BRPI1007572B1 - composição de geopolímero modificado e método para preparar um substrato de polímero orgânico revestido com geopolímero - Google Patents
composição de geopolímero modificado e método para preparar um substrato de polímero orgânico revestido com geopolímero Download PDFInfo
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- BRPI1007572B1 BRPI1007572B1 BRPI1007572A BRPI1007572A BRPI1007572B1 BR PI1007572 B1 BRPI1007572 B1 BR PI1007572B1 BR PI1007572 A BRPI1007572 A BR PI1007572A BR PI1007572 A BRPI1007572 A BR PI1007572A BR PI1007572 B1 BRPI1007572 B1 BR PI1007572B1
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- Prior art keywords
- organic polymer
- geopolymer
- latex
- composition
- modified
- Prior art date
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- 229920000620 organic polymer Polymers 0.000 title claims abstract description 191
- 229920000876 geopolymer Polymers 0.000 title claims abstract description 186
- 239000000203 mixture Substances 0.000 title claims abstract description 169
- 239000000758 substrate Substances 0.000 title claims abstract description 74
- 238000000034 method Methods 0.000 title claims abstract description 34
- 229920000126 latex Polymers 0.000 claims description 137
- 239000004816 latex Substances 0.000 claims description 137
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 117
- 229910001868 water Inorganic materials 0.000 claims description 117
- 239000002243 precursor Substances 0.000 claims description 51
- 238000001035 drying Methods 0.000 claims description 37
- 239000011248 coating agent Substances 0.000 claims description 35
- 238000000576 coating method Methods 0.000 claims description 35
- 239000002174 Styrene-butadiene Substances 0.000 claims description 17
- 230000001464 adherent effect Effects 0.000 claims description 17
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 17
- 239000011115 styrene butadiene Substances 0.000 claims description 17
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 17
- 239000003381 stabilizer Substances 0.000 claims description 16
- 230000009477 glass transition Effects 0.000 claims description 12
- -1 polypropylene Polymers 0.000 claims description 12
- 229920000642 polymer Polymers 0.000 claims description 10
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- 150000001768 cations Chemical class 0.000 claims description 9
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- 238000004519 manufacturing process Methods 0.000 abstract description 4
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- 238000012360 testing method Methods 0.000 description 26
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- 230000000052 comparative effect Effects 0.000 description 19
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 12
- 238000002360 preparation method Methods 0.000 description 12
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 12
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- 239000000126 substance Substances 0.000 description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 6
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical class [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
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- 244000043261 Hevea brasiliensis Species 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
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- 238000005054 agglomeration Methods 0.000 description 2
- 230000002776 aggregation Effects 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical group [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 2
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- 238000005266 casting Methods 0.000 description 2
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- 150000001991 dicarboxylic acids Chemical class 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
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- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
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- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
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- 229910018516 Al—O Inorganic materials 0.000 description 1
- DHMQDGOQFOQNFH-UHFFFAOYSA-M Aminoacetate Chemical compound NCC([O-])=O DHMQDGOQFOQNFH-UHFFFAOYSA-M 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 206010053567 Coagulopathies Diseases 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 229910002656 O–Si–O Inorganic materials 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 229910052581 Si3N4 Inorganic materials 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- PNFQZZCDNRLKRJ-UHFFFAOYSA-M [O-2].[OH-].O.O.[Al+3] Chemical class [O-2].[OH-].O.O.[Al+3] PNFQZZCDNRLKRJ-UHFFFAOYSA-M 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
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- 125000000217 alkyl group Chemical group 0.000 description 1
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- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 239000000292 calcium oxide Substances 0.000 description 1
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 1
- 150000001720 carbohydrates Chemical class 0.000 description 1
- 235000014633 carbohydrates Nutrition 0.000 description 1
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- 238000000113 differential scanning calorimetry Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
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- 229910052731 fluorine Inorganic materials 0.000 description 1
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- 235000011852 gelatine desserts Nutrition 0.000 description 1
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- 239000005020 polyethylene terephthalate Substances 0.000 description 1
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- 235000019353 potassium silicate Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
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- 150000003839 salts Chemical class 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/10—Coating or impregnating
- C04B20/1055—Coating or impregnating with inorganic materials
- C04B20/1074—Silicates, e.g. glass
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/006—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing mineral polymers, e.g. geopolymers of the Davidovits type
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/10—Production of cement, e.g. improving or optimising the production methods; Cement grinding
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31931—Polyene monomer-containing
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31938—Polymer of monoethylenically unsaturated hydrocarbon
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Geology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Wood Science & Technology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Paints Or Removers (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Prostheses (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Adhesives Or Adhesive Processes (AREA)
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| US18187009P | 2009-05-28 | 2009-05-28 | |
| PCT/US2010/035383 WO2010138351A2 (en) | 2009-05-28 | 2010-05-19 | Modified geopolymer compositions, processes and uses |
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| BRPI1007572A2 BRPI1007572A2 (pt) | 2016-07-26 |
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| JP6243400B2 (ja) * | 2012-03-30 | 2017-12-06 | ダウ グローバル テクノロジーズ エルエルシー | 耐火性複合構造体 |
| MX2014011837A (es) * | 2012-03-30 | 2014-12-10 | Dow Global Technologies Llc | Composiciones de aerogel precursor de geopolimero. |
| US20140194328A1 (en) * | 2013-01-07 | 2014-07-10 | Vince Alessi | Thermoset ceramic compositions and a method of preparation therefor |
| BR102014018660A2 (pt) * | 2013-08-15 | 2016-03-22 | Dow Global Technologies Llc | composição de dois componentes para formar um geopolímero, e, método para preparar a composição de geopolímero |
| US20150114640A1 (en) * | 2013-10-30 | 2015-04-30 | Baker Hughes Incorporated | Proppants with improved strength |
| ITUB20152158A1 (it) * | 2015-07-14 | 2017-01-14 | Itt Italia Srl | Materiale di attrito, in particolare per la fabbricazione di una pastiglia freno, e metodi di preparazione associati |
| KR101749281B1 (ko) * | 2015-11-13 | 2017-06-21 | 강범형 | 난연 입자 및 그 제조방법, 그리고 이를 이용한 난연 스티로폼 |
| CN105385126A (zh) * | 2015-12-17 | 2016-03-09 | 梅庆波 | 一种聚乳酸/多孔地聚物复合材料的制备方法 |
| CN109641798A (zh) * | 2016-07-20 | 2019-04-16 | 西索斯公司 | 改性地质聚合物和改性地质聚合物复合材料及其生产工艺 |
| WO2018015490A1 (en) | 2016-07-20 | 2018-01-25 | Synthos S.A. | Process for the production of geopolymer or geopolymer composite |
| BR112019000679A2 (pt) | 2016-07-20 | 2019-04-24 | Synthos S.A. | uso do aditivo de geopolímero em combinação com retardante de chama não bromado em espumas de polímero |
| CN110577410A (zh) * | 2019-06-18 | 2019-12-17 | 佛山市涂无忧建材有限公司 | 一种水泥基防水填充材料 |
| KR20210143513A (ko) | 2020-05-20 | 2021-11-29 | 현대자동차주식회사 | 3d 프린팅용 지오폴리머 조성물 및 이를 이용한 3d 프린팅 방법 |
| KR20210143511A (ko) | 2020-05-20 | 2021-11-29 | 현대자동차주식회사 | 3d 프린팅용 지오폴리머 조성물 및 이를 이용한 3d 프린팅 방법 |
| KR20220087207A (ko) | 2020-12-17 | 2022-06-24 | 현대자동차주식회사 | 3d 프린팅용 지오폴리머 조성물 |
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| US4110293A (en) * | 1977-04-22 | 1978-08-29 | The Goodyear Tire & Rubber Company | Process for stabilizing latex and stable latices produced thereby |
| FR2464227B1 (fr) * | 1979-09-04 | 1985-09-20 | Cordi Coord Dev Innovation | Polymere mineral |
| JPS61247654A (ja) * | 1986-04-25 | 1986-11-04 | 桜田 康之 | 珪酸ナトリウム系接着剤 |
| JP3018341B2 (ja) * | 1988-02-23 | 2000-03-13 | ザ ヘラ コーポレーション | ジオポリマー複合材料 |
| US5244726A (en) * | 1988-02-23 | 1993-09-14 | The Hera Corporation | Advanced geopolymer composites |
| JP3300010B2 (ja) * | 1992-03-04 | 2002-07-08 | 太平洋セメント株式会社 | モデル材料 |
| FR2731697A1 (fr) * | 1995-03-15 | 1996-09-20 | Michel Davidovics | Matrice geopolymerique alumino-silicate alcaline, pour materiaux composites a renforts fibreux, et procede d'obtention |
| JPH10139523A (ja) | 1996-10-31 | 1998-05-26 | Sekisui Chem Co Ltd | 硬化性無機質組成物 |
| US5925449A (en) * | 1996-12-26 | 1999-07-20 | Davidovits; Joseph | Method for bonding fiber reinforcement on concrete and steel structures and resultant products |
| GB9816269D0 (en) * | 1998-07-27 | 1998-09-23 | Pilkington Plc | Plastic glazings |
| US7094285B2 (en) * | 2000-09-20 | 2006-08-22 | Goodrich Corporation | Inorganic matrix compositions, composites incorporating the matrix, and process of making the same |
| US6992027B1 (en) * | 2000-11-13 | 2006-01-31 | Hexcel Composites Ltd | Composite panel with fire resistant face sheets |
| JP2003119386A (ja) * | 2001-08-08 | 2003-04-23 | Sekisui Chem Co Ltd | 無機ポリマー組成物、その製造方法、それを用いた無機コーティング剤、及び塗装品。 |
| FR2839970B1 (fr) * | 2002-05-27 | 2005-07-22 | Joseph Davidovits | Ciment geopolymerique a base de poly(sialate-disiloxo) et procede d'obtention |
| DE10341171B4 (de) * | 2003-02-27 | 2007-09-20 | Bauhaus Universität Weimar | Verwendung eines Materials zur Beschichtung von Bauelementen in chemisch aggressiver Umgebung |
| NZ547507A (en) * | 2003-12-02 | 2010-03-26 | Commw Scient Ind Res Org | Hybrid organic / inorganic polymers, and compositions thereof useful for producing flame retardant coatings for timber |
| US7745363B2 (en) * | 2005-05-09 | 2010-06-29 | Corning Incorporated | Geopolymer composites and structures formed therefrom |
| US8574358B2 (en) * | 2005-12-06 | 2013-11-05 | James Hardie Technology Limited | Geopolymeric particles, fibers, shaped articles and methods of manufacture |
| WO2007109862A1 (en) | 2006-03-29 | 2007-10-04 | Zeobond Research Pty Ltd | Dry mix cement composition, methods and systems involving same |
| US7776433B2 (en) * | 2006-11-30 | 2010-08-17 | General Electric Company | Thermal oxidative barrier coatings for organic matrix composite substrates and coated articles |
| ATE516335T1 (de) | 2006-08-07 | 2011-07-15 | Prad Res & Dev Nv | Geopolymerzusammensetzung und seine anwendung für kohlenstoffdioxydlagerung |
| CN101045832A (zh) * | 2007-03-22 | 2007-10-03 | 袁景华 | 地聚涂料组合物及其制备方法 |
| EP2071003A1 (en) * | 2007-12-12 | 2009-06-17 | Services Pétroliers Schlumberger | Squeeze composition for restoring isolation |
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- 2010-05-19 JP JP2012513129A patent/JP5681172B2/ja active Active
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Also Published As
| Publication number | Publication date |
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| EP2438027A2 (en) | 2012-04-11 |
| KR101771404B1 (ko) | 2017-08-25 |
| ES2741552T3 (es) | 2020-02-11 |
| CN102741191A (zh) | 2012-10-17 |
| WO2010138351A3 (en) | 2011-09-01 |
| CA2763509A1 (en) | 2010-12-02 |
| PL2438027T3 (pl) | 2019-12-31 |
| US8901230B2 (en) | 2014-12-02 |
| US20130136938A1 (en) | 2013-05-30 |
| KR20120030464A (ko) | 2012-03-28 |
| BRPI1007572A2 (pt) | 2016-07-26 |
| WO2010138351A2 (en) | 2010-12-02 |
| JP2012528066A (ja) | 2012-11-12 |
| CN102741191B (zh) | 2014-09-17 |
| JP5681172B2 (ja) | 2015-03-04 |
| US20100304165A1 (en) | 2010-12-02 |
| US8815348B2 (en) | 2014-08-26 |
| EP2438027B1 (en) | 2019-06-26 |
| CA2763509C (en) | 2018-01-16 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 19/05/2010, OBSERVADAS AS CONDICOES LEGAIS. |