BRPI0816740B8 - processo de preparo de acroleína, ácido acrílico e acrilonitrila a partir de glicerol e uso de um sistema catalítico - Google Patents

processo de preparo de acroleína, ácido acrílico e acrilonitrila a partir de glicerol e uso de um sistema catalítico

Info

Publication number
BRPI0816740B8
BRPI0816740B8 BRPI0816740A BRPI0816740A BRPI0816740B8 BR PI0816740 B8 BRPI0816740 B8 BR PI0816740B8 BR PI0816740 A BRPI0816740 A BR PI0816740A BR PI0816740 A BRPI0816740 A BR PI0816740A BR PI0816740 B8 BRPI0816740 B8 BR PI0816740B8
Authority
BR
Brazil
Prior art keywords
acrylonitrile
glycerol
acrylic acid
catalytic system
preparing acrolein
Prior art date
Application number
BRPI0816740A
Other languages
English (en)
Inventor
Dubois Jean-Luc
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0816740A2 publication Critical patent/BRPI0816740A2/pt
Publication of BRPI0816740B1 publication Critical patent/BRPI0816740B1/pt
Publication of BRPI0816740B8 publication Critical patent/BRPI0816740B8/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/24—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons
    • C07C253/26—Preparation of carboxylic acid nitriles by ammoxidation of hydrocarbons or substituted hydrocarbons containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B61/00—Other general methods
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C255/00—Carboxylic acid nitriles
    • C07C255/01—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms
    • C07C255/06—Carboxylic acid nitriles having cyano groups bound to acyclic carbon atoms of an acyclic and unsaturated carbon skeleton
    • C07C255/07—Mononitriles
    • C07C255/08—Acrylonitrile; Methacrylonitrile
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02—Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03—Monocarboxylic acids
    • C07C57/04—Acrylic acid; Methacrylic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
BRPI0816740A 2007-09-20 2008-09-11 processo de preparo de acroleína, ácido acrílico e acrilonitrila a partir de glicerol e uso de um sistema catalítico BRPI0816740B8 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR07.57708 2007-09-20
FR0757708A FR2921361B1 (fr) 2007-09-20 2007-09-20 Procede de fabrication d'acroleine a partir de glycerol
PCT/FR2008/051620 WO2009044081A1 (fr) 2007-09-20 2008-09-11 Procede de fabrication d'acroleine a partir de glycerol

Publications (3)

Publication Number Publication Date
BRPI0816740A2 BRPI0816740A2 (pt) 2015-03-17
BRPI0816740B1 BRPI0816740B1 (pt) 2017-06-13
BRPI0816740B8 true BRPI0816740B8 (pt) 2017-11-07

Family

ID=39382067

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0816740A BRPI0816740B8 (pt) 2007-09-20 2008-09-11 processo de preparo de acroleína, ácido acrílico e acrilonitrila a partir de glicerol e uso de um sistema catalítico

Country Status (9)

Country Link
US (1) US8829246B2 (pt)
EP (1) EP2188241B1 (pt)
JP (1) JP5808912B2 (pt)
KR (1) KR101541934B1 (pt)
CN (1) CN101801902B (pt)
BR (1) BRPI0816740B8 (pt)
FR (1) FR2921361B1 (pt)
MY (1) MY158736A (pt)
WO (1) WO2009044081A1 (pt)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2179981A1 (en) * 2008-10-24 2010-04-28 Arkema France Process for manufacturing acrolein from glycerol
JP5684818B2 (ja) * 2009-10-15 2015-03-18 日本化薬株式会社 グリセリンの脱水反応によって不飽和アルデヒドおよび／または不飽和カルボン酸を製造するのに使用する触媒の製造方法と、この方法で得られる触媒
FR2953829B1 (fr) 2009-12-14 2011-12-09 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
FR2953830B1 (fr) 2009-12-14 2012-01-20 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
MX2012007074A (es) * 2009-12-18 2012-08-31 Battelle Memorial Institute Sistemas de deshidratacion de compuestos multihidricos, composiciones cataliticas y metodos.
JP5721238B2 (ja) * 2010-03-01 2015-05-20 国立大学法人北海道大学 低品位グリセリンからのアリルアルコールとプロピレンの製造方法、及びそのための触媒
WO2012101471A1 (en) 2011-01-28 2012-08-02 Arkema France Improved process for manufacturing acrolein/acrylic acid
JP5881620B2 (ja) * 2011-01-28 2016-03-09 日本化薬株式会社 飽和アルデヒドを選択的に低減させる触媒と、その製造方法
FR2975922B1 (fr) 2011-06-06 2013-05-31 Arkema France Reacteur a plaques avec injection in situ
FR2977809B1 (fr) 2011-07-12 2016-01-08 Arkema France Regeneration de catalyseur en continu dans un reacteur a lit fluidise
WO2013008279A1 (en) * 2011-07-14 2013-01-17 Nippon Kayaku Kabushiki Kaisha Process for preparing catalyst used in production of acrolein and/or acrylic acid and process for preparing acrolein and/or acrylic acid by dehydration reaction of glycerin
WO2013017904A1 (en) 2011-07-29 2013-02-07 Arkema France Improved process of dehydration reactions
WO2013018752A2 (ja) * 2011-07-29 2013-02-07 日本化薬株式会社 グリセリンの脱水反応によるアクロレイン及びアクリル酸の製造用触媒と、その製造法
FR2989684B1 (fr) 2012-04-18 2014-10-31 Arkema France Procede de fabrication d'acroleine et/ou d'acide acrylique a partir de glycerol
WO2015168683A1 (en) 2014-05-02 2015-11-05 University Of Tennessee Research Foundation Novel glycerol dehydration methods and products thereof
KR102052708B1 (ko) * 2015-12-22 2019-12-09 주식회사 엘지화학 글리세린 탈수 반응용 촉매, 이의 제조 방법 및 상기 촉매를 이용한 아크롤레인의 제조 방법
KR102044428B1 (ko) 2015-12-23 2019-12-02 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
WO2017111391A1 (ko) * 2015-12-23 2017-06-29 주식회사 엘지화학 글리세린으로부터 아크릴산의 제조방법
CN109305909B (zh) * 2017-07-28 2021-08-03 中国石油化工股份有限公司 甘油一步法合成丙烯酸的方法
CN109304162B (zh) * 2017-07-28 2021-06-22 中国石油化工股份有限公司 甘油生产丙烯酸的方法
CN109304163B (zh) * 2017-07-28 2021-06-18 中国石油化工股份有限公司 甘油生产丙烯酸的催化剂

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FR695931A (fr) * 1929-06-15 1930-12-23 Schering Kahlbaum Ag Procédé de fabrication d'acroléine
GB616260A (en) 1943-12-30 1949-01-19 Koppers Co Inc Improvements in and relating to catalysts for polymerisation and condensation of hydrocarbons
US2558520A (en) * 1948-01-29 1951-06-26 Us Ind Chemicals Inc Production of acrolein from glycerol
US3094551A (en) 1959-09-04 1963-06-18 Union Carbide Corp Process for preparing cyano-esters
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CA676881A (en) * 1961-05-31 1963-12-24 Shell Oil Company Production of lower aliphatic nitriles
US3173962A (en) * 1962-06-20 1965-03-16 Goodrich Co B F Oxychlorination of lower alkanes
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US3716545A (en) * 1970-01-16 1973-02-13 Phillips Petroleum Co Oxidative conversion including dehydrogenation
US3725494A (en) * 1971-08-02 1973-04-03 Phillips Petroleum Co Two-stage dehydrogenation process for producing diolefins
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US4473707A (en) * 1981-01-16 1984-09-25 The Standard Oil Company Oxidative dehydrogenation of carboxylic acids with mixed metal phosphorus oxide coated catalysts
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US4366088A (en) * 1981-01-26 1982-12-28 Ashland Oil, Inc. Support for a phosphate-containing catalyst
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US4381411A (en) * 1981-06-22 1983-04-26 The Standard Oil Company Production of methacrolein from isobutyraldehyde utilizing promoted iron phosphorus oxide catalysts
GB2195264B (en) 1986-09-09 1990-10-24 Norsolor Sa A process for regenerating a catalyst and its application to an oxidative dehydrogenation process
FR2657792B1 (fr) 1990-02-07 1992-05-15 Norsolor Sa Systeme catalytique et son application a l'oxydeshydrogenation d'acides carboxyliques satures.
DE4238493C1 (de) * 1992-11-14 1994-04-21 Degussa Verfahren zur Herstellung von Acrolein und dessen Verwendung
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JPH08295687A (ja) 1995-04-28 1996-11-12 Ube Ind Ltd 無水シトラコン酸の製造法
JPH10287610A (ja) 1997-04-08 1998-10-27 Ube Ind Ltd メチルグリオキサールの製造方法
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DE10019381B4 (de) 2000-04-19 2006-05-18 Daun, Klaus-Dieter, Dipl.-Ing. Reaktor für die katalytische Umsetzung von Reaktionsmedien, insbesondere von gasförmigen Reaktionsmedien
JP3989226B2 (ja) 2001-11-12 2007-10-10 三菱レイヨン株式会社 ピルビン酸の製造方法
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FR2884818B1 (fr) * 2005-04-25 2007-07-13 Arkema Sa Procede de preparation d'acide acrylique a partir de glycerol
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JP4041512B2 (ja) * 2006-03-30 2008-01-30 株式会社日本触媒 グリセリン脱水用触媒、グリセリン脱水用触媒の製造方法、アクロレインの製造方法、およびアクロレイン誘導体の製造方法
FR2909999B1 (fr) 2006-12-19 2009-04-03 Arkema France Procede de preparation d'acide acrylique a partir de glycerol

Also Published As

Publication number Publication date
JP5808912B2 (ja) 2015-11-10
EP2188241A1 (fr) 2010-05-26
US8829246B2 (en) 2014-09-09
WO2009044081A1 (fr) 2009-04-09
BRPI0816740B1 (pt) 2017-06-13
CN101801902A (zh) 2010-08-11
CN101801902B (zh) 2015-01-28
MY158736A (en) 2016-11-15
EP2188241B1 (fr) 2016-07-20
JP2010539224A (ja) 2010-12-16
FR2921361B1 (fr) 2012-10-12
KR20100059891A (ko) 2010-06-04
US20100204502A1 (en) 2010-08-12
KR101541934B1 (ko) 2015-08-04
BRPI0816740A2 (pt) 2015-03-17
FR2921361A1 (fr) 2009-03-27

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Legal Events

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B07A Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted
B16C Correction of notification of the grant

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/09/2008, OBSERVADAS AS CONDICOES LEGAIS. (CO) REFERENTE A PUBLICACAO NA RPI 2423 DE 13/06/2017 QUANTO AO ENDERECO DO TITULAR.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2531 DE 09-07-2019 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.