BR112015027356A2 - processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos - Google Patents

processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos

Info

Publication number
BR112015027356A2
BR112015027356A2 BR112015027356A BR112015027356A BR112015027356A2 BR 112015027356 A2 BR112015027356 A2 BR 112015027356A2 BR 112015027356 A BR112015027356 A BR 112015027356A BR 112015027356 A BR112015027356 A BR 112015027356A BR 112015027356 A2 BR112015027356 A2 BR 112015027356A2
Authority
BR
Brazil
Prior art keywords
bioleaching
copper
zinc
solvent extraction
extraction
Prior art date
Application number
BR112015027356A
Other languages
English (en)
Other versions
BR112015027356B1 (pt
Inventor
Lopez-Juarez Alfonso
Sanchez-Vasquez Belisario
David Buendia-Cachu Eric
Estrada-De Los Santos Francisco
Monter-Valenzuela Ulises
Original Assignee
Servicios Condumex Sa
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Servicios Condumex Sa filed Critical Servicios Condumex Sa
Publication of BR112015027356A2 publication Critical patent/BR112015027356A2/pt
Publication of BR112015027356B1 publication Critical patent/BR112015027356B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/18—Extraction of metal compounds from ores or concentrates by wet processes with the aid of microorganisms or enzymes, e.g. bacteria or algae
    • C—CHEMISTRY; METALLURGY
    • C21—METALLURGY OF IRON
    • C21B—MANUFACTURE OF IRON OR STEEL
    • C21B15/00—Other processes for the manufacture of iron from iron compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B15/00—Obtaining copper
    • C22B15/0063—Hydrometallurgy
    • C22B15/0065—Leaching or slurrying
    • C22B15/0067—Leaching or slurrying with acids or salts thereof
    • C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/20—Obtaining zinc otherwise than by distilling
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B19/00—Obtaining zinc or zinc oxide
    • C22B19/20—Obtaining zinc otherwise than by distilling
    • C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
    • C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
    • C22B3/12—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic alkaline solutions
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/22—Treatment or purification of solutions, e.g. obtained by leaching by physical processes, e.g. by filtration, by magnetic means, or by thermal decomposition
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
    • C—CHEMISTRY; METALLURGY
    • C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
    • C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
    • C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
    • C22B3/44—Treatment or purification of solutions, e.g. obtained by leaching by chemical processes
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
    • C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/10—Reduction of greenhouse gas [GHG] emissions
    • Y02P10/134—Reduction of greenhouse gas [GHG] emissions by avoiding CO2, e.g. using hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00—Technologies related to metal processing
    • Y02P10/20—Recycling

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Metallurgy (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Mechanical Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Microbiology (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacture And Refinement Of Metals (AREA)
  • Extraction Or Liquid Replacement (AREA)

Abstract

resumo “processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos” a invenção refere-se a um processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos, que compreende um processo de biolixiviação e redução de íons férrico e um processo de extração por solventes de cobre e zinco. o processo de biolixiviação e redução de íons férrico compreende uma etapa de condicionamento de uma polpa de concentrados; uma etapa de biolixiviação onde a polpa uma vez condicionada é submetida a um processo de biolixiviação empregando uma pluralidade de biorreatores do tipo de tanque agitado com um sistema para injeção e difusão de ar, o que permite manejar uma densidade de polpa maior que 15%; uma etapa de separação de sólidos de uma solução rica em íons metálicos proveniente da etapa de biolixiviação; e, uma etapa de redução de íons férrico, onde a polpa proveniente da etapa anterior é submetida uma etapa de transformação de íons férrico em íons ferroso. a etapa de extração por solventes compreende uma etapa de extração por solventes e eletrólise de cobre; uma etapa de controle de arsênio onde se controla o arsênio da solução já sem cobre; e uma etapa de extração por solventes e eletrólise de zinco, que emprega uma solução extratora de zinco a base de ácidos fosfínicos.
BR112015027356-4A 2013-04-29 2013-10-30 processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos BR112015027356B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
MXMX/A/2013/004855 2013-04-29
MX2013004855A MX2013004855A (es) 2013-04-29 2013-04-29 Procedimiento de biolixiviacion y extracción por disolventes con recuperación selectiva de cobre y zinc a partir de concentrados polimetalicos de sulfuros.
PCT/IB2013/002418 WO2014177903A1 (es) 2013-04-29 2013-10-30 Procedimiento de biolixiviacion y estracción por disolventes con recuperación selectiva de cobre y zinc a partir de concentrados polimetálicos de sulfuros

Publications (2)

Publication Number Publication Date
BR112015027356A2 true BR112015027356A2 (pt) 2017-09-12
BR112015027356B1 BR112015027356B1 (pt) 2019-09-10

Family

ID=51843214

Family Applications (1)

Application Number Title Priority Date Filing Date
BR112015027356-4A BR112015027356B1 (pt) 2013-04-29 2013-10-30 processo de biolixiviação e extração por solventes com recuperação seletiva de cobre e zinco a partir de concentrados polimetálicos de sulfetos

Country Status (9)

Country Link
US (1) US10280481B2 (pt)
AU (1) AU2013388340B2 (pt)
BR (1) BR112015027356B1 (pt)
CA (1) CA2910768C (pt)
CL (1) CL2015003189A1 (pt)
MX (1) MX2013004855A (pt)
PE (1) PE20151918A1 (pt)
WO (1) WO2014177903A1 (pt)
ZA (1) ZA201508360B (pt)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106830091B (zh) * 2016-12-21 2018-06-19 中南大学 一种从含砷溶液中沉淀得到高浸出稳定性臭葱石的方法
CN110527831A (zh) * 2019-09-20 2019-12-03 常州工学院 一种使用铜萃取剂回收铜的方法
CN110564963A (zh) * 2019-10-17 2019-12-13 中南大学 一种采用微生物从含锌铜精矿中选择性脱锌的方法
CN112458277B (zh) * 2020-11-25 2022-06-21 铜陵有色金属集团股份有限公司 一种从深海多金属硫化矿中回收有价金属的方法
CN113637856A (zh) * 2021-07-02 2021-11-12 深圳市中金岭南有色金属股份有限公司丹霞冶炼厂 一种从锌冶炼过程中分离富集砷的工艺
CN114959262A (zh) * 2022-05-27 2022-08-30 中国恩菲工程技术有限公司 铜锌混合矿联合提取金属铜、锌的方法
CN115612865A (zh) * 2022-12-15 2023-01-17 矿冶科技集团有限公司 从含铅烟灰中回收铟的方法

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
PE11095A1 (es) 1993-05-25 1995-05-08 Mim Holdings Ltd Proceso integrado de lixiviacion biologica/proceso de extraccion con solventes para la produccion de metal de cinc a partir de concentrados de cinc
AUPP655998A0 (en) 1998-10-16 1998-11-05 Bactech (Australia) Pty Limited Process for bioleaching of copper concentrates
SE514338C2 (sv) * 1999-06-01 2001-02-12 Boliden Mineral Ab Förfarande för rening av sur laklösning
SE514403C2 (sv) 1999-06-22 2001-02-19 Boliden Mineral Ab Förfarande samt användning av förfarande för utvinning av värdemetall ur laklösning
US7455715B2 (en) 2001-07-13 2008-11-25 Teck Cominco Metals Ltd. Heap bioleaching process for the extraction of zinc
MX2011011147A (es) 2011-10-21 2013-04-22 Servicios Condumex Sa Biorreactor para biolixiviacion cm un sistema para inyeccion y difusion de aire.

Also Published As

Publication number Publication date
CA2910768C (en) 2021-06-29
MX2013004855A (es) 2014-10-29
AU2013388340B2 (en) 2018-08-23
CA2910768A1 (en) 2014-11-06
US10280481B2 (en) 2019-05-07
WO2014177903A1 (es) 2014-11-06
ZA201508360B (en) 2017-01-25
CL2015003189A1 (es) 2016-07-08
AU2013388340A1 (en) 2015-12-03
US20160115564A1 (en) 2016-04-28
BR112015027356B1 (pt) 2019-09-10
PE20151918A1 (es) 2015-12-28

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Legal Events

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B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B06T Formal requirements before examination [chapter 6.20 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

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B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

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B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2642 DE 24-08-2021 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.