BRPI0417643A - processo para a preparação de glicolaldeìdo, composição catalisadora, e, processo para a preparação de etileno glicol - Google Patents
processo para a preparação de glicolaldeìdo, composição catalisadora, e, processo para a preparação de etileno glicolInfo
- Publication number
- BRPI0417643A BRPI0417643A BRPI0417643-0A BRPI0417643A BRPI0417643A BR PI0417643 A BRPI0417643 A BR PI0417643A BR PI0417643 A BRPI0417643 A BR PI0417643A BR PI0417643 A BRPI0417643 A BR PI0417643A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- catalyst composition
- glycolaldehyde
- ethylene glycol
- optionally substituted
- Prior art date
Links
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title abstract 9
- WGCNASOHLSPBMP-UHFFFAOYSA-N Glycolaldehyde Chemical compound OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 5
- 239000003054 catalyst Substances 0.000 title abstract 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000004519 manufacturing process Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910002091 carbon monoxide Inorganic materials 0.000 abstract 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 abstract 1
- 125000005842 heteroatom Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 125000004437 phosphorous atom Chemical group 0.000 abstract 1
- 229910052698 phosphorus Inorganic materials 0.000 abstract 1
- 229910052703 rhodium Inorganic materials 0.000 abstract 1
- 239000010948 rhodium Substances 0.000 abstract 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/24—Phosphines, i.e. phosphorus bonded to only carbon atoms, or to both carbon and hydrogen atoms, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, phosphole or anionic phospholide ligands
- B01J31/2404—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring
- B01J31/2442—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems
- B01J31/2461—Cyclic ligands, including e.g. non-condensed polycyclic ligands, the phosphine-P atom being a ring member or a substituent on the ring comprising condensed ring systems and phosphine-P atoms as ring members in the condensed ring system or in a further ring
- B01J31/248—Bridged ring systems, e.g. 9-phosphabicyclononane
- B01J31/2485—Tricyclic systems, e.g. phosphaadamantanes and hetero analogues
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
- B01J2231/60—Reduction reactions, e.g. hydrogenation
- B01J2231/64—Reductions in general of organic substrates, e.g. hydride reductions or hydrogenations
- B01J2231/641—Hydrogenation of organic substrates, i.e. H2 or H-transfer hydrogenations, e.g. Fischer-Tropsch processes
- B01J2231/648—Fischer-Tropsch-type reactions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
- B01J2531/80—Complexes comprising metals of Group VIII as the central metal
- B01J2531/82—Metals of the platinum group
- B01J2531/822—Rhodium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/20—Carbonyls
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
- B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
- B01J31/22—Organic complexes
- B01J31/2204—Organic complexes the ligands containing oxygen or sulfur as complexing atoms
- B01J31/2208—Oxygen, e.g. acetylacetonates
- B01J31/2226—Anionic ligands, i.e. the overall ligand carries at least one formal negative charge
- B01J31/223—At least two oxygen atoms present in one at least bidentate or bridging ligand
- B01J31/2234—Beta-dicarbonyl ligands, e.g. acetylacetonates
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Materials Engineering (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP03257883 | 2003-12-16 | ||
| PCT/EP2004/053492 WO2005058788A1 (en) | 2003-12-16 | 2004-12-15 | Process of preparing glycolaldehyde |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0417643A true BRPI0417643A (pt) | 2007-03-27 |
Family
ID=34684623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0417643-0A BRPI0417643A (pt) | 2003-12-16 | 2004-12-15 | processo para a preparação de glicolaldeìdo, composição catalisadora, e, processo para a preparação de etileno glicol |
Country Status (11)
| Country | Link |
|---|---|
| US (2) | US7449607B2 (https=) |
| EP (1) | EP1697291A1 (https=) |
| JP (1) | JP4474419B2 (https=) |
| KR (1) | KR20060117345A (https=) |
| CN (1) | CN100434412C (https=) |
| AU (1) | AU2004298446B2 (https=) |
| BR (1) | BRPI0417643A (https=) |
| CA (1) | CA2549456A1 (https=) |
| MX (1) | MXPA06006705A (https=) |
| RU (1) | RU2371429C2 (https=) |
| WO (1) | WO2005058788A1 (https=) |
Families Citing this family (27)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7858787B2 (en) * | 2006-09-22 | 2010-12-28 | Shell Oil Company | Process for producing olefins |
| US7301054B1 (en) | 2006-09-29 | 2007-11-27 | Eastman Chemical Company | Process for the preparation of glycolaldehyde |
| US7420093B2 (en) | 2006-09-29 | 2008-09-02 | Eastman Chemical Company | Process for the preparation of glycolaldehyde |
| US7674937B2 (en) | 2008-05-28 | 2010-03-09 | Eastman Chemical Company | Hydroformylation catalysts |
| FR2943061B1 (fr) * | 2009-03-13 | 2011-02-25 | Rhodia Operations | Composes organophosphores, systemes catalytiques comprenant ces composes et procede d'hydrocyanation ou d'hydroformylation utilisant ces systemes catalytiques |
| JP5791628B2 (ja) | 2009-12-17 | 2015-10-07 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 高級エタノールアミンの製造方法 |
| EP2513036B1 (de) | 2009-12-17 | 2019-04-17 | Basf Se | Umsetzung von glykolaldehyd mit einem aminierungsmittel |
| CN101811933B (zh) * | 2010-04-26 | 2013-05-08 | 常州大学 | 一种催化合成乙二醇的方法 |
| TWI508937B (zh) * | 2014-04-30 | 2015-11-21 | Chien An Chen | 使用甲醇為原料經由甲醛、乙醇醛的中間產物而合成乙二醇的製造方法 |
| CN105085211B (zh) * | 2014-05-16 | 2017-09-05 | 陈建安 | 一种甲醛、乙醇醛及乙二醇的制造方法 |
| MY184090A (en) * | 2014-05-19 | 2021-03-17 | Iowa Corn Promotion Board | Process for the continuous production of ethylene glycol from carbohydrates |
| CN106470965B (zh) * | 2014-06-30 | 2019-07-26 | 托普索公司 | 从糖制备乙二醇的方法 |
| UA123868C2 (uk) | 2016-01-07 | 2021-06-16 | Хальдор Топсьое А/С | Спосіб одержання етиленгліколю з цукрів |
| MX2018007750A (es) | 2016-01-07 | 2018-11-14 | Topsoe Haldor As | Proceso para la preparacion de etilenglicol a partir de azucares. |
| CN105618035B (zh) * | 2016-02-02 | 2018-05-11 | 中国科学院福建物质结构研究所 | 合成气制备乙醇醛所用的负载型铑催化剂及其制备方法 |
| RU2759538C2 (ru) | 2016-12-08 | 2021-11-15 | Хальдор Топсёэ А/С | Получение гликолевого альдегида термолитической фрагментацией |
| GB201904612D0 (en) | 2019-04-02 | 2019-05-15 | Univ Leuven Kath | Reaction of glycoladehyde |
| WO2020095147A1 (en) * | 2018-11-07 | 2020-05-14 | Sabic Global Technologies B.V. | Catalyst systems and methods for their use in selective hydroformylation of formaldehyde to glycolaldehyde |
| WO2020249428A1 (en) | 2019-06-11 | 2020-12-17 | Basf Se | Products obtained by the conversion of glycolaldehyde derivatives and aminating agents and their conversion to ethyleneamines and ethanolamines |
| WO2020249426A1 (en) | 2019-06-11 | 2020-12-17 | Basf Se | Conversion of glycolaldehyde with an aminating agent |
| CN114008016B (zh) | 2019-06-11 | 2025-03-04 | 巴斯夫欧洲公司 | 通过乙醇醛衍生物和胺化剂的转化以及它们向亚乙基胺类和乙醇胺类的转化获得的产物 |
| CN112337508A (zh) * | 2020-11-03 | 2021-02-09 | 中国科学院福建物质结构研究所 | 一种乙醇醛合成用铑基催化剂及其制备方法 |
| DE202021103519U1 (de) | 2021-07-01 | 2021-07-16 | Schill + Seilacher Gmbh | Gerbmittel, Verwendung des Gerbmittels zum Gerben von Tierhäuten und Fellen und daraus erhaltenes Leder |
| ES2975566T3 (es) | 2021-07-01 | 2024-07-09 | Schill Seilacher Gmbh | Agente curtiente, uso de un curtiente y procedimiento de curtido de pieles de animales y del cuero obtenido a partir de las mismas |
| CN114751813B (zh) * | 2022-05-05 | 2023-12-15 | 天津大学 | 一种甲醛氢甲酰化制备乙醇醛的方法 |
| CN115340440B (zh) * | 2022-08-18 | 2024-09-06 | 山东能源集团有限公司 | 一种制备乙二醇的方法 |
| CN115108887A (zh) * | 2022-08-18 | 2022-09-27 | 山东能源集团有限公司 | 一种乙二醇的制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3026327A (en) | 1960-07-06 | 1962-03-20 | American Cyanamid Co | Substituted 1, 3, 5, 7-tetraalkyl-2, 6, 9-trioxa-10-phosphatricyclo [3.3.1.1.3,7] decanes |
| US4414421A (en) * | 1981-08-03 | 1983-11-08 | Shell Oil Company | Process for the preparation of glycol aldehyde |
| US4608444A (en) * | 1984-04-05 | 1986-08-26 | The Halcon Sd Group, Inc. | Process and accompanying catalysts for the hydroformylation of formaldehyde to glycol-aldehyde |
| US4847423A (en) * | 1988-03-03 | 1989-07-11 | Hoechst Celanese Corporation | Hydroformylation of aqueous formaldehyde using a rhodium-tricyclohexylphosphine catalyst system |
| SU1608182A1 (ru) * | 1988-09-15 | 1990-11-23 | Предприятие П/Я В-2287 | Способ получени гликолевого альдегида |
| US5567856A (en) * | 1995-05-30 | 1996-10-22 | Hoechst Celanese Corporation | Synthesis of and hydroformylation with fluoro-substituted bidentate phosphine ligands |
| US6156934A (en) * | 1997-03-26 | 2000-12-05 | Shell Oil Company | Diphosphines |
| DE10023468A1 (de) | 2000-05-12 | 2001-11-15 | Basf Ag | Verfahren zur Hydroformylierung ethylenisch ungesättigter Verbindungen und Ligand-Metall-Komplex als Katalysator hierfür |
-
2004
- 2004-12-15 US US10/583,109 patent/US7449607B2/en not_active Expired - Fee Related
- 2004-12-15 BR BRPI0417643-0A patent/BRPI0417643A/pt not_active IP Right Cessation
- 2004-12-15 KR KR1020067012776A patent/KR20060117345A/ko not_active Ceased
- 2004-12-15 CA CA002549456A patent/CA2549456A1/en not_active Abandoned
- 2004-12-15 EP EP04804845A patent/EP1697291A1/en not_active Withdrawn
- 2004-12-15 MX MXPA06006705A patent/MXPA06006705A/es active IP Right Grant
- 2004-12-15 WO PCT/EP2004/053492 patent/WO2005058788A1/en not_active Ceased
- 2004-12-15 CN CNB2004800376940A patent/CN100434412C/zh not_active Expired - Lifetime
- 2004-12-15 RU RU2006125408/04A patent/RU2371429C2/ru not_active IP Right Cessation
- 2004-12-15 AU AU2004298446A patent/AU2004298446B2/en not_active Ceased
- 2004-12-15 JP JP2006544436A patent/JP4474419B2/ja not_active Expired - Lifetime
-
2008
- 2008-09-10 US US12/208,149 patent/US7511178B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7511178B2 (en) | 2009-03-31 |
| CN1894188A (zh) | 2007-01-10 |
| US20070249871A1 (en) | 2007-10-25 |
| EP1697291A1 (en) | 2006-09-06 |
| CA2549456A1 (en) | 2005-06-30 |
| AU2004298446A1 (en) | 2005-06-30 |
| US7449607B2 (en) | 2008-11-11 |
| AU2004298446B2 (en) | 2008-07-31 |
| CN100434412C (zh) | 2008-11-19 |
| US20090012333A1 (en) | 2009-01-08 |
| RU2006125408A (ru) | 2008-01-27 |
| MXPA06006705A (es) | 2006-08-23 |
| JP2007516976A (ja) | 2007-06-28 |
| JP4474419B2 (ja) | 2010-06-02 |
| WO2005058788A1 (en) | 2005-06-30 |
| KR20060117345A (ko) | 2006-11-16 |
| RU2371429C2 (ru) | 2009-10-27 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
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