BR112017003585A2 - composições compreendendo um material de fibra e um aglutinante termoplástico - Google Patents
composições compreendendo um material de fibra e um aglutinante termoplásticoInfo
- Publication number
- BR112017003585A2 BR112017003585A2 BR112017003585A BR112017003585A BR112017003585A2 BR 112017003585 A2 BR112017003585 A2 BR 112017003585A2 BR 112017003585 A BR112017003585 A BR 112017003585A BR 112017003585 A BR112017003585 A BR 112017003585A BR 112017003585 A2 BR112017003585 A2 BR 112017003585A2
- Authority
- BR
- Brazil
- Prior art keywords
- polyester polyol
- present
- polyurethane polymer
- reinforced composite
- fiber reinforced
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
- C08J5/0405—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
- C08J5/043—Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/4009—Two or more macromolecular compounds not provided for in one single group of groups C08G18/42 - C08G18/64
- C08G18/4018—Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C45/00—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor
- B29C45/0005—Injection moulding, i.e. forcing the required volume of moulding material through a nozzle into a closed mould; Apparatus therefor using fibre reinforcements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4202—Two or more polyesters of different physical or chemical nature
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
- C08G18/4205—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups
- C08G18/4208—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups
- C08G18/4211—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols
- C08G18/4216—Polycondensates having carboxylic or carbonic ester groups in the main chain containing cyclic groups containing aromatic groups derived from aromatic dicarboxylic acids and dialcohols from mixtures or combinations of aromatic dicarboxylic acids and aliphatic dicarboxylic acids and dialcohols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4829—Polyethers containing at least three hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6633—Compounds of group C08G18/42
- C08G18/6637—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/664—Compounds of group C08G18/42 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
- C08G18/7671—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups containing only one alkylene bisphenyl group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/04—Reinforcing macromolecular compounds with loose or coherent fibrous material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/24—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
- C08J5/241—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
- C08J5/244—Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using glass fibres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/06—Polyurethanes from polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
- Reinforced Plastic Materials (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
a presente invenção refere-se a composições compreendendo um material de fibra e um aglutinante termoplástico específico. o aglutinante termoplástico compreende pelo menos um polímero de poliuretano termoplástico (a), em que o dito polímero de poliuretano termoplástico (a) compreende um produto de reação de (i) pelo menos um poliol de poliéster e (ii) pelo menos um poli-isocianato, opcionalmente pelo menos um diol (iii) que é diferente do poliol de poliéster (i) está contido. a razão molar dos grupos nco do dito poli-isocianato (ii) para a soma de grupos oh do dito poliol de poliéster (i) e do dito opcionalmente contendo diol (iii) é menos do que 1,00:1. o dito poliol de poliéster (i) compreende (a) pelo menos um poliol de poliéster semicristalino tendo um ponto de fusão (tm) de 40 a 180°c, e (b) pelo menos um poliol de poliéster não cristalino. além disso, a presente invenção refere-se a um compósito reforçado com fibra compreendendo uma matriz de polímero de poliuretano termofixo curada reforçada pela composição de acordo com a presente invenção. além disso, um método para a fabricação do compósito reforçado com fibra de acordo com a presente invenção e uso da composição ou do compósito reforçado com fibra em veículos ferroviários, veículos automotivos, aeronaves, barcos, veículos espaciais, motocicletas, bicicletas, artigos esportivos, capacetes, vestuário funcional, sapatos, peças de construção em pontes e edifícios ou palhetas de turbina eólica são descritos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14187022.0A EP3002309B1 (en) | 2014-09-30 | 2014-09-30 | Compositions comprising a fiber material and a thermoplastic binder |
PCT/EP2015/071417 WO2016050531A1 (en) | 2014-09-30 | 2015-09-18 | Compositions comprising a fiber material and a thermoplastic binder |
Publications (1)
Publication Number | Publication Date |
---|---|
BR112017003585A2 true BR112017003585A2 (pt) | 2017-12-05 |
Family
ID=51625950
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112017003585A BR112017003585A2 (pt) | 2014-09-30 | 2015-09-18 | composições compreendendo um material de fibra e um aglutinante termoplástico |
Country Status (11)
Country | Link |
---|---|
US (1) | US10526460B2 (pt) |
EP (1) | EP3002309B1 (pt) |
JP (1) | JP6701184B2 (pt) |
KR (1) | KR102396890B1 (pt) |
CN (1) | CN107075066B (pt) |
BR (1) | BR112017003585A2 (pt) |
CA (1) | CA2958436A1 (pt) |
ES (1) | ES2620980T3 (pt) |
MX (1) | MX2017004087A (pt) |
TW (1) | TW201615792A (pt) |
WO (1) | WO2016050531A1 (pt) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ITUB20150557A1 (it) * | 2015-03-12 | 2016-09-12 | Novamont Spa | Composizione legante e suo impiego in processi di produzione di pannelli in fibra di legno. |
EP3333209B1 (en) | 2016-12-07 | 2023-09-20 | Henkel AG & Co. KGaA | Thermoplastic polyurethane matrix resin |
EP3336116A1 (en) | 2016-12-16 | 2018-06-20 | Henkel AG & Co. KGaA | Compositions comprising a fiber material and a thermoplastic binder |
KR102001017B1 (ko) * | 2018-02-27 | 2019-07-17 | (주)부성텍스텍 | 내습윤성 탄소섬유 보강재의 제조방법 및 이에 의해 제조되는 내습윤성 탄소섬유 보강재 |
WO2019213932A1 (en) * | 2018-05-11 | 2019-11-14 | Covestro Deutschland Ag | Thermoplastic polyurethane composition and use thereof |
CN112601792B (zh) | 2018-08-23 | 2023-09-01 | 汉高股份有限及两合公司 | 可湿气固化的聚氨酯粘合剂组合物 |
EP3898739A4 (en) * | 2018-12-21 | 2022-08-03 | Dow Global Technologies Llc | TWO-PART SOLVENT-FREE ADHESIVE COMPOSITION |
CN110144149B (zh) * | 2019-04-28 | 2021-10-26 | 宁波激智科技股份有限公司 | 一种氟碳涂层涂布液及使用该涂层的太阳能背板 |
EP3738989A1 (en) * | 2019-05-17 | 2020-11-18 | Henkel AG & Co. KGaA | Sizing agent comprising a polyurethane polymer |
KR102187819B1 (ko) * | 2019-10-30 | 2020-12-08 | 주식회사 서연이화 | 천연 섬유를 함유한 차량의 내장재용 복합소재 및 그 제조방법 |
KR102187800B1 (ko) * | 2019-10-30 | 2020-12-08 | 주식회사 서연이화 | 천연 섬유를 함유한 차량의 내장재용 복합소재 및 그 제조방법 |
CN113690440B (zh) * | 2021-07-30 | 2023-01-10 | 深圳市研一新材料有限责任公司 | 一种电极浆料组合物、极片及其二次电池 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4836959B1 (pt) * | 1969-03-25 | 1973-11-08 | ||
DE2847808C2 (de) | 1978-11-02 | 1986-04-10 | Siemens AG, 1000 Berlin und 8000 München | Kontaktanordnung für Druckgasschalter |
DE3242089A1 (de) * | 1982-11-13 | 1984-05-17 | Basf Ag | Verfahren zur kontinuierlichen herstellung von halbzeug aus faserverstaerkten, thermoplastischen polyurethanen |
US4695509A (en) * | 1985-12-23 | 1987-09-22 | Allied Corporation | Polyamide fiber reinforcement in thermoset polyurethane composites |
US5418310A (en) * | 1990-04-27 | 1995-05-23 | Minnesota Mining And Manufacturing Company | Mixture of isocyanate-terminated polyurethane prepolymers having good adhesion |
NL1010568C1 (nl) * | 1998-11-16 | 2000-05-17 | Dsm Nv | Polyurethaan composiet. |
AR024533A1 (es) * | 1999-02-23 | 2002-10-16 | Huntsman Ici Chem Llc | Elastomeros de poliuretano provistos de una resistencia mejorada a la hidrolisis. |
US7182832B2 (en) | 2003-05-09 | 2007-02-27 | Lear Corporation | Adhesive precoated headliner materials |
KR100733150B1 (ko) | 2004-10-04 | 2007-06-27 | 롬 앤드 하아스 컴패니 | 반응성 핫-멜트 접착제 |
EP2058348A1 (en) | 2006-08-31 | 2009-05-13 | Ube Industries, Ltd. | Reactive hot-melt composition and molded article using the same |
EP2316866A1 (de) | 2009-10-29 | 2011-05-04 | Bayer MaterialScience AG | Wässrige Zubereitung auf Basis kristalliner oder semikristalliner Polyurethanpolymere |
US20120305295A1 (en) * | 2010-02-03 | 2012-12-06 | Showa Denko K.K. | Thermosetting composition |
CN102191730B (zh) * | 2010-03-09 | 2015-08-26 | 拜耳材料科技(中国)有限公司 | 聚氨酯弹性体道砟垫及其制备方法 |
CN104136477B (zh) * | 2012-02-28 | 2016-06-29 | 汉高股份有限及两合公司 | 具有相分离的双组分聚氨酯体系 |
PT2944662T (pt) * | 2014-05-16 | 2018-08-06 | Henkel Ag & Co Kgaa | Adesivo termofusível de poliuretano termoplástico |
EP2944661B1 (en) * | 2014-05-16 | 2019-09-18 | Henkel AG & Co. KGaA | Thermoplastic polyurethane hot melt adhesive |
-
2014
- 2014-09-30 ES ES14187022.0T patent/ES2620980T3/es active Active
- 2014-09-30 EP EP14187022.0A patent/EP3002309B1/en active Active
-
2015
- 2015-08-26 TW TW104127819A patent/TW201615792A/zh unknown
- 2015-09-18 JP JP2017517314A patent/JP6701184B2/ja active Active
- 2015-09-18 CA CA2958436A patent/CA2958436A1/en not_active Abandoned
- 2015-09-18 MX MX2017004087A patent/MX2017004087A/es active IP Right Grant
- 2015-09-18 CN CN201580052749.3A patent/CN107075066B/zh active Active
- 2015-09-18 WO PCT/EP2015/071417 patent/WO2016050531A1/en active Application Filing
- 2015-09-18 KR KR1020177008869A patent/KR102396890B1/ko active IP Right Grant
- 2015-09-18 BR BR112017003585A patent/BR112017003585A2/pt not_active Application Discontinuation
-
2017
- 2017-03-22 US US15/465,966 patent/US10526460B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
CA2958436A1 (en) | 2016-04-07 |
KR20170063661A (ko) | 2017-06-08 |
WO2016050531A1 (en) | 2016-04-07 |
ES2620980T3 (es) | 2017-06-30 |
JP6701184B2 (ja) | 2020-05-27 |
JP2017530240A (ja) | 2017-10-12 |
EP3002309A1 (en) | 2016-04-06 |
EP3002309B1 (en) | 2017-01-11 |
CN107075066B (zh) | 2020-04-07 |
CN107075066A (zh) | 2017-08-18 |
MX2017004087A (es) | 2017-06-12 |
KR102396890B1 (ko) | 2022-05-11 |
US20170190852A1 (en) | 2017-07-06 |
US10526460B2 (en) | 2020-01-07 |
TW201615792A (zh) | 2016-05-01 |
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