BR112017015797A2 - sistema e método para preparação de pó de pentóxido de vanádio de alta pureza - Google Patents
sistema e método para preparação de pó de pentóxido de vanádio de alta purezaInfo
- Publication number
- BR112017015797A2 BR112017015797A2 BR112017015797-7A BR112017015797A BR112017015797A2 BR 112017015797 A2 BR112017015797 A2 BR 112017015797A2 BR 112017015797 A BR112017015797 A BR 112017015797A BR 112017015797 A2 BR112017015797 A2 BR 112017015797A2
- Authority
- BR
- Brazil
- Prior art keywords
- chlorination
- vanadium pentoxide
- high purity
- gas
- purity vanadium
- Prior art date
Links
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 title abstract 10
- 238000000034 method Methods 0.000 title abstract 3
- 239000000843 powder Substances 0.000 title abstract 3
- 238000005660 chlorination reaction Methods 0.000 abstract 6
- 150000003863 ammonium salts Chemical class 0.000 abstract 2
- 238000001354 calcination Methods 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 238000001556 precipitation Methods 0.000 abstract 2
- JBIQAPKSNFTACH-UHFFFAOYSA-K vanadium oxytrichloride Chemical compound Cl[V](Cl)(Cl)=O JBIQAPKSNFTACH-UHFFFAOYSA-K 0.000 abstract 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000003546 flue gas Substances 0.000 abstract 1
- 238000011031 large-scale manufacturing process Methods 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/02—Oxides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/02—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping in boilers or stills
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D3/00—Distillation or related exchange processes in which liquids are contacted with gaseous media, e.g. stripping
- B01D3/14—Fractional distillation or use of a fractionation or rectification column
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/06—Solidifying liquids
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/24—Stationary reactors without moving elements inside
- B01J19/245—Stationary reactors without moving elements inside placed in series
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
- B01J6/001—Calcining
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
- B01J8/0055—Separating solid material from the gas/liquid stream using cyclones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1818—Feeding of the fluidising gas
- B01J8/1827—Feeding of the fluidising gas the fluidising gas being a reactant
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1836—Heating and cooling the reactor
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G31/00—Compounds of vanadium
- C01G31/04—Halides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00743—Feeding or discharging of solids
- B01J2208/00752—Feeding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00743—Feeding or discharging of solids
- B01J2208/00761—Discharging
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/80—Compositional purity
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
a presente invenção provê um sistema e um método para a preparação de um pó de pentóxido de vanádio de alta pureza. um pentóxido de vanádio de grau industrial é convertido em oxitricloreto de vanádio por uma cloração de fluidização de baixa temperatura, em que um gás de cloração é pré-aquecido através de uma troca de calor entre um gás de fluidização e um gás de combustão de cloração, e uma quantidade apropriada de ar é adicionada para se permitir que uma parte do pó de carbono queime de modo a se obter um suprimento de calor equilibrado durante a cloração, desse modo se aumentando a eficiência de cloração e garantindo uma boa seletividade em uma cloração à baixa temperatura. o oxitricloreto de vanádio é submetido a uma purificação por retificação, precipitação de sal de amônio e calcinação fluidizada, desse modo se obtendo um pentóxido de vanádio de alta pureza, em que o gás de amônia produzido durante uma calcinação é condensado e, então, reciclado para precipitação de sal de amônio. o sistema e o método têm vantagens de adaptabilidade favorável para uma matéria-prima, menos poluição, baixo consumo de energia na produção e baixo custo de operação, uma qualidade de produto estável e assim por diante, e são adequados para uma produção em larga escala de um pó de pentóxido de vanádio de alta pureza com uma pureza acima de 4n.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510052262.7 | 2015-01-30 | ||
| CN201510052262.7A CN105984900B (zh) | 2015-01-30 | 2015-01-30 | 一种制备高纯五氧化二钒粉体的系统及方法 |
| PCT/CN2016/072517 WO2016119716A1 (zh) | 2015-01-30 | 2016-01-28 | 一种制备高纯五氧化二钒粉体的系统及方法 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR112017015797A2 true BR112017015797A2 (pt) | 2018-06-19 |
Family
ID=56542443
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR112017015797-7A BR112017015797A2 (pt) | 2015-01-30 | 2016-01-28 | sistema e método para preparação de pó de pentóxido de vanádio de alta pureza |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US10053371B2 (pt) |
| EP (1) | EP3243798B8 (pt) |
| JP (1) | JP6347903B2 (pt) |
| CN (1) | CN105984900B (pt) |
| AU (1) | AU2016212538B2 (pt) |
| BR (1) | BR112017015797A2 (pt) |
| CA (1) | CA2973491C (pt) |
| NZ (1) | NZ733920A (pt) |
| PH (1) | PH12017550059A1 (pt) |
| RU (1) | RU2663777C1 (pt) |
| WO (1) | WO2016119716A1 (pt) |
| ZA (1) | ZA201704629B (pt) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105984897B (zh) * | 2015-01-30 | 2017-05-17 | 中国科学院过程工程研究所 | 一种生产高纯五氧化二钒粉体的系统及方法 |
| CN105984896B (zh) * | 2015-01-30 | 2017-06-13 | 中国科学院过程工程研究所 | 一种提纯制备高纯五氧化二钒粉体的系统及方法 |
| CN105984898B (zh) * | 2015-01-30 | 2017-06-13 | 中国科学院过程工程研究所 | 一种生产高纯四氧化二钒粉体的系统及方法 |
| CN106257726B (zh) * | 2016-01-28 | 2018-03-23 | 中国科学院过程工程研究所 | 一种生产高纯度高活性钒电解液的系统及方法 |
| CN108622936B (zh) * | 2017-03-17 | 2020-02-18 | 中国科学院过程工程研究所 | 一种高效清洁氯化法制备高纯五氧化二钒粉体的系统及方法 |
| CN109835951B (zh) * | 2017-11-24 | 2020-04-14 | 中国科学院过程工程研究所 | 一种氯化法生产粉钒的系统和方法 |
| CN110683579B (zh) * | 2018-07-06 | 2020-12-11 | 中国科学院过程工程研究所 | 一种四氯化钛精制除钒尾渣生产高纯五氧化二钒的方法 |
| CN109338112B (zh) * | 2018-11-28 | 2020-03-31 | 湖南众鑫新材料科技股份有限公司 | 一种五氧化二钒提纯的方法 |
| CN114408971B (zh) * | 2022-02-28 | 2024-04-26 | 武汉科技大学 | 一种清洁高效制备99级五氧化二钒的方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| US3355244A (en) * | 1965-05-14 | 1967-11-28 | Nat Distillers Chem Corp | Production of vanadium oxytrichloride |
| EP0103940A1 (en) * | 1982-08-16 | 1984-03-28 | Stauffer Chemical Company | Process for preparing vanadium halides |
| FR2563206B1 (fr) * | 1984-04-24 | 1986-06-13 | Elf Aquitaine | Nouveau procede de synthese de l'oxyde de vanadium |
| IT1196515B (it) * | 1986-07-17 | 1988-11-16 | Ente Minerario Siciliano | Procedimento per il recupero con alte rese del vanadio da residui della combustione del petrolio |
| JP3085634B2 (ja) | 1994-11-17 | 2000-09-11 | 鹿島北共同発電株式会社 | 高純度バナジウム電解液の製造法 |
| RU2175990C1 (ru) * | 2000-04-05 | 2001-11-20 | Открытое акционерное общество "АВИСМА титано-магниевый комбинат" | Способ получения пентаоксида ванадия |
| JP2005200231A (ja) * | 2004-01-13 | 2005-07-28 | Kashima Kita Electric Power Corp | メタバナジン酸アンモニウムの製造方法 |
| RU41719U1 (ru) * | 2004-06-01 | 2004-11-10 | Общество с ограниченной ответственностью Научно-производственная экологическая фирма "ЭКО-технология" | Технологическая линия для получения пентаоксида ванадия |
| RU41021U1 (ru) * | 2004-06-01 | 2004-10-10 | Общество с ограниченной ответственностью Научно-производственная экологическая фирма "ЭКО-технология" | Производственный участок для получения товарного пентаоксида ванадия |
| CN1843938A (zh) | 2006-04-30 | 2006-10-11 | 宿素满 | 一种五氧化二钒的生产方法 |
| CN101845552B (zh) * | 2010-04-23 | 2012-03-21 | 河北钢铁股份有限公司承德分公司 | 一种钒渣梯度氯化回收有价元素的方法 |
| CN102234117B (zh) * | 2010-05-05 | 2015-11-25 | 刘基扬 | 一种含可水解卤原子的物质的水解方法 |
| CN102730757A (zh) | 2011-04-03 | 2012-10-17 | 崇阳县恒通工贸有限公司 | 一种用偏钒酸铵制备高纯五氧化二钒的方法 |
| CN102181635A (zh) | 2011-04-08 | 2011-09-14 | 北京矿冶研究总院 | 一种石煤钒矿硫酸浸出液制备五氧化二钒的方法 |
| CN103130279B (zh) * | 2011-11-29 | 2015-08-05 | 刘艳梅 | 一种氯化生产高纯五氧化二钒的方法 |
| CN103515642A (zh) | 2012-06-25 | 2014-01-15 | 中国人民解放军63971部队 | 一种高纯度高浓度钒电池电解液的制备方法 |
| CN102923775A (zh) | 2012-11-27 | 2013-02-13 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种高纯度五氧化二钒的制备方法 |
| CN103145187B (zh) | 2013-03-22 | 2014-11-05 | 中南大学 | 一种无害化高纯五氧化二钒的生产工艺 |
| CN103194603B (zh) | 2013-04-01 | 2015-06-10 | 攀枝花学院 | 高纯五氧化二钒的制备方法 |
| CN103606694B (zh) | 2013-11-15 | 2015-07-08 | 河北钢铁股份有限公司承德分公司 | 一种商用钒电池电解液的制备方法 |
| CN103663557B (zh) | 2014-01-07 | 2015-06-17 | 湖南有色金属研究院 | 一种粗钒制备高纯五氧化二钒的方法 |
| CN103787414B (zh) | 2014-01-26 | 2016-04-13 | 贵州义信矿业有限公司 | 焙烧法钒溶液制取高纯五氧化二钒的方法 |
| CN103922403B (zh) * | 2014-03-24 | 2015-09-16 | 攀钢集团攀枝花钢铁研究院有限公司 | 一种多钒酸铵流态化生产粉状五氧化二钒的方法 |
| CN105984897B (zh) * | 2015-01-30 | 2017-05-17 | 中国科学院过程工程研究所 | 一种生产高纯五氧化二钒粉体的系统及方法 |
| CN105984898B (zh) * | 2015-01-30 | 2017-06-13 | 中国科学院过程工程研究所 | 一种生产高纯四氧化二钒粉体的系统及方法 |
| CN105984896B (zh) * | 2015-01-30 | 2017-06-13 | 中国科学院过程工程研究所 | 一种提纯制备高纯五氧化二钒粉体的系统及方法 |
| CN105984899B (zh) * | 2015-01-30 | 2017-05-17 | 中国科学院过程工程研究所 | 一种提纯五氧化二钒的系统及方法 |
-
2015
- 2015-01-30 CN CN201510052262.7A patent/CN105984900B/zh active Active
-
2016
- 2016-01-28 JP JP2017558607A patent/JP6347903B2/ja not_active Expired - Fee Related
- 2016-01-28 EP EP16742778.0A patent/EP3243798B8/en not_active Not-in-force
- 2016-01-28 RU RU2017130365A patent/RU2663777C1/ru not_active IP Right Cessation
- 2016-01-28 BR BR112017015797-7A patent/BR112017015797A2/pt not_active IP Right Cessation
- 2016-01-28 US US15/547,076 patent/US10053371B2/en active Active
- 2016-01-28 WO PCT/CN2016/072517 patent/WO2016119716A1/zh active Application Filing
- 2016-01-28 CA CA2973491A patent/CA2973491C/en not_active Expired - Fee Related
- 2016-01-28 NZ NZ733920A patent/NZ733920A/en not_active IP Right Cessation
- 2016-01-28 AU AU2016212538A patent/AU2016212538B2/en not_active Ceased
-
2017
- 2017-07-10 ZA ZA2017/04629A patent/ZA201704629B/en unknown
- 2017-07-28 PH PH12017550059A patent/PH12017550059A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20180022616A1 (en) | 2018-01-25 |
| AU2016212538A1 (en) | 2017-08-31 |
| EP3243798B1 (en) | 2018-11-28 |
| JP2018505123A (ja) | 2018-02-22 |
| ZA201704629B (en) | 2019-06-26 |
| EP3243798A1 (en) | 2017-11-15 |
| CA2973491C (en) | 2020-01-28 |
| PH12017550059A1 (en) | 2018-02-05 |
| WO2016119716A1 (zh) | 2016-08-04 |
| CN105984900A (zh) | 2016-10-05 |
| EP3243798B8 (en) | 2019-05-22 |
| CA2973491A1 (en) | 2016-08-04 |
| NZ733920A (en) | 2018-08-31 |
| RU2663777C1 (ru) | 2018-08-09 |
| EP3243798A4 (en) | 2018-01-03 |
| JP6347903B2 (ja) | 2018-06-27 |
| CN105984900B (zh) | 2017-06-13 |
| AU2016212538B2 (en) | 2018-01-18 |
| US10053371B2 (en) | 2018-08-21 |
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