BRPI0821792B1 - Processo para a polimerização de fase de gás de olefinas - Google Patents
Processo para a polimerização de fase de gás de olefinas Download PDFInfo
- Publication number
- BRPI0821792B1 BRPI0821792B1 BRPI0821792-0A BRPI0821792A BRPI0821792B1 BR PI0821792 B1 BRPI0821792 B1 BR PI0821792B1 BR PI0821792 A BRPI0821792 A BR PI0821792A BR PI0821792 B1 BRPI0821792 B1 BR PI0821792B1
- Authority
- BR
- Brazil
- Prior art keywords
- tube
- polymer
- polymerization
- gas
- flow rate
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 42
- 230000008569 process Effects 0.000 title claims abstract description 40
- 238000012685 gas phase polymerization Methods 0.000 title claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 103
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 94
- 239000000203 mixture Substances 0.000 claims abstract description 68
- 239000007788 liquid Substances 0.000 claims abstract description 59
- 239000002245 particle Substances 0.000 claims abstract description 31
- 238000005243 fluidization Methods 0.000 claims abstract description 11
- 239000004711 α-olefin Substances 0.000 claims abstract description 5
- 239000007789 gas Substances 0.000 claims description 80
- 230000004888 barrier function Effects 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 17
- 239000000178 monomer Substances 0.000 claims description 16
- 230000001174 ascending effect Effects 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 10
- 229910052739 hydrogen Inorganic materials 0.000 claims description 9
- 239000001257 hydrogen Substances 0.000 claims description 9
- 150000001336 alkenes Chemical class 0.000 claims description 8
- 239000004215 Carbon black (E152) Substances 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 6
- 238000009833 condensation Methods 0.000 claims description 4
- 230000005494 condensation Effects 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 3
- 230000036961 partial effect Effects 0.000 claims description 2
- 239000008246 gaseous mixture Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 description 26
- -1 hydrocarbon radical Chemical group 0.000 description 22
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 21
- 239000012071 phase Substances 0.000 description 20
- 230000002902 bimodal effect Effects 0.000 description 15
- 239000007787 solid Substances 0.000 description 13
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 12
- 239000004743 Polypropylene Substances 0.000 description 10
- 229920001155 polypropylene Polymers 0.000 description 10
- 239000010936 titanium Substances 0.000 description 10
- 238000005516 engineering process Methods 0.000 description 9
- 239000001294 propane Substances 0.000 description 9
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 7
- 229920001577 copolymer Polymers 0.000 description 7
- 238000009826 distribution Methods 0.000 description 7
- 229920000098 polyolefin Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 7
- 238000011144 upstream manufacturing Methods 0.000 description 7
- 229920005604 random copolymer Polymers 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 6
- 229910052719 titanium Inorganic materials 0.000 description 6
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 239000005977 Ethylene Substances 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000003085 diluting agent Substances 0.000 description 5
- 229910052736 halogen Inorganic materials 0.000 description 5
- 239000003701 inert diluent Substances 0.000 description 5
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 125000001424 substituent group Chemical group 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000002367 halogens Chemical group 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 239000002685 polymerization catalyst Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 125000005234 alkyl aluminium group Chemical group 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 230000003197 catalytic effect Effects 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 230000005484 gravity Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 230000000737 periodic effect Effects 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 239000011949 solid catalyst Substances 0.000 description 3
- 150000003609 titanium compounds Chemical class 0.000 description 3
- 150000003623 transition metal compounds Chemical class 0.000 description 3
- 229910052720 vanadium Inorganic materials 0.000 description 3
- 150000003682 vanadium compounds Chemical class 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 238000010924 continuous production Methods 0.000 description 2
- 230000002596 correlated effect Effects 0.000 description 2
- 150000001923 cyclic compounds Chemical class 0.000 description 2
- 150000004292 cyclic ethers Chemical class 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 229910052735 hafnium Inorganic materials 0.000 description 2
- GJRQTCIYDGXPES-UHFFFAOYSA-N isobutyl acetate Chemical compound CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropyl acetate Chemical compound CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- 230000000670 limiting effect Effects 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- TZIHFWKZFHZASV-UHFFFAOYSA-N methyl formate Chemical compound COC=O TZIHFWKZFHZASV-UHFFFAOYSA-N 0.000 description 2
- 150000002902 organometallic compounds Chemical class 0.000 description 2
- UUEVFMOUBSLVJW-UHFFFAOYSA-N oxo-[[1-[2-[2-[2-[4-(oxoazaniumylmethylidene)pyridin-1-yl]ethoxy]ethoxy]ethyl]pyridin-4-ylidene]methyl]azanium;dibromide Chemical compound [Br-].[Br-].C1=CC(=C[NH+]=O)C=CN1CCOCCOCCN1C=CC(=C[NH+]=O)C=C1 UUEVFMOUBSLVJW-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 230000000630 rising effect Effects 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- BWLBGMIXKSTLSX-UHFFFAOYSA-N 2-hydroxyisobutyric acid Chemical compound CC(C)(O)C(O)=O BWLBGMIXKSTLSX-UHFFFAOYSA-N 0.000 description 1
- GNVZOPJOZQRTBU-UHFFFAOYSA-N CC([V])=O Chemical compound CC([V])=O GNVZOPJOZQRTBU-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910010062 TiCl3 Inorganic materials 0.000 description 1
- 229910003074 TiCl4 Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical group [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 150000001242 acetic acid derivatives Chemical class 0.000 description 1
- KXKVLQRXCPHEJC-UHFFFAOYSA-N acetic acid trimethyl ester Natural products COC(C)=O KXKVLQRXCPHEJC-UHFFFAOYSA-N 0.000 description 1
- 150000001255 actinides Chemical group 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000005054 agglomeration Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000005840 aryl radicals Chemical class 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001845 chromium compounds Chemical class 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- 230000001010 compromised effect Effects 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000000058 cyclopentadienyl group Chemical group C1(=CC=CC1)* 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- WGFNXLQURMLAGC-UHFFFAOYSA-N diethyl 2,3-di(propan-2-yl)butanedioate Chemical compound CCOC(=O)C(C(C)C)C(C(C)C)C(=O)OCC WGFNXLQURMLAGC-UHFFFAOYSA-N 0.000 description 1
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical group [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical group [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 230000010355 oscillation Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- JTJMJGYZQZDUJJ-UHFFFAOYSA-N phencyclidine Chemical group C1CCCCN1C1(C=2C=CC=CC=2)CCCCC1 JTJMJGYZQZDUJJ-UHFFFAOYSA-N 0.000 description 1
- 239000011990 phillips catalyst Substances 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000002829 reductive effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003890 succinate salts Chemical class 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 238000009827 uniform distribution Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/2415—Tubular reactors
- B01J19/2435—Loop-type reactors
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
- B01J2219/00166—Controlling or regulating processes controlling the flow controlling the residence time inside the reactor vessel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00171—Controlling or regulating processes controlling the density
- B01J2219/00173—Physical density
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F110/04—Monomers containing three or four carbon atoms
- C08F110/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP07150383.3 | 2007-12-21 | ||
| EP07150383 | 2007-12-21 | ||
| PCT/EP2008/067772 WO2009080660A1 (en) | 2007-12-21 | 2008-12-17 | Process for the gas-phase polymerization of olefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0821792A2 BRPI0821792A2 (pt) | 2016-06-07 |
| BRPI0821792B1 true BRPI0821792B1 (pt) | 2019-05-07 |
Family
ID=40639896
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0821792-0A BRPI0821792B1 (pt) | 2007-12-21 | 2008-12-17 | Processo para a polimerização de fase de gás de olefinas |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8198383B2 (https=) |
| EP (1) | EP2225022B1 (https=) |
| JP (1) | JP5695423B2 (https=) |
| KR (1) | KR101582792B1 (https=) |
| CN (2) | CN105461835A (https=) |
| AT (1) | ATE511919T1 (https=) |
| BR (1) | BRPI0821792B1 (https=) |
| RU (1) | RU2466787C2 (https=) |
| WO (1) | WO2009080660A1 (https=) |
Families Citing this family (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9073027B2 (en) | 2010-09-09 | 2015-07-07 | Basell Poliolefine Italia S.R.L. | Process and apparatus for the gas-phase polymerization of olefins |
| EP2495038B1 (en) * | 2011-03-02 | 2020-09-02 | Borealis AG | A process for the production polymers |
| PT2495037T (pt) | 2011-03-02 | 2020-09-15 | Borealis Ag | Montagem de reator de alto rendimento para a polimerização de olefinas |
| EP2890490B1 (en) | 2012-08-29 | 2020-05-06 | Borealis AG | Reactor assembly and method for polymerization of olefins |
| EP2711379A1 (en) * | 2012-09-21 | 2014-03-26 | Basell Poliolefine Italia S.r.l. | Process for the gas-phase polymerization of olefins |
| CN103575333B (zh) * | 2013-11-06 | 2015-10-07 | 中沙（天津）石化有限公司 | 多区循环反应器中颗粒结块的检测方法 |
| SG11201903559YA (en) * | 2016-11-10 | 2019-05-30 | Basell Polyolefine Gmbh | Olefin polymerization process in a gas-phase reactor comprising a riser unit and a downcomer |
| WO2018091261A1 (en) * | 2016-11-17 | 2018-05-24 | Basell Polyolefine Gmbh | Polyethylene composition having high swell ratio |
| KR102109307B1 (ko) * | 2016-11-24 | 2020-05-12 | 바젤 폴리올레핀 게엠베하 | 높은 스웰비 및 충격 저항을 갖는 블로우 성형용 폴리에틸렌 조성물 |
| ES2834034T3 (es) * | 2016-11-24 | 2021-06-16 | Basell Polyolefine Gmbh | Composición de polietileno para moldeado por soplado que tiene alta resistencia a la rotura por tensión |
| KR102043838B1 (ko) * | 2016-12-22 | 2019-11-13 | 바젤 폴리올레핀 게엠베하 | 멀티존 순환 반응기의 기동방법 |
| RU2733752C9 (ru) * | 2017-03-27 | 2020-11-24 | Базелл Полиолефин Италия С.Р.Л. | Способ газофазной полимеризации олефинов |
| FI3601383T3 (fi) * | 2017-03-27 | 2024-05-30 | Basell Poliolefine Italia Srl | Propyleenietyleenisatunnaiskopolymeeri |
| EP3450011B1 (en) | 2017-08-29 | 2020-11-25 | Sumitomo Chemical Company, Limited | Method for producing polyolefin and polyolefin production system |
| EP3450008B1 (en) | 2017-08-29 | 2022-07-13 | Sumitomo Chemical Company, Limited | Method for producing polyolefin and polyolefin production system |
| AR112897A1 (es) | 2017-09-21 | 2019-12-26 | Basell Poliolefine Italia Srl | Proceso para la polimerización de olefinas en fase gaseosa |
| EP3524343A1 (en) | 2018-02-07 | 2019-08-14 | Basell Polyolefine GmbH | Process for polymerizing olefins in the gas-phase |
| JP7314275B2 (ja) | 2018-12-18 | 2023-07-25 | バーゼル・ポリオレフィン・ゲーエムベーハー | エチレンポリマーの気相製造プロセス |
| US10781273B2 (en) | 2018-12-27 | 2020-09-22 | Chevron Phillips Chemical Company Lp | Multiple reactor and multiple zone polyolefin polymerization |
| EP3834923A1 (en) * | 2019-12-11 | 2021-06-16 | Basell Polyolefine GmbH | Apparatus and process for the gas-phase polymerization |
| CN111875726B (zh) * | 2020-08-12 | 2023-02-24 | 上海赛科石油化工有限责任公司 | 一种聚丙烯生产操作控制方法 |
| WO2022122749A1 (en) | 2020-12-09 | 2022-06-16 | Basell Polyolefine Gmbh | Reactor for a gas-phase olefin polymerization |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2097520T3 (es) * | 1992-05-29 | 1997-04-01 | Amoco Corp | Polimerizacion de alfa-olefinas. |
| IT1275573B (it) * | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
| CN1137142C (zh) * | 1998-07-08 | 2004-02-04 | 蒙特尔技术有限公司 | 气相聚合的方法和设备 |
| KR100681597B1 (ko) * | 2000-07-24 | 2007-02-09 | 후루까와덴끼고오교 가부시끼가이샤 | 칩안테나 및 그 제조방법 |
| KR100457154B1 (ko) * | 2001-03-15 | 2004-11-12 | 김순희 | 폭약용기 및 이를 이용한 정밀 화약장전방법 |
| ATE393787T1 (de) * | 2003-03-05 | 2008-05-15 | Basell Poliolefine Srl | Steuerungsverfahren bei einem polymerisationsprozess |
| WO2005019280A1 (en) | 2003-08-20 | 2005-03-03 | Basell Poliolefine Italia S.R.L. | Process and apparatus for the polymerization of ethylene |
| DE602005013495D1 (de) * | 2004-03-03 | 2009-05-07 | Basell Poliolefine Srl | Verfahren zur steuerung des polymerflusses in einem polymerisationsprozess |
| US7687588B2 (en) * | 2005-05-13 | 2010-03-30 | Basel Poliolefine Italia S.R.L. | Process for the gas-phase polymerization of olefins |
| BRPI0621073B1 (pt) * | 2005-12-23 | 2017-12-05 | Basell Poliolefine Italia S.R.L. | Gas phase process and apparatus for polymerization of olefins |
| BRPI0722416A2 (pt) * | 2006-05-26 | 2012-12-25 | Ineos Mfg Belgium Nv | processo de polimerizaÇço de fase de pasta |
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- 2008-12-17 AT AT08863810T patent/ATE511919T1/de not_active IP Right Cessation
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| KR20100098412A (ko) | 2010-09-06 |
| CN105461835A (zh) | 2016-04-06 |
| JP5695423B2 (ja) | 2015-04-08 |
| JP2011508800A (ja) | 2011-03-17 |
| EP2225022B1 (en) | 2011-06-08 |
| US8198383B2 (en) | 2012-06-12 |
| RU2010130498A (ru) | 2012-01-27 |
| BRPI0821792A2 (pt) | 2016-06-07 |
| WO2009080660A1 (en) | 2009-07-02 |
| US20100317811A1 (en) | 2010-12-16 |
| RU2466787C2 (ru) | 2012-11-20 |
| EP2225022A1 (en) | 2010-09-08 |
| CN101952030A (zh) | 2011-01-19 |
| KR101582792B1 (ko) | 2016-01-07 |
| ATE511919T1 (de) | 2011-06-15 |
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