BRPI0716769A8 - Material compósito, processo de preparação de um material compósito, utilização de um material compósito e filtro de cigarro - Google Patents

Material compósito, processo de preparação de um material compósito, utilização de um material compósito e filtro de cigarro

Info

Publication number
BRPI0716769A8
BRPI0716769A8 BRPI0716769A BRPI0716769A BRPI0716769A8 BR PI0716769 A8 BRPI0716769 A8 BR PI0716769A8 BR PI0716769 A BRPI0716769 A BR PI0716769A BR PI0716769 A BRPI0716769 A BR PI0716769A BR PI0716769 A8 BRPI0716769 A8 BR PI0716769A8
Authority
BR
Brazil
Prior art keywords
composite material
preparing
cigarette filter
relates
liquid
Prior art date
Application number
BRPI0716769A
Other languages
English (en)
Inventor
Eberhardt Robert
Perin Eric
Original Assignee
Rhodia Operations
Solvay Acetow Gmbh
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Rhodia Operations, Solvay Acetow Gmbh filed Critical Rhodia Operations
Publication of BRPI0716769A2 publication Critical patent/BRPI0716769A2/pt
Publication of BRPI0716769A8 publication Critical patent/BRPI0716769A8/pt
Publication of BRPI0716769B1 publication Critical patent/BRPI0716769B1/pt

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/08Use of materials for tobacco smoke filters of organic materials as carrier or major constituent
    • A24D3/10Use of materials for tobacco smoke filters of organic materials as carrier or major constituent of cellulose or cellulose derivatives
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/163Carbon
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/06Use of materials for tobacco smoke filters
    • A24D3/16Use of materials for tobacco smoke filters of inorganic materials
    • A24D3/166Silicic acid or silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • B01J20/08Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04 comprising aluminium oxide or hydroxide; comprising bauxite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/103Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate comprising silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28002Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their physical properties
    • B01J20/28004Sorbent size or size distribution, e.g. particle size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28016Particle form
    • B01J20/28019Spherical, ellipsoidal or cylindrical
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/28026Particles within, immobilised, dispersed, entrapped in or on a matrix, e.g. a resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28014Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
    • B01J20/2803Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057Surface area, e.g. B.E.T specific surface area
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • B01J20/2808Pore diameter being less than 2 nm, i.e. micropores or nanopores
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28078Pore diameter
    • B01J20/28083Pore diameter being in the range 2-50 nm, i.e. mesopores

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Dispersion Chemistry (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Silicon Compounds (AREA)
  • Filtering Materials (AREA)
  • Catalysts (AREA)

Abstract

MATERIAL COMPÓSITO, PROCESSO DE PREPARAÇÃO DE UM MATERIAL COMPÓSITO, UTILIZAÇÃO DE UM MATERIAL COMPÓSITO E FILTRO DE CIGARRO. A invenção se refere a um material compósito de coesão elevada, formado de pelo menos um polímero e de pelo menos um composto escolhido dentre os óxidos minerais, os silico-aluminatos e o carvão ativo, o referido material compósito possuindo: um tamanho médio de partículas de pelo menos 100 µm, um volume poroso (V dl ), constituído pelos poros de diâmetro compreendidos entre 3,6 e 1000 nm, de pelo menos 0,2 cm3/g, uma coesão tal que sua taxa de partículas de tamanho inferior a 100 µm obtido após uma resistência de pressão de ar de 2 bars é inferior a 1,5%, de preferência igual a 0,0%, em volume. Ela se refere igualmente a um processo de preparação de material compósito. Ela se refere também a utilização deste material compósito como suporte de líquido, suporte de catalisador, aditivo ou para a filtragem líquida ou gasosa, em particular nos filtros de cigarros.
BRPI0716769-5A 2006-09-13 2007-09-11 Composite material, process for preparing a composite material, using a composite material and cigarette filter BRPI0716769B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0608000A FR2905628B1 (fr) 2006-09-13 2006-09-13 Materiau composite de cohesion elevee, procede de preparation et utilisations, notamment dans les filtres a cigarettes.
FR06/08000 2006-09-13
PCT/EP2007/059515 WO2008031816A2 (fr) 2006-09-13 2007-09-11 Materiau composite de cohesion elevee, procede de preparation et utilisations, notamment dans les filtres a cigarettes

Publications (3)

Publication Number Publication Date
BRPI0716769A2 BRPI0716769A2 (pt) 2013-09-17
BRPI0716769A8 true BRPI0716769A8 (pt) 2017-04-04
BRPI0716769B1 BRPI0716769B1 (pt) 2018-02-06

Family

ID=37712469

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0716769-5A BRPI0716769B1 (pt) 2006-09-13 2007-09-11 Composite material, process for preparing a composite material, using a composite material and cigarette filter

Country Status (12)

Country Link
US (1) US9808785B2 (pt)
EP (1) EP2066439A2 (pt)
JP (1) JP5204109B2 (pt)
KR (1) KR101160501B1 (pt)
CN (1) CN101583417B (pt)
BR (1) BRPI0716769B1 (pt)
CA (1) CA2663549C (pt)
FR (1) FR2905628B1 (pt)
MX (1) MX2009002752A (pt)
RU (1) RU2436624C2 (pt)
UA (1) UA102217C2 (pt)
WO (1) WO2008031816A2 (pt)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2928565B1 (fr) * 2008-03-14 2012-08-31 Rhodia Operations Materiau composite de cohesion elevee, procede de preparation et utilisations, notamment dans les filtres a cigarettes.
FR2936429B1 (fr) * 2008-09-30 2011-05-20 Rhodia Operations Procede de traitement d'un gaz pour diminuer sa teneur en dioxyde de carbone
GB201005547D0 (en) * 2010-04-01 2010-05-19 British American Tobacco Co Composite additive materials
CN101919591B (zh) * 2010-09-10 2011-12-28 浙江中烟工业有限责任公司 降低苯酚类物质含量的聚氨基葡萄糖己二酸乙烯酯材料
CN101919590B (zh) * 2010-09-10 2012-02-01 浙江中烟工业有限责任公司 降低苯酚类物质含量的聚氨基葡萄糖己二酸乙烯酯添加剂
CN102029146B (zh) * 2010-11-14 2012-09-05 中国烟草总公司郑州烟草研究院 一种保水材料及其制备方法和在滤棒中的应用
KR101430294B1 (ko) * 2011-11-11 2014-08-14 주식회사 케이티앤지 천연 추출물 코팅 흡착제 적용 담배 필터 및 그의 흡착제 제조 방법
JP6336396B2 (ja) 2011-11-24 2018-06-06 インディアン インスティテュート オブ テクノロジー 水精製のための多層有機−テンプレート−ベーマイト−ナノアーキテクチャ
JP6367182B2 (ja) 2012-04-17 2018-08-01 インディアン インスティテュート オブ テクノロジー 量子クラスタを使用する水流の量の検出
CN103271440B (zh) * 2013-05-31 2014-12-10 广东中烟工业有限责任公司 卷烟的净化减害试剂及颗粒及卷烟及颗粒的制备方法
CN108367987A (zh) * 2015-10-07 2018-08-03 罗地亚阿塞托有限公司 复合材料在结构材料中的用途、结构材料和净化空气的方法
CN113576026B (zh) * 2021-08-25 2023-10-13 上海烟草集团有限责任公司 一种用于降低卷烟烟气中愈创木酚的复合滤棒及卷烟

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GB1045694A (en) * 1964-01-14 1966-10-19 A D S Chemical Company Ltd Method for the manufacture of new adsorbents and adsorbents obtained by the said method
US3716063A (en) 1970-09-25 1973-02-13 Brown & Williamson Tobacco Selective gas phase filter material
GB1465519A (en) 1973-07-31 1977-02-23 Nat Patent Dev Corp Sorbents coated with a synthetic solid water-insoluble hydro philic polymer
US4637990A (en) * 1978-08-28 1987-01-20 Torobin Leonard B Hollow porous microspheres as substrates and containers for catalysts and method of making same
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JPH05339410A (ja) * 1992-06-08 1993-12-21 Rengo Co Ltd 活性炭含有多孔質セルロースとその製造方法
CA2127817C (en) * 1993-07-13 2007-07-03 Hitoshi Tsugaya Tobacco filters and method of producing the same
JP2001095552A (ja) * 1999-09-28 2001-04-10 Daicel Chem Ind Ltd たばこ煙用フィルター
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HU230306B1 (hu) * 2001-02-22 2015-12-28 Philip Morris Products Inc Cigaretta és szűrő alsó aromaadalékkal
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Also Published As

Publication number Publication date
BRPI0716769B1 (pt) 2018-02-06
US9808785B2 (en) 2017-11-07
CN101583417B (zh) 2013-10-30
KR20090069274A (ko) 2009-06-30
RU2436624C2 (ru) 2011-12-20
UA102217C2 (ru) 2013-06-25
RU2009113600A (ru) 2010-10-20
MX2009002752A (es) 2009-03-26
JP5204109B2 (ja) 2013-06-05
CA2663549C (fr) 2014-11-18
EP2066439A2 (fr) 2009-06-10
FR2905628B1 (fr) 2011-01-21
WO2008031816A3 (fr) 2008-06-26
CA2663549A1 (fr) 2008-03-20
BRPI0716769A2 (pt) 2013-09-17
US20100043813A1 (en) 2010-02-25
JP2010503391A (ja) 2010-02-04
FR2905628A1 (fr) 2008-03-14
CN101583417A (zh) 2009-11-18
KR101160501B1 (ko) 2012-06-28
WO2008031816A2 (fr) 2008-03-20

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