BR112016012327B1 - Processo para a produção de poliuretanos, poliuretano e uso de poliuretanos - Google Patents
Processo para a produção de poliuretanos, poliuretano e uso de poliuretanos Download PDFInfo
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- BR112016012327B1 BR112016012327B1 BR112016012327-1A BR112016012327A BR112016012327B1 BR 112016012327 B1 BR112016012327 B1 BR 112016012327B1 BR 112016012327 A BR112016012327 A BR 112016012327A BR 112016012327 B1 BR112016012327 B1 BR 112016012327B1
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- BR
- Brazil
- Prior art keywords
- polyurethane
- polyurethanes
- process according
- groups
- compounds
- Prior art date
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- 229920002635 polyurethane Polymers 0.000 title claims abstract description 91
- 239000004814 polyurethane Substances 0.000 title claims abstract description 91
- 238000000034 method Methods 0.000 title claims abstract description 26
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 22
- 239000012948 isocyanate Substances 0.000 claims abstract description 35
- 150000002513 isocyanates Chemical class 0.000 claims abstract description 35
- 239000003054 catalyst Substances 0.000 claims abstract description 30
- 229920000642 polymer Polymers 0.000 claims abstract description 19
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 18
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- 239000004970 Chain extender Substances 0.000 claims abstract description 16
- 239000000654 additive Substances 0.000 claims abstract description 16
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- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 12
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- 125000004434 sulfur atom Chemical group 0.000 claims abstract description 6
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- 238000006243 chemical reaction Methods 0.000 claims description 8
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- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
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- 229910052784 alkaline earth metal Inorganic materials 0.000 claims 1
- 150000001342 alkaline earth metals Chemical class 0.000 claims 1
- 125000000129 anionic group Chemical group 0.000 claims 1
- 125000002091 cationic group Chemical group 0.000 claims 1
- 150000001768 cations Chemical class 0.000 claims 1
- 125000001472 tertiary aliphatic amine group Chemical group 0.000 claims 1
- 125000001302 tertiary amino group Chemical group 0.000 claims 1
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- 150000003624 transition metals Chemical class 0.000 claims 1
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- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
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- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
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- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 2
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- 239000004433 Thermoplastic polyurethane Substances 0.000 description 2
- 229910001413 alkali metal ion Inorganic materials 0.000 description 2
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 description 2
- 230000001588 bifunctional effect Effects 0.000 description 2
- 229910052797 bismuth Inorganic materials 0.000 description 2
- 150000001718 carbodiimides Chemical group 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 125000002843 carboxylic acid group Chemical group 0.000 description 2
- KLSBASGQHCAVHQ-UHFFFAOYSA-L disodium;2-hydroxy-2-sulfinatoacetate Chemical compound [Na+].[Na+].[O-]C(=O)C(O)S([O-])=O KLSBASGQHCAVHQ-UHFFFAOYSA-L 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
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- 230000006872 improvement Effects 0.000 description 2
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical group OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 2
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- 229920002803 thermoplastic polyurethane Polymers 0.000 description 2
- IUTCEZPPWBHGIX-UHFFFAOYSA-N tin(2+) Chemical class [Sn+2] IUTCEZPPWBHGIX-UHFFFAOYSA-N 0.000 description 2
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- GEEGPFGTMRWCID-UHFFFAOYSA-N 1-n,1-n,1-n',1-n'-tetramethylbutane-1,1-diamine Chemical compound CCCC(N(C)C)N(C)C GEEGPFGTMRWCID-UHFFFAOYSA-N 0.000 description 1
- HORQAOAYAYGIBM-UHFFFAOYSA-N 2,4-dinitrophenylhydrazine Chemical compound NNC1=CC=C([N+]([O-])=O)C=C1[N+]([O-])=O HORQAOAYAYGIBM-UHFFFAOYSA-N 0.000 description 1
- JZRJVXYQKBRUMY-UHFFFAOYSA-N 2-[bis[3-(dimethylamino)propyl]amino]ethanol Chemical compound CN(C)CCCN(CCO)CCCN(C)C JZRJVXYQKBRUMY-UHFFFAOYSA-N 0.000 description 1
- BFSVOASYOCHEOV-UHFFFAOYSA-N 2-diethylaminoethanol Chemical compound CCN(CC)CCO BFSVOASYOCHEOV-UHFFFAOYSA-N 0.000 description 1
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- TXXWBTOATXBWDR-UHFFFAOYSA-N n,n,n',n'-tetramethylhexane-1,6-diamine Chemical compound CN(C)CCCCCCN(C)C TXXWBTOATXBWDR-UHFFFAOYSA-N 0.000 description 1
- BXYVQNNEFZOBOZ-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-n',n'-dimethylpropane-1,3-diamine Chemical compound CN(C)CCCNCCCN(C)C BXYVQNNEFZOBOZ-UHFFFAOYSA-N 0.000 description 1
- YBEFXFBAXWUBNQ-UHFFFAOYSA-N n-methylmethanamine;propan-1-amine Chemical compound CNC.CCCN YBEFXFBAXWUBNQ-UHFFFAOYSA-N 0.000 description 1
- 239000005445 natural material Substances 0.000 description 1
- 150000002924 oxiranes Chemical class 0.000 description 1
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 description 1
- 229960004624 perflexane Drugs 0.000 description 1
- ZJIJAJXFLBMLCK-UHFFFAOYSA-N perfluorohexane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F ZJIJAJXFLBMLCK-UHFFFAOYSA-N 0.000 description 1
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- 229920005906 polyester polyol Polymers 0.000 description 1
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- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 239000011527 polyurethane coating Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- ADRDEXBBJTUCND-UHFFFAOYSA-N pyrrolizidine Chemical compound C1CCN2CCCC21 ADRDEXBBJTUCND-UHFFFAOYSA-N 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 239000012279 sodium borohydride Substances 0.000 description 1
- 229910000033 sodium borohydride Inorganic materials 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- SGHFQOUMIOXWEM-UHFFFAOYSA-M sodium hydroxy-(2-hydroxyphenyl)methanesulfinate Chemical compound [Na+].OC(c1ccccc1O)S([O-])=O SGHFQOUMIOXWEM-UHFFFAOYSA-M 0.000 description 1
- FMDFPSSMTNQSIV-UHFFFAOYSA-M sodium hydroxy-(4-methoxyphenyl)methanesulfinate Chemical compound [Na+].COc1ccc(cc1)C(O)S([O-])=O FMDFPSSMTNQSIV-UHFFFAOYSA-M 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- UOULCEYHQNCFFH-UHFFFAOYSA-M sodium;hydroxymethanesulfonate Chemical compound [Na+].OCS([O-])(=O)=O UOULCEYHQNCFFH-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- CSABAZBYIWDIDE-UHFFFAOYSA-N sulfino hydrogen sulfite Chemical class OS(=O)OS(O)=O CSABAZBYIWDIDE-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- IMFACGCPASFAPR-UHFFFAOYSA-N tributylamine Chemical compound CCCCN(CCCC)CCCC IMFACGCPASFAPR-UHFFFAOYSA-N 0.000 description 1
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical group NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 239000012855 volatile organic compound Substances 0.000 description 1
- PYQMDBXJLFCVAS-UHFFFAOYSA-L zinc 2-hydroxy-2-sulfinatoacetate Chemical compound [Zn++].OC(C([O-])=O)S([O-])=O PYQMDBXJLFCVAS-UHFFFAOYSA-L 0.000 description 1
Classifications
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- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08J9/0014—Use of organic additives
- C08J9/0033—Use of organic additives containing sulfur
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/1808—Catalysts containing secondary or tertiary amines or salts thereof having alkylene polyamine groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/3278—Hydroxyamines containing at least three hydroxy groups
- C08G18/3281—Hydroxyamines containing at least three hydroxy groups containing three hydroxy groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/40—High-molecular-weight compounds
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- C08G18/5024—Polyethers having heteroatoms other than oxygen having nitrogen containing primary and/or secondary amino groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
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-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
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- C08G18/725—Combination of polyisocyanates of C08G18/78 with other polyisocyanates
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
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- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
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- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/41—Compounds containing sulfur bound to oxygen
- C08K5/42—Sulfonic acids; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2207/00—Foams characterised by their intended use
- C08J2207/06—Electrical wire insulation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2375/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
- C08J2375/04—Polyurethanes
- C08J2375/08—Polyurethanes from polyethers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Polyurethanes Or Polyureas (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13195356 | 2013-12-02 | ||
| EP13195356.4 | 2013-12-02 | ||
| PCT/EP2014/075387 WO2015082242A1 (de) | 2013-12-02 | 2014-11-24 | Polyurethane mit reduzierter aldehydemission |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| BR112016012327A2 BR112016012327A2 (https=) | 2017-08-08 |
| BR112016012327A8 BR112016012327A8 (pt) | 2020-05-19 |
| BR112016012327B1 true BR112016012327B1 (pt) | 2021-08-17 |
Family
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| Application Number | Title | Priority Date | Filing Date |
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| BR112016012327-1A BR112016012327B1 (pt) | 2013-12-02 | 2014-11-24 | Processo para a produção de poliuretanos, poliuretano e uso de poliuretanos |
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| Country | Link |
|---|---|
| US (1) | US10316160B2 (https=) |
| EP (1) | EP3077438B1 (https=) |
| JP (1) | JP6698526B2 (https=) |
| KR (1) | KR102308495B1 (https=) |
| CN (1) | CN105992782B (https=) |
| BR (1) | BR112016012327B1 (https=) |
| MX (1) | MX382706B (https=) |
| WO (1) | WO2015082242A1 (https=) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3303430B1 (de) | 2015-05-28 | 2019-04-03 | Basf Se | Polyurethane mit reduzierter aldehydemission |
| US10683385B2 (en) | 2015-06-16 | 2020-06-16 | Evonik Operations Gmbh | Aldehyde scavengers for polyurethane foams |
| US10696777B2 (en) | 2015-06-16 | 2020-06-30 | Evonik Operations Gmbh | Aldehyde scavengers mixtures for polyurethane foams |
| WO2018024559A1 (de) | 2016-08-01 | 2018-02-08 | Basf Se | Polymerdispersionen mit verringerter emission von acetaldehyd |
| EP3555162B1 (en) | 2016-12-15 | 2021-05-19 | Dow Global Technologies LLC | Polyurethane product with sulfur-containing polyol |
| WO2019119196A1 (en) * | 2017-12-18 | 2019-06-27 | Huntsman International Llc | A composition with reduced aldehyde emission |
| CN112638974B (zh) * | 2018-08-02 | 2023-08-01 | 陶氏环球技术有限责任公司 | 减少聚氨酯泡沫中醛排放的方法 |
| EP3830158A4 (en) * | 2018-08-02 | 2022-03-23 | Dow Global Technologies LLC | Methods for reducing aldehyde emissions in polyurethane foams |
| EP3696206A1 (de) * | 2019-02-12 | 2020-08-19 | Hilti Aktiengesellschaft | Schäumbare, dämmschichtbildende mehrkomponenten-zusammensetzung und deren verwendung |
| CN110964173B (zh) * | 2019-12-13 | 2022-07-12 | 万华化学（北京）有限公司 | 用于蜂窝复合材料的聚氨酯组合物及其制备方法、聚氨酯泡沫及其应用 |
| PT3971248T (pt) * | 2020-09-22 | 2024-02-05 | CHT Germany GmbH | Tinta de estamparia isenta de formaldeído para estampagem sobre tecidos |
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| DE111394C (https=) | ||||
| US3523093A (en) | 1961-11-28 | 1970-08-04 | Paul Stamberger | Method of producing polyurethanes by reacting polyisocyanate with a preformed polymer resulting from polymerization of ethylenically unsaturated monomers |
| GB1022434A (en) | 1961-11-28 | 1966-03-16 | Union Carbide Corp | Improvements in and relating to polymers |
| US3304273A (en) | 1963-02-06 | 1967-02-14 | Stamberger Paul | Method of preparing polyurethanes from liquid, stable, reactive, filmforming polymer/polyol mixtures formed by polymerizing an ethylenically unsaturated monomer in a polyol |
| DE1152536B (de) | 1962-03-30 | 1963-08-08 | Bayer Ag | Verfahren zur Herstellung Urethangruppen enthaltender Schaumstoffe |
| DE1152537B (de) | 1962-06-02 | 1963-08-08 | Bayer Ag | Verfahren zur Herstellung von homogenen, Urethangruppen aufweisenden Kunststoffen |
| DE2615804C2 (de) * | 1976-04-10 | 1986-04-24 | Continental Gummi-Werke Ag, 3000 Hannover | Verfahren zur Herstellung von Urethanschaumstoffen |
| AU551979B2 (en) | 1982-03-31 | 1986-05-15 | Shell Internationale Research Maatschappij B.V. | Epoxy polymerisation catalysts |
| DE3621040A1 (de) * | 1986-06-24 | 1988-01-07 | Bayer Ag | Verfahren zur herstellung und polysiloxan-ionomeren, polysiloxan-ionomere und ihre verwendung zur herstellung von zelligen polyurethanelastomeren |
| DE3835193A1 (de) | 1988-10-15 | 1990-04-19 | Basf Ag | Verfahren zur herstellung von formkoerpern mit einer verdichteten randzone und einem zelligen kern, vorzugsweise schuhsohlen |
| US5506275A (en) | 1995-05-15 | 1996-04-09 | Basf Corporation | 1,1,1,2-tetrafluoroethane as a blowing agent in integral skin polyurethane shoe soles |
| DE19618392A1 (de) | 1996-05-08 | 1997-11-13 | Basf Ag | Verfahren zur Herstellung von elastischen Polyurethan-Formkörpern mit kompakter Oberfläche und zelligem Kern |
| JP4147637B2 (ja) | 1998-09-21 | 2008-09-10 | 東ソー株式会社 | ポリウレタン製造用の触媒 |
| JP2000248033A (ja) * | 1998-12-29 | 2000-09-12 | Sanyo Chem Ind Ltd | ポリウレタンフォームの製造方法 |
| DE10116757A1 (de) | 2001-04-04 | 2002-10-10 | Basf Ag | Verwendung von offenzelligen, hydrophilen, aliphatischen Polymethan-Schaumstoffen in Hygieneartikeln |
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| CN101824131A (zh) * | 2010-04-15 | 2010-09-08 | 上海子元汽车零部件有限公司 | 环保型阻燃高回弹泡沫材料及其制备方法 |
-
2014
- 2014-11-24 JP JP2016536222A patent/JP6698526B2/ja active Active
- 2014-11-24 WO PCT/EP2014/075387 patent/WO2015082242A1/de not_active Ceased
- 2014-11-24 MX MX2016006934A patent/MX382706B/es unknown
- 2014-11-24 KR KR1020167017806A patent/KR102308495B1/ko active Active
- 2014-11-24 US US15/101,183 patent/US10316160B2/en active Active
- 2014-11-24 EP EP14802646.1A patent/EP3077438B1/de active Active
- 2014-11-24 BR BR112016012327-1A patent/BR112016012327B1/pt active IP Right Grant
- 2014-11-24 CN CN201480065729.5A patent/CN105992782B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| KR102308495B1 (ko) | 2021-10-06 |
| KR20160095044A (ko) | 2016-08-10 |
| BR112016012327A2 (https=) | 2017-08-08 |
| US10316160B2 (en) | 2019-06-11 |
| EP3077438A1 (de) | 2016-10-12 |
| JP2017501258A (ja) | 2017-01-12 |
| WO2015082242A1 (de) | 2015-06-11 |
| US20160304687A1 (en) | 2016-10-20 |
| CN105992782A (zh) | 2016-10-05 |
| JP6698526B2 (ja) | 2020-05-27 |
| BR112016012327A8 (pt) | 2020-05-19 |
| MX2016006934A (es) | 2016-09-27 |
| MX382706B (es) | 2025-03-13 |
| EP3077438B1 (de) | 2018-03-07 |
| CN105992782B (zh) | 2019-07-30 |
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