CA1054672A - Secondary battery or cell using sulphur and an alkali metal as reactants - Google Patents
Secondary battery or cell using sulphur and an alkali metal as reactantsInfo
- Publication number
- CA1054672A CA1054672A CA252235A CA252235A CA1054672A CA 1054672 A CA1054672 A CA 1054672A CA 252235 A CA252235 A CA 252235A CA 252235 A CA252235 A CA 252235A CA 1054672 A CA1054672 A CA 1054672A
- Authority
- CA
- Canada
- Prior art keywords
- reactant
- cathodic
- metals
- cell
- anodic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000376 reactant Substances 0.000 title claims abstract description 68
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229910052783 alkali metal Inorganic materials 0.000 title claims abstract description 23
- 150000001340 alkali metals Chemical class 0.000 title claims abstract description 23
- 239000005864 Sulphur Substances 0.000 title abstract 2
- 229910052751 metal Inorganic materials 0.000 claims abstract description 63
- 239000002184 metal Substances 0.000 claims abstract description 63
- 150000002739 metals Chemical class 0.000 claims abstract description 33
- 238000010349 cathodic reaction Methods 0.000 claims abstract description 25
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 24
- 239000011593 sulfur Substances 0.000 claims abstract description 24
- 239000000203 mixture Substances 0.000 claims abstract description 23
- 150000003839 salts Chemical class 0.000 claims abstract description 23
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000004020 conductor Substances 0.000 claims abstract description 17
- 230000004888 barrier function Effects 0.000 claims abstract description 16
- 230000006872 improvement Effects 0.000 claims abstract description 16
- 239000005077 polysulfide Substances 0.000 claims abstract description 15
- 229920001021 polysulfide Polymers 0.000 claims abstract description 15
- 150000008117 polysulfides Polymers 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 10
- 238000012546 transfer Methods 0.000 claims abstract description 9
- 229920006395 saturated elastomer Polymers 0.000 claims abstract description 8
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 4
- 239000000956 alloy Substances 0.000 claims abstract description 4
- 239000000654 additive Substances 0.000 claims description 17
- 239000011734 sodium Substances 0.000 claims description 13
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 230000000996 additive effect Effects 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 150000001768 cations Chemical class 0.000 claims description 7
- 150000004767 nitrides Chemical class 0.000 claims description 4
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 150000001247 metal acetylides Chemical class 0.000 claims description 3
- 150000002823 nitrates Chemical class 0.000 claims description 3
- 150000003568 thioethers Chemical class 0.000 claims description 3
- 230000007704 transition Effects 0.000 claims description 3
- 229910052787 antimony Inorganic materials 0.000 claims description 2
- 150000004820 halides Chemical class 0.000 claims description 2
- 150000004679 hydroxides Chemical class 0.000 claims description 2
- 150000002826 nitrites Chemical class 0.000 claims description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 2
- 150000003567 thiocyanates Chemical class 0.000 claims description 2
- 230000000737 periodic effect Effects 0.000 claims 2
- QQHJESKHUUVSIC-UHFFFAOYSA-N antimony lead Chemical compound [Sb].[Pb] QQHJESKHUUVSIC-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 18
- 229910002804 graphite Inorganic materials 0.000 description 15
- 239000010439 graphite Substances 0.000 description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000003792 electrolyte Substances 0.000 description 10
- 239000000919 ceramic Substances 0.000 description 9
- 239000000463 material Substances 0.000 description 9
- 239000011521 glass Substances 0.000 description 8
- 150000002500 ions Chemical class 0.000 description 8
- 150000002736 metal compounds Chemical class 0.000 description 8
- 239000007784 solid electrolyte Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- RZVAJINKPMORJF-UHFFFAOYSA-N Acetaminophen Chemical compound CC(=O)NC1=CC=C(O)C=C1 RZVAJINKPMORJF-UHFFFAOYSA-N 0.000 description 4
- 239000011244 liquid electrolyte Substances 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 239000005297 pyrex Substances 0.000 description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 229910052810 boron oxide Inorganic materials 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 230000003247 decreasing effect Effects 0.000 description 3
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910001948 sodium oxide Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KEAYESYHFKHZAL-UHFFFAOYSA-N Sodium Chemical compound [Na] KEAYESYHFKHZAL-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- -1 e.g. Substances 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 229910000873 Beta-alumina solid electrolyte Inorganic materials 0.000 description 1
- 241000905957 Channa melasoma Species 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- 241000282326 Felis catus Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 241000534944 Thia Species 0.000 description 1
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 238000010420 art technique Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000005816 glass manufacturing process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- BALXUFOVQVENIU-KXNXZCPBSA-N pseudoephedrine hydrochloride Chemical compound [H+].[Cl-].CN[C@@H](C)[C@@H](O)C1=CC=CC=C1 BALXUFOVQVENIU-KXNXZCPBSA-N 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052716 thallium Inorganic materials 0.000 description 1
- BKVIYDNLLOSFOA-UHFFFAOYSA-N thallium Chemical compound [Tl] BKVIYDNLLOSFOA-UHFFFAOYSA-N 0.000 description 1
- 210000005239 tubule Anatomy 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
- H01M10/39—Accumulators not provided for in groups H01M10/05-H01M10/34 working at high temperature
- H01M10/3909—Sodium-sulfur cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/605,943 US4002806A (en) | 1975-08-20 | 1975-08-20 | Secondary battery or cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1054672A true CA1054672A (en) | 1979-05-15 |
Family
ID=24425856
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA252235A Expired CA1054672A (en) | 1975-08-20 | 1976-05-11 | Secondary battery or cell using sulphur and an alkali metal as reactants |
Country Status (18)
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298447A (en) * | 1980-03-07 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Cathode and cell for lowering hydrogen overvoltage in a chlor-akali cell |
| US4337127A (en) * | 1980-03-07 | 1982-06-29 | E. I. Du Pont De Nemours And Company | Method for making a cathode, and method for lowering hydrogen overvoltage in a chlor-alkali cell |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1528672A (en) * | 1976-02-18 | 1978-10-18 | Chloride Silent Power Ltd | Sodium sulphur cells |
| DE2653966C3 (de) * | 1976-11-27 | 1980-09-25 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische Speicherzelle oder -Batterie auf Basis von Alkalimetall und Schwefel |
| US4117208A (en) * | 1977-09-15 | 1978-09-26 | Ford Motor Company | Electrical conversion device with ceramic electrode |
| FR2466107A1 (fr) * | 1979-08-08 | 1981-03-27 | Comp Generale Electricite | Generateur electrochimique sodium-soufre |
| SE8008330L (sv) * | 1979-12-05 | 1981-06-06 | Western Electric Co | Elektrolytisk cell |
| DE3507697A1 (de) * | 1985-03-05 | 1986-09-11 | Brown, Boveri & Cie Ag, 6800 Mannheim | Elektrochemische speicherzelle |
| JPS62221229A (ja) * | 1986-03-22 | 1987-09-29 | Matsushita Electric Works Ltd | 無線デ−タ伝送システム |
| US4767684A (en) * | 1987-08-19 | 1988-08-30 | Ford Motor Company | Method of chargeability improvement and reduced corrosion for sodium-sulfur cells |
| US5578393A (en) * | 1995-03-10 | 1996-11-26 | United States Advanced Battery Consortium | Thermal contact sheet for high temperature batteries |
| DE19706510C1 (de) * | 1997-02-19 | 1998-06-10 | Peter Prof Dr Ing Schiesl | Elektrodenbaugruppe für ein Korrosionsmeßsystem zum Feststellen von Korrosion von in einem Bauteil aus einem ionenleitendem Baustoff, insbesondere Beton, eingebettetem Metall |
| JP5055734B2 (ja) * | 2005-09-27 | 2012-10-24 | カシオ計算機株式会社 | 燃料電池用燃料改質器 |
| CN111416091A (zh) * | 2020-03-13 | 2020-07-14 | 上海电力大学 | 一种双金属氮化物改性隔膜及其制备方法和应用 |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3413150A (en) * | 1966-09-28 | 1968-11-26 | Ford Motor Co | Battery having a molten alkali metal anode and a molten sulfur cathode |
| US3468709A (en) * | 1967-04-03 | 1969-09-23 | Ford Motor Co | Secondary battery employing an electronically - insulative,cationically-conductive solid electrolyte with anodic and cathodic feeder means |
| US3554806A (en) * | 1968-12-30 | 1971-01-12 | Nasa | Heat activated cell with alkali anode and alkali salt electrolyte |
| US3672995A (en) * | 1969-05-08 | 1972-06-27 | Dow Chemical Co | Solid electrolyte for electrical cells |
| FR2119117A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1970-12-21 | 1972-08-04 | Comp Generale Electricite | |
| US3811943A (en) * | 1971-02-16 | 1974-05-21 | Ford Motor Co | Mass transportation electrode for energy conversion device |
| JPS4827534A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1971-08-18 | 1973-04-11 | ||
| US3718505A (en) * | 1971-12-07 | 1973-02-27 | Esb Inc | Sodium-sulfur battery having aluminum sulfide or aluminum polysulfide in the electrolyte |
| JPS5037371A (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1973-08-06 | 1975-04-08 |
-
1975
- 1975-08-20 US US05/605,943 patent/US4002806A/en not_active Expired - Lifetime
-
1976
- 1976-05-11 CA CA252235A patent/CA1054672A/en not_active Expired
- 1976-05-12 ZA ZA762824A patent/ZA762824B/xx unknown
- 1976-05-18 IT IT49542/76A patent/IT1074469B/it active
- 1976-05-18 NL NL7605309A patent/NL7605309A/xx active Search and Examination
- 1976-05-19 GB GB20646/76A patent/GB1555132A/en not_active Expired
- 1976-05-19 PT PT65112A patent/PT65112B/pt unknown
- 1976-05-19 NO NO761696A patent/NO148656C/no unknown
- 1976-05-19 DE DE2622333A patent/DE2622333C3/de not_active Expired
- 1976-05-19 JP JP51056780A patent/JPS5225228A/ja active Pending
- 1976-05-19 BR BR7603146A patent/BR7603146A/pt unknown
- 1976-05-19 ES ES448081A patent/ES448081A1/es not_active Expired
- 1976-05-19 FR FR7615052A patent/FR2321775A1/fr active Granted
- 1976-05-19 AR AR263323A patent/AR213092A1/es active
- 1976-05-19 DK DK220876A patent/DK220876A/da unknown
- 1976-05-19 SE SE7605666A patent/SE424680B/xx not_active IP Right Cessation
- 1976-05-20 CH CH635976A patent/CH631578A5/de not_active IP Right Cessation
- 1976-05-20 BE BE167181A patent/BE842026A/xx not_active IP Right Cessation
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4298447A (en) * | 1980-03-07 | 1981-11-03 | E. I. Du Pont De Nemours And Company | Cathode and cell for lowering hydrogen overvoltage in a chlor-akali cell |
| US4337127A (en) * | 1980-03-07 | 1982-06-29 | E. I. Du Pont De Nemours And Company | Method for making a cathode, and method for lowering hydrogen overvoltage in a chlor-alkali cell |
Also Published As
| Publication number | Publication date |
|---|---|
| NL7605309A (nl) | 1977-02-22 |
| ES448081A1 (es) | 1977-11-01 |
| DE2622333C3 (de) | 1982-01-14 |
| NO148656B (no) | 1983-08-08 |
| NO761696L (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1977-02-22 |
| US4002806A (en) | 1977-01-11 |
| BE842026A (fr) | 1976-09-16 |
| DE2622333A1 (de) | 1977-03-03 |
| SE7605666L (sv) | 1977-02-21 |
| AU1398976A (en) | 1977-11-24 |
| IT1074469B (it) | 1985-04-20 |
| AR213092A1 (es) | 1978-12-15 |
| JPS5225228A (en) | 1977-02-25 |
| BR7603146A (pt) | 1977-05-24 |
| SE424680B (sv) | 1982-08-02 |
| DK220876A (da) | 1977-02-21 |
| PT65112B (en) | 1977-10-10 |
| FR2321775B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-05-04 |
| DE2622333B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-02-12 |
| FR2321775A1 (fr) | 1977-03-18 |
| NO148656C (no) | 1983-11-16 |
| CH631578A5 (de) | 1982-08-13 |
| ZA762824B (en) | 1977-04-27 |
| PT65112A (en) | 1976-06-01 |
| GB1555132A (en) | 1979-11-07 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA1060090A (en) | Alkali metal/sulfur battery or cell with single phase sulfur electrode | |
| CA1054672A (en) | Secondary battery or cell using sulphur and an alkali metal as reactants | |
| US4069372A (en) | Electric accumulator with a solid electrolyte | |
| CA1073040A (en) | Secondary battery or cell with composite electrode | |
| CA1089531A (en) | Secondary battery or cell with polysulfide wettable electrode | |
| CA1116231A (en) | Electrochemical device with solid separator and solid electrolyte | |
| CA1134318A (en) | Disposing molten electrolyte adjacent aluminium oxide separator in electrochemical metal recovery from salt | |
| USRE30353E (en) | Electric accumulator with a solid electrolyte | |
| EP0092575B1 (en) | Improved electrochemical cell utilizing molten alkali metal electrode-reactant | |
| EP3284134B1 (en) | Sodium-aluminum battery with sodium ion conductive ceramic separator | |
| US4975343A (en) | Electrochemical cell | |
| CA1054670A (en) | Sodium sulfur battery or cell with improved ampere-hour capacity | |
| CA1073525A (en) | Secondary battery or cell with dual electrode | |
| CA1054673A (en) | Sodium sulfur battery or cell with external storage | |
| US4064325A (en) | Electric storage batteries | |
| US3730771A (en) | Electric accumulator | |
| CA1042066A (en) | Sodium-aluminum halide, sulfur battery | |
| JPS60501732A (ja) | 結晶固体リチウムカチオン導電性電解質 | |
| CA1073041A (en) | Secondary battery with separate charge and discharge zones | |
| CA1042982A (en) | Process for recharging secondary batteries | |
| CA1108229A (en) | Metal clad ceramic conductor with multiple open channels | |
| KR20160060693A (ko) | 중온 나트륨-금속 할라이드 배터리 | |
| US4357399A (en) | Alkali metal-sulfur cells | |
| US4609596A (en) | Electrochemical devices utilizing molten alkali metal electrode-reactant | |
| US3976504A (en) | Sealed lithium-iodine cell |