde |
US6524653B1 (en) | 2000-11-01 | 2003-02-25 | Niponi, Llc | Cellulose-based fire retardant composition |
US7786031B2 (en) * | 2007-01-26 | 2010-08-31 | Milliken & Company | Flame resistant textile |
AT510909B1 (de) * | 2010-12-20 | 2013-04-15 | Chemiefaser Lenzing Ag | Flammgehemmte cellulosische man-made-fasern |
CN103334173B (zh) * | 2013-07-11 | 2015-04-22 | 宜宾丝丽雅股份有限公司 | 一种阻燃粘胶纤维及其制备方法 |
US9624312B2 (en) | 2014-03-26 | 2017-04-18 | International Business Machines Corporation | Flame retardant modified cellulosic nanomaterials (FR-CNs) prepared using phosphorus-containing monomers |
EP3476985A1 (de) | 2017-10-27 | 2019-05-01 | Lenzing Aktiengesellschaft | Flammgehemmte cellulosische man-made-fasern |
NL2020326B1 (en) * | 2018-01-26 | 2019-07-31 | Ten Cate Protect Bv | Method for Producing a Flame-Resistant Textile Article |
WO2019101852A1 (en) * | 2017-11-22 | 2019-05-31 | Ten Cate Protect Bv | Method for producing a flame-resistant textile article |
CN117626459B (zh) * | 2023-12-11 | 2024-05-14 | 江苏垶恒复合材料有限公司 | 一种阻燃再生纤维素纤维 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA736508A (en) | 1966-06-14 | L. O'brien Joseph | Dialkylphosphatoalkyl acrylates and methacrylates and process for preparing same | |
US2582181A (en) * | 1949-03-25 | 1952-01-08 | Rudolf F Hlavaty | Fireproofing compositions containing water-insoluble phosphorylamides, and articles fireproofed therewith |
US2816004A (en) * | 1951-06-30 | 1957-12-10 | Monsanto Chemicals | Cellulosic solutions containing fire retardant and method of extruding |
US3034919A (en) * | 1960-03-18 | 1962-05-15 | Stauffer Chemical Co | Fire retardant composition and cellulosic fabric treated therewith |
US3266918A (en) * | 1962-12-19 | 1966-08-16 | Fmc Corp | Viscose solutions for making flame retardant rayon |
US3455713A (en) * | 1966-07-21 | 1969-07-15 | Fmc Corp | Flame-retardant regenerated cellulose |
US3783016A (en) * | 1971-06-01 | 1974-01-01 | D Randall | Method for imparting flame resistance to fibrous materials |
IT969954B (it) * | 1972-10-26 | 1974-04-10 | Snia Viscosa | Metodo per la produzione di fibre cellulosiche e polinosiche aventi alta resistenza alla combustione e fibre e prodotti tessili ottenu ti secondo tale metodo |
DE2311180C3 (de) * | 1973-03-07 | 1982-02-25 | Chemiefaser Lenzing AG, 4860 Lenzing, Oberösterreich | Verfahren zur Herstellung flammfester Celluloseregeneratfasern |
US3925274A (en) * | 1974-10-02 | 1975-12-09 | Scott Paper Co | Abrasion resistant cellulosic fabrics containing graft polymerized diethylphosphatoethylmethacrylate and/or diethylphosphato-ethyl acrylate |
-
1974
- 1974-08-20 AT AT675974A patent/AT333932B/de not_active IP Right Cessation
-
1975
- 1975-07-21 CH CH952475A patent/CH582251A5/xx not_active IP Right Cessation
- 1975-07-29 CA CA232,448A patent/CA1089613A/en not_active Expired
- 1975-07-30 SU SU752163066A patent/SU635886A3/ru active
- 1975-08-05 GB GB32691/75A patent/GB1485533A/en not_active Expired
- 1975-08-14 US US05/604,489 patent/US4063883A/en not_active Expired - Lifetime
- 1975-08-18 BE BE159273A patent/BE832514A/xx unknown
- 1975-08-18 IT IT50975/75A patent/IT1041259B/it active
- 1975-08-18 DD DD187913A patent/DD119622A5/xx unknown
- 1975-08-19 FR FR7525671A patent/FR2282489A1/fr active Granted
- 1975-08-19 BR BR7505286*A patent/BR7505286A/pt unknown
- 1975-08-19 NL NL7509847A patent/NL7509847A/xx not_active Application Discontinuation
- 1975-08-19 DK DK374075A patent/DK145187C/da not_active Application Discontinuation
- 1975-08-19 SE SE7509250A patent/SE410202B/xx unknown
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2012094723A1 (en) * | 2011-01-13 | 2012-07-19 | Blmh Technologies Inc. | Method for forming a fire resistant cellulose product, and associated apparatus |
Also Published As
Publication number | Publication date |
---|---|
SE410202B (sv) | 1979-10-01 |
DK145187B (da) | 1982-09-27 |
SU635886A3 (ru) | 1978-11-30 |
IT1041259B (it) | 1980-01-10 |
FR2282489B1 (forum.php) | 1979-03-09 |
FR2282489A1 (fr) | 1976-03-19 |
CH582251A5 (forum.php) | 1976-11-30 |
NL7509847A (nl) | 1976-02-24 |
ATA675974A (de) | 1976-04-15 |
DD119622A5 (forum.php) | 1976-05-05 |
DK145187C (da) | 1983-02-21 |
AT333932B (de) | 1976-12-27 |
BE832514A (fr) | 1976-02-18 |
DK374075A (da) | 1976-02-21 |
GB1485533A (en) | 1977-09-14 |
SE7509250L (sv) | 1976-02-23 |
BR7505286A (pt) | 1976-08-03 |
US4063883A (en) | 1977-12-20 |
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