BR112018069301A2 - procedimento para a valorização de compostos oxigenados presentes em frações aquosas derivadas de biomassa - Google Patents
procedimento para a valorização de compostos oxigenados presentes em frações aquosas derivadas de biomassaInfo
- Publication number
- BR112018069301A2 BR112018069301A2 BR112018069301A BR112018069301A BR112018069301A2 BR 112018069301 A2 BR112018069301 A2 BR 112018069301A2 BR 112018069301 A BR112018069301 A BR 112018069301A BR 112018069301 A BR112018069301 A BR 112018069301A BR 112018069301 A2 BR112018069301 A2 BR 112018069301A2
- Authority
- BR
- Brazil
- Prior art keywords
- biomass
- procedure
- compounds present
- recovery
- aqueous fractions
- Prior art date
Links
- 239000002028 Biomass Substances 0.000 title abstract 4
- 239000012223 aqueous fraction Substances 0.000 title abstract 3
- 150000001875 compounds Chemical class 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000011084 recovery Methods 0.000 title abstract 2
- 239000000203 mixture Substances 0.000 abstract 3
- 239000003054 catalyst Substances 0.000 abstract 2
- 230000003197 catalytic effect Effects 0.000 abstract 2
- 239000007788 liquid Substances 0.000 abstract 2
- 239000008346 aqueous phase Substances 0.000 abstract 1
- 150000001491 aromatic compounds Chemical class 0.000 abstract 1
- 239000000446 fuel Substances 0.000 abstract 1
- 229930195733 hydrocarbon Natural products 0.000 abstract 1
- 150000002430 hydrocarbons Chemical class 0.000 abstract 1
- 239000012074 organic phase Substances 0.000 abstract 1
- 150000002927 oxygen compounds Chemical class 0.000 abstract 1
- 238000000926 separation method Methods 0.000 abstract 1
- 230000009466 transformation Effects 0.000 abstract 1
- 238000011282 treatment Methods 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
- C10G3/42—Catalytic treatment
- C10G3/44—Catalytic treatment characterised by the catalyst used
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/10—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of rare earths
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/20—Vanadium, niobium or tantalum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/30—Tungsten
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/847—Vanadium, niobium or tantalum or polonium
- B01J23/8474—Niobium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/888—Tungsten
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- B01J35/30—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0236—Drying, e.g. preparing a suspension, adding a soluble salt and drying
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/08—Heat treatment
- B01J37/10—Heat treatment in the presence of water, e.g. steam
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/03—Precipitation; Co-precipitation
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/1011—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/70—Catalyst aspects
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/30—Aromatics
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P30/00—Technologies relating to oil refining and petrochemical industry
- Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Thermal Sciences (AREA)
- Physics & Mathematics (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Catalysts (AREA)
- Processing Of Solid Wastes (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
procedimento para a valorização de compostos oxigenados presentes em frações aquosas derivadas de biomassa refere-se a um procedimento para a produção de misturas de hidrocarbonetos e compostos aromáticos, para seu posterior uso como componentes de combustíveis (de preferência, na faixa de c5 a c16), mediante a transformação catalítica de compostos oxigenados presentes em frações aquosas derivadas de tratamentos primários da biomassa, que pode compreender pelo menos as seguintes etapas: i) colocar a mistura aquosa contendo os compostos oxigenados derivados da biomassa em contato com um catalizador que compreende pelo menos w e/ou nb e combinações de nb e w com outros elementos, ii) fazer a mistura reagir com o catalizador em um reator catalítico a temperaturas entre 50 e 450 °c e pressões de 0,1 a 12 mpa (1 a 120 bar); e iii) recuperar os produtos obtidos mediante um processo de separação líquido/líquido das fases aquosa e orgânica.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
ES201630339A ES2638719B1 (es) | 2016-03-22 | 2016-03-22 | Procedimiento para la valorización de compuestos oxigenados presentes en fracciones acuosas derivadas de biomasa |
ESP201630339 | 2016-03-22 | ||
PCT/ES2017/070167 WO2017162900A1 (es) | 2016-03-22 | 2017-03-22 | Procedimiento para la valorización de compuestos oxigenados presentes en fracciones acuosas derivadas de biomasa |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112018069301A2 true BR112018069301A2 (pt) | 2019-01-22 |
BR112018069301B1 BR112018069301B1 (pt) | 2022-03-29 |
Family
ID=59899982
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112018069301-4A BR112018069301B1 (pt) | 2016-03-22 | 2017-03-22 | Procedimento para a valorização de compostos orgânicos oxigenados presentes em frações aquosas derivadas de biomassa |
Country Status (6)
Country | Link |
---|---|
US (1) | US10876049B2 (pt) |
EP (1) | EP3434364A4 (pt) |
JP (1) | JP6944947B2 (pt) |
BR (1) | BR112018069301B1 (pt) |
ES (1) | ES2638719B1 (pt) |
WO (1) | WO2017162900A1 (pt) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2732747B2 (es) * | 2018-05-25 | 2020-07-02 | Consejo Superior Investigacion | Proceso catalitico para la produccion de hidrocarburos y compuestos aromaticos a partir de compuestos oxigenados presentes en mezclas acuosas |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU2009285699B2 (en) * | 2008-08-27 | 2014-04-10 | Virent, Inc. | Synthesis of liquid fuels from biomass |
CN101870881B (zh) | 2010-06-21 | 2013-04-24 | 中国科学院广州能源研究所 | 一种生物油水相催化提质制取液体烷烃燃料方法 |
BR112013005821A2 (pt) | 2010-09-14 | 2019-09-24 | Radlein Desmond | métodos de transformação de bio-óleo em combustíveis de hidrocarboneto do tipo de transporte |
KR101748442B1 (ko) * | 2010-10-21 | 2017-06-19 | 에스케이이노베이션 주식회사 | 바이오매스 혹은 유기성 폐기물로부터 탄화수소를 제조하는 방법 |
US20120222349A1 (en) * | 2011-03-03 | 2012-09-06 | Conocophillips Company | One-step hydrodeoxygenation and reformation of alditols |
US20130079566A1 (en) | 2011-09-27 | 2013-03-28 | Nevada, | Catalytic process for conversion of biomass into hydrocarbon fuels |
US9382185B2 (en) * | 2013-03-15 | 2016-07-05 | Virent, Inc. | Processes for converting biomass-derived feedstocks to chemicals and liquid fuels |
KR102063945B1 (ko) * | 2013-06-05 | 2020-01-09 | 에스케이이노베이션 주식회사 | 바이오매스 유래 아세트산으로부터 방향족 화합물을 제조하는 방법 |
-
2016
- 2016-03-22 ES ES201630339A patent/ES2638719B1/es active Active
-
2017
- 2017-03-22 WO PCT/ES2017/070167 patent/WO2017162900A1/es active Application Filing
- 2017-03-22 US US16/087,803 patent/US10876049B2/en active Active
- 2017-03-22 BR BR112018069301-4A patent/BR112018069301B1/pt active IP Right Grant
- 2017-03-22 JP JP2018550388A patent/JP6944947B2/ja active Active
- 2017-03-22 EP EP17769506.1A patent/EP3434364A4/en active Pending
Also Published As
Publication number | Publication date |
---|---|
JP6944947B2 (ja) | 2021-10-06 |
EP3434364A4 (en) | 2020-05-27 |
EP3434364A1 (en) | 2019-01-30 |
ES2638719A1 (es) | 2017-10-23 |
JP2019512530A (ja) | 2019-05-16 |
WO2017162900A1 (es) | 2017-09-28 |
US10876049B2 (en) | 2020-12-29 |
US20190367816A1 (en) | 2019-12-05 |
ES2638719B1 (es) | 2018-08-01 |
BR112018069301B1 (pt) | 2022-03-29 |
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B350 | Update of information on the portal [chapter 15.35 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 22/03/2017, OBSERVADAS AS CONDICOES LEGAIS. |