BRPI0515480A - processo para a conversão seletiva de uma alimentação de oxigenado em propileno - Google Patents

processo para a conversão seletiva de uma alimentação de oxigenado em propileno

Info

Publication number
BRPI0515480A
BRPI0515480A BRPI0515480-4A BRPI0515480A BRPI0515480A BR PI0515480 A BRPI0515480 A BR PI0515480A BR PI0515480 A BRPI0515480 A BR PI0515480A BR PI0515480 A BRPI0515480 A BR PI0515480A
Authority
BR
Brazil
Prior art keywords
propylene
oxygenate
olefin
cycle
conversion
Prior art date
Application number
BRPI0515480-4A
Other languages
English (en)
Inventor
Tom N Kalnes
Daniel H Wei
Bryan K Glover
Original Assignee
Uop Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Uop Llc filed Critical Uop Llc
Publication of BRPI0515480A publication Critical patent/BRPI0515480A/pt
Publication of BRPI0515480B1 publication Critical patent/BRPI0515480B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/06—Propene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

PROCESSO PARA A CONVERSãO SELETIVA DE UMA ALIMENTAçãO DE OXIGENADO EM PROPILENO. A seletividade do propileno de ciclo médio de um processo de oxigenado para propileno (OTP) usando um ou mais leitos fixos ou móveis de um catalisador de conversão do oxigenado de função dupla com reciclo de uma ou mais frações ricas de olefina C4+ é substancialmente intensificada mediante o uso da tecnologia de hidrotratamento seletivo nestas correntes de reciclo ricas em olefina C4+ para substancialmente eliminar precursores de coque prejudiciais tais como dienos e hidrocarbonetos acetilênicos. Esta etapa de hidrotratamento ajuda a sustentar a formação de depósitos de coque prejudiciais sobre o catalisador em um nível que substancialmente não degrada a atividade do catalisador de função dupla, a conversão de oxigenado e a seletividade do propileno, desse modo permitindo uma melhora substancial no rendimento de ciclo médio do propileno. A melhora de rendimento de ciclo médio do propileno permitida pela presente invenção sobre o sistema da técnica anterior mas sem o uso da etapa de hidrotratamento na corrente de reciclo rica em olefina C4+ é da ordem de 1,5 a 5,5 % em peso ou mais.
BRPI0515480-4A 2004-09-21 2005-08-25 Processo para a conversão seletiva de uma alimentação de oxigenado em propileno BRPI0515480B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US10/946,605 US7405337B2 (en) 2004-09-21 2004-09-21 Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream
US10/946,605 2004-09-21
PCT/US2005/030075 WO2006033759A2 (en) 2004-09-21 2005-08-25 Conversion of oxygenate to propylene with selective hydrogen treatment of heavy olefin recycle stream

Publications (2)

Publication Number Publication Date
BRPI0515480A true BRPI0515480A (pt) 2008-07-22
BRPI0515480B1 BRPI0515480B1 (pt) 2014-09-23

Family

ID=36074971

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0515480-4A BRPI0515480B1 (pt) 2004-09-21 2005-08-25 Processo para a conversão seletiva de uma alimentação de oxigenado em propileno

Country Status (10)

Country Link
US (1) US7405337B2 (pt)
EP (1) EP1794103B1 (pt)
JP (1) JP5501564B2 (pt)
KR (1) KR101115079B1 (pt)
CN (1) CN101023048A (pt)
AU (1) AU2005287368B2 (pt)
BR (1) BRPI0515480B1 (pt)
MY (1) MY144863A (pt)
RU (1) RU2375337C2 (pt)
WO (1) WO2006033759A2 (pt)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102005015923B4 (de) * 2005-04-06 2014-12-04 Air Liquide Global E&C Solutions Germany Gmbh Verfahren zur Herstellung von C2- bis C4-Olefinen aus einem Oxygenate und Wasserdampf enthaltenden Einsatzstrom
JP5330635B2 (ja) * 2006-01-20 2013-10-30 豊田通商株式会社 プロピレンの製造方法、触媒の再生方法、固体酸触媒
DE102006026103B4 (de) * 2006-06-03 2010-05-06 Lurgi Gmbh Reaktor zur Herstellung von C2- bis C8- Olefinen aus einem Oxygenat, Wasserdampf und einen oder mehrere Kohlenwasserstoffe enthaltendem Stoffstrom
US7741526B2 (en) 2006-07-19 2010-06-22 Exxonmobil Chemical Patents Inc. Feedstock preparation of olefins for oligomerization to produce fuels
US7722825B1 (en) * 2006-07-31 2010-05-25 Uop Llc Preparing a light-olefin containing product stream from an oxygenate-containing feed stream using reactors directing a flow of a fluidized dual-function catalyst system
KR101435230B1 (ko) * 2006-09-21 2014-08-28 미쓰비시 가가꾸 가부시키가이샤 프로필렌의 제조 방법
EP2027918A1 (en) * 2007-07-31 2009-02-25 Total Petrochemicals Research Feluy Mixtures of molecular sieves comprising MeAPO, their use in conversion of organics to olefins
EP2108635A1 (en) * 2008-04-11 2009-10-14 Total Petrochemicals Research Feluy Process to make olefins from ethanol
CN101939276B (zh) * 2008-02-07 2013-05-08 道达尔石油化学产品研究弗吕公司 由乙醇制造烯烃的方法
US8349754B2 (en) 2008-03-26 2013-01-08 Council Of Scientific & Industrial Research Modified zeolite catalyst useful for the conversion of paraffins, olefins and aromatics in a mixed feedstock into isoparaffins and a process thereof
WO2010052208A2 (en) * 2008-11-05 2010-05-14 Biofuel-Solution Ab A process for preparing lower hydrocarbons from glycerol
JP5497411B2 (ja) * 2008-12-01 2014-05-21 三井化学株式会社 オレフィンの製造方法
US8680355B2 (en) * 2008-12-01 2014-03-25 Mitsui Chemcials, Inc. Olefin production process
WO2010100069A1 (en) * 2009-03-03 2010-09-10 Total Petrochemicals Research Feluy Process to make olefins from organics and paraffins
US8552239B2 (en) 2009-03-16 2013-10-08 Mitsui Chemicals, Inc. Olefin production process
CN101659592B (zh) * 2009-09-10 2014-02-12 惠生工程（中国）有限公司 一种粗甲醇直接制备丙烯的方法
EP2338865A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
EP2338864A1 (en) 2009-12-22 2011-06-29 Total Petrochemicals Research Feluy Process for removing oxygenated contaminants from an hydrocarbon stream
CN102276384B (zh) * 2010-06-11 2013-12-04 中国石油化工股份有限公司 保持低碳烯烃选择性稳定的方法
CN102875307B (zh) * 2011-07-11 2016-01-13 中国石油化工股份有限公司 甲醇制丙烯的方法
DE102011114367A1 (de) * 2011-09-27 2013-03-28 Lurgi Gmbh Verfahren und Anlage zur Herstellung von Olefinen aus Dimethylether
WO2014090801A1 (en) * 2012-12-10 2014-06-19 Shell Internationale Research Maatschappij B.V. Fertilizer composition and process to prepare said fertilizer composition
WO2014102291A1 (en) * 2012-12-28 2014-07-03 Shell Internationale Research Maatschappij B.V. Process for the preparation of an olefinic product comprising ethylene and/or propylene
DE102013101577B4 (de) * 2013-02-18 2019-01-31 L’AIR LIQUIDE Société Anonyme pour l’Etude et l’Exploitation des Procédés Georges Claude Verfahren und Anlage zur Herstellung von Olefinen aus Oxygenaten
CN103922882B (zh) * 2014-04-02 2016-01-06 黄河三角洲京博化工研究院有限公司 一种提高mtp反应中丙烯选择性的方法
KR101616827B1 (ko) * 2014-05-15 2016-04-29 한국화학연구원 경질 올레핀의 제조공정 및 이를 위한 제조장치
AU2016374791B2 (en) * 2015-12-22 2020-08-20 Eco-Oil Miljöbränslen I Sverige AB Conversion of alcohols to hydrocarbons using a dual catalyst system comprising basic oxide on mixed oxide or mesoporous carrier and etched metal loaded zeolite catalyst
CN107032944B (zh) * 2016-02-03 2019-12-17 中石化广州工程有限公司 一种甲醇转化为丙烯的方法
AR111149A1 (es) 2017-02-06 2019-06-12 Dow Global Technologies Llc Procesos para mejorar la actividad de los catalizadores híbridos
WO2018210827A1 (en) 2017-05-17 2018-11-22 Total Research & Technology Feluy Mto-ocp upgrading process to maximize the selectivity to propylene
CN110041157B (zh) * 2019-05-10 2022-07-01 国家能源投资集团有限责任公司 一种提高甲醇制丙烯收率和延长催化剂寿命的方法

Family Cites Families (30)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4061724A (en) 1975-09-22 1977-12-06 Union Carbide Corporation Crystalline silica
US4073865A (en) 1976-09-27 1978-02-14 Union Carbide Corporation Silica polymorph and process for preparing same
US4310440A (en) 1980-07-07 1982-01-12 Union Carbide Corporation Crystalline metallophosphate compositions
DE3135618A1 (de) 1981-09-09 1983-03-17 Basf Ag, 6700 Ludwigshafen Verfahren zur herstellung von olefinen aus methanol und/oder dimethylether
US4387263A (en) 1982-05-14 1983-06-07 Hoechst Aktiengesellschaft Process for mixing olefins
ZA834412B (en) * 1982-07-20 1985-02-27 Mobil Oil Corp Two-stage,zeolite catalyzed process for the conversion of alcohols to hydrocarbons
US4440871A (en) 1982-07-26 1984-04-03 Union Carbide Corporation Crystalline silicoaluminophosphates
US4677243A (en) 1982-10-04 1987-06-30 Union Carbide Corporation Production of light olefins from aliphatic hetero compounds
US4554143A (en) 1983-07-15 1985-11-19 Union Carbide Corporation Crystalline ferroaluminophosphates
US4527001A (en) 1983-11-15 1985-07-02 Union Carbide Corporation Small olefin interconversions
US4793984A (en) 1984-04-13 1988-12-27 Union Carbide Corporation Molecular sieve compositions
US4587373A (en) 1984-12-12 1986-05-06 Mobil Oil Corporation Dimethylether recovery and/or recycle in an MTC conversion plant
US4579999A (en) 1985-01-17 1986-04-01 Mobil Oil Corporation Multistage process for converting oxygenates to liquid hydrocarbons with aliphatic recycle
FR2577549B1 (fr) 1985-02-15 1987-03-20 Inst Francais Du Petrole Procede de conversion de methanol ou de dimethylether en olefines
US4752651A (en) 1986-06-16 1988-06-21 Union Carbide Corporation Production of light olefins
US4853197A (en) 1987-06-04 1989-08-01 Uop Crystalline metal aluminophosphates
US4873390A (en) 1987-07-07 1989-10-10 Uop Chemical conversion process
DE4009459A1 (de) 1990-03-23 1991-09-26 Metallgesellschaft Ag Verfahren zur erzeugung von niederen olefinen
US5157181A (en) 1990-12-03 1992-10-20 Uop Moving bed hydrocarbon conversion process
US5095163A (en) 1991-02-28 1992-03-10 Uop Methanol conversion process using SAPO catalysts
US5191141A (en) 1991-11-13 1993-03-02 Uop Process for converting methanol to olefins using an improved metal aluminophosphate catalyst
US5126308A (en) 1991-11-13 1992-06-30 Uop Metal aluminophosphate catalyst for converting methanol to light olefins
FR2689517B1 (fr) * 1992-04-02 1995-07-28 Inst Francais Du Petrole Procede d'hydrogenation selective des hydrocarbures.
US6455749B1 (en) 1997-10-03 2002-09-24 Exxonmobil Chemical Patents, Inc. Method for increasing light olefin yield by conversion of a heavy hydrocarbon fraction of a product to light olefins
US6121504A (en) * 1998-04-29 2000-09-19 Exxon Chemical Patents Inc. Process for converting oxygenates to olefins with direct product quenching for heat recovery
DE19932060A1 (de) * 1999-07-12 2001-01-18 Basf Ag Verfahren zur Herstellung von C¶5¶-/C¶6¶-Olefinen
US6437208B1 (en) * 1999-09-29 2002-08-20 Exxonmobil Chemical Patents Inc. Making an olefin product from an oxygenate
DE10117248A1 (de) 2000-05-31 2002-10-10 Mg Technologies Ag Verfahren zum Erzeugen von Propylen aus Methanol
US20040122272A1 (en) * 2002-12-23 2004-06-24 Van Egmond Cor F. Process and apparatus for removing unsaturated impurities from oxygenates to olefins streams
US7115789B2 (en) * 2003-03-28 2006-10-03 Exxon Mobil Chemical Patents Inc. Process for removal of alkynes and/or dienes from an olefin stream

Also Published As

Publication number Publication date
CN101023048A (zh) 2007-08-22
US20060063956A1 (en) 2006-03-23
WO2006033759A3 (en) 2006-09-14
RU2007115066A (ru) 2008-11-10
BRPI0515480B1 (pt) 2014-09-23
EP1794103B1 (en) 2012-01-25
JP2008513449A (ja) 2008-05-01
JP5501564B2 (ja) 2014-05-21
AU2005287368B2 (en) 2011-03-17
KR20070055613A (ko) 2007-05-30
MY144863A (en) 2011-11-30
RU2375337C2 (ru) 2009-12-10
WO2006033759A2 (en) 2006-03-30
AU2005287368A1 (en) 2006-03-30
KR101115079B1 (ko) 2012-02-28
EP1794103A4 (en) 2009-12-23
EP1794103A2 (en) 2007-06-13
US7405337B2 (en) 2008-07-29

Similar Documents

Publication Publication Date Title
BRPI0515480A (pt) processo para a conversão seletiva de uma alimentação de oxigenado em propileno
BRPI0512530A (pt) processo contìnuo para conversão seletiva de uma alimentação de oxigenado em propileno
BR9714506A (pt) Sistema de recuperação em planta de olefinas empregando destilação catalìtica.
MY155951A (en) Process for producing olefins
BRPI0505413A (pt) processo para hidroformilação de olefinas
BR0301030A (pt) Processo e aparelho para preparação de olefinas
BRPI0513338A (pt) métodos de produção de etileno e propileno
BR112013002360A2 (pt) processo combinado para fazer celefinas a partir de um isobutanol
PH12019500563A1 (en) Fluid catalytic cracking process and apparatus for maximizing light olefin yield and other applications
EA202090313A1 (ru) Объединенный термический и каталитический крекинг для получения олефинов
RU2010119514A (ru) Способ гидрокрекинга
PH12015500278B1 (en) Method for converting hydrocarbon feedstocks by means of thermal steam cracking
EA200900205A1 (ru) Каталитические композиции для высокоселективного гидродеалкилирования алкилароматических углеводородов
BR9904376A (pt) Processo para o hidrocraqueamento de uma alimentação hidrocarbonácea
SA519410038B1 (ar) دمج عملية تكسير حفزي مع عملية تحويل خام إلى مواد كيميائية
WO2011075523A3 (en) Process and system to convert light olefins to diesel and other distillates
AR033144A1 (es) Catalizador para la reduccion de azufre de gasolina para proceso de cracking catalitico fluido y dicho proceso
BR112020017161B8 (pt) Processo para a produção de etileno glicol
BRPI0505365A (pt) processo de obtenção de zeólitas mais resistentes à desativação hidrotérmica
WO2014154849A3 (en) Process for the fluid catalytic cracking of oxygenated hydrocarbon compounds from biological origin
BR112016013610A2 (pt) Método para reduzir enxofre presente como enxofre ou compostos de enxofre em um fluxo de alimentação de hidrocarboneto
MX2022000575A (es) Proceso y aparato de craqueo catalitico de fluidos para maximizar el rendimiento de olefinas ligeras y otras aplicaciones.
BR9808964A (pt) Processo para a conversão de hidrocarbonetos a olefinas e aromáticos
BR9809454A (pt) Processo de hidrossulfurizar uma alimentação combinada de hidrocarboneto.
BR0301025A (pt) Processo e aparelhagem para preparação de olefinas

Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 25/08/2005, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 11A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.