BRPI0815466A2 - Conversão de uma etapa de lignina sólida para produtos líquidos - Google Patents

Conversão de uma etapa de lignina sólida para produtos líquidos

Info

Publication number
BRPI0815466A2
BRPI0815466A2 BRPI0815466-0A BRPI0815466A BRPI0815466A2 BR PI0815466 A2 BRPI0815466 A2 BR PI0815466A2 BR PI0815466 A BRPI0815466 A BR PI0815466A BR PI0815466 A2 BRPI0815466 A2 BR PI0815466A2
Authority
BR
Brazil
Prior art keywords
converting
liquid products
solid lignin
lignin step
liquid product
Prior art date
Application number
BRPI0815466-0A
Other languages
English (en)
Inventor
Mike Kleinert
Tatjana Tanja Barth
Original Assignee
Bergen Teknologioverforing As
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=38969398&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BRPI0815466(A2) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Bergen Teknologioverforing As filed Critical Bergen Teknologioverforing As
Publication of BRPI0815466A2 publication Critical patent/BRPI0815466A2/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/004—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by obtaining phenols from plant material or from animal material
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C37/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring
    • C07C37/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms
    • C07C37/52—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms by splitting polyaromatic compounds, e.g. polyphenolalkanes
    • C07C37/54—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom of a six-membered aromatic ring by reactions decreasing the number of carbon atoms by splitting polyaromatic compounds, e.g. polyphenolalkanes by hydrolysis of lignin or sulfite waste liquor
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C39/00—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring
    • C07C39/02—Compounds having at least one hydroxy or O-metal group bound to a carbon atom of a six-membered aromatic ring monocyclic with no unsaturation outside the aromatic ring
    • C07C39/06—Alkylated phenols
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4025—Yield
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Botany (AREA)
  • Wood Science & Technology (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Compounds Of Unknown Constitution (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Catalysts (AREA)
BRPI0815466-0A 2007-08-14 2008-08-13 Conversão de uma etapa de lignina sólida para produtos líquidos BRPI0815466A2 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07015978A EP2025735A1 (en) 2007-08-14 2007-08-14 One-step conversion of solid lignin to liquid products
PCT/EP2008/006672 WO2009021733A2 (en) 2007-08-14 2008-08-13 One-step conversion of solid lignin to liquid products

Publications (1)

Publication Number Publication Date
BRPI0815466A2 true BRPI0815466A2 (pt) 2015-08-25

Family

ID=38969398

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0815466-0A BRPI0815466A2 (pt) 2007-08-14 2008-08-13 Conversão de uma etapa de lignina sólida para produtos líquidos

Country Status (10)

Country Link
US (1) US8673027B2 (pt)
EP (2) EP2025735A1 (pt)
CN (1) CN101932670B (pt)
AT (1) ATE554153T1 (pt)
BR (1) BRPI0815466A2 (pt)
CA (1) CA2696268C (pt)
DK (1) DK2190949T3 (pt)
PL (1) PL2190949T3 (pt)
RU (1) RU2476581C2 (pt)
WO (1) WO2009021733A2 (pt)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ592089A (en) * 2008-10-01 2013-03-28 Licella Pty Ltd Bio-oil production utilising supercritical aqueous alcohol
CN102459425B (zh) 2009-05-28 2015-06-17 丽格诺创新有限公司 来自硬木原料的天然木素衍生物
US9051244B2 (en) 2010-01-27 2015-06-09 Council Of Scientific And Industrial Research Depolymerization of lignin using solid acid catalysts
CA2798268C (en) 2010-02-15 2019-02-12 Lignol Innovations Ltd. Carbon fibre compositions comprising lignin derivatives
CN102959033B (zh) 2010-02-15 2016-10-12 丽格诺新创有限公司 含有木素衍生物的粘合剂组合物
ES2862178T3 (es) 2010-06-26 2021-10-07 Virdia Llc Métodos de producción de mezclas de azúcares
IL206678A0 (en) 2010-06-28 2010-12-30 Hcl Cleantech Ltd A method for the production of fermentable sugars
IL207329A0 (en) 2010-08-01 2010-12-30 Robert Jansen A method for refining a recycle extractant and for processing a lignocellulosic material and for the production of a carbohydrate composition
AU2011354496B2 (en) * 2011-01-05 2014-07-03 Ignite Resources Pty Ltd Processing of organic matter
US9120712B2 (en) 2011-02-01 2015-09-01 University Of Maine System Board Of Trustees Process for improving the energy density of feedstocks using formate salts
EP2688959A4 (en) 2011-03-24 2014-09-10 Lignol Innovations Ltd COMPOSITIONS OF LIGNOCELLULOSE BIOMASS AND ORGANIC SOLVENT
US9512495B2 (en) 2011-04-07 2016-12-06 Virdia, Inc. Lignocellulose conversion processes and products
BR112013031803A2 (pt) * 2011-06-10 2017-01-31 Steeper Energy Aps processo e aparelho para a produção de hidrocarbonetos líquidos
US9080109B2 (en) * 2011-12-14 2015-07-14 Uop Llc Methods for deoxygenating biomass-derived pyrolysis oil
IN2014MN01731A (pt) * 2012-02-24 2015-07-03 Biochemtex Spa
CN103304821B (zh) * 2012-03-09 2016-01-20 东北林业大学 一种木质素的精制方法
UA116535C2 (uk) * 2012-03-30 2018-04-10 Рдінновейшн Апс Сполуки бензолполікарбонових кислот та їх застосування як лікарських засобів
RU2488445C1 (ru) * 2012-04-26 2013-07-27 Общество с ограниченной ответственностью "Целлокорм" Синтез многофункционального катализатора окислительного крекинга органического сырья и способ жидкофазного низкотемпературного окислительного крекинга органического сырья (варианты)
GB2517338B (en) 2012-05-03 2020-03-25 Virdia Inc A method for fractionating a liquid sample
CN103073395B (zh) * 2012-12-11 2015-04-08 浙江大学 微波强化木质素在供氢剂中连续降解制备小分子酚类化合物的工艺
CN105026525B (zh) 2013-01-25 2017-10-10 雷恩生物燃料公司 用于精炼的生物质材料的组合物
US9657146B2 (en) 2013-03-14 2017-05-23 Virdia, Inc. Methods for treating lignocellulosic materials
CN105377958B (zh) 2013-05-03 2019-01-01 威尔迪亚公司 用于处理木质纤维素材料的方法
WO2014179777A1 (en) 2013-05-03 2014-11-06 Virdia, Inc. Methods for preparing thermally stable lignin fractions
CN103274904B (zh) * 2013-06-08 2015-11-18 中国科学院过程工程研究所 一种微波辅助木质素定向转化苯酚的方法
CN103508871B (zh) * 2013-10-25 2015-06-17 东南大学 一种黑液木质素液相降解制取4-羟基-3-甲氧基苯基乙酮的方法
PL3083652T3 (pl) * 2013-12-16 2021-12-27 Ren Fuel K2B Ab Kompozycja zawierająca estry ligniny i olejów lub kwasów tłuszczowych
KR20170005418A (ko) 2014-05-01 2017-01-13 렌매틱스, 인코포레이티드. 반응성 추출을 통한 리그닌-함유 잔류물로부터의 리그닌 업그레이드
EP3166954B1 (en) 2014-07-09 2019-03-27 Virdia, Inc. Methods for separating and refining lignin from black liquor and compositions thereof
EP2982733A1 (en) * 2014-08-05 2016-02-10 Linde Aktiengesellschaft Method of recovering oleagineous compounds from hydrothermally biomass
EP3245186A1 (en) 2015-01-16 2017-11-22 Nederlandse Organisatie voor toegepast- natuurwetenschappelijk onderzoek TNO Method to prepare phenolics from biomass
FI127675B (fi) * 2015-02-06 2018-11-30 Upm Kymmene Corp Menetelmä ja laitteisto liukoista hiilihydraattia sisältävän fraktion konsentraation lisäämiseksi, liukoista hiilihydraattia sisältävä fraktio, kiintoainefraktio ja niiden käyttö
CN106367095B (zh) * 2015-07-21 2019-03-08 中国石油化工股份有限公司 一种生物质共炼产物的加工方法
CN106350090B (zh) * 2015-07-21 2019-03-08 中国石油化工股份有限公司 一种生物质共炼产物的加工方法
SE543595C2 (en) * 2015-12-01 2021-04-06 Ren Fuel K2B Ab Depolymerized lignin in hydrocarbon oil
FR3061492B1 (fr) * 2017-01-03 2019-05-24 D.M.S Procede de production de carburant par craquage catalytique d'un materiau solide hydrocarbone et dispositif pour sa mise en œuvre
DK201870095A1 (en) * 2018-02-16 2019-09-24 Københavns Universitet A biofuel composition comprising lignin
FI130333B (en) 2021-12-23 2023-06-26 Upm Kymmene Corp Solvolysis method for combined feed

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3186923A (en) * 1961-06-12 1965-06-01 Buckeye Cellulose Corp Process for improving the low molecular weight yield in bark pyrolysis
US3976437A (en) * 1972-06-23 1976-08-24 Sun Ventures, Inc. Composition comprising a methyl phenol and an ether for gasoline fuels
AU518450B2 (en) * 1979-08-10 1981-10-01 Robert Jeno Hamor Improvements in or relating to the hydrolysis of cellulose
GB8511587D0 (en) 1985-05-08 1985-06-12 Shell Int Research Producing hydrocarbon-containing liquids
US4731491A (en) * 1986-01-22 1988-03-15 Uop Inc. Process for liquefaction of lignin
US5196069A (en) * 1991-07-05 1993-03-23 The United States Of America As Represented By The United States National Aeronautics And Space Administration Apparatus and method for cellulose processing using microwave pretreatment
FR2770543B1 (fr) * 1997-10-30 2000-05-05 Michel Delmas Procede de production de pate a papier, lignignes sucres et acide acetique par fractionnement de matiere vegetale lignocellulosique em milieu acide formique/acide acetique
US6143856A (en) * 1999-01-29 2000-11-07 Pyrovac Technologies Inc. Process for the production of phenolic-rich pyrolysis oils for use in making phenol-formaldehyde resole resins
CN1566289A (zh) 2003-07-03 2005-01-19 陕西科技大学 木素醇燃料制造工艺
PL2007945T3 (pl) * 2006-03-29 2011-06-30 Virginia Tech Intellectual Properties Inc Frakcjonowanie lignocelulozy oparte na rozpuszczalniku celulozy w umiarkowanych warunkach reakcji i z obiegiem odczynnika

Also Published As

Publication number Publication date
WO2009021733A3 (en) 2009-06-25
EP2025735A1 (en) 2009-02-18
CA2696268C (en) 2015-11-24
WO2009021733A2 (en) 2009-02-19
CN101932670A (zh) 2010-12-29
US20110173875A1 (en) 2011-07-21
CN101932670B (zh) 2014-04-02
EP2190949A2 (en) 2010-06-02
ATE554153T1 (de) 2012-05-15
DK2190949T3 (da) 2012-05-21
PL2190949T3 (pl) 2012-11-30
CA2696268A1 (en) 2009-02-19
EP2190949B1 (en) 2012-04-18
US8673027B2 (en) 2014-03-18
RU2010109383A (ru) 2011-09-20
RU2476581C2 (ru) 2013-02-27

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B08F Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette]

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B08K Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette]

Free format text: EM VIRTUDE DO ARQUIVAMENTO PUBLICADO NA RPI 2344 DE 08-12-2015 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDO O ARQUIVAMENTO DO PEDIDO DE PATENTE, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.