BRPI0507938A - processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular - Google Patents
processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecularInfo
- Publication number
- BRPI0507938A BRPI0507938A BRPI0507938-1A BRPI0507938A BRPI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A
- Authority
- BR
- Brazil
- Prior art keywords
- molecular weight
- nitrile rubber
- hydrogenated nitrile
- hydrogenated
- low molecular
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/08—Depolymerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/02—Hydrogenation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/42—Nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
PROCESSO PARA A PREPARAçãO DE BORRACHA DE NITRILA HIDROGENADA DE BAIXO PESO MOLECULAR. A presente invenção refere-se a polímeros de borracha de nitrila hidrogenada, que têm pesos moleculares mais baixos e distribuições de peso molecular mais estreitas do que aquelas conhecidas na técnica anterior, são preparadas por uma processo realizado na presença de hidrogênio e opcionalmente pelo menos uma co-olefina. De acordo com o processo, o substrato é simultaneamente submetido a uma reação de metátese e uma reação de hidrogenação. A reação ocorre na presença de um catalisador a base de alquiledeno de ósmio ou rutênio. A borracha de nitrila hidrogenada produzida tem um peso molecular (Mw) na faixa de 20.000 a 250.000. uma viscosidade Mooney (ML 1+4 em 100 graus C) na faixa de 1 a 50, e uma MWD de menos de 2,6. A borracha de nitrita hidrogenada obtida é usada em indústrias automotivas, elétricas, de engenharia mecânica e de construção de navios.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CA002462005A CA2462005A1 (en) | 2004-02-23 | 2004-02-23 | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
PCT/CA2005/000255 WO2005080456A1 (en) | 2004-02-23 | 2005-02-22 | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
Publications (2)
Publication Number | Publication Date |
---|---|
BRPI0507938A true BRPI0507938A (pt) | 2007-07-17 |
BRPI0507938B1 BRPI0507938B1 (pt) | 2016-01-12 |
Family
ID=34865994
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0507938A BRPI0507938B1 (pt) | 2004-02-23 | 2005-02-22 | processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular |
Country Status (11)
Country | Link |
---|---|
US (1) | US7585920B2 (pt) |
EP (1) | EP1720920B1 (pt) |
JP (1) | JP4611371B2 (pt) |
KR (1) | KR101236031B1 (pt) |
CN (1) | CN100526353C (pt) |
BR (1) | BRPI0507938B1 (pt) |
CA (1) | CA2462005A1 (pt) |
MX (1) | MXPA06009368A (pt) |
PL (1) | PL1720920T3 (pt) |
TW (1) | TWI347328B (pt) |
WO (1) | WO2005080456A1 (pt) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2350280A1 (en) | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
US6841623B2 (en) | 2001-06-29 | 2005-01-11 | Bayer Inc. | Low molecular weight nitrile rubber |
JP5210860B2 (ja) * | 2005-05-20 | 2013-06-12 | 株式会社ブリヂストン | 低分子量ポリマーの調製方法 |
DE102006008521A1 (de) * | 2006-02-22 | 2007-08-23 | Lanxess Deutschland Gmbh | Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese |
DE102006040569A1 (de) * | 2006-08-30 | 2008-03-06 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuken |
DE102007039525A1 (de) * | 2007-08-21 | 2009-02-26 | Lanxess Deutschland Gmbh | Verfahren zum Metathese-Abbau von Nitrilkautschuk |
EP2147721A1 (de) * | 2008-07-08 | 2010-01-27 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
EP2143489A1 (de) * | 2008-07-08 | 2010-01-13 | Lanxess Deutschland GmbH | Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen |
EP2289620A1 (en) * | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Process for the preparation of hydrogenated nitrile rubber |
JP5536890B2 (ja) | 2009-08-31 | 2014-07-02 | ランクセス・ドイチュランド・ゲーエムベーハー | 場合により水素化された低分子量ニトリルゴムを含有する加硫性ポリマー組成物 |
EP2289621A1 (en) | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
EP2289623A1 (en) | 2009-08-31 | 2011-03-02 | LANXESS Deutschland GmbH | Metathesis of nitrile rubbers in the presence of transition metal catalysts |
WO2011079439A1 (en) * | 2009-12-30 | 2011-07-07 | Zannan Scitech Co., Ltd. | Highly active metathesis catalysts selective for romp and rcm reactions |
WO2013056400A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056461A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056463A1 (en) | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013056459A1 (en) * | 2011-10-21 | 2013-04-25 | Lanxess Deutschland Gmbh | Catalyst compositions and their use for hydrogenation of nitrile rubber |
WO2013159365A1 (en) | 2012-04-28 | 2013-10-31 | Lanxess Deutschland Gmbh | Hydrogenation of nitrile rubber |
CN104271607B (zh) * | 2012-04-28 | 2017-05-24 | 阿朗新科德国有限责任公司 | 丁腈橡胶的氢化 |
EP2676971B1 (en) | 2012-06-22 | 2015-04-08 | University Of Waterloo | Hydrogenation of a diene-based polymer latex |
EP2676969B1 (en) | 2012-06-22 | 2016-06-01 | University Of Waterloo | Tandem metathesis and hydrogenation of diene-based polymers in latex |
CN105542037B (zh) * | 2014-10-29 | 2017-08-25 | 中国石油化工股份有限公司 | 一种不饱和共聚物的加氢方法 |
TWI566835B (zh) | 2014-12-25 | 2017-01-21 | 財團法人工業技術研究院 | 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法 |
CN107540765B (zh) * | 2016-06-24 | 2020-06-09 | 中国石油天然气股份有限公司 | 一种丁腈橡胶用阻燃型增塑剂的制备方法 |
EP3827029A1 (en) | 2018-07-23 | 2021-06-02 | ARLANXEO Deutschland GmbH | Method for producing hydrogenated nitrile rubber and hnbr compositions thereof |
CN114262394B (zh) * | 2020-09-16 | 2023-08-18 | 浙江赞昇新材料有限公司 | 液体氢化丁腈橡胶及其制备方法和应用 |
JP2022131899A (ja) * | 2021-02-26 | 2022-09-07 | 横浜ゴム株式会社 | ホース用ゴム組成物及びホース |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19907519A1 (de) * | 1999-02-22 | 2000-08-31 | Basf Ag | Verfahren zur Herstellung von substituierten Olefinen |
CA2350280A1 (en) * | 2001-06-12 | 2002-12-12 | Bayer Inc. | Low molecular weight hydrogenated nitrile rubber |
TW593386B (en) * | 2001-06-12 | 2004-06-21 | Bayer Inc | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
CA2413636A1 (en) * | 2002-12-05 | 2004-06-05 | Bayer Inc. | Adhesive compositions |
CA2413607A1 (en) * | 2002-12-05 | 2004-06-05 | Bayer Inc. | Process for the preparation of low molecular weight hydrogenated nitrile rubber |
-
2004
- 2004-02-23 CA CA002462005A patent/CA2462005A1/en not_active Abandoned
-
2005
- 2005-02-22 US US10/589,763 patent/US7585920B2/en active Active
- 2005-02-22 BR BRPI0507938A patent/BRPI0507938B1/pt not_active IP Right Cessation
- 2005-02-22 JP JP2007500022A patent/JP4611371B2/ja active Active
- 2005-02-22 CN CNB2005800057615A patent/CN100526353C/zh not_active Expired - Fee Related
- 2005-02-22 MX MXPA06009368A patent/MXPA06009368A/es active IP Right Grant
- 2005-02-22 PL PL05714497T patent/PL1720920T3/pl unknown
- 2005-02-22 WO PCT/CA2005/000255 patent/WO2005080456A1/en active Application Filing
- 2005-02-22 KR KR1020067016808A patent/KR101236031B1/ko active IP Right Grant
- 2005-02-22 EP EP05714497A patent/EP1720920B1/en not_active Not-in-force
- 2005-02-22 TW TW094105243A patent/TWI347328B/zh not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
EP1720920B1 (en) | 2012-06-13 |
US7585920B2 (en) | 2009-09-08 |
TWI347328B (en) | 2011-08-21 |
BRPI0507938B1 (pt) | 2016-01-12 |
TW200604222A (en) | 2006-02-01 |
EP1720920A1 (en) | 2006-11-15 |
MXPA06009368A (es) | 2007-01-26 |
KR20070032278A (ko) | 2007-03-21 |
PL1720920T3 (pl) | 2012-11-30 |
US20080214741A1 (en) | 2008-09-04 |
JP2007534797A (ja) | 2007-11-29 |
EP1720920A4 (en) | 2010-07-28 |
CN1922224A (zh) | 2007-02-28 |
CA2462005A1 (en) | 2005-08-23 |
CN100526353C (zh) | 2009-08-12 |
WO2005080456A1 (en) | 2005-09-01 |
JP4611371B2 (ja) | 2011-01-12 |
KR101236031B1 (ko) | 2013-02-21 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 12/01/2016, OBSERVADAS AS CONDICOES LEGAIS. |
|
B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2450 DE 19-12-2017 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |