CA1081714A - Process for the manufacture of styrene - Google Patents

Process for the manufacture of styrene

Info

Publication number
CA1081714A
CA1081714A CA276,229A CA276229A CA1081714A CA 1081714 A CA1081714 A CA 1081714A CA 276229 A CA276229 A CA 276229A CA 1081714 A CA1081714 A CA 1081714A
Authority
CA
Canada
Prior art keywords
catalyst
group
acid
phenylacetic acid
benzyl
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA276,229A
Other languages
English (en)
French (fr)
Inventor
I-Der Huang
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Technology and Engineering Co
Original Assignee
Exxon Research and Engineering Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxon Research and Engineering Co filed Critical Exxon Research and Engineering Co
Application granted granted Critical
Publication of CA1081714A publication Critical patent/CA1081714A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
    • C07C51/12—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide on an oxygen-containing group in organic compounds, e.g. alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C07C1/24—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms by elimination of water
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
    • C07C15/40—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals
    • C07C15/42—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic
    • C07C15/44—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts substituted by unsaturated carbon radicals monocyclic the hydrocarbon substituent containing a carbon-to-carbon double bond
    • C07C15/46—Styrene; Ring-alkylated styrenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/147—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof
    • C07C29/149—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of carboxylic acids or derivatives thereof with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/035—Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with saturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA276,229A 1976-05-10 1977-04-15 Process for the manufacture of styrene Expired CA1081714A (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US68505776A 1976-05-10 1976-05-10
US685,057 1976-05-10
US75524576A 1976-12-29 1976-12-29
US755,245 1991-09-05

Publications (1)

Publication Number Publication Date
CA1081714A true CA1081714A (en) 1980-07-15

Family

ID=27103482

Family Applications (1)

Application Number Title Priority Date Filing Date
CA276,229A Expired CA1081714A (en) 1976-05-10 1977-04-15 Process for the manufacture of styrene

Country Status (8)

Country Link
JP (1) JPS52136133A (OSRAM)
AU (1) AU506781B2 (OSRAM)
BR (1) BR7703000A (OSRAM)
CA (1) CA1081714A (OSRAM)
DE (1) DE2719840A1 (OSRAM)
FR (1) FR2351072A1 (OSRAM)
GB (1) GB1583091A (OSRAM)
NL (1) NL7705003A (OSRAM)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS53147039A (en) * 1977-05-30 1978-12-21 Ube Ind Ltd Preparation of carboxylic acid ester of hydroxymethyl-substituted aromatic compound
JPS5519247A (en) * 1978-07-28 1980-02-09 Sumitomo Chem Co Ltd Preparation of high-purity styrene by dehydration reaction of alpha-phenylethyl alcohol
JPS61293936A (ja) * 1985-06-21 1986-12-24 Kureha Chem Ind Co Ltd 芳香族側鎖α−位アルコ−ルの液相脱水法
AU2003263197A1 (en) * 2002-08-06 2004-02-25 Shell Internationale Research Maatschappij B.V. Process
CN113274996A (zh) * 2021-05-13 2021-08-20 山东齐鲁华信高科有限公司 一种α-苯乙醇气相脱水制苯乙烯用催化剂

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB981987A (en) * 1962-02-03 1965-02-03 Bayer Ag A process for the production of organic acetates
DE1235879B (de) * 1964-03-17 1967-03-09 Basf Ag Verfahren zur Herstellung von Alkoholen durch katalytische Hydrierung von Carbonsaeuren
US3526674A (en) * 1968-08-05 1970-09-01 Halcon International Inc Process for the dehydration of aralkanols
DE2107913C3 (de) * 1971-02-19 1979-10-04 Bayer Ag, 5090 Leverkusen Verfahren zur Herstellung von Benzylacetat

Also Published As

Publication number Publication date
DE2719840A1 (de) 1977-11-24
FR2351072B1 (OSRAM) 1983-10-14
FR2351072A1 (fr) 1977-12-09
JPS52136133A (en) 1977-11-14
BR7703000A (pt) 1978-02-08
AU2432077A (en) 1978-10-19
AU506781B2 (en) 1980-01-24
NL7705003A (nl) 1977-11-14
GB1583091A (en) 1981-01-21

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Legal Events

Date Code Title Description
MKEX Expiry