BRPI0400322A - Processo de alcoólise de óleos ácidos de origem vegetal ou animal - Google Patents
Processo de alcoólise de óleos ácidos de origem vegetal ou animalInfo
- Publication number
- BRPI0400322A BRPI0400322A BR0400322-5A BRPI0400322A BRPI0400322A BR PI0400322 A BRPI0400322 A BR PI0400322A BR PI0400322 A BRPI0400322 A BR PI0400322A BR PI0400322 A BRPI0400322 A BR PI0400322A
- Authority
- BR
- Brazil
- Prior art keywords
- oils
- vegetable
- acid
- palm
- animal
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
- C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
- C11C3/04—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
- C11C3/10—Ester interchange
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Fats And Perfumes (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO DE ALCOóLISE DE óLEOS áCIDOS DE ORIGEM VEGETAL OU ANIMAL". Um processo que emprega um catalisador heterogêneo que compreende um óxido misto aluminato de zinco e que responde à fórmula: ZnAL~ 2~0~ 4~, x ZnO, y AL~ 2~O~ 3~ x e y representando cada um deles um número compreendido entre O e 2, e no qual o aluminato de zinco é mais especialmente de tipo espinela, permite, com o auxílio de monoalcoóis de C1 a C5, transesterificar óleos vegetais ou animais, que possuem uma acidez livre natural, como por exemplo os óleos brutos submetidos a uma desmucilagem de colza, de soja, de girassol, ou óleos exóticos, do tipo de palma, de dendê ou de copra, naturalmente ricos em ácidos graxos, e esterificar simultaneamente a acidez livre dos mesmos, e assim utilizar óleos ácidos brutos, desembaraçados de seus fosfolipídios ou mucilagens e dos quais o índice de ácido está compreendido entre 0,5 e 20, por exemplo entre 1 e 15 e de preferência compreendido entre 2 e 12, para assegurar notadamente a produção de ésteres, por exemplo, metílicos para uso carburante.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0303575A FR2852602B1 (fr) | 2003-03-17 | 2003-03-17 | Procede d'alcoolyse d'huiles acides d'origine vegetale ou animale |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BRPI0400322A true BRPI0400322A (pt) | 2005-06-07 |
| BRPI0400322B1 BRPI0400322B1 (pt) | 2013-11-26 |
| BRPI0400322B8 BRPI0400322B8 (pt) | 2016-05-17 |
Family
ID=32799724
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0400322A BRPI0400322B8 (pt) | 2003-03-17 | 2004-03-15 | processo de alcoólise de óleos ácidos de origem vegetal ou animal |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US7420073B2 (pt) |
| EP (1) | EP1460124B1 (pt) |
| BR (1) | BRPI0400322B8 (pt) |
| ES (1) | ES2391392T3 (pt) |
| FR (1) | FR2852602B1 (pt) |
| MY (1) | MY146016A (pt) |
| PL (1) | PL207033B1 (pt) |
Families Citing this family (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BRPI0414031A (pt) | 2003-08-29 | 2006-10-24 | Nippon Catalytic Chem Ind | método de produção de ésteres alquìlicos de ácidos graxos e/ou glicerina e composição contendo éster alquìlico de ácido graxo |
| DE102005002700A1 (de) * | 2005-01-19 | 2006-07-27 | Cognis Deutschland Gmbh & Co. Kg | Zusammensetzungen verwendbar als Biotreibstoff |
| BRPI0502577B1 (pt) * | 2005-07-07 | 2015-11-03 | Petroleo Brasileiro Sa | processo de craqueamento catalítico para produção de diesel a partir de óleos vegetais |
| FR2890963A1 (fr) * | 2005-09-16 | 2007-03-23 | Inst Francais Du Petrole | Procede de fabrication d'esters ethyliques d'acides gras a partir de triglycerides et d'alcools |
| JP5154015B2 (ja) * | 2005-12-20 | 2013-02-27 | 花王株式会社 | 脂肪酸アルキルエステル及びグリセリンの製造法 |
| JP5047499B2 (ja) * | 2005-12-28 | 2012-10-10 | 花王株式会社 | 脂肪酸アルキルエステルの製造方法 |
| DE102006028560A1 (de) | 2006-06-22 | 2007-12-27 | Cognis Ip Management Gmbh | Verfahren zur Umesterung von Triglyceriden |
| EP1878716A1 (en) * | 2006-07-14 | 2008-01-16 | Rohm and Haas Company | Method for transesterification of triglycerides |
| WO2008070756A2 (en) * | 2006-12-06 | 2008-06-12 | Southern Illinois University Carbondale | Processes for the production of fatty acid alkyl esters |
| US20080289248A1 (en) * | 2007-05-23 | 2008-11-27 | Southern Illinois University Carbondale | Immobilized esterification catalysts for producing fatty acid alkyl esters |
| US20080282606A1 (en) * | 2007-04-16 | 2008-11-20 | Plaza John P | System and process for producing biodiesel |
| KR100868387B1 (ko) | 2007-08-29 | 2008-11-12 | 한국화학연구원 | 동ㆍ식물유의 에스테르교환 반응용 촉매 제조방법 |
| US8039651B2 (en) * | 2007-10-31 | 2011-10-18 | Nippon Shokubai Co., Ltd. | Method for producing fatty acid alkyl ester and/or glycerin |
| PL2257518T3 (pl) * | 2008-04-01 | 2016-09-30 | Sposób wytwarzania estru alkilowego kwasu tłuszczowego z użyciem kwasu tłuszczowego | |
| WO2010020998A2 (en) * | 2008-07-30 | 2010-02-25 | Indian Oil Corporation Limited | A catalyst composition for transesterification of organically/naturally derived oils and fats to produce alkyl esters and process for preparing the same |
| FR2962727B1 (fr) | 2009-09-11 | 2012-08-10 | IFP Energies Nouvelles | Procede de preparation d'esters alcooliques et de glycerine a partir de triglycerides et d'alcools au moyen d'un catalyseur heterogene en presence d'eau en teneur controlee |
| FR2962728A1 (fr) * | 2009-09-11 | 2012-01-20 | Inst Francais Du Petrole | Procede de preparation d'esters alcooliques et de glycerine a partir de triglycerides et d'alcools au moyen d'un catalyseur heterogene en presence d'eau en teneur controlee |
| FR2951092B1 (fr) | 2009-10-14 | 2013-03-08 | Inst Francais Du Petrole | Catalyseur heterogene de type spinelle aluminate de zinc sur-stoechiometrique en zinc et son utilisation dans un procede de preparation d'esters alcooliques a partir de triglycerides et d'alcools |
| US20110092725A1 (en) * | 2009-10-19 | 2011-04-21 | Lurgi Psi, Inc. | Catalysis Of Fats And Oils To Alkyl Esters Using Hydrolysis As Pretreatment |
| KR100991418B1 (ko) | 2010-04-20 | 2010-11-03 | 애경유화 주식회사 | 아민고정화 염기촉매를 이용한 지방산 알킬 에스테르의 제조방법 |
| KR101000365B1 (ko) | 2010-04-30 | 2010-12-13 | 애경유화 주식회사 | 복합촉매를 이용한 지방산 알킬 에스테르를 제조하는 방법 |
| EP2450425B1 (en) * | 2010-11-08 | 2014-05-14 | Neste Oil Oyj | A method for lipid extraction from biomass |
| CN103370405B (zh) | 2011-02-14 | 2016-05-11 | 科学与工业研究委员会 | 使用生态友好固体碱催化剂由甘油三酯油制备脂肪酸烷基酯(生物柴油)的改进方法 |
| WO2012177348A1 (en) | 2011-06-21 | 2012-12-27 | W. R. Grace & Co.-Conn. | Catalytic purification of fatty acid alkyl esters used in fuels |
| CN103801282B (zh) * | 2012-11-12 | 2016-04-20 | 中国科学院大连化学物理研究所 | 一种固体碱催化剂及其制备和应用 |
| US9328054B1 (en) | 2013-09-27 | 2016-05-03 | Travis Danner | Method of alcoholisis of fatty acids and fatty acid gyicerides |
| TW201602336A (zh) | 2014-06-09 | 2016-01-16 | Ｗ Ｒ 康格雷氏公司 | 天然油及脂之催化脫氧方法 |
| US10654789B2 (en) * | 2017-03-14 | 2020-05-19 | The Hong Kong Polytechnic University Shenzhen Research Institute | Catalyst and method for biodiesel production from unrefined low-grade oil and crude aqueous alcohols |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2383601A (en) * | 1943-04-28 | 1945-08-28 | Colgate Palmolive Peet Co | Treating fats and fatty oils |
| US6245727B1 (en) * | 1989-03-20 | 2001-06-12 | Henkel Kommanditgesellschaft Auf Aktien | Discontinuous process for conducting a heterogeneously catalyzed reaction and installation for heterogeneously catalyzed manufacture of products |
| DE4122530A1 (de) * | 1991-07-08 | 1993-01-14 | Henkel Kgaa | Verfahren zur herstellung von fettsaeureniedrigalkylestern |
| FR2752242B1 (fr) * | 1996-08-08 | 1998-10-16 | Inst Francais Du Petrole | Procede de fabrication d'esters a partir d'huiles vegetales ou animales et d'alcools |
| FR2772756B1 (fr) * | 1997-12-18 | 2000-02-11 | Inst Francais Du Petrole | Procede de fabrication d'esters de corps gras et les esters de haute purete obtenus |
| PL198770B1 (pl) * | 2000-12-04 | 2008-07-31 | Westfalia Separator Ag | Sposób wstępnej obróbki surowych olejów i surowych tłuszczów do wytwarzania estrów kwasów tłuszczowych |
| FR2838433B1 (fr) * | 2002-04-11 | 2005-08-19 | Inst Francais Du Petrole | Procede de production d'esters alkyliques a partir d'une huile vegetale ou animale et d'un monoalcool aliphatique |
-
2003
- 2003-03-17 FR FR0303575A patent/FR2852602B1/fr not_active Expired - Fee Related
-
2004
- 2004-02-20 ES ES04290455T patent/ES2391392T3/es not_active Expired - Lifetime
- 2004-02-20 EP EP04290455A patent/EP1460124B1/fr not_active Expired - Lifetime
- 2004-03-13 MY MYPI20040892A patent/MY146016A/en unknown
- 2004-03-15 PL PL366276A patent/PL207033B1/pl unknown
- 2004-03-15 BR BRPI0400322A patent/BRPI0400322B8/pt not_active IP Right Cessation
- 2004-03-17 US US10/802,042 patent/US7420073B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| BRPI0400322B1 (pt) | 2013-11-26 |
| US7420073B2 (en) | 2008-09-02 |
| PL366276A1 (en) | 2004-09-20 |
| MY146016A (en) | 2012-06-15 |
| FR2852602A1 (fr) | 2004-09-24 |
| EP1460124B1 (fr) | 2012-07-11 |
| BRPI0400322B8 (pt) | 2016-05-17 |
| EP1460124A1 (fr) | 2004-09-22 |
| US20050113588A1 (en) | 2005-05-26 |
| PL207033B1 (pl) | 2010-10-29 |
| FR2852602B1 (fr) | 2007-08-10 |
| ES2391392T3 (es) | 2012-11-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06F | Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette] | ||
| B07A | Technical examination (opinion): publication of technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 15/03/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B16C | Correction of notification of the grant |
Free format text: REFERENTE A PUBLICACAO NA RPI 2238 DE 26/11/2013 QUANTO A FORMATACAO DO DOCUMENTO. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 12A ANUIDADE. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2370 DE 07-06-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |