BR112016019834B1 - Método para produzir um catalisador, e, ferrierita - Google Patents

Método para produzir um catalisador, e, ferrierita Download PDF

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Publication number
BR112016019834B1
BR112016019834B1 BR112016019834-4A BR112016019834A BR112016019834B1 BR 112016019834 B1 BR112016019834 B1 BR 112016019834B1 BR 112016019834 A BR112016019834 A BR 112016019834A BR 112016019834 B1 BR112016019834 B1 BR 112016019834B1
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Brazil
Prior art keywords
iron
molecular sieve
hydrothermal
hours
temperature
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BR112016019834-4A
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English (en)
Portuguese (pt)
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BR112016019834A2 (enExample
Inventor
Guy Richard Chandler
Jillian Elaine Collier
Alexander Nicholas Michael Green
Desiree DURAN-MARTIN
Paul Richard Phillips
Raj Rao Rajaram
Stuart David Reid
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Johnson Matthey Public Limited Company
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Publication of BR112016019834A2 publication Critical patent/BR112016019834A2/pt
Publication of BR112016019834B1 publication Critical patent/BR112016019834B1/pt

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9404Removing only nitrogen compounds
    • B01D53/9409Nitrogen oxides
    • B01D53/9413Processes characterised by a specific catalyst
    • B01D53/9418Processes characterised by a specific catalyst for removing nitrogen oxides by selective catalytic reduction [SCR] using a reducing agent in a lean exhaust gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46Iron group metals or copper
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    • B01J29/072Iron group metals or copper
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    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
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    • B01D53/92Chemical or biological purification of waste gases of engine exhaust gases
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    • B01J29/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B01J29/66Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively containing iron group metals, noble metals or copper
    • B01J29/68Iron group metals or copper
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    • B01J29/72Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/76Iron group metals or copper
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    • B01J29/76Iron group metals or copper
    • B01J29/763CHA-type, e.g. Chabazite, LZ-218
    • BPERFORMING OPERATIONS; TRANSPORTING
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    • B01J29/82Phosphates
    • B01J29/84Aluminophosphates containing other elements, e.g. metals, boron
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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
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    • B01J37/0027Powdering
    • B01J37/0045Drying a slurry, e.g. spray drying
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • Inorganic Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
BR112016019834-4A 2014-02-28 2015-02-27 Método para produzir um catalisador, e, ferrierita BR112016019834B1 (pt)

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Application Number Priority Date Filing Date Title
US201461946065P 2014-02-28 2014-02-28
US61/946,065 2014-02-28
PCT/GB2015/050569 WO2015128663A1 (en) 2014-02-28 2015-02-27 Scr catalysts having improved low temperature performance, and methods of making and using the same

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BR112016019834A2 BR112016019834A2 (enExample) 2017-08-15
BR112016019834B1 true BR112016019834B1 (pt) 2021-09-28

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US (2) US10272419B2 (enExample)
EP (1) EP3110550B1 (enExample)
JP (1) JP6653661B2 (enExample)
KR (1) KR20160129030A (enExample)
CN (2) CN106029228A (enExample)
BR (1) BR112016019834B1 (enExample)
DE (1) DE112015001052T5 (enExample)
GB (1) GB2543165B (enExample)
RU (1) RU2702988C2 (enExample)
WO (1) WO2015128663A1 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE112015001052T5 (de) * 2014-02-28 2016-12-08 Johnson Matthey Public Limited Company SCR-Katalysatoren mit verbesserter Niedertemperaturleistung und Verfahren zur Herstellung und Verwendung derselben
EP3124435A4 (en) * 2014-03-26 2017-11-22 Mitsubishi Chemical Corporation Method for producing transition metal-containing zeolite, transition metal-containing zeolite obtained by said method, and exhaust gas purifying catalyst using said zeolite
KR20240051329A (ko) * 2015-02-27 2024-04-19 바스프 코포레이션 배기 가스 처리 시스템
GB2551871A (en) * 2016-04-22 2018-01-03 Johnson Matthey Plc STA-18, A new member of the SFW family of molecular sieve zeotypes, methods of preparation and use
JP7155108B2 (ja) * 2016-08-05 2022-10-18 ビーエーエスエフ コーポレーション 選択的触媒還元物品およびシステム
KR101879695B1 (ko) * 2016-12-02 2018-07-18 희성촉매 주식회사 2가 구리 이온들을 특정비율로 담지한 제올라이트, 이의 제조방법 및 이를 포함하는 촉매조성물
GB201705241D0 (en) * 2017-03-31 2017-05-17 Johnson Matthey Catalysts (Germany) Gmbh Catalyst composition
JP7700048B2 (ja) * 2019-05-09 2025-06-30 ビーエーエスエフ モバイル エミッションズ カタリスツ エルエルシー 炭酸銅を含む選択的触媒還元触媒
KR102465459B1 (ko) 2020-12-08 2022-11-10 한국생산기술연구원 바나듐 기반의 결정성 scr 촉매의 제조방법 및 이를 이용한 결정성 scr 촉매
CN114345402B (zh) * 2021-08-30 2024-09-17 武汉科技大学 一种铁基分子筛催化剂的制备方法
CN114950576B (zh) * 2022-06-20 2023-08-22 济南大学 一种提高金属基小孔分子筛水热稳定性的方法及所得产品和应用
CN117680190A (zh) * 2022-08-24 2024-03-12 中国神华能源股份有限公司国华电力分公司 一种蜂窝式高温脱硝催化剂及其制备方法
CN121001962A (zh) * 2023-05-12 2025-11-21 东曹株式会社 含铁fer型沸石及其制造方法
DE102024000427A1 (de) * 2024-02-09 2025-08-14 C&Cs Catalysts And Chemical Specialties Gmbh Katalysator mit niedriger Aktivierungstemperatur zur Einstellung des temperaturabhängigen Gleichgewichtes von ortho-para Wasserstoffgemischen

Family Cites Families (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4255349A (en) 1978-12-18 1981-03-10 Mobil Oil Corporation Conversion of synthesis gas with iron-containing catalyst
US4961917A (en) * 1989-04-20 1990-10-09 Engelhard Corporation Method for reduction of nitrogen oxides with ammonia using promoted zeolite catalysts
US5520895A (en) * 1994-07-07 1996-05-28 Mobil Oil Corporation Method for the reduction of nitrogen oxides using iron impregnated zeolites
US5552129A (en) * 1994-07-07 1996-09-03 Mobil Oil Corporation Catalytic system for the reduction of nitrogen oxides
FR2773144B1 (fr) * 1997-12-31 2000-02-04 Grande Paroisse Sa Catalyseur a base de ferrierite/fer pour la reduction catalytique de la teneur de gaz en protoxyde d'azote. son procede d'obtention. application au traitement de gaz industriels
DE102005022650A1 (de) * 2005-05-11 2006-11-16 Uhde Gmbh Verfahren zur Verringerung des Gehaltes an Stickoxiden in Gasen
JP5261189B2 (ja) 2005-12-14 2013-08-14 ビーエーエスエフ コーポレーション Nox選択的触媒還元効率の改善されたゼオライト触媒
JP4803487B2 (ja) * 2006-02-22 2011-10-26 株式会社豊田中央研究所 窒素酸化物選択還元触媒及びその製造方法
MY179762A (en) * 2007-03-26 2020-11-12 Pq Corp Novel microporous crystalline material comprising a molecular sieve or zeolite having an 8-ring pore opening structure and methods of making and using same
DE102009015592A1 (de) 2009-03-30 2010-10-07 Süd-Chemie AG Alterungsstabiler Katalysator zur Oxidation von NO zu NO2 in Abgasströmen
WO2010121257A1 (en) * 2009-04-17 2010-10-21 Johnson Matthey Public Limited Company Small pore molecular sieve supported copper catalysts durable against lean/rich aging for the reduction of nitrogen oxides
DE102009040352A1 (de) * 2009-09-05 2011-03-17 Johnson Matthey Catalysts (Germany) Gmbh Verfahren zur Herstellung eines SCR aktiven Zeolith-Katalysators sowie SCR aktiver Zeolith-Katalysator
JP2011125845A (ja) * 2009-11-19 2011-06-30 Ibiden Co Ltd ハニカム構造体の製造方法
RU2674020C2 (ru) * 2013-02-18 2018-12-04 Джонсон Мэтти Паблик Лимитед Компани СОСТАВ ЛОВУШКИ ДЛЯ NOx
DE112015001052T5 (de) * 2014-02-28 2016-12-08 Johnson Matthey Public Limited Company SCR-Katalysatoren mit verbesserter Niedertemperaturleistung und Verfahren zur Herstellung und Verwendung derselben
JP6126141B2 (ja) * 2014-05-30 2017-05-10 トヨタ自動車株式会社 排ガス浄化用触媒の製造方法

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