BR9706970A - Processo para a preparação de condensados e adutos contendo amino e uso das frações poliméricas de elevado peso molecular - Google Patents
Processo para a preparação de condensados e adutos contendo amino e uso das frações poliméricas de elevado peso molecularInfo
- Publication number
- BR9706970A BR9706970A BR9706970A BR9706970A BR9706970A BR 9706970 A BR9706970 A BR 9706970A BR 9706970 A BR9706970 A BR 9706970A BR 9706970 A BR9706970 A BR 9706970A BR 9706970 A BR9706970 A BR 9706970A
- Authority
- BR
- Brazil
- Prior art keywords
- condensates
- adducts
- pct
- amino
- preparation
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/91—Graft copolymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/01—Separation of suspended solid particles from liquids by sedimentation using flocculating agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
- B01D61/14—Ultrafiltration; Microfiltration
- B01D61/145—Ultrafiltration
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/0206—Polyalkylene(poly)amines
- C08G73/0213—Preparatory process
- C08G73/0226—Quaternisation of polyalkylene(poly)amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
- C08G73/02—Polyamines
- C08G73/028—Polyamidoamines
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
- D21H17/56—Polyamines; Polyimines; Polyester-imides
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/06—Paper forming aids
- D21H21/10—Retention agents or drainage improvers
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/20—Macromolecular organic compounds
- D21H17/33—Synthetic macromolecular compounds
- D21H17/46—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D21H17/54—Synthetic macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Organic Chemistry (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Water Supply & Treatment (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Engineering & Computer Science (AREA)
- Dermatology (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Paper (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Polyamides (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Laminated Bodies (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE1996100366 DE19600366A1 (de) | 1996-01-08 | 1996-01-08 | Verfahren zur Herstellung von wasserlöslichen, Ethylenimin-Einheiten enthaltenden Polymeren und ihre Verwendung |
DE1996121300 DE19621300A1 (de) | 1996-05-28 | 1996-05-28 | Verfahren zur Erhöhung der Wirksamkeit von wasserlöslichen, Aminogruppen enthaltenden Kondensaten und Additionsprodukten und ihre Verwendung |
PCT/EP1997/000009 WO1997025367A1 (de) | 1996-01-08 | 1997-01-03 | Verfahren zur herstellung von wasserlöslichen, aminogruppen enthaltenden kondensaten und additionsprodukten und ihre verwendung |
Publications (1)
Publication Number | Publication Date |
---|---|
BR9706970A true BR9706970A (pt) | 1999-04-06 |
Family
ID=26021927
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR9706970A BR9706970A (pt) | 1996-01-08 | 1997-01-03 | Processo para a preparação de condensados e adutos contendo amino e uso das frações poliméricas de elevado peso molecular |
Country Status (14)
Country | Link |
---|---|
US (1) | US6056967A (pt) |
EP (1) | EP0873371B1 (pt) |
JP (1) | JP2000505124A (pt) |
KR (1) | KR100468801B1 (pt) |
CN (1) | CN1105134C (pt) |
AT (1) | ATE186932T1 (pt) |
AU (1) | AU711553B2 (pt) |
BR (1) | BR9706970A (pt) |
DE (1) | DE59700753D1 (pt) |
ES (1) | ES2140954T3 (pt) |
NO (1) | NO983128L (pt) |
NZ (1) | NZ325851A (pt) |
PT (1) | PT873371E (pt) |
WO (1) | WO1997025367A1 (pt) |
Families Citing this family (33)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE19850817A1 (de) | 1998-11-04 | 2000-05-11 | Basf Ag | Modifizierte kationische Polymere, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Papierherstellung |
DE19921507A1 (de) * | 1999-05-10 | 2000-11-16 | Basf Ag | Verfahren zur Fraktionierung von in Wasser löslichen oder dispergierbaren aminogruppenhaltigen Polymeren mit breiter Molmassenverteilung |
US6551986B1 (en) * | 2000-02-16 | 2003-04-22 | The Procter & Gamble Company | Fabric enhancement compositions |
DE10029028A1 (de) * | 2000-06-13 | 2001-12-20 | Basf Ag | Verwendung von acylierten Polyaminen zur Modifizierung von Oberflächen |
US20050043506A1 (en) * | 2000-09-27 | 2005-02-24 | Michigan Biotechnology Institute | Polyamide materials based on unsaturated carboxylic acids and amines |
US6495657B1 (en) | 2000-10-27 | 2002-12-17 | Michigan Biotechnology Institute | Two dimensional polyamides prepared from unsaturated carboxylic acids and amines |
US6797743B2 (en) * | 2000-09-27 | 2004-09-28 | Michigan Biotechnology Institute | Antimicrobial polymer |
US6426121B1 (en) * | 2000-10-17 | 2002-07-30 | Air Products Polymers, L.P. | Dual crosslinkable emulsion polymers at ambient conditions |
WO2003043670A1 (en) | 2001-11-21 | 2003-05-30 | Basf Aktiengesellschaft | Crosslinked polyamine coating on superabsorbent hydrogels |
US6939554B2 (en) * | 2002-02-05 | 2005-09-06 | Michigan Biotechnology Institute | Antimicrobial polymer |
US7204940B2 (en) | 2002-03-20 | 2007-04-17 | Michigan Biotechnology Institute | Conductive polymer-based material |
EP1369448A1 (de) * | 2002-06-07 | 2003-12-10 | Bayer Ag | Verfahren zur Herstellung von polymeren Kondensaten und ihre Verwendung |
US6951902B2 (en) * | 2002-08-16 | 2005-10-04 | Michigan Biotechnology Institute | Two dimensional polymer that generates nitric oxide |
CA2461629C (en) * | 2003-03-24 | 2012-05-08 | Nof Corporation | Paper additive composition and method for producing paper using the same |
DE102004058587A1 (de) | 2004-12-03 | 2006-06-14 | Basf Ag | Verfahren zur Herstellung von Papieren mit hohen Flächengewichten |
JP2009520849A (ja) * | 2005-12-22 | 2009-05-28 | クラリアント インターナショナル リミティド | 紙およびボードの生産用乾燥強度系 |
US7932349B2 (en) * | 2006-09-18 | 2011-04-26 | Hercules Incorporated | Membrane separation process for removing residuals polyamine-epihalohydrin resins |
US7868071B2 (en) * | 2007-07-30 | 2011-01-11 | Georgia-Pacific Chemicals Llc | Method of stabilizing aqueous cationic polymers |
WO2010020551A1 (de) | 2008-08-18 | 2010-02-25 | Basf Se | Verfahren zur erhöhung der trockenfestigkeit von papier, pappe und karton |
ES2691384T3 (es) * | 2008-09-02 | 2018-11-27 | Basf Se | Procedimiento para la fabricación de papel, cartón y cartulina usando endo-beta-1,4-glucanasas como agente de drenaje |
US8926797B2 (en) * | 2009-06-16 | 2015-01-06 | Basf Se | Method for increasing the dry strength of paper, paperboard, and cardboard |
DE102010026490A1 (de) | 2010-07-07 | 2012-01-12 | Basf Se | Verfahren zur Herstellung von feinstrukturierten Oberflächen |
US9296896B2 (en) | 2010-11-23 | 2016-03-29 | Basf Se | Polyamides with nanoparticles on the surface |
KR101905206B1 (ko) | 2010-11-23 | 2018-10-05 | 바스프 에스이 | 표면 상에 나노입자를 갖는 폴리아미드 |
CN103443204A (zh) | 2011-01-18 | 2013-12-11 | 巴斯夫欧洲公司 | 热塑性模塑组合物 |
US8486427B2 (en) | 2011-02-11 | 2013-07-16 | Kimberly-Clark Worldwide, Inc. | Wipe for use with a germicidal solution |
JP2014534249A (ja) * | 2011-11-25 | 2014-12-18 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | 水素の存在下でのアルコールの均一系接触アミノ化による低い色数を有するポリアルキレンポリアミンの合成 |
PT2809845T (pt) | 2012-02-01 | 2019-03-22 | Basf Se | Processo para o fabrico de papel e cartão |
WO2013127731A1 (en) | 2012-03-01 | 2013-09-06 | Basf Se | Process for the manufacture of paper and paperboard |
US9051687B2 (en) | 2012-08-22 | 2015-06-09 | Basf Se | Production of paper, card and board |
CA2897185C (en) | 2013-01-11 | 2018-10-09 | Basf Se | Process for the manufacture of paper and paperboard |
CN107223171A (zh) | 2014-12-16 | 2017-09-29 | 巴斯夫欧洲公司 | 制造纸和纸板的方法 |
EP3173449A1 (de) | 2015-11-27 | 2017-05-31 | BASF Coatings GmbH | Verbund aus zwei festkörpern |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2182306A (en) * | 1935-05-10 | 1939-12-05 | Ig Farbenindustrie Ag | Polymerization of ethylene imines |
US3203910A (en) * | 1962-04-13 | 1965-08-31 | Dow Chemical Co | Polymerization of alkylenimines |
DE1771814C2 (de) * | 1968-07-16 | 1974-05-09 | Bayer Ag, 5090 Leverkusen | Hilfsmittel-Verwendung für die Papierfabrikation |
DE2162567A1 (de) * | 1970-12-23 | 1972-07-20 | Sandoz Ag | Verfahren zur Herstellung von kationischen wasserlöslichen, hitzehärtbaren, stark verzweigten Harzen |
US4144123A (en) * | 1974-07-19 | 1979-03-13 | Basf Aktiengesellschaft | Incorporating a crosslinked polyamidoamine condensation product into paper-making pulp |
DE2436386C2 (de) * | 1974-07-29 | 1982-09-23 | Basf Ag, 6700 Ludwigshafen | Verwendung stickstoffhaltiger Kondensationsprodukte |
DE2916356C2 (de) * | 1979-04-23 | 1982-06-09 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von wasserlöslichen Polyätheraminen |
DE3925439A1 (de) * | 1989-08-01 | 1991-02-07 | Bayer Ag | Basische kondensate |
US5055197A (en) * | 1991-04-05 | 1991-10-08 | Rohm And Haas Company | Process for removing residual monomers and oligemers from amine-containing polymers |
DE4240110A1 (de) * | 1992-11-28 | 1994-06-01 | Basf Ag | Kondensationsprodukte von Polyalkylenpolyaminen, Verfahren zu ihrer Herstellung und ihre Verwendung bei der Herstellung von Papier |
DE4244194A1 (de) * | 1992-12-24 | 1994-06-30 | Basf Ag | Wasserlösliche Kondensationsprodukte aus Aminogruppen enthaltenden Verbindungen und Vernetzern, Verfahren zu ihrer Herstellung und ihre Verwendung |
DE4319934A1 (de) * | 1993-06-16 | 1994-12-22 | Basf Ag | Gepfropfte Polyamidoamine und gepfropfte Polyethylenimine, Verfahren zu ihrer Herstellung und ihre Verwendung als Zusatz zu Waschmitteln |
-
1997
- 1997-01-03 US US09/101,184 patent/US6056967A/en not_active Expired - Lifetime
- 1997-01-03 JP JP9524835A patent/JP2000505124A/ja active Pending
- 1997-01-03 AT AT97900557T patent/ATE186932T1/de active
- 1997-01-03 WO PCT/EP1997/000009 patent/WO1997025367A1/de active IP Right Grant
- 1997-01-03 PT PT97900557T patent/PT873371E/pt unknown
- 1997-01-03 AU AU13094/97A patent/AU711553B2/en not_active Ceased
- 1997-01-03 BR BR9706970A patent/BR9706970A/pt not_active IP Right Cessation
- 1997-01-03 NZ NZ325851A patent/NZ325851A/xx unknown
- 1997-01-03 ES ES97900557T patent/ES2140954T3/es not_active Expired - Lifetime
- 1997-01-03 KR KR10-1998-0705183A patent/KR100468801B1/ko not_active IP Right Cessation
- 1997-01-03 DE DE59700753T patent/DE59700753D1/de not_active Expired - Lifetime
- 1997-01-03 EP EP97900557A patent/EP0873371B1/de not_active Expired - Lifetime
- 1997-01-03 CN CN97192627A patent/CN1105134C/zh not_active Expired - Fee Related
-
1998
- 1998-07-07 NO NO983128A patent/NO983128L/no not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
NO983128L (no) | 1998-09-07 |
AU711553B2 (en) | 1999-10-14 |
US6056967A (en) | 2000-05-02 |
JP2000505124A (ja) | 2000-04-25 |
KR19990077050A (ko) | 1999-10-25 |
NZ325851A (en) | 1999-06-29 |
PT873371E (pt) | 2000-05-31 |
KR100468801B1 (ko) | 2005-07-11 |
ATE186932T1 (de) | 1999-12-15 |
ES2140954T3 (es) | 2000-03-01 |
DE59700753D1 (de) | 1999-12-30 |
WO1997025367A1 (de) | 1997-07-17 |
CN1212713A (zh) | 1999-03-31 |
EP0873371B1 (de) | 1999-11-24 |
EP0873371A1 (de) | 1998-10-28 |
CN1105134C (zh) | 2003-04-09 |
AU1309497A (en) | 1997-08-01 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
FF | Decision: intention to grant | ||
HHFF | Decision: republication | ||
FG9A | Patent or certificate of addition granted | ||
B24C | Patent annual fee: request for for restoration |
Free format text: REFERENTE A 11A E 12A ANUIDADE(S). |
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B24H | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi) | ||
B24F | Patent annual fee: publication cancelled |
Free format text: ANULADA A PUBLICACAO CODIGO 24.8 NA RPI NO 2258 DE 15/04/2014 POR TER SIDO INDEVIDA. |
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B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE AS 11A E 12A ANUIDADES. |
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B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2607 DE 22-12-2020 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |