CA1042179A - Production of zirconium carbonate - Google Patents
Production of zirconium carbonateInfo
- Publication number
- CA1042179A CA1042179A CA222,315A CA222315A CA1042179A CA 1042179 A CA1042179 A CA 1042179A CA 222315 A CA222315 A CA 222315A CA 1042179 A CA1042179 A CA 1042179A
- Authority
- CA
- Canada
- Prior art keywords
- carbonate
- zirconium
- solution
- basic
- salt
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XJUNLJFOHNHSAR-UHFFFAOYSA-J zirconium(4+);dicarbonate Chemical compound [Zr+4].[O-]C([O-])=O.[O-]C([O-])=O XJUNLJFOHNHSAR-UHFFFAOYSA-J 0.000 title claims abstract description 41
- 238000004519 manufacturing process Methods 0.000 title abstract description 10
- 239000000243 solution Substances 0.000 claims abstract description 50
- 238000000034 method Methods 0.000 claims abstract description 29
- 230000008569 process Effects 0.000 claims abstract description 24
- 150000003754 zirconium Chemical class 0.000 claims abstract description 18
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims abstract description 15
- 239000007864 aqueous solution Substances 0.000 claims abstract description 11
- 239000001099 ammonium carbonate Substances 0.000 claims abstract description 10
- ZXAUZSQITFJWPS-UHFFFAOYSA-J zirconium(4+);disulfate Chemical compound [Zr+4].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZXAUZSQITFJWPS-UHFFFAOYSA-J 0.000 claims abstract description 8
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000012501 ammonium carbonate Nutrition 0.000 claims abstract description 7
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 34
- 239000002244 precipitate Substances 0.000 claims description 13
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical group [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 12
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 6
- RDFNWUYMULDLCS-UHFFFAOYSA-L hydron;oxozirconium(2+);disulfate Chemical compound [H+].[H+].[Zr+2]=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RDFNWUYMULDLCS-UHFFFAOYSA-L 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 229910000288 alkali metal carbonate Inorganic materials 0.000 claims description 3
- 150000008041 alkali metal carbonates Chemical class 0.000 claims description 3
- 238000005406 washing Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 239000011541 reaction mixture Substances 0.000 claims 5
- -1 alkali metal bicarbonate Chemical class 0.000 claims 2
- 239000012266 salt solution Substances 0.000 claims 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims 2
- 238000001556 precipitation Methods 0.000 claims 1
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical group Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 claims 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 16
- 229910052726 zirconium Inorganic materials 0.000 abstract description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical compound OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 abstract description 7
- 239000002253 acid Substances 0.000 abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 5
- 150000001340 alkali metals Chemical class 0.000 abstract description 4
- 150000007524 organic acids Chemical class 0.000 abstract description 4
- 235000012538 ammonium bicarbonate Nutrition 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 235000005985 organic acids Nutrition 0.000 abstract description 2
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 17
- 239000000047 product Substances 0.000 description 12
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 10
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000000543 intermediate Substances 0.000 description 10
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 6
- IPCAPQRVQMIMAN-UHFFFAOYSA-L zirconyl chloride Chemical compound Cl[Zr](Cl)=O IPCAPQRVQMIMAN-UHFFFAOYSA-L 0.000 description 5
- 238000005755 formation reaction Methods 0.000 description 4
- 239000012535 impurity Substances 0.000 description 4
- 229940001593 sodium carbonate Drugs 0.000 description 4
- 235000017550 sodium carbonate Nutrition 0.000 description 4
- 230000001052 transient effect Effects 0.000 description 4
- 238000000354 decomposition reaction Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- QRTRRDMHGTZPBF-UHFFFAOYSA-L oxygen(2-);zirconium(4+);sulfate Chemical compound [O-2].[Zr+4].[O-]S([O-])(=O)=O QRTRRDMHGTZPBF-UHFFFAOYSA-L 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 229940023462 paste product Drugs 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000002844 continuous effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000012527 feed solution Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000011877 solvent mixture Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical group [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G25/00—Compounds of zirconium
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB11840/74A GB1495267A (en) | 1974-03-18 | 1974-03-18 | Process for the production of basic zirconium carbonate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1042179A true CA1042179A (en) | 1978-11-14 |
Family
ID=9993663
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA222,315A Expired CA1042179A (en) | 1974-03-18 | 1975-03-17 | Production of zirconium carbonate |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS50127897A (https=) |
| CA (1) | CA1042179A (https=) |
| DE (1) | DE2510743A1 (https=) |
| FR (1) | FR2264780B1 (https=) |
| GB (1) | GB1495267A (https=) |
| ZA (1) | ZA751656B (https=) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4256718A (en) * | 1978-03-20 | 1981-03-17 | Organon Teknika Corporation | Sodium zirconium carbonate compound and the method of its preparation |
| JPS54155199A (en) * | 1978-03-20 | 1979-12-06 | Organon Teknika Bv | Sodium zirconium carbonate compound and its manufacture |
| US4360507A (en) * | 1979-01-24 | 1982-11-23 | Organon Teknika Corporation | Sodium zirconium carbonate compound and the method of its preparation |
| DE3143921C2 (de) * | 1981-11-05 | 1984-06-28 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von basischem Zirkoniumkarbonat |
| NZ215774A (en) * | 1985-05-02 | 1988-08-30 | Ici Australia Ltd | Purification of zirconium compounds |
| AU607920B2 (en) * | 1986-06-17 | 1991-03-21 | Commonwealth Scientific And Industrial Research Organisation | Preparation of hydrolysed zirconium salt precursors and high purity zirconia |
| US6627164B1 (en) * | 2000-11-28 | 2003-09-30 | Renal Solutions, Inc. | Sodium zirconium carbonate and zirconium basic carbonate and methods of making the same |
| CN115340126B (zh) * | 2022-09-15 | 2024-04-12 | 包头稀土研究院 | 稀土锆酸盐颗粒及其制备方法 |
-
1974
- 1974-03-18 GB GB11840/74A patent/GB1495267A/en not_active Expired
-
1975
- 1975-03-12 DE DE19752510743 patent/DE2510743A1/de not_active Withdrawn
- 1975-03-17 CA CA222,315A patent/CA1042179A/en not_active Expired
- 1975-03-17 FR FR7508229A patent/FR2264780B1/fr not_active Expired
- 1975-03-18 ZA ZA00751656A patent/ZA751656B/xx unknown
- 1975-03-18 JP JP50031916A patent/JPS50127897A/ja active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| FR2264780A1 (https=) | 1975-10-17 |
| DE2510743A1 (de) | 1975-09-25 |
| GB1495267A (en) | 1977-12-14 |
| JPS50127897A (https=) | 1975-10-08 |
| ZA751656B (en) | 1976-03-31 |
| FR2264780B1 (https=) | 1981-01-16 |
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