BRPI0512096A - processo, e planta, para realizar sìntese fischer-tropsch em gás de alimentação - Google Patents

processo, e planta, para realizar sìntese fischer-tropsch em gás de alimentação

Info

Publication number
BRPI0512096A
BRPI0512096A BRPI0512096-9A BRPI0512096A BRPI0512096A BR PI0512096 A BRPI0512096 A BR PI0512096A BR PI0512096 A BRPI0512096 A BR PI0512096A BR PI0512096 A BRPI0512096 A BR PI0512096A
Authority
BR
Brazil
Prior art keywords
stage
plant
tropsch synthesis
modules
channels
Prior art date
Application number
BRPI0512096-9A
Other languages
English (en)
Inventor
Bowe Michael Joseph
Original Assignee
Compactgtl Plc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Compactgtl Plc filed Critical Compactgtl Plc
Publication of BRPI0512096A publication Critical patent/BRPI0512096A/pt
Publication of BRPI0512096B1 publication Critical patent/BRPI0512096B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/34—Apparatus, reactors
    • C10G2/341—Apparatus, reactors with stationary catalyst bed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/04—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds the fluid passing successively through two or more beds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/24—Stationary reactors without moving elements inside
    • B01J19/248—Reactors comprising multiple separated flow channels
    • B01J19/249—Plate-type reactors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00002—Chemical plants
    • B01J2219/00018—Construction aspects
    • B01J2219/0002—Plants assembled from modules joined together
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00819—Materials of construction
    • B01J2219/00835—Comprising catalytically active material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00867—Microreactors placed in series, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00869—Microreactors placed in parallel, on the same or on different supports
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00851—Additional features
    • B01J2219/00871—Modular assembly
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781—Aspects relating to microreactors
    • B01J2219/00873—Heat exchange
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2453—Plates arranged in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2458—Flat plates, i.e. plates which are not corrugated or otherwise structured, e.g. plates with cylindrical shape
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2451—Geometry of the reactor
    • B01J2219/2456—Geometry of the plates
    • B01J2219/2459—Corrugated plates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2461—Heat exchange aspects
    • B01J2219/2462—Heat exchange aspects the reactants being in indirect heat exchange with a non reacting heat exchange medium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/24—Stationary reactors without moving elements inside
    • B01J2219/2401—Reactors comprising multiple separate flow channels
    • B01J2219/245—Plate-type reactors
    • B01J2219/2476—Construction materials
    • B01J2219/2477—Construction materials of the catalysts
    • B01J2219/2479—Catalysts coated on the surface of plates or inserts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

PROCESSO, E PLANTA, PARA REALIZAR SìNTESE FISCHER-TROPSCH EM UM GáS DE ALIMENTAçãO A síntese Fischer-Tropsch é realizada em um gás de alimentação CO/H*2 usando uma pluralidade de módulos compactos (12) de reator catalítico cada definindo canais de reação catalítica e canais de líquido refrigerante, em dois estágios sucessivos, com o mesmo número de módulos de reator para cada estágio. A velocidade de fluxo do gás no primeiro estágio é suficientemente elevada, de modo que não mais que 75% do CO sofrem conversão. Os gases são resfriados (16) entre estágios sucessivos de modo a remover vapor d'água, e a pressão é reduzida (20) antes dos mesmos serem submetidos ao segundo estágio. Além disso, a temperatura de reação para o segundo estágio é menor do que para o primeiro estágio, de modo que não mais que 75% do monóxido de carbono restante também sofrem conversão durante o segundo estágio. O efeito deletério de vapor d'água sobre o catalisador é, assim, suprimido, enquanto a capacidade global da planta (10) pode ser ajustada por fechamento de módulos em cada estágio, enquanto mantendo iguais os números.
BRPI0512096A 2004-06-16 2005-05-24 Processo, e planta, para realizar síntese fischer-tropsch em um gás de alimentação BRPI0512096B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GBGB0413400.3A GB0413400D0 (en) 2004-06-16 2004-06-16 Catalytic plant and process
GB0413400.3 2004-06-16
PCT/GB2005/050070 WO2005123883A1 (en) 2004-06-16 2005-05-24 Catalytic plant and process for performing fiscger-tropsch synthesis

Publications (2)

Publication Number Publication Date
BRPI0512096A true BRPI0512096A (pt) 2008-02-06
BRPI0512096B1 BRPI0512096B1 (pt) 2015-09-22

Family

ID=32749962

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0512096A BRPI0512096B1 (pt) 2004-06-16 2005-05-24 Processo, e planta, para realizar síntese fischer-tropsch em um gás de alimentação

Country Status (19)

Country Link
US (1) US7067561B2 (pt)
EP (1) EP1756249B1 (pt)
JP (1) JP4913047B2 (pt)
KR (1) KR101129508B1 (pt)
CN (1) CN1977033B (pt)
AP (1) AP2007003876A0 (pt)
AT (1) ATE384111T1 (pt)
AU (1) AU2005254793B2 (pt)
BR (1) BRPI0512096B1 (pt)
CA (1) CA2568702C (pt)
DE (1) DE602005004405T2 (pt)
DK (1) DK1756249T3 (pt)
GB (1) GB0413400D0 (pt)
MX (1) MXPA06014601A (pt)
MY (1) MY141242A (pt)
NO (1) NO339154B1 (pt)
RU (1) RU2375406C2 (pt)
TW (1) TWI367780B (pt)
WO (1) WO2005123883A1 (pt)

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DE602006006091D1 (de) * 2005-10-27 2009-05-14 Avery Dennison Corp Fluoreszierender artikel mit mehreren lagen
DE102007023762A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage und Verfahren zur kontinuierlichen industriellen Herstellung von 3-Glycidyloxypropylalkoxysilanen
DE102007023756A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage und Verfahren zur kontinuierlichen industriellen Herstellung von Alkylalkoxysilanen
DE102007023760A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage, Reaktor und Verfahren zur kontinuierlichen industriellen Herstellung von 3-Methacryloxypropylalkoxysilanen
DE102007023764A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage und Vorrichtung zur kontinuierlichen industriellen Herstellung von 3-Chlorpropylchlorsilanen
DE102007023763A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage, Reaktor und Verfahren zur kontinuierlichen industriellen Herstellung von Polyetheralkylalkoxysilanen
DE102007023757A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage und Verfahen zur kontinuierlichen industriellen Herstellung von Organosilanen
DE102007023759A1 (de) * 2006-08-10 2008-02-14 Evonik Degussa Gmbh Anlage und Verfahren zur kontinuierlichen industriellen Herstellung von Fluoralkylchlorsilan
JP5383508B2 (ja) 2007-01-19 2014-01-08 ヴェロシス，インク． マイクロチャネルプロセス技術を用いて天然ガスを分子量の高くなった炭化水素に変換するためのプロセスおよび装置
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RU2489207C1 (ru) * 2012-05-04 2013-08-10 Федеральное государственное бюджетное учреждение науки Ордена Трудового Красного Знамени Институт нефтехимического синтеза им. А.В. Топчиева Российской академии наук (ИНХС РАН) Катализатор и способ получения алифатических углеводородов из оксида углерода и водорода в его присутствии
US9676623B2 (en) 2013-03-14 2017-06-13 Velocys, Inc. Process and apparatus for conducting simultaneous endothermic and exothermic reactions
AR110129A1 (es) 2016-11-16 2019-02-27 Dow Global Technologies Llc Procesos y sistemas para obtener alta conversión de carbono a productos deseados en un sistema de catalizador híbrido
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Also Published As

Publication number Publication date
ATE384111T1 (de) 2008-02-15
RU2375406C2 (ru) 2009-12-10
MY141242A (en) 2010-03-31
EP1756249B1 (en) 2008-01-16
NO339154B1 (no) 2016-11-14
DE602005004405T2 (de) 2009-01-02
TWI367780B (en) 2012-07-11
CA2568702C (en) 2012-05-22
MXPA06014601A (es) 2007-03-23
DE602005004405D1 (de) 2008-03-06
CN1977033B (zh) 2014-12-17
CA2568702A1 (en) 2005-12-29
DK1756249T3 (da) 2008-05-19
NO20070094L (no) 2007-03-16
JP2008502766A (ja) 2008-01-31
TW200607787A (en) 2006-03-01
CN1977033A (zh) 2007-06-06
AU2005254793B2 (en) 2011-02-10
JP4913047B2 (ja) 2012-04-11
GB0413400D0 (en) 2004-07-21
KR20070022757A (ko) 2007-02-27
RU2007101393A (ru) 2008-07-27
AU2005254793A2 (en) 2005-12-29
AP2007003876A0 (en) 2007-02-28
EP1756249A1 (en) 2007-02-28
BRPI0512096B1 (pt) 2015-09-22
US20050282918A1 (en) 2005-12-22
US7067561B2 (en) 2006-06-27
WO2005123883A1 (en) 2005-12-29
KR101129508B1 (ko) 2012-03-29
AU2005254793A1 (en) 2005-12-29

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