CA1065340A - Process for the preparation of acrylic acid and methacrylic acid from corresponding aldehydes - Google Patents

Process for the preparation of acrylic acid and methacrylic acid from corresponding aldehydes

Info

Publication number
CA1065340A
CA1065340A CA246,949A CA246949A CA1065340A CA 1065340 A CA1065340 A CA 1065340A CA 246949 A CA246949 A CA 246949A CA 1065340 A CA1065340 A CA 1065340A
Authority
CA
Canada
Prior art keywords
catalyst
acrylic acid
methacrylic acid
antimony
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA246,949A
Other languages
English (en)
French (fr)
Inventor
James R. Rege
Robert K. Grasselli
James F. White
Dev D. Suresh
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/562,709 external-priority patent/US4070397A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Application granted granted Critical
Publication of CA1065340A publication Critical patent/CA1065340A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/30—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6527—Tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B01J23/68—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/683—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten
    • B01J23/687—Silver or gold with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with chromium, molybdenum or tungsten with tungsten
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA246,949A 1975-03-27 1976-03-02 Process for the preparation of acrylic acid and methacrylic acid from corresponding aldehydes Expired CA1065340A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/562,709 US4070397A (en) 1973-10-11 1975-03-27 Process for the preparation of methacrylic acid from the corresponding aldehyde

Publications (1)

Publication Number Publication Date
CA1065340A true CA1065340A (en) 1979-10-30

Family

ID=24247437

Family Applications (1)

Application Number Title Priority Date Filing Date
CA246,949A Expired CA1065340A (en) 1975-03-27 1976-03-02 Process for the preparation of acrylic acid and methacrylic acid from corresponding aldehydes

Country Status (19)

Country Link
JP (1) JPS51115416A (enrdf_load_stackoverflow)
AT (1) AT352094B (enrdf_load_stackoverflow)
BE (1) BE839047A (enrdf_load_stackoverflow)
BR (1) BR7601868A (enrdf_load_stackoverflow)
CA (1) CA1065340A (enrdf_load_stackoverflow)
CH (1) CH615900A5 (enrdf_load_stackoverflow)
CS (1) CS199275B2 (enrdf_load_stackoverflow)
DD (1) DD124473A5 (enrdf_load_stackoverflow)
DE (1) DE2610358A1 (enrdf_load_stackoverflow)
EG (1) EG12802A (enrdf_load_stackoverflow)
ES (1) ES446289A1 (enrdf_load_stackoverflow)
FR (1) FR2305424A1 (enrdf_load_stackoverflow)
GB (1) GB1534348A (enrdf_load_stackoverflow)
IN (1) IN144956B (enrdf_load_stackoverflow)
IT (1) IT1056925B (enrdf_load_stackoverflow)
NL (1) NL7603226A (enrdf_load_stackoverflow)
NO (1) NO761056L (enrdf_load_stackoverflow)
PT (1) PT64910B (enrdf_load_stackoverflow)
RO (1) RO68993A (enrdf_load_stackoverflow)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS52138499A (en) * 1976-05-17 1977-11-18 Mitsubishi Chem Ind Ltd Production of heteropolyacid
JPS5331615A (en) * 1976-09-06 1978-03-25 Nippon Kayaku Co Ltd Production of methacrylic acid and catalyst used thereof
EP0005769B1 (en) * 1978-05-31 1982-04-21 Nippon Kayaku Kabushiki Kaisha A process for producing methacrolein and methacrylic acid
US4212767A (en) * 1978-10-17 1980-07-15 Air Products And Chemicals, Inc. Method of preparing an oxidation catalyst containing a molybdate anion
DD148728A5 (de) * 1978-12-13 1981-06-10 Nippon Kayaku Kk Verfahren zur herstellung eines katalysators mit heteropolysaeurestruktur
JPS57130548A (en) * 1981-02-05 1982-08-13 Mitsubishi Chem Ind Ltd Catalyst composition
DE3308625A1 (de) * 1983-03-11 1984-09-13 Basf Ag, 6700 Ludwigshafen Verfahren und katalysator zur herstellung von methacrylsaeure

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1289710A (fr) * 1961-04-15 1962-04-06 Bayer Ag Procédé de préparation d'acides carboxyliques non saturés en alpha, bêta
US3925464A (en) * 1971-12-14 1975-12-09 Asahi Glass Co Ltd Process for preparing unsaturated carboxylic acids from the corresponding unsaturated aldehydes
US4077912A (en) * 1972-10-12 1978-03-07 Standard Oil Company Catalysts useful for exothermic reactions
CH569926A5 (enrdf_load_stackoverflow) * 1973-06-15 1975-11-28 Bartolomeis Spa Forni Ed Impia
US3875220A (en) * 1973-10-11 1975-04-01 Standard Oil Co Ohio Process for the preparation of methacrylic acid from methacrolein

Also Published As

Publication number Publication date
RO68993A (ro) 1980-12-30
DE2610358A1 (de) 1976-10-07
BE839047A (fr) 1976-06-16
DD124473A5 (enrdf_load_stackoverflow) 1977-02-23
IT1056925B (it) 1982-02-20
JPS51115416A (en) 1976-10-12
BR7601868A (pt) 1976-09-28
NL7603226A (nl) 1976-09-29
PT64910B (en) 1977-08-18
ATA195776A (de) 1979-02-15
CS199275B2 (en) 1980-07-31
ES446289A1 (es) 1977-06-16
EG12802A (en) 1979-09-30
CH615900A5 (en) 1980-02-29
GB1534348A (en) 1978-12-06
IN144956B (enrdf_load_stackoverflow) 1978-08-05
AT352094B (de) 1979-08-27
FR2305424A1 (fr) 1976-10-22
PT64910A (en) 1976-04-01
NO761056L (enrdf_load_stackoverflow) 1976-09-28
FR2305424B1 (enrdf_load_stackoverflow) 1979-09-07

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