CA1025475A - Racemization of optically active 2,2-dimethyl-3-(1'-alkenyl)-cyclopropane-1-carboxylic acids - Google Patents

Racemization of optically active 2,2-dimethyl-3-(1'-alkenyl)-cyclopropane-1-carboxylic acids

Info

Publication number
CA1025475A
CA1025475A CA213,346A CA213346A CA1025475A CA 1025475 A CA1025475 A CA 1025475A CA 213346 A CA213346 A CA 213346A CA 1025475 A CA1025475 A CA 1025475A
Authority
CA
Canada
Prior art keywords
racemization
cyclopropane
alkenyl
dimethyl
carboxylic acids
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CA213,346A
Other languages
English (en)
French (fr)
Inventor
Tsuneyuki Nagase
Gohu Suzukamo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of CA1025475A publication Critical patent/CA1025475A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CA213,346A 1973-11-12 1974-11-08 Racemization of optically active 2,2-dimethyl-3-(1'-alkenyl)-cyclopropane-1-carboxylic acids Expired CA1025475A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP12750273A JPS5337858B2 (de) 1973-11-12 1973-11-12

Publications (1)

Publication Number Publication Date
CA1025475A true CA1025475A (en) 1978-01-31

Family

ID=14961548

Family Applications (1)

Application Number Title Priority Date Filing Date
CA213,346A Expired CA1025475A (en) 1973-11-12 1974-11-08 Racemization of optically active 2,2-dimethyl-3-(1'-alkenyl)-cyclopropane-1-carboxylic acids

Country Status (11)

Country Link
US (1) US3989750A (de)
JP (1) JPS5337858B2 (de)
BE (1) BE822046A (de)
CA (1) CA1025475A (de)
CH (1) CH615411A5 (de)
DK (1) DK586374A (de)
FR (1) FR2250728B1 (de)
GB (1) GB1448316A (de)
IT (1) IT1024802B (de)
NL (1) NL7414766A (de)
SU (1) SU722479A3 (de)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4206140A (en) * 1966-08-26 1980-06-03 Roussel Uclaf Novel cyclopropanecarboxylic acids and esters
JPS52144651A (en) * 1976-05-24 1977-12-02 Sumitomo Chem Co Ltd Racemization of optical active 2,2-dimethyl-3-(1-alkenyl)-cyclopropane-1-carboxylic acid
JPS57163341A (en) * 1981-03-30 1982-10-07 Sumitomo Chem Co Ltd Preparation of racemized cyclopropanecarboxylic acid derivative
US4473703A (en) * 1981-03-30 1984-09-25 Sumitomo Chemical Company, Limited Method of epimerization of alkyl chrysanthemate
JPS5869831A (ja) * 1981-10-22 1983-04-26 Sumitomo Chem Co Ltd （＋）−トランス第一菊酸の製造法
DE3565397D1 (en) * 1984-02-22 1988-11-10 Sumitomo Chemical Co Method for racemization of chrysanthemic acid or its ester
DE3578164D1 (de) * 1984-06-15 1990-07-19 Sumitomo Chemical Co Verfahren zur razemisierung von chrysanthemumsaeure oder ihrer ester.
JPS62198643A (ja) * 1986-02-27 1987-09-02 Sumitomo Chem Co Ltd ラセミ第一菊酸類の製造法
HU202171B (en) * 1986-09-04 1991-02-28 Sumitomo Chemical Co Process for racemization of chrysanthemic acid and its esters, as well as for conversion of the racemic mixture
EP0282221B1 (de) * 1987-03-09 1992-01-15 Sumitomo Chemical Company, Limited Verfahren zur Racemisierung von optisch aktiver Chrysanthemumsäure oder ihren Estern
HU203513B (en) * 1987-04-28 1991-08-28 Sumitomo Chemical Co Process for racemizing and trans-isomerizing optically active chrisanthemic acid derivatives
JPH0688933B2 (ja) * 1987-07-17 1994-11-09 住友化学工業株式会社 光学活性第一菊酸類のラセミ化法
EP0342843B1 (de) * 1988-05-19 1993-03-03 Sumitomo Chemical Company, Limited Verfahren zur Herstellung von racemischen Cyclopropancarbonsäurehalogeniden
US5840958A (en) * 1996-10-17 1998-11-24 Fmc Corporation 1S to 1R Epimerizations of pyrethroid intermediates
CN114539045B (zh) * 2020-11-18 2023-07-21 中国科学院大连化学物理研究所 一种反式左旋菊酸的消旋化方法

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2038019A5 (de) * 1969-03-22 1970-12-31 Sumitomo Chemical Co

Also Published As

Publication number Publication date
FR2250728A1 (de) 1975-06-06
BE822046A (fr) 1975-05-12
JPS5337858B2 (de) 1978-10-12
JPS5077346A (de) 1975-06-24
CH615411A5 (de) 1980-01-31
DE2453639B2 (de) 1977-06-23
DK586374A (de) 1975-07-14
GB1448316A (en) 1976-09-02
US3989750A (en) 1976-11-02
FR2250728B1 (de) 1976-12-31
IT1024802B (it) 1978-07-20
SU722479A3 (ru) 1980-03-15
DE2453639A1 (de) 1975-05-15
NL7414766A (nl) 1975-05-14

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