BR9913065A - Material de eletrodo positivo de alta capacidade e vida longa em ciclos, processo de fabricação do mesmo, e, material de eletrodo positivo hidróxido de nìquel de alta capacidade - Google Patents
Material de eletrodo positivo de alta capacidade e vida longa em ciclos, processo de fabricação do mesmo, e, material de eletrodo positivo hidróxido de nìquel de alta capacidadeInfo
- Publication number
- BR9913065A BR9913065A BR9913065-3A BR9913065A BR9913065A BR 9913065 A BR9913065 A BR 9913065A BR 9913065 A BR9913065 A BR 9913065A BR 9913065 A BR9913065 A BR 9913065A
- Authority
- BR
- Brazil
- Prior art keywords
- positive electrode
- electrode material
- capacity
- long
- manufacturing process
- Prior art date
Links
- 239000007774 positive electrode material Substances 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- BFDHFSHZJLFAMC-UHFFFAOYSA-L nickel(ii) hydroxide Chemical compound [OH-].[OH-].[Ni+2] BFDHFSHZJLFAMC-UHFFFAOYSA-L 0.000 title abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 230000004913 activation Effects 0.000 abstract 1
- 239000011149 active material Substances 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000003607 modifier Substances 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/04—Oxides; Hydroxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/006—Compounds containing, besides nickel, two or more other elements, with the exception of oxygen or hydrogen
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/34—Gastight accumulators
- H01M10/345—Gastight metal hydride accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/24—Electrodes for alkaline accumulators
- H01M4/32—Nickel oxide or hydroxide electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/77—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by unit-cell parameters, atom positions or structure diagrams
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/78—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by stacking-plane distances or stacking sequences
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/32—Spheres
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/30—Nickel accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
"MATERIAL DE ELETRODO POSITIVO DE ALTA CAPACIDADE E VIDA LONGA EM CICLOS, PROCESSO DE FABRICAçãO DO MESMO, E, MATERIAL DE ELETRODO POSITIVO HIDRóXIDO DE NìQUEL DE ALTA CAPACIDADE". é descrito um material para eletrodo positivo de hidróxido de níquel modificado, com alta capacidade e vida longa em ciclos, para uso em células alcalinas recarregáveis com pelo menos um modificador, que tem energia de ativação, potencial químico e condutividade elétrica modificados. Tamanho de partícula, distribuição de tamanho de partícula, condutividade elétrica foram controladas introduzindo-se elementos modificadores na massa de material ativo e controlando-se parâmetros de processo.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/135,477 US6228535B1 (en) | 1998-08-17 | 1998-08-17 | Nickel hydroxide positive electrode material exhibiting improved conductivity and engineered activation energy |
PCT/US1999/018362 WO2000010211A1 (en) | 1998-08-17 | 1999-08-12 | Nickel hydroxide positive electrode material exhibiting improved conductivity and engineered activation energy |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9913065A true BR9913065A (pt) | 2001-09-25 |
Family
ID=22468282
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9913065-3A BR9913065A (pt) | 1998-08-17 | 1999-08-12 | Material de eletrodo positivo de alta capacidade e vida longa em ciclos, processo de fabricação do mesmo, e, material de eletrodo positivo hidróxido de nìquel de alta capacidade |
Country Status (11)
Country | Link |
---|---|
US (3) | US6228535B1 (pt) |
EP (3) | EP1744387A3 (pt) |
JP (1) | JP2002522893A (pt) |
KR (1) | KR100542597B1 (pt) |
AU (1) | AU5397999A (pt) |
BR (1) | BR9913065A (pt) |
CA (1) | CA2339213A1 (pt) |
DE (1) | DE69938928D1 (pt) |
MX (1) | MX234116B (pt) |
TW (1) | TW477086B (pt) |
WO (1) | WO2000010211A1 (pt) |
Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
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JP3191752B2 (ja) * | 1996-12-26 | 2001-07-23 | 松下電器産業株式会社 | ニッケル−水素二次電池およびその電極の製造方法 |
US6228535B1 (en) * | 1998-08-17 | 2001-05-08 | Ovonic Battery Company, Inc. | Nickel hydroxide positive electrode material exhibiting improved conductivity and engineered activation energy |
JP4474722B2 (ja) * | 2000-03-21 | 2010-06-09 | パナソニック株式会社 | アルカリ蓄電池とそれに用いるアルカリ蓄電池用正極 |
TW520575B (en) | 2000-04-21 | 2003-02-11 | Sony Corp | Positive electrode material and nickel-zinc battery |
WO2001097305A1 (fr) * | 2000-06-16 | 2001-12-20 | Matsushita Electric Industrial Co., Ltd. | Matiere active d'anode pour accumulateur alcalin, anode comprenant cette matiere et accumulateur alcalin |
MX241166B (es) * | 2001-06-29 | 2006-10-16 | Ovonic Battery Co | Bacteria de almacenamiento de hidrogeno; electrodo de niquel positivo; material activo de electrodo positivo y metodos para fabricarlos. |
DE10132895A1 (de) * | 2001-07-06 | 2003-01-16 | Starck H C Gmbh | Nickelhydroxid und Verfahren zu dessen Herstellung |
WO2004027901A2 (en) * | 2002-09-17 | 2004-04-01 | Diffusion Science, Inc. | Electrochemical generation, storage and reaction of hydrogen and oxygen using gas permeable catalyst-coated hollow microspheres |
US6830725B2 (en) * | 2003-04-01 | 2004-12-14 | Texaco Ovonic Battery Systems, Llc | Hydrogen storage alloys having a high porosity surface layer |
US7175826B2 (en) * | 2003-12-29 | 2007-02-13 | General Electric Company | Compositions and methods for hydrogen storage and recovery |
US7211541B2 (en) * | 2003-12-11 | 2007-05-01 | Ovonic Hydrogen Systems Llc | Mg—Ni hydrogen storage composite having high storage capacity and excellent room temperature kinetics |
EP1719195B1 (en) * | 2004-01-08 | 2009-06-17 | Ovonic Battery Company, Inc. | Positive electrode active material for a nickel electrode |
US7344677B2 (en) * | 2004-04-02 | 2008-03-18 | Ovonic Battery Company, Inc. | Hydrogen storage alloys having improved cycle life and low temperature operating characteristics |
CN100405658C (zh) * | 2004-07-23 | 2008-07-23 | 日本无公害电池研究所 | 电池用镍极及使用该镍极的碱性蓄电池 |
US20060057019A1 (en) | 2004-09-16 | 2006-03-16 | Kwo Young | Hydrogen storage alloys having reduced PCT hysteresis |
US8802294B2 (en) * | 2006-12-22 | 2014-08-12 | Panasonic Corporation | Nickel hydroxide, method for producing positive electrode active material for non-aqueous electrolyte secondary battery, electrode for non-aqueous electrolyte secondary battery, and non-aqueous electrolyte secondary battery |
US9425456B2 (en) | 2012-02-07 | 2016-08-23 | Ovonic Battery Company, Inc. | Rechargeable battery cell with improved high temperature performance |
US9406934B2 (en) | 2012-02-07 | 2016-08-02 | Basf Corporation | Rechargeable battery cell with improved high temperature performance |
JP6090673B2 (ja) | 2012-09-28 | 2017-03-08 | 株式会社Gsユアサ | アルカリ蓄電池とアルカリ蓄電池用の正極材 |
JP6585063B2 (ja) * | 2014-09-11 | 2019-10-02 | 株式会社東芝 | 電極材料およびそれを用いた電極層、電池並びにエレクトロクロミック素子 |
WO2016079746A1 (en) | 2014-11-19 | 2016-05-26 | Technion Research & Development Foundation Limited | Methods and system for hydrogen production by water electrolysis |
US9935315B2 (en) | 2015-02-05 | 2018-04-03 | Basf Corporation | Nickel hydroxide positive electrode for alkaline rechargeable battery |
US9899676B2 (en) | 2015-02-05 | 2018-02-20 | Basf Corporation | Nickel hydroxide positive electrode for alkaline rechargeable battery |
WO2016126622A1 (en) * | 2015-02-05 | 2016-08-11 | Basf Corporation | Nickel hydroxide positive electrode for alkaline rechargeable battery |
US10587012B2 (en) | 2015-03-26 | 2020-03-10 | Basf Corporation | Electrolyte compositions comprising ionic liquids and metal hydride batteries comprising same |
KR20180091938A (ko) * | 2016-01-05 | 2018-08-16 | 바스프 코포레이션 | 알칼리 재충전식 배터리를 위한 수산화니켈 복합 물질 |
US10326165B2 (en) | 2016-03-28 | 2019-06-18 | Basf Corporation | Silicon-based solid electrolyte for rechargeable battery |
WO2018018036A1 (en) | 2016-07-22 | 2018-01-25 | Fluidic, Inc. | Moisture and carbon dioxide management system in electrochemical cells |
US11394035B2 (en) | 2017-04-06 | 2022-07-19 | Form Energy, Inc. | Refuelable battery for the electric grid and method of using thereof |
US11611115B2 (en) | 2017-12-29 | 2023-03-21 | Form Energy, Inc. | Long life sealed alkaline secondary batteries |
EP3815167A4 (en) | 2018-06-29 | 2022-03-16 | Form Energy, Inc. | ELECTROCHEMICAL CELL BASED ON AQUEOUS POLYSULFIDE |
US11552290B2 (en) | 2018-07-27 | 2023-01-10 | Form Energy, Inc. | Negative electrodes for electrochemical cells |
EP3961767A4 (en) * | 2019-04-26 | 2024-02-21 | Kyocera Corporation | SECONDARY BATTERY AND SECONDARY BATTERY SYSTEM |
US11949129B2 (en) | 2019-10-04 | 2024-04-02 | Form Energy, Inc. | Refuelable battery for the electric grid and method of using thereof |
WO2022145027A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Ionic liquid electrolytes including salt additives for use in proton-conducting rechargeable batteries |
WO2022145031A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Processes of hydrogen annealing of si-surfaces |
WO2022145028A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Group 14 element-containing metal hydrides with a superlattice structure for use in proton-conducting rechargeable batteries |
WO2022145026A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Si-containing alloy for the anode of proton-conducting rechargeable batteries |
US20240063376A1 (en) | 2020-12-29 | 2024-02-22 | Kawasaki Motors, Ltd. | Bulk si-anode for use in proton-conducting rechargeable batteries |
WO2022145030A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Salt containing electrolytes that promote the formation of proton-conducting rechargeable batteries |
WO2022145029A1 (en) | 2020-12-29 | 2022-07-07 | Kawasaki Motors, Ltd. | Group 14 element-containing metal hydride with a superlattice structure for use in hydrogen storage. |
WO2022239204A1 (en) | 2021-05-13 | 2022-11-17 | Kawasaki Motors, Ltd. | Bipolar battery with proton and hydroxide ion conducting polymer based separator |
CN117546335A (zh) | 2021-06-21 | 2024-02-09 | 川崎摩托株式会社 | 质子传导性充电电池及方法 |
WO2023007751A1 (en) | 2021-07-30 | 2023-02-02 | Kawasaki Motors, Ltd. | Si-containing metal hydrides with expanded superlattice structure for use in proton-conducting rechargeable electrochemical cells |
Family Cites Families (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS6045131B2 (ja) * | 1980-04-24 | 1985-10-08 | 同和鉱業株式会社 | アルカリ電池用活物質の製造法 |
US5700596A (en) * | 1991-07-08 | 1997-12-23 | Matsushita Electric Industrial Co., Ltd. | Nickel hydroxide active material powder and nickel positive electrode and alkali storage battery using them |
JPH0541213A (ja) * | 1991-08-06 | 1993-02-19 | Sanyo Electric Co Ltd | アルカリ蓄電池用非焼結式ニツケル正極 |
US5348822A (en) * | 1992-11-12 | 1994-09-20 | Ovonic Battery Company, Inc. | Chemically and compositionally modified solid solution disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells |
US5344728A (en) * | 1992-11-12 | 1994-09-06 | Ovonic Battery Company, Inc. | Compositionally and structurally disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells |
US5861225A (en) * | 1992-11-12 | 1999-01-19 | Ovonic Battery Company, Inc. | Nickel battery electrode having multiple composition nickel hydroxide active materials |
US5523182A (en) * | 1992-11-12 | 1996-06-04 | Ovonic Battery Company, Inc. | Enhanced nickel hydroxide positive electrode materials for alkaline rechargeable electrochemical cells |
KR0148827B1 (ko) * | 1994-05-20 | 1998-10-15 | 전성원 | 알카리전지용 고밀도 수산화니켈의 제조방법 |
FR2731297B1 (fr) * | 1995-03-03 | 1997-04-04 | Accumulateurs Fixes | Electrode au nickel pour accumulateur alcalin |
JP3196605B2 (ja) * | 1995-10-24 | 2001-08-06 | 松下電器産業株式会社 | 非焼結式ニッケル正極及びその正極を用いたアルカリ蓄電池 |
KR100373724B1 (ko) * | 1995-12-15 | 2003-05-16 | 삼성에스디아이 주식회사 | 알칼리축전지용양극및음극극판과그제조방법 |
US5788943A (en) * | 1996-09-05 | 1998-08-04 | The Hall Chemical Company | Battery-grade nickel hydroxide and method for its preparation |
EP1195824B1 (en) * | 1996-09-20 | 2011-10-05 | Panasonic Corporation | Positive electrode active material for alkaline storage batteries |
AU7671096A (en) * | 1996-11-07 | 1998-05-29 | Energy Conversion Devices Inc. | Beta to gamma phase cycleable electrochemically active nickel hydroxide material |
CN1129198C (zh) | 1997-02-03 | 2003-11-26 | 松下电器产业株式会社 | 碱性蓄电池的正极活性材料的制造方法 |
JP3094062B2 (ja) * | 1998-01-30 | 2000-10-03 | 東芝電池株式会社 | ペースト式ニッケル極の製造方法及びアルカリ蓄電池の製造方法 |
US6228535B1 (en) * | 1998-08-17 | 2001-05-08 | Ovonic Battery Company, Inc. | Nickel hydroxide positive electrode material exhibiting improved conductivity and engineered activation energy |
US6576205B2 (en) * | 2001-09-04 | 2003-06-10 | Inco Limited | Method for reducing the crystallinity of nickel hydroxide powders |
-
1998
- 1998-08-17 US US09/135,477 patent/US6228535B1/en not_active Expired - Lifetime
-
1999
- 1999-08-12 CA CA002339213A patent/CA2339213A1/en not_active Abandoned
- 1999-08-12 EP EP06023021A patent/EP1744387A3/en not_active Withdrawn
- 1999-08-12 EP EP99939741A patent/EP1110258B1/en not_active Expired - Lifetime
- 1999-08-12 JP JP2000565575A patent/JP2002522893A/ja active Pending
- 1999-08-12 EP EP06003365A patent/EP1672724A3/en not_active Withdrawn
- 1999-08-12 KR KR1020017001992A patent/KR100542597B1/ko not_active IP Right Cessation
- 1999-08-12 BR BR9913065-3A patent/BR9913065A/pt not_active Application Discontinuation
- 1999-08-12 DE DE69938928T patent/DE69938928D1/de not_active Expired - Lifetime
- 1999-08-12 AU AU53979/99A patent/AU5397999A/en not_active Abandoned
- 1999-08-12 WO PCT/US1999/018362 patent/WO2000010211A1/en active IP Right Grant
- 1999-08-20 TW TW088113991A patent/TW477086B/zh not_active IP Right Cessation
-
2000
- 2000-10-11 US US09/686,567 patent/US6447953B1/en not_active Expired - Lifetime
-
2001
- 2001-02-12 MX MXPA01001583 patent/MX234116B/es active IP Right Grant
-
2002
- 2002-08-30 US US10/232,031 patent/US7294434B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
KR100542597B1 (ko) | 2006-01-16 |
EP1672724A2 (en) | 2006-06-21 |
TW477086B (en) | 2002-02-21 |
EP1744387A2 (en) | 2007-01-17 |
MXPA01001583A (es) | 2003-04-22 |
MX234116B (en) | 2006-02-02 |
CA2339213A1 (en) | 2000-02-24 |
US6447953B1 (en) | 2002-09-10 |
US20030035996A1 (en) | 2003-02-20 |
EP1110258A1 (en) | 2001-06-27 |
EP1110258A4 (en) | 2006-06-28 |
KR20010072693A (ko) | 2001-07-31 |
EP1672724A3 (en) | 2006-10-25 |
WO2000010211A1 (en) | 2000-02-24 |
DE69938928D1 (de) | 2008-07-31 |
EP1110258B1 (en) | 2008-06-18 |
EP1744387A3 (en) | 2007-07-18 |
JP2002522893A (ja) | 2002-07-23 |
US7294434B2 (en) | 2007-11-13 |
US6228535B1 (en) | 2001-05-08 |
AU5397999A (en) | 2000-03-06 |
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