BR112022021798A2 - Processo para a remoção de metais pesados de uma composição contendo ácido fosfórico usando um tensoativo polimérico iônico e uso do dito tensoativo na precipitação de metais pesados em uma composição contendo ácido fosfórico - Google Patents
Processo para a remoção de metais pesados de uma composição contendo ácido fosfórico usando um tensoativo polimérico iônico e uso do dito tensoativo na precipitação de metais pesados em uma composição contendo ácido fosfóricoInfo
- Publication number
- BR112022021798A2 BR112022021798A2 BR112022021798A BR112022021798A BR112022021798A2 BR 112022021798 A2 BR112022021798 A2 BR 112022021798A2 BR 112022021798 A BR112022021798 A BR 112022021798A BR 112022021798 A BR112022021798 A BR 112022021798A BR 112022021798 A2 BR112022021798 A2 BR 112022021798A2
- Authority
- BR
- Brazil
- Prior art keywords
- phosphoric acid
- heavy metals
- composition containing
- surfactant
- containing phosphoric
- Prior art date
Links
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title abstract 14
- 229910000147 aluminium phosphate Inorganic materials 0.000 title abstract 7
- 229910001385 heavy metal Inorganic materials 0.000 title abstract 7
- 239000004094 surface-active agent Substances 0.000 title abstract 6
- 238000000034 method Methods 0.000 title abstract 3
- 238000001556 precipitation Methods 0.000 title abstract 3
- 239000002563 ionic surfactant Substances 0.000 title 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 abstract 1
- 238000000184 acid digestion Methods 0.000 abstract 1
- 229910052793 cadmium Inorganic materials 0.000 abstract 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 abstract 1
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 229910017604 nitric acid Inorganic materials 0.000 abstract 1
- 239000002367 phosphate rock Substances 0.000 abstract 1
- 229920002401 polyacrylamide Polymers 0.000 abstract 1
- 230000001376 precipitating effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B25/00—Phosphorus; Compounds thereof
- C01B25/16—Oxyacids of phosphorus; Salts thereof
- C01B25/18—Phosphoric acid
- C01B25/234—Purification; Stabilisation; Concentration
- C01B25/237—Selective elimination of impurities
- C01B25/238—Cationic impurities, e.g. arsenic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09B—DISPOSAL OF SOLID WASTE NOT OTHERWISE PROVIDED FOR
- B09B3/00—Destroying solid waste or transforming solid waste into something useful or harmless
- B09B3/80—Destroying solid waste or transforming solid waste into something useful or harmless involving an extraction step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B11/00—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes
- C05B11/04—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid
- C05B11/06—Fertilisers produced by wet-treating or leaching raw materials either with acids in such amounts and concentrations as to yield solutions followed by neutralisation, or with alkaline lyes using mineral acid using nitric acid (nitrophosphates)
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F11/00—Treatment of sludge; Devices therefor
- C02F11/12—Treatment of sludge; Devices therefor by de-watering, drying or thickening
- C02F11/121—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering
- C02F11/127—Treatment of sludge; Devices therefor by de-watering, drying or thickening by mechanical de-watering by centrifugation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/20—Heavy metals or heavy metal compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/10—Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
- C07F9/301—Acyclic saturated acids which can have further substituents on alkyl
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Water Supply & Treatment (AREA)
- Removal Of Specific Substances (AREA)
Abstract
PROCESSO PARA A REMOÇÃO DE METAIS PESADOS DE UMA COMPOSIÇÃO CONTENDO ÁCIDO FOSFÓRICO USANDO UM TENSOATIVO POLIMÉRICO IÔNICO E USO DO DITO TENSOATIVO NA PRECIPITAÇÃO DE METAIS PESADOS EM UMA COMPOSIÇÃO CONTENDO ÁCIDO FOSFÓRICO. A presente descrição provê métodos aprimorados para a remoção de metais pesados, em particular cádmio, de uma composição aquosa contendo ácido fosfórico, em que um agente de precipitação de metal pesado organotiofosforado e um tensoativo polimérico iônico, particularmente um tensoativo copolimérico de poliacrilamida catiônica, são ambos adicionados a uma composição contendo ácido fosfórico, particularmente sob condições de mistura suaves, tais como entre 500 e 700 rpm. O tensoativo polimérico iônico promove a precipitação dos metais pesados. Mais particularmente, a composição contendo ácido fosfórico é obtida pela digestão ácida de rocha fosfatada, preferencialmente por ácido nítrico, ácido sulfúrico ou uma combinação dos mesmos.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP20180341.8A EP3925710A1 (en) | 2020-06-16 | 2020-06-16 | Method for treating solid hazardous heavy metal-containing compositions |
| EP20195110.0A EP3964477A1 (en) | 2020-09-08 | 2020-09-08 | Process for the removal of heavy metals from a phosphoric acid containing composition using an ionic polymeric surfactant |
| PCT/EP2021/066246 WO2021255097A1 (en) | 2020-06-16 | 2021-06-16 | Process for the removal of heavy metals from a phosphoric acid containing composition using an ionic polymeric surfactant and use of said surfactant in the precipitation of heavy metals in a phosphoric acid containing composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112022021798A2 true BR112022021798A2 (pt) | 2022-12-27 |
Family
ID=76695700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112022021798A BR112022021798A2 (pt) | 2020-06-16 | 2021-06-16 | Processo para a remoção de metais pesados de uma composição contendo ácido fosfórico usando um tensoativo polimérico iônico e uso do dito tensoativo na precipitação de metais pesados em uma composição contendo ácido fosfórico |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US20230234847A1 (pt) |
| EP (1) | EP4164985A1 (pt) |
| AU (1) | AU2021290982A1 (pt) |
| BR (1) | BR112022021798A2 (pt) |
| CA (1) | CA3180517A1 (pt) |
| WO (1) | WO2021255097A1 (pt) |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SE418845B (sv) | 1979-05-10 | 1981-06-29 | Boliden Ab | Forfarande for rening av vatprocessfosforsyra |
| CA1126285A (en) | 1980-01-31 | 1982-06-22 | Allan J. Robertson | Preparation of dialkyldithiophosphinates |
| DE3212675A1 (de) | 1982-04-05 | 1983-10-06 | Hoechst Ag | Verfahren zur abtrennung von schwermetallverbindungen aus zwischenprodukten der fabrikation von phosphorduengemitteln |
| NO164768C (no) | 1988-03-04 | 1990-11-14 | Norsk Hydro As | Fremgangsmaate for fjerning av tungmetaller, spesielt kadmium, fra fosforsyreholdige loesninger. |
| US20040179984A1 (en) | 2003-03-13 | 2004-09-16 | Nagaraj D. R. | Process for removing metal impurities from wet process phosphoric acid and compositions thereof |
| WO2019071108A2 (en) | 2017-10-08 | 2019-04-11 | Cytec Industries Inc. | COMPOSITIONS AND METHODS FOR REMOVING HEAVY METALS FROM PHOSPHORIC ACID SOURCES |
-
2021
- 2021-06-16 BR BR112022021798A patent/BR112022021798A2/pt unknown
- 2021-06-16 AU AU2021290982A patent/AU2021290982A1/en active Pending
- 2021-06-16 WO PCT/EP2021/066246 patent/WO2021255097A1/en unknown
- 2021-06-16 US US18/008,880 patent/US20230234847A1/en active Pending
- 2021-06-16 CA CA3180517A patent/CA3180517A1/en active Pending
- 2021-06-16 EP EP21730453.4A patent/EP4164985A1/en active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| US20230234847A1 (en) | 2023-07-27 |
| AU2021290982A1 (en) | 2023-02-09 |
| EP4164985A1 (en) | 2023-04-19 |
| CN115605430A (zh) | 2023-01-13 |
| WO2021255097A1 (en) | 2021-12-23 |
| CA3180517A1 (en) | 2021-12-23 |
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